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By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961

By P. R. Jones

"The paper describes the CDN$400 million expansion at Hudson Bay Mining and Smelting Co., Limited’s operations. The company has continuously produced copper and zinc at the Flin Flon metallurgical plant since 1930. The paper details the company’s operational turnaround since 1995 and “The 777 Project” which includes two new mines, expansion and modification of the concentrators, expansion of the zinc pressure leach plant, a new zinc electrolytic cellhouse and modifications to the copper smelter gas handling system to reduce ground level gas emissions. IntroductionHudson Bay Mining and Smelting Co., Limited (HBMS) was incorporated in 1927 to mine and process the world-class Flin Flon copper and zinc orebody. Ore concentration and metallurgical facilities were constructed in Flin Flon. The metallurgical complex capability is currently 89 000 tonnes of copper metal and 98 000 tonnes of zinc metal from both HBMS and purchased concentrates.Flin Flon, with a population of 7000, is in Manitoba and partly in the province of Saskatchewan. The location is isolated with Winnipeg 800 km to the south and Saskatoon 500 km southwest.Today, three underground mines feed the Flin Flon concentrator, one feeds the Ruttan concentrator at Leaf Rapids, 200 km to the north of Flin Flon, and Chisel North mine feeds the Snow Lake concentrator (Fig. 1).The Flin Flon volcanic massive sulphide proximal and distal orebodies are within the Flin Flon greenstone belt which stretches from the west of Flin Flon to the east of Snow Lake, a distance of 250 km. The belt is approximately 100 km wide before disappearing below the paleozoic cover to the south."

Jan 1, 2001

By J. H. Archibald

"In mines employing cut-and-fill stoping (sand fill), ore passes are built as mining progresses upward. These ore pass raises are generally made from timber and form a vertical ""chimney"", like a very tall log cabin. Traditionally the chimney, or raise, is square in shape and is constructed from square timbers with stepped ends as shown in Figure I. The timbered raise is thus surrounded by sandfill on its outside, leaving the centre open for passing ore down through it. Each layer consists of four timbers and rests flush on the layer below. The corners are frequently pinned or spiked.Under certain conditions in sandfilled stopes large horizontal loads may be transmined to the raise cribbing timbers, or the ""chimney's"" walls. In deep mines, where rock bursts are a problem, it can be shown that one of the conditions for rockbursts to occur is that the burst zone be stiffer and weaker than the surrounding rock(l). This allows a strain energy build-Up in the rock surrounding the burst zone, and the rate of release of this strain energy is known to be related directly to the over-all strength and stiffness of the rock in the burst zone. In stopes that are sandfilled, attempts are, therefore, usually made to increase the strength of the sandfill by the addition of large-sized waste rock and Portland cement. These measures usually achieve the desired strength of the sandfill and, consequently, the severity and frequency of rockbursts can be reduced.Problems may arise when the now chunky sandfill transmits high loads to the raise cribbing along with relatively large move- merits. This leads to heavily stressed and strained cribbing timbers the Coeur d'Alene district in Idaho, raise cribbing failures are common. A typical mode of cribbing failure is shown in Figure 2. One learns in statics that a structure shaped like the crib in Figure I is inherently unstable , at least from a structural standpoint. The crib has pivoted, in Figure 2, into a rhombi c shape and supports very little load. Soon the four-foot square raise cribbing made from 5 in. by 5 in. timbers will no longer pass ore."

Jan 1, 1991

By Philippe Caudal

This paper presents a case study in which a slope failure was observed on the west wall of the LAB Chrysotile mine in the vicinity of the main ramp in January 2010. Airborne LiDAR results were used to evaluate slope geometry before and after the failure occurred. Back analysis of the failure was performed to assess rock mass properties at the slope scale using various numerical techniques: limit equilibrium, finite elements and fracture networks. The various approaches correlated well with field observations.

