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By L. Bos

The availability and reliability of large grinding mills and their Gearless Mill Drives (GMDs) are of paramount importance for the grinding process. Although GMDs have been in service for decades, and are known for their operational efficiency (reliability and robustness with reduced operating cost per ton), compared to conventional drives, in the last decade due to certain reasons some failures led to serious unscheduled shutdowns and significant insurance events. The majority of these notable "insured" failures have happened on GMDs installed on relatively large mills, as the financial impact of a failure is proportional to the through-put of the mill. Despite the occurrences of these events, as mining operations are driven by lower ore grades and the ability to continue reducing operating costs per ton, the trend for having larger mills is still very present and there is no reason why this trend should not continue. It is obvious that if not handled correctly, the possibility of large value GMD loss events, coupled with the continuing increase in mill size or required availability and reliability targets, could potentially lead to major conflicts as it becomes difficult for the insurance companies to judge the risk and hence may result in hesitation to insure these grinding circuits. This paper will not only describe the conflicting situation from both an insurer's perspective and from an equipment supplier's perspective, but also how these conflicting challenges can be successfully mastered. It has to be noted that not only the mining companies themselves, but also their insurance companies and the involved equipment suppliers have a common interest: to reach the highest availability and reliability in order to avoid or at least minimize unscheduled shut down times, and most importantly prevent unplanned events that result in extended production stoppages or reductions in through-put of GMD driven mills. From the very beginning onwards, the complete service concept together with emergency plans must be integrated on every level in the design of the grinding circuit. This approach must be implemented continuously and without compromises by all involved parties during all following stages, such as basic design, detail design, manufacturing, quality inspection and testing, packing, transportation, storage, installation, commissioning, operation and maintenance. The concept of formal risk analysis related to mill operations, maintenance and spare parts strategies must be an integral part of mining companies? decisions related to the selection for installation and continued use of large mills powered by GMDs. The service concept in place for operating mills shall also have a clear focus on very early detection of any abnormalities, so that the risk can be mitigated and unscheduled shutdown times avoided. However, if a major failure occurs, then procedures and tools shall already be available in order to ensure that production impact is minimized.

Jan 1, 2012

By Bin Tang, Suping Yao

In the last decade, the copper industry in China has developed rapidly and attracted the world’s attention. The production capacity of refined copper has grown remarkably from 4.578 million tons in 2010 up to 9.029 million tons in 2018, accounting for about 40% of the global refined copper production. And now, China has become the biggest refined copper producer in the world. This paper summarizes the application of modern copper metallurgical technologies such as Outotec flash smelting/converting technology, Cyclone smelting technology, TSL (ISA/Ausmelt) smelting/converting technology, Jinfeng side blown smelting and Baiyin side blown smelting technology, Chifeng side blown smelting and continuous top blown converting technology, SKS bottom blowing technology, Dongying two-step smelting technology, copper electrorefining with high current density, etc. in China’s copper industry, analyzes and compares the characteristics of those technologies and presents the great efforts of China’s copper smelters in adapting to the increasingly strict emission standards and improving economic benefits of copper smelters. INTRODUCTION China has been the biggest refined copper producer in the world for many years. China produced million tons of refined copper in 2018, accounting for 40% of the copper smelting production in the world, and of which, roughly, 70% of the copper concentrate was imported, mainly from Chile, Peru and Australia. ICSG (International Copper Study Group, 2017) shows clearly the position of top 20 countries of copper production and copper mine production (Figures 1 and 2). Blast Furnaces, Reverb Furnaces and Electric Furnaces dominated China Copper Smelting for quite long time till 1980s. The first modern copper smelting technology (flash copper smelting) was introduced into China in 1980s, then followed by Noranda, Ausmelt and ISA. Since then, China copper smelting technology stepped into modern time. Since 2000, old processes (Blast Furnace, Reverb Furnaces and Electric Furnaces) were phased out and replaced by modern smelting technologies. China Copper Production has been increasing dramatically (Figure 3).

