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By D-J Min

Strategies and achievements in the Asian steel industry to construct industrial ecological chain are reviewed largely in the case of Japan, Korea and China. Emphasis is placed on the development of resource circulatory system for the minimisation of various wastes and emissions of green house gases (GHG), toxic gases and polluting particulates. The minimisation includes:Rationalisation of iron and steelmaking processes; Implementation of available relevant measures/technologies; Life cycle assessment in designing steel from semis to assembled products; Reduction, reuse and recycling of materials and energies; and Utilisation of core competence technologies to process domestic and industrial wastes. In view of global nature of the above wastes- and emission-issues, inter-industrial linkage and international cooperation across the borders in the Asian countries have become more important. Inter-industrial linkage definitely serves to cut back the wastes and emissions. Examples of such linkage and factors influencing the sustainability of the linkage are described with expectation for further development of the linkage. Importance of international cooperation cannot be overstressed under the circumstances where steel production in China exceeded 220 Mt and world production exceeded 945 Mt in 2003 and is still increasing. Practical measures are discussed to enhance the linkage and cooperation for effectively promoting the reduction, reuse and recycling, including implications for the nonferrous industry.

Jan 1, 2004

By T Raynlyn, R J. Holmes, J R. Manuel, A Poliakov, L Lu

The prediction of sintering performance of iron ore fines and the possibility of targeted optimisation of specific sinter properties are very important for both the iron ore industry and related research organisations. Physical pilot-scale sinter runs require large amounts of raw materials and are expensive, so it is critical to target large test work programs with many different sintering parameters effectively. To predict values for sintering performance parameters such as tumble index (TI), low temperature reduction disintegration index (RDI) and productivity, a comprehensive database of pilot-scale sintering experimental results has been established and empirical modeling conducted. Similarly to earlier work, physical, chemical and mineralogical characteristics of the iron ores have been considered. However, in contrast to the previous work where only one textural parameter was taken into account, namely the proportion of dense haematite ore texture, the current model includes the abundances of several different textures which were combined into different textural factors corresponding to different sinter properties. Coefficients for the variables within specific regression equations can provide a better understanding of the effect of the variables on the corresponding sintering performance. The modelling results have also been used for predicting the sintering performance of mixtures that were not part of the database used for establishing the models. Comparison of experimental and modeling results for the verification test data is also reported in this paper.

Jan 1, 2009

By M I. Pownceby, S Bhargava, F Charalambous, S McMaster, R Ram, J Tardio

"A key component of any geometallurgical investigation involves being able to predict element or mineral recoveries from simplified input data such as bulk chemistry and/or mineralogy. This relies on the metallurgist having access to accurate information regarding the chemistry of the ore and gangue minerals as well as the likely impact on processing/extraction caused by the impurities (present either as gangue or as substitutional impurities). In this study the chemical properties of two commercially important uranium minerals, brannerite (U4+Ti2O6), and uraninite (U4+O2), were characterised using X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). Significant levels of impurities were present in both samples with the uranium minerals deviating significantly from their ideal chemical formulae. Differences in chemistry were due to: cationic substitution decay of the uranium isotopes into radiogenic lead and other daughter products mixed uranium oxidation states post-depositional alteration.As well, the brannerite sample showed evidence of significant radiation-induced metamictisation. Leach tests to measure the ease of extraction of uranium from both samples were conducted over a wide range of conditions (temperature, acid concentration and oxidant concentration). For uraninite, the lower U dissolution rates observed in the natural sample compared to a synthetic UO2 sample were directly attributed to the presence of impurities. For brannerite, significant metamictisation of the natural sample led to enhanced U extraction rates compared to a heat treated fully crystalline sample. This study highlights the importance of detailed mineralogical characterisation studies in any uranium process mineralogy investigation as the compositional, textural and microstructural aspects of the main uranium phases present will likely play an important role in any process to extract uranium.CITATION:Ram, R, Charalambous, F, McMaster, S, Pownceby, M I, Tardio, J and Bhargava, S, 2013. Chemical and microstructural characterisation studies on naturally occurring uranium minerals - implications for processing, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 325-334 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