Aug 1, 2013

By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By Pamela Paradis-Sokoloski, Deni Thibodeau, J. Denis, Samantha J. Espley, P. O’Donnell

"During the previous decade, the role of spray-on liners within the mining industry was limited to providing a corrosion resistant coating to screen and bolts; however, increasingly, liners are being used as ground support products. Expanding use and testing of liners have demonstrated their ground support function, yet the definitive support mechanism is still under debate. The most promising theory is the retain/hold/reinforcement concept (Kaiser et al.,1992). This conceptual theory has been the basis for the recent underground trials at INCO where, specifically, shotcrete and MIROC Mineguard were tested in two trials to further define limitations and applications of each liner.In a cursory overview, shotcrete is becoming accepted as a support product, while Mineguard is only slowly gaining acceptance.This discrepancy is the result of the corresponding life-spans within the industry, whereby shotcrete has had wide-spread use for decades, yet Mineguard has only recently been introduced. Currently at INCO, shotcrete is primarily used: to provide support in poor ground conditions, to add stability when developing through backfill, and to provide damage control in seismically active mines. It is also used to protect production headings and secondary-blasting chambers from fly-rock damage during blasting. Despite an obvious support function of the liner, shotcrete has always been used in addition to bolts and screen. Comparatively, Mineguard is still in the testing stage, where the greatest potential is increased productivity for applications in multi-tasking development headings. In this scenario, Mineguard provides instant support to replace screen, and bolts temporarily. When the heading has advanced, the drill and support crews work in tandem, drilling off the next round and installing bolts for long-term radial support, respectively. Other potential applications of Mineguard are within production headings to replace screen in the back, and screen and bolts in walls. The potential for both liners to replace conventional support is clearly war-ranted, such that defining the support role was the primary goal of the two underground trials."

Jan 1, 1996

By N. Campbell

"The fault under consideration follows a northerly trend past the west; side of the original settlement of Yell ow knife; which is situated 600 miles; north of Edmonton and 400 miles from the Northern Alberta Railway; terminus at Waterways; Alberta. The mining properties chiefly concerned; include the southern part of the Giant claims; on the east side of the fault; and the Con-Rycon-Demelt claims; on the west side 3 1/2 miles to the south.; Geological data were also obtained from the eastern part of the A.Y.E.; property; which lies south of the Giant claims; and from the Negus; Meg; Yellorex; and Kam properties; which are south and southeast of the ConRycon-; Demelt claims (see Frontispiece; also Fig. 5).Recognition of the major faults in the Yellowknife Bay area, including the West Bay fault, which appears to be the greatest, resulted from the work of A. W. Jolliffe (formerly of the Geological Survey of Canada) in 1935 and subsequent years. It has been stated with little exaggeration that these faults rank with the largest known steeply dipping dislocations of the earth's crust.In the winter of 1939, a mineralized shear zone named the 'Creek vein' was found on the Giant property. It was noted that the space relationship between this shear zone and a body of quartz-feldspar porphyry is roughly the same as that between the Con C-4 shear zone and a body of acid flows lying north of the Con property. Coupling this relationship with the assumption that the movement along the fault is dominantly horizontal, it was postulated that the Giant shear zone represented the faulted extension of the Con C-4 shear zone.As geological information became more extensive, certain weaknesses in this concept became apparent, and when spectacular orebodies were discovered on the Giant property in 1944 the question of possible faulted extensions became an important consideration. Consequently, in the spring of 1944, an extended investigation was undertaken, the results of which are embodied in this paper."

Jan 1, 1954

By Dwayne D. Tannant

The Adra tunnel near Naramata BC experienced a fire in 2010 that burned timber sets within the tunnel and caused severe spalling of rock from the roof and tunnel walls. The nature of the damage is documented and efforts completed to rehabilitate and open a portion of this tunnel to the public are described. The use of shortcrete and rock bolts is a technically and economically superior support system to timber sets as well as being far more fire resistant.

Jun 1, 2012

By T. Grammatikopoulos, SGS Canada Inc.