Jan 1, 2019

By P. G. Smith, A. Axiuk

The objective of this paper is to present, from a practical perspective, a review of the most relevant maintenance procedures that are accepted or prescribed to be the most effective in optimising service life potential and to ensure continued safe use of steel wire ropes for shaft mining applications. The paper will address the most common operational issues encountered in the care and operation of shaft ropes for both conventional drum hoists and multi-rope friction winders. For each distinct maintenance procedure presented, a limited amount of theory is discussed to identify the underlying mechanisms at play that must be addressed and to emphasize the logical basis for the recommended course of action. It is recognised that each installation is unique and that the recommended maintenance procedures may not always be practical or cost effective from an operations standpoint under select circumstances, however the intent remains to promote industry best practices for the knowledge and benefit of the mine hoisting community, from experienced maintenance personnel to new entrants to the industry alike.

Jan 1, 2023

By Karla Kaboth, Brad Garraway

"The surface of many concentrate thickeners has traditionally looked like that of a flotation cell. Over the last three years Normandy Golden Grove Concentrator, in partnership with Outokumpu Technology have developed and implemented an innovative breakthrough deaeration technology to address this problem.When installed in the thickener feedline, the system successfully detached air bubbles adhering to the solid particles and removed air bubbles from the feed stream, subsequently presenting a fully deaerated feed to the thickener feedwell.Tests to date have shown an 80% reduction in overflow solids. As a result, costs associated with concentrate loss and measures to recover concentrate that settles in process tanks and ponds have been minimized.MOTIVATIONIt is recognised in mineral processing operations that the entrainment of finely divided air in thickener feeds can cause significant problems in the operation of a thickener. This is particularly the case with thickening of flotation concentrates, in which air bubbles are strongly attached to the mineral particles and are difficult to remove. Such particles attached to fine air bubbles rise to the thickener surface, and hence over the weir and into the thickener overflow. High solids carryover can lead to a direct loss of mineral product, and if the product settles in process water tanks and ponds, the recovery of this product by means of intermittent dredging operations is usually expensive and inconvenient.Many concentrate thickeners are fitted with devices which attempt to alleviate this problem. Froth rings or baffles, skimmers and froth sprays, all play a part in reducing the amount of solids carried over into the overflow. However, many froths are very stable and persist despite these measures. In the worst cases, a thick froth layer forms which builds up to a depth greater than the froth ring, and hence may overflow or pass beneath the ring . Any concentrate that finds its way past the froth ring can also cause blockage of the overflow weir and launder, and has the potential to upset clarification performance by cutting off sections of the overflow handling system. The formation of a froth layer on the thickener also makes it more difficult for the operator to monitor the clarification performance."

Jan 1, 2001

By P. J. Williams, A. R. Foster

Petrographic studies, assay records, and laser ablation-inductively coupled plasma-mass spectrometer (LA-ICP-MS) analyses of major sulfides suggest nearly all of the gold at the Ernest Henry Cu-Au deposit occurs in the form of native gold or electrum (95-65 wt.% Au); sylvanite and dissolved gold in cobaltite, chalcopyrite, and pyrite make only minor contributions. LA-ICP-MS analyses of the gold contents of chalcopyrite gave from 8 to 139 ppb (mean = 56 ppb), more than an order of magnitude lower than those experimentally determined in chalcopyrite in equilibrium with native gold at the estimated mineralization temperatures (350°-450°C). Gold content is more variable in pyrite (1-400 ppb, mean = 77 ppb) and highest in narrow growth zones of a subordinate type of complexly zoned pyrite wherein it is associated with elevated As, Ag, Sn, Sb, Te, and Bi. Deposition of gold-electrum was closely associated with, but preceded some of the chalcopyrite deposition, as indicated by microtextures and lower bulk Au:Cu ratios in late-stage chalcopyrite-rich veins. Gold grains have maximum dimensions from <1 to 50 micrometers, and are heterogeneously distributed with most occurring in microscale clusters. Fifty-five out of 76 grains recorded in polished sections are in contact with both chalcopyrite and pyrite, and many of the rest are in sites where such a relationship could exist in the third dimension. The dominant textural sites are intergrowths with chalcopyrite in microveinlets cutting pyrite, and on faces of pyrite grains in contact with chalcopyrite. Scanning electron microscopy, electron microprobe analysis, and proton induced X-ray emission studies show that pyrite associated with gold includes complexly zoned, weakly zoned, arsenian, and arsenic-poor types. The textures are compatible with the possibility that most gold was deposited electrochemically as native metal on pyrite surfaces. The textural distribution of gold has important metallurgical implications given that the ore processing circuits at Ernest Henry and most other sulfide copper mines are designed to exclude pyrite (and arsenic) from concentrates.