Australia is presently the world's principal producer of rutile and zircon, and also provides a major share of the world's ilmenite. Since 1980, Australia's share of the world's output of these minerals has fallen. Exhaustion of known resources, together with the changing composition of new deposits, is expected to result in Australia's share of the rutile and zircon output continuing to decline. Its role as a major supplier of upgraded ilmenite, that is synthetic rutile, is expected to increase. In 1994, the Bureau of Resource Sciences assessed Australia's demonstrated resources of mineral sands as follows: rutile 14.4 Mt, ilmenite 132.5 Mt, and zircon 21.0 Mt. These resources are located along the coast of Queensland and New South Wales, in the Murray Basin of New South Wales and Victoria, in the southwest corner of Western Australia, and in the Eneabba region, north of Perth. However, some 45 per cent of rutile and zircon resources along the coast of Queensland and New South Wales are not available for mining because of environmental concerns. World demonstrated resources are estimated at 40 Mt (contained TiO2) for rutile, 50 Mt for zircon and approximately 312 Mt (contained T1O2) for ilmenite. Outside of Australia, the most important resources of rutile, ilmenite and zircon are in South Africa (rutile, zircon , and ilmenite in the form of titania slag), Sierra Leone (rutile), India (ilmenite, zircon and rutile), and Canada (hard rock ilmenite). Significant resources of ilmenite occur in Madagascar and Mozambique.

Jan 1, 1996

A combination of the needs of business, employee desires and safety and health considerations is stimulating increasing attention to the time spent by people at work and the timing of that work. Particularly we are seeing: - innovative work schedules for 24-hour mining businesses; and - response from industry to accommodate the needs, even the desires, of employees in return for systems which are more productive and more capital efficient. There appears to be an evolutionary trend for business management to become more sophisticated and responsive to the need for achieving close to best cost work schedules to sustain continuous improvement. The underlying motivating forces driving this trend for improved techniques in organising attendance at, and time spent at work, is the seemingly inseparable combination of technological advance and ever-increasing accumulation of capital. The mining industry has not remained untouched by this thrust for ever-increasing need for best use of labour, to adopt advances in technology and to provide attractive opportunities for putting accumulated capital to work. An essential component of this on-going thrust is a substantial effort by the mining industry to improve the performance of labour by providing most-productive work schedules.

Jan 1, 1996

By Nilmani M, Malone J, Taylor RN, Floyd JM, Gray NB, Fountain CR

CSIRO staff and University of Melbourne staff and students collaborated in an intense programme of investigation on the CSIRO 50 kg Sirosmelt pilot plant.In two days of operation copper matte converting and zinc slag fuming trials were performed, whilst investigation of the process dynamics and process chemistry was carried out. This exercise is an example of the techniques available for process evaluation, which can rapidly advance the understanding of pyrometallurgical operations by use of a team approach covering a wide range of experiments.

Jan 1, 1985

By R Memary

The environmental and economic impacts of a significant dependence on fossil fuels are affecting the future of sectors such as of mining. These impacts are prompting the Australian Government to seek solutions for reducing its dependence on fossil fuels more generally, such developing clean energy and improving energy efficiency. However, limited research has been undertaken to assess the potential synergies between clean energy and mining in an uncertain global future. This paper analyses current energy use by mining in Australia and reviews the drivers and opportunities for energy efficiency and cleaner energy technologies to be coupled to mining under three future scenarios. Linkages between mining and clean energy are investigated for three global scenarios for mining and metals to 2030, developed by the World Economic Forum (WEF), namely Green Trade Alliance, Rebased Globalism and Resource Security. These scenarios are applied to assess how they could change the barriers, opportunities and trade-offs required for the development of a more sustainable energy sources by the minerals industry in Australia.

Nov 22, 2011

By H Mischo, G Barakos, J Gutzmer

The continuously growing demand for rare earth elements (REEs), in combination with the crisis of 2009 and the price spike of 2011, has initiated a treasure hunt for rare earth deposits all over the world in recent years. Since then, commodity prices have declined and are now quite stable, yet the world is still dependent on China’s dominance of the market and its export policies. Exploration is unremitting and numerous resources of potential interest have already been revealed in many countries; however, proceeding to mining operations is not that simple, especially when it comes to the exploitation of rare earth deposits. Evaluating the feasibility of a mining project is always a unique, sensitive and rather complex process that depends on multiple criteria.This paper focuses on clarifying the present and future global situation in the development of respective deposits and on identifying rare earth-specific criteria that influence the overall feasibility assessments of any potential (especially underground) mining projects. Environmental impacts, legislation issues and the presence of radioactive pollutants are some of the notable boundary conditions that govern rare earth mining operations and need to be taken into consideration. Furthermore, the balance problem between the supply and demand of the different REEs can determine decisively whether a deposit of specific REEs is economically exploitable. For this reason, evaluations are made regarding the future strategies to be enacted in order for the rest of the world to detach itself from this situation. The ultimate goal of these evaluations is for them to be incorporated in an overall assessment tool for rare earth underground mining procedures that will be implemented in real case studies to determine their sustainability.CITATION:Barakos, G, Mischo, H and Gutzmer