"The Nechalacho rare metal deposit, located in the Northwest Territories, Canada, is currently being taken through Feasibility Study by Avalon Rare Metals Inc. QEMSCAN analysis and supplementary electron microprobe analysis were utilized to identify and quantify the mineralogy of the deposit, and determine REE distribution among the minerals. QEMSCAN mineralogy was performed to provide textural information on the mineralization, determine the variability of the ore and identify REE domains, and the liberation and association of the REE minerals. The sample matrix consists predominantly of silicate minerals. The REE minerals include allanite, monazite, synchysite, columbite, fergusonite, and bastnaesite. Zircon is present in considerable amounts and is a REE carrier. Fergusonite and zircon account for most of the HREE, and monazite, allanite, synchysite and bastnaesite the LREE. QEMSCAN mineralogical data is extremely valuable in assessing the mineralogy of the ore. The data are implemented to define the mineralogy of the ore body, support metallurgical test work, and predict recoveries and grades.INTRODUCTIONThe term rare earth elements (REE) is used to describe the 15 lanthanide elements or metals and, more recently, the metals yttrium and scandium, which display similar physical and chemical properties.Economic and potentially economic REE deposits form two main groups, a more commonly occurring “light rare earth element” (LREE) group containing lanthanum, cerium, praseodymium, neodymium, and samarium and a less commonly occurring “heavy rare earth element” (HREE) group which, in addition to the LREE, contains elevated concentrations of the more valuable REE, europium, gadolinium, terbium, dysprosium, holmium, yttrium, erbium, thulium, ytterbium, lutetium and scandium. The first group is hosted primarily by carbonatites and the second by highly alkaline (Na + K > Al) silicate igneous rocks. The LREE are produced mainly from bastnaesite, monazite, etc., while HREE are produced almost exclusively from low-grade secondary ion adsorption clay deposits in which the REE are adsorbed onto the surfaces of kaolinite and halloysite, clay minerals produced by the weathering of granite and sediments. HREE are also found in fegusonite, zircon, xenotime, etc but are not produced presently from these minerals. China is responsible for 97% of the World’s production of the REE, mainly from the giant Bayan Obo, carbonatite-related deposit and from the clay deposits mentioned above.Quantitative automated mineralogy is increasingly being applied to ore deposits. It helps users to understand and improve mineralogical parameters for geological and metallurgical purposes. Data include textural characterization, to quantification and distribution of ore and gangue minerals, liberation and association of the REE minerals. The data can be used to define mineralogical domains and predict the metallurgical response of the ore (Gunning, de Souza, & Grammatikopoulos, 2009)."

Jan 1, 2012

By R. A. Campbell

The electric smelting of five lowgrade Canadian manganese ores has been investigated at the Mines Branch, Department of Mines and Technical Surveys, Ottawa. Ferromanganese, silkomanganese, and spiegeleisen were produced 1by special smelting processes from these ores since the latter were too low grade to be treated by conventional smelting methods. In one case the results were considered to be sufficiently promising to justify the construction of a pilot plant, by the Company concerned, for the further development of the process.

Jan 1, 1956

By G. Wren

As base metal sulphide resources become increasingly challenging to process, producers seek alternative options to treat concentrates. This study considers the mineral, elemental, and leaching character of a West Australian nickel sulphide deposit (Cosmos Nickel Project). After a brief review of the published work bench top leach tests were conducted to examine the factors which impact the kinetics of nickel sulphide leaching such as particle size, temperature, acid strength and type, concentration of copper sulphate and sodium chloride, and oxygen partial pressure. The effect of sodium chloride was considered due to the common occurrence of hyper saline water at West Australian nickel sulphide mine sites. Ultrafine grinding to an 80% passing size of 10 µm resulted in high nickel leaching efficiency. Moreover, higher concentrations of acid, copper(II) and sodium chloride also gave higher nickel and cobalt leaching efficiencies but arsenic precipitated as FeAsO4. Under the most suitable conditions the extractions of nickel, cobalt and arsenic at 90oC after 6 hours were >95%, 90% and <5%, respectively. The comparison with results from high pressure operations indicates the possibility of using a hydrometallurgical flowsheet based on fine grinding and atmospheric pressure leaching and warrants further investigations.

Jan 1, 2014

By G. B. Harris, C. W. White

Cyanide has been used for the recovery of gold since the mid 1800s, but several jurisdictions have already banned its use, and environmental pressures are increasing to finding an alternative. Gold also forms chloride complexes similar to those of cyanide, but the use of chloride has never achieved widespread acceptance. This paper describes a chloride-based flowsheet, wherein the key unit process is the recovery and recycle of chloride ion. It is shown that the chloride-based flowsheet is competitive economically with the conventional cyanide-based flowsheets, and that it has a number of other advantages, particularly environmentally.