Jan 1, 2007

By Jan E. Nesset, James A. Finch, Wei Zhang

"Bubbles are unquestionably the heart of the flotation process. Their size and combined surface area are largely what drive the recovery process. This suggests that plant engineers should be aware of where their plants are operating with respect to what is achievable for these key parameters. The paper presents a model of how the key operating variables of frother type and concentration, gas rate, altitude (above sea level) and viscosity affect the Sauter mean bubble size (D32) and bubble surface area flux (Sb). The results are compared to a set of plant measurements that demonstrate the benchmarking capability of the approach. A case study is used to link hydrodynamic change to improved metallurgical performance.INTRODUCTION At the beginning of the 20th Century the early practitioners of flotation were aware of the importance of understanding bubble behaviour (Rickard, 1916) but measurement of individual bubble and gas behaviour in the industrial environment was not possible due to a lack of adequate sensors. This situation was not rectified until three quarters of a century later with the advent of industrially-robust sensors developed, notably, at the University of Queensland’s Julius Kruttschnitt Mineral Research Centre (JKMRC) (Schwarz & Alexander, 2006) and McGill University (Gomez & Finch, 2002). What emerged was not the chaotic environment perhaps expected, but defined relationships between gas rate, gas holdup, bubble size and the total surface area of bubbles. These relationships could be defined by mathematical expressions and predicted from an understanding of the key process variables (Gorain, Franzidis & Manlapig, 1997; 1999) (Hernandez-Aguilar, Gomez & Finch, 2002) (Gomez, Cortes-Lopez & Finch, 2003) (Nesset, Gomez & Finch, 2007). The early JKMRC work focused on a large pilot cell (3 m3) installed in plant environments, while the McGill work was initiated on flotation columns (Finch & Dobby, 1990) (Xu, Finch & Uribe-Sales, 1991) and later adapted to industrial mechanical cells (Cooper, Scott, Dahlke, Finch & Gomez, 2004) (Dahlke, Gomez & Finch, 2005) (Nesset, Gomez, Finch, Hernandez-Aguilar & Difeo, 2005). Yianatos of Santa Maria University (Chile), a graduate of the McGill research team, carried the work to industrial settings in South and Central America (Yianatos, Bergh, Condori & Aguilera, 2001). The methods of gas dispersion measurement are now well accepted and most major research centres and flotation cell manufacturers have adopted the technology (Pyecha, Sim, Lacouture, Hope & Stradling, 2006) (Yañez et al., 2009) (Collins, Schwarz & Alexander, 2009)."