Jan 1, 2011

By Wm Petruk

"The tungsten-bismuth-molybdenum deposit in southwestern New Brunswick occurs in greisenized and silicified tuffite * and feldspar porphyry in and adjacent to volcanic necks. The ore minerals occur as veins and veinlets and as disseminated grains in gangue. These minerals can be grouped into three assemblages. Assemblage 1 consists of oxides and phosphates of W, Ti, Fe, Nb, Sn, Ta and rare-earth elements, with the main minerals being deposited in the sequence wolframite, rutile, cassiterite. Assemblage 2 consists of arsenopyrite, molybdenite and bismuth, and assemblage 3 of sulphides with minor cassiterite and arsenopyrite. Sphalerite is the main sulphide mineral, but it contains minute inclusions of copper-tin- and indium-bearing minerals. Textural relations suggest that most of the elements can be recovered from this ore by conventional mineral beneficiation and extraction methods, but a variety of techniques must be employed. It is expected that the wolframite and molybdenite can be recovered satisfactorily, but poor recoveries are expected for bismuth and cassiterite. A sphalerite concentrate can be readily obtained by flotation, but it would contain a wide variety of elements. It is suggested that leaching be used to recover the bismuth and the elements in the sphalerite concentrate."

Jan 1, 1973

By T. Gerritsen, T. Plikas, K. Ochoa, M. Loveless, R. MacRosty, J. Reichart, R. Pula

Sidewall accretion in a smelting furnace plays an important role in furnace integrity as it provides protection to the sidewall cooling elements and thereby extends the furnace campaign life. The extreme thermal and mechanical stresses in the furnace and changes in the slag chemistry can cause the sidewall accretion to melt or break away decreasing the lining protecting the cooling elements. Thin accretion is highly undesirable as it increases the risk of exposing the cooling elements to the molten bath and in the worst case may lead to a failure. Therefore, monitoring the sidewall accretion on an operating furnace is extremely important to manage furnace integrity and to support safe furnace operation. Operators often generate estimates for sidewall accretion and refractory thickness using either copper cooler temperatures or heat load into the cooling water circuits. Multivariate statistical models, on the other hand, have the capability to consider all the process measurements simultaneously to provide a more reliable estimate. This paper describes the application of multivariate statistical models for sidewall integrity monitoring on a Flash Converting Furnace (FCF) and also discusses the online implementation of these models as the Sidewall Accretion Monitoring System. INTRODUCTION Rio Tinto’s Kennecott Utah Copper (KUC) smelter located near Salt Lake city, Utah operates a Flash Smelting Furnace (FSF) and a Flash Converting Furnace (FCF) to produce high-grade matte and blister copper respectively. Since the commissioning of smelter in 1995, several improvements were made to these furnaces to increase their efficiency and operational safety. At present, Kennecott smelter is known to be among the lowest-emission and highest energy recovery copper smelters in the world. Since the smelter start-up, Kennecott has invested in several advanced furnace monitoring practices to evaluate the integrity of the furnaces and improve their campaign life. An example is their temperature monitoring system installed for the smelting and converting furnaces, which continuously monitors the furnace sidewall temperatures and notifies the operators during temperature excursions. During an investigation on the converting furnace, it was revealed that there were frequent temperature excursions in the settler sidewall area towards the reaction shaft end of the furnace that caused significant furnace downtime. The reason for the sidewall temperature excursions was not clearly known.

Jan 1, 2019

By W. D. Sinclair, R. J. Cathro, E. M. Jensen

"The Cash is one of the largest porphyry copper-molybdenum Deposits found in Yukon to date. It is 80 km northwest of Carmacks, within the unglaciated portion of the Dawson Range, and is associated with the Big Creek fault, an important tectonic feature. Part of the mineralized zone is blanketed by up to 70 m of alluvial drift . The remainder is covered by a relatively thin residual soil layer. The mineralized zone, however, was not detected by conventional stream-sediment sampling because pathfinder elements, such as Cu and Mo, have not been geochemically dispersed into the main drainage system. The deposit was discovered by a combination of soil analysis and inspection of rock fragments from small pits.Twenty widely spaced, shallow drill holes have outlined an areaover 2700 m long and 550 to over 1000m wide that grades more than 0.1% copper equivalent (% CuE = % Cu + (5 x % MoS2)). Two smaller zones grading over 0.4% copper equivalent occur within the larger area. The limits of the widest end of the deposit have not been delineated.The Cash deposit is fairly typical of high-level, calc-alkaline porphyry copper-molydenum occurrrences in the Canadian Cordillera {cf, CIM Special Volume 15) and is representative of most prospects in the Dawson Range. It is associated genetically with a subvolcanic complex of small, irregular stocks and dykes of feldspar porphyry and related breccias of Late Cretaceous age. Copper and molybdenum sulphides occur along fractures, in quartz veinlets and disseminated in feldspar porphyry and in older metasedimentary and intrusive rocks. Higher-grade zones of copper and molybdenum have associated potassic alteration. Phyllic alteration is, in part, superimposed on potassic alteration. Argillic alteration occurs locally.This paper describes the history of the discovery and the geochemical and geophysical characteristics, together .with the regional geology, and the nature and distribution of the host rocks, hypogene mineralization and hydrothermal alteration."

Jan 1, 1981

By W. G. Hatch

Introduction In November, 1927, a paper was presented at the Annual Meeting of the British Columbia Division by H. A. Pearse(l), in which he described the milling practice at Britannia and set forth the metallurgical results which were being obtained at that time. In the intervening four years, various changes and additions have been made in equipment and practice, which have resulted in marked improvements in efficiency and costs. These changes and their effects are discussed in the present paper. During the past few years two major changes have been made in plant equipment. The first of these was the. elimination of an intermediate crushing stage by discarding two gyratory crushers in favour of two Symons cone crushers. The latter installation-now effects in one stage a greater reduction than was formerly accomplished in two, that is, by the gyratories together with a set of rolls. The second important change in equipment took place when the original M.S. flotation machines were replaced by six Forrester pneumatic machines, so that now the flotation department consists entirely of machines of this type. A number of minor changes and some further additions to equipment have also been effective in raising plant capacity and concentrate grade, while making noticeable reductions in tailing losses and costs of ore treatment.

Jan 1, 1932

By Sarah Bélair, Denis Beltrami, Valérie Weigel

"Mabounié is a polymetallic deposit in Gabon containing niobium (1.2%), tantalum (0.03%), rare earth elements (REE) (1.4%) and uranium (0.03%) that are mostly carried by Pyrochlore minerals. Classical route for niobium recovery is a pyrometallurgical process that consists in pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF.ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore. After solubilisation of the valuable elements, niobium / tantalum are precipitated as a concentrate (12% w/w Nb and 0.3% w/w Ta) while REE (2.7 g L-1) and uranium (90 mg L-1) remain in solution. Nearly 90% of REE are recovered from the solution by conventional REE double salt precipitation [NaREE(SO4)2.xH2O) method but some REE still remain in solution as this method does not allow to quantitatively recover medium (Sm, Eu, Gd, Tb, Dy) and heavy (Ho, Er, Tm, Yb, Lu, Y) rare earth elements. From the different process routes studied (solvent extraction, precipitation, ionic exchange etc.), an innovative method has been developed and patented to recover REE residual concentration in solution. This is based on an aluminum removal step followed by precipitation of REE as REE phosphate concentrate (REEPO4) by phosphate addition into solution. The phosphate concentrate is then purified according to the conventional monazite treatment, i.e. caustic conversion and REE solubilisation in acidic media."

Jan 1, 2016

By Derek Apela, Coralee Heske, Bunyamin Kahraman, Muhammad Adi

Effective blast fragmentation is essential in underground mining, as it directly influences downstream processing efficiency and operational expenses. This study investigates the application of Non-Newtonian Fluids (NNF) as stemming materials, presenting a novel method to enhance energy confinement, minimize environmental impact, and optimize blast performance. NNFs exhibit shear-thickening behaviour, enabling them to transition between fluid-like and solid-like states under stress, which renders them suitable for regulating explosive gas ejection during blasting. Field trials were performed by Vale Base Metals in Thompson, Manitoba, in their underground nickel mine to evaluate conventional slag stemming against NNF-based stemming in production-scale blasts. Emulsion explosives were employed, and blast performance was assessed through velocity of detonation (VOD) measurements, vibration monitoring, and AI-assisted fragmentation analysis using WipFrag. Preliminary results indicate that NNF stemming improves fragmentation, resulting in a reduction of D50 by as much as 38%, enhances energy confinement, and may decrease the incidence of hole plugging and re-drilling in subsequent blasts. This study presents an alternative to conventional stemming methods, highlighting potential advantages for enhanced safety, efficiency, and sustainability in blasting operations. Additional research and field trials are necessary to improve implementation protocols and facilitate the widespread adoption of this unique method in the mining sector.

May 4, 2025

By D. W. Davis, P. Landais, L. J. Robb

Abstract -Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Pb-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter ?13C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoid­ and sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994