Jan 1, 2012

By G. Roy, D. R. Lentz, A. O. Wills

"Abstract - Diamond-drill hole DDH-B357, located 1.5 km north of the Brunswick No. 6 Zn-Pb- Cu-Ag volcanic-sediment-hosted massive sulfide (VSHMS) deposit, intersects three exhalative horizons within variably altered felsic volcanic rocks of the Nepisiguit Falls and Flat Landing Brook formations. These three petrographically indistinguishable iron formation intervals (Fe2O3T = 21.4 wt.%) likely represent cogenetic hydrothermal sedimentary units because they display a common geochemical signature: Fe2O3T = 42.9 ± 10.5 wt.%, MnO = 5.4 ± 3.1 wt.%, elevated base metal values (Zn+Pb = 1999 ± 1091 ppm), strong enrichment in additional exhalative components (CaO = 5.3 ± 3.9 wt.%; P2O5 = 1.43 ± 1.00 wt.%), oxidized signature (Fe/Mn = 10 ± 6), as well as a common immobile element signature (Zr/TiO2 = 0.025 ± 0.007) representative of a pelagic source. The calc-alkaline to transitional host volcanic rocks can be discriminated by Zr/TiO2, and to a lesser extent by Th/Nb: Nepisiguit Falls Formation: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Flat Landing Brook Formation: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. A symmetrical repetition of the footwall-iron formation-hanging wall stratigraphic sequence is observed in DDH-B357, with distinct felsic volcanic rock domains separated by the three iron formations. This is best explained by parasitic F2 folds on the west flank of the south-plunging Brunswick antiform, similar to the fold closures known to host massive sulfide accumulations in the Brunswick No. 6 and No. 12 mines. Iron formation geochemistry and felsic volcanic rock chemostratigraphy from drill core sampling can provide an effective mineral exploration tool for the structurally complex rocks of the Bathurst Mining Camp. Sommaire - Le forage au diamant DDH-B357, situé à 1.5 km au nord du gisement de Sulfures Massifs à Encaissant Volcanique et Sédimentaire (SMEVS) de Zn-Pb-Cu-Ag Brunswick No. 6 recoupe trois horizons exhalatifs au sein des roches volcaniques felsiques diversement altérées des formations de Nepisiguit Falls et de Flat Landing Brook. Ces trois intervalles de formation de fer, impossibles à distinguer pétrographiquement les uns des autres, représentent vraisemblablement des unités sédimentaires hydrothermales cogénétiques sur la base de leur signature géochimique commune: Fe2O3T = 42.9 ± 10.5 % poids, MnO = 5.4 ± 3.1 % poids, des teneurs élevées en métaux usuels (Zn+Pb = 1999 ± 1091 ppm), un fort enrichissement en composantes exhalatives additionnelles (CaO = 5.3 ± 3.9 % poids; P2O5 = 1.43 ± 1.00 % poids), une signature oxydée (Fe/ Mn = 10 ± 6), ainsi qu’une signature d’éléments immobiles communs (Zr/TiO2 = 0.025 ± 0.007) indicative d’une source pélagique. Les roches volcaniques encaissantes calco-alcalines à transitionnelles peuvent êtres reconnues par leur rapport Zr/TiO2, et à un moindre degré par leur rapport Th/Nb: Formation de Nepisiguit Falls: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Formation de Flat Landing Brook: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. Une répétition symétrique de la séquence stratigraphique Mur-Formation de Fer-Toit a été observée dans le forage DDH-B357, avec des domaines distincts constitués de roches volcaniques felsiques séparés par les trois formations de fer. La meilleure explication est que le flanc ouest de l’anticlinal Brunswick à plongée sud est affecté par des plis parasites F2, similaires aux zones de charnière contenant les sulfures massifs des mines Brunswick No. 6 et No. 12. La géochimie des formations de fer et la chimiostratigraphie des roches volcaniques felsiques en forage peuvent fournir un outil d’exploration minérale efficace dans les roches structuralement complexes du Camp Minier de Bathurst."

Jan 1, 2006

By A. Warczok, T. A. Utigard

"Slags from smelting of copper concentrates contains from 1 to 15% of copper. Copper is present in the form of copper or copper matte inclusions of size from 2 to 1000 micro, and as dissolved cuprous oxide. Removal of the copper requires the slag reduction, primarily reduction of magnetite and co-reduction of cuprous oxide. Thus, the kinetics of the slag reduction play an important role in copper recovery. Instantaneously, at the contact of carbon and a slag the gaseous film is formed. The magnetite and cuprous oxide reduction is going through a gaseous film, separating the slag and carbon of a coke or electrodes. The thickness of a gaseous film grows to a critical value and gas bubbles, containing CO and CO2, are created and rise up in the slag. Results of measurements of kinetic of the slag reduction with graphite showed high value of activation energy, close to the value of activation energy of Boudouard reaction. Strong temperature dependence of the reaction rate points out the thermal instability of the reacting system. It was found that the slowest process in the reduction stages determines the loop of CO and CO2 transfer and magnetite diffusion to the slag/gas film boundary. Strongly endothermic Boudouard reaction seems to cause thermal instability on the reaction surface. So, heat transfer to the reaction surface is very important. Due to low thermal conductivity of a slag the convection dominates in the heat transfer. So, any slag stirring accelerates the rate of reduction and coalescence of metallic copper or copper matte inclusions."

Jan 1, 2015

By J. Basi, D. F. Rucker

"A review of historic operating practices of the heap leach pads at the Los Filos Mine, Mexico, revealed periods of restricted cyanide addition, reduced leach time, and insufficient irrigation flow. These issues all led to the buildup of partially leached recoverable gold inventory within the leach pads. Drawing down this inventory represented an opportunity to bring value forward. This paper outlines the strategic initiatives which were implemented as efforts to accelerate the inventory drawdown, including geophysical mapping and pressure injection.INTRODUCTION Los Filos is a heap-leach operation located in the Guerrero gold belt in southern Mexico. Operational and hydraulic challenges at the Los Filos Mine have led to a buildup of gold in inventory within the leach pads. Operationally, periods of restricted reagent addition, reduced leach time, and insufficient irrigation flow have compounded over the last eight years, and resulted in significant inventory growth. Hydraulically, the leach pad has issues with low permeability and solution channeling due to the fines and clay content of the ore. The leach pad is storing high-grade pregnant leach solution (PLS) as perched aquifers above areas that are compacted and difficult to drain. These operational and hydraulic challenges made it particularly difficult to spatially predict the precise locations of the inventory build-up. Fortunately, the challenges at Los Filos are not unique to the mine, and others have taken steps elsewhere to reduce metal inventory through a program that targets areas for inventory drawdown. For example, Ghorbani et al. (2016) noted that a method of injecting barren reagent solutions, applied directly to specific areas of a leach pad to reduce inventory, was presented by Wan and Brierley (1997) and Wan (1997). Seal (2004; 2007), Seal and Jung (2005), and Seal et al. (2012) have put the injection methodology into practice in Nevada and Colorado gold mines with a technology called Hydro-Jex®. The goal of Hydro-Jex has been to supply reagents at a high pressure over a short duration, followed by periodical low pressure rinse periods to remove leached metal and resupply fresh reagent to the ore."

Jan 1, 2017

By Roxanne Scott

Outline ? Overview of Community Investment in the Mining Sector ? Emerging Good Practice: ?Strategic Integrated Community Investment? ? Assessing Local Context: ? Institutional Assessment ? Partnership Assessment Approaches to Community Investment Isolation: No proactive engagement in community development Ad hoc philanthropy: small infrastructure, sponsorships, donations Strategic philanthropy: Community proposes options for development Company decides what to do and carries it out, e.g. building schools, health posts, roads Strategic integrated community investment: ? Aligned with government/community development goals and priorities ? Communities and government involved in decisions and execution ? Focused on training and capacity building ? Partnerships ? Continuation in absence of company support Measured returns on investment

May 1, 2010

By H. L. Snyder

This paper outlines the approach to the underground construction work involved in the Churchill Falls Power Project. It is the first in a series of papers which CIM Bulletin plans to publish as the different 11hases of this large-scale operation evolve.

Jan 1, 1968

By J. A. Finch, A. R. Laplante, R. Espinosa-Gomez

"The Niobec concentrator rejects up to /5% of the Nb as slimes (-10u.m). The recovery of Nb from these slimes by column flotation is being studied. An essential condition for selective flotation is slimes dispersion. A particle size analyzer, the Sedigraph 5000D, was used to monitor dispersion in plant waters with combinations of organic and inorganic dispersants and flotation reagents. Flotation reagents were particularly detrimental to dispersion with sodium silicate. The best dispersion conditions were selected for column flotation tests. These tests revealed that reagent combination had a pronounced effect on froth stability. Careful frother selection achieved good froth stability under conditions of good dispersion. Plant water increased the required dispersant concentration causing mineral depression.IntroductionSlimes (-10 u.m) rejected at Niobec contain up to 15070 of the over-all Nb content . Recovery of Nb from these slimes would significantly increase over-all recovery. A suggested recovery route involves two phases: (1) carbonate flotation (to remove most of the carbonates) depressing silicates and pyrochlore (as currently done at Niobec); and (2) selective (direct) pyrochlore flotation from the silicates. Phase 2 has been addressed and several routes to achieve selective flotation are available. Phase I was attempted with the selective reagent scheme used at Niobec but a considerable amount of pyrochlore floated with the carbonates due to poor slimes dispersion."

Jan 1, 1987

By S. Yadav, T. G. Murthy, C. Saldana

"An experimental study has been carried out in order to study the deformation of porous brittle materials under plane strain indentation. Gypsum, which is well known model system for understanding the behaviour of soft rocks, is used in this study. The effect of wedge angle is investigated in this research through this series of experiments, using wedges of 3 different apical angles. High-speed, high-resolution images are captured using a CMOS camera during the experiment. The images obtained are analyzed using a Particle Image Velocimetry (PIV) algorithm in order to obtain the evolving velocity, strain-rate and strain fields.INTRODUCTIONThe problem of indentation, which is usually referred to in the context of hardness testing is ubiquitous as a material characterization technique for a large class of solids. Mechanical properties of materials such as yield stress, flow stress, fracture toughness, elastic moduli etc. can be related to the hardness of a given solid. The indentation problem involves a given material or solid (whose properties are to be determined) indented by a relatively harder material (indenter) allowing the solid to undergo plastic deformation, which is then related to the yield stress of the material. The problem of indentation and its variants see many applications ranging from mining and petroleum industry, infrastructure industry, manufacturing, and biomedical sectors. Indentation has been extensively studied in metals, with accurate measurement of deformation parameters, stresses and comparison with analytical solutions. On the other hand, understanding of indentation in other class of solids such as cellular solids, porous solids, rocks, and soft solids is still nascent. In case of rocks, a comprehensive understanding of the indentation problem is very crucial because of the obvious applications in mining, petroleum and infrastructure sectors. The inherent porosity, the brittle nature of the rocks, adds to the complexity of indentation in these porous brittle solids. Various theoretical models with degrees of simplifying assumptions have been proposed to study the indentation in rocks. The most common model used in the study of indentation in rocks is a cavity expansion model, wherein a blunt indenter indenting into a rock is approximated with the expansion of cylindrical or spherical cavity in an elastic-plastic material. Complementary studies in understanding fracture initiation and propagation due to indentation has been largely based on the studies of traditional brittle materials such as glass."

Jan 1, 2015

By N. Coli

The exhausted Santa Barbara open pit mine (Tuscany, Italy), owned by the main electric power company in Italy (ENEL S.p.A,) extracted lignite as a fuel for the Santa Barbara thermoelectric power plant. The mining activity led to the excavation of a wide slope (with maximum height of 200 m and a planar extension of about 1300 m x 500 m) in the Shale Limestone Chaotic Complex (SLCC) (Figure 1). Since the beginning of its excavation the slope underwent rotational landslides and diffuse instability phenomena. From a geotechnical point of view the SLCC represents a typical bimrock (block-in-matrix rock) (Medley 1994, Medley 2002, Medley 2007) characterized by a mixture of a highly sheared, scaly-fabric, clayey matrix and calcareous blocks ranging from a few millimetres to tens of metres in size. Since the geometrical properties of blocks (grain-size distribution, shape, orientation and volumetric proportion) have been proved to influence the mechanical behaviour of bimrocks (Lindquist & Goodman 1994, Goodman & Ahlgren 2000, Kim et al. 2004, Sonmez et al. 2006), the aim of the present study is to investigate the geometrical properties of calcareous blocks in order to properly characterize the mechanical behaviour of the SLCC bimrock and to further assess the stability of the slope. Block size-distribution and shape were investigated by means of advanced image analysis techniques of SLCC pictures taken in the field. Geostatistical semivariograms and variographic maps were also used in order to investigate the anisotropy of block spatial distribution. Finally, in-situ large sized sieving tests were carried out to investigate the volumetric block proportion within the clayey matrix.

May 1, 2009

Building off the enthusiasm generated by Credit Suisse First Boston on the potential benefits of an industry-wide effort to market gold jewellery, a group of gold producers, led by Randall Oliphant, CEO of Barrick Gold, decides to investigate the long -term impact of launching a significant marketing initiative to stimulate demand for gold jewellery. The group establishes an international Steering Committee representing producers of differing sizes, members and non-members of the World Gold Council. This Committee comprises representatives from AngloGold, Barrick, Gympie Gold, Kinross, Randgold, and Sons of Gwalia and is supported by the Australian Gold Council, the Gold and Silver Institute, and CSFB. The Steering Committee hires McKinsey to assist it by conducting an independent review of whether investment in a large-scale marketing initiative for gold jewellery would be effective in increasing demand for gold, and ultimately of significant economic benefit of the gold industry. Based on McKinsey?s review* and its own discussions with key stakeholders across the industry, the Steering Committee strongly believes the case for marketing is compelling and sufficiently proven to persuade the industry to undertake a major initiative over the next few years. The Steering Committee, supported by McKinsey, conducts briefings with a range of gold producers to share its findings and to understand producers? perspectives on an industry-funded marketing campaign. The Steering Committee is asking for your support to bring this industry-funded marketing campaign to life.

May 1, 2002

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By L. Nichols, H. Keele, K. Czajewski

"The oil sands industry in northern Alberta disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called consolidated tailings or composite tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long-term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long-term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities.Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are longterm stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface.The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process."

Jan 1, 2008

By R. S. Bowman, G. S. Austin, J. M. Barker, P. S. Freeman

The physical, chemical and mineralogic characteristics of zeolites allow commercially important applications. While adoption of zeolite technology is slow in the United States compared to other regions of the world, continued testing and research has shown a wide range of uses for these minerals. They are important catalysts in petroleum refining, molecular sieves able to separate gases, and chemically inert carriers of reactants. The zeolite clinoptilolite produced by St. Cloud Mining Company (clino) (SC) is used in animal hygiene and animal feed, especially concentrated animal feeding operations (CAFOs), horticulture, water treatment, floor dry, aquariums, air and other filters, and odour control. Clino can remove cations from solution, and surface-modified zeolite (SMZ) is a sorbent for the removal of anions and neutral organics from water. Specific clino applications are: control of chemical pollution in groundwater, removal of organic compounds from oil field waters, and elimination of pathogens from sewage effluent. Combining the sorption capabilities of SMZ with chemical or biological transformations can yield complete removal of toxic materials from contaminated water. Continued development and marketing of zeolite products will be a growth market far into the future. The CAFO market for zeolites is the most significant growth area in the United States over the next few years. SMZ, currently less than 1% of St. Cloud sales, will continue to gain market penetration for many years.

Jan 1, 2004

By Franciszek Letowski

"Recovery of precious metals associated with a sulphidic matrix has an important economic effect on complex sulphide ore treatment. Because a significant portion of the silver and gold associated with pyrite are rejected to tailings during the selective flotation of pyritic Zn-Pb-Cu ore, other ore processing routes have been investigated.Direct leaching of the ore with ferric sulphate solution followed by separation of different components of the solid suspension by flotation was applied. Such a process allows for: production of zinc sulphate solution; transformation of galena PbS to insoluble lead sulphate PbS04 and its accumulation in a non-floatable fraction together with precipitated geothite FeOOH and other insoluble gangue minerals; separation of sulphur and non-decomposed sulphides in the floatable fraction.Laboratory research carried out on the ore samples from an Alaskan pyritic deposit from the Delta region indicates that gold and silver are mostly concentrated in the floatable fraction.Total recovery of zinc from the ore attains 96.5% to 98.5% after ferric sulphate leaching. About 85% of copper was extracted from the ore during the ferric sulphate and subsequent ferric chloride leaching, and about 6% of the copper remained in the non-floatable fraction and mixed fraction during the leaching-flotation step. Extraction of lead from the nonfloatable fraction during leaching with calcium chloride solution attained 98% to 99%. Extraction of silver from the floatable fraction during leaching with ferric chloride solution reached 98%. Extraction of gold from the floatable fraction during cyanide or thiourea leaching reached 71% to 89%. The results of the laboratory research are presented."

Jan 1, 1987

By J E. Curfman

This paper deals with using track-type and rubber-tired machines in the ripping and handling of overburden and ores. The techniques and proper attachments pertaining to the ripping of materials are covered in some detail. Production and relative costs of ripping, as against other methods, are covered in cases pertaining to the mining industry. The use of the refraction seismograph in predetermining the rippability of materials, including a chart relat-ing velocity to rippability, is covered. This operates on the principle that sound waves travel through subsurface materials at different velocities, depending upon the degree of consolidation of the material. It is known that the same factors that affect consolidation also affect rippability. Proper equipping of the tractor to insure maximum efficiency is also covered in some detail. Introduction T HE idea of loosening consolidated materials prior to further handling and processing is probably as old as man. The purpose of ripping is to provide fragmentation of rock and loosening of consolidated materials.

Jan 1, 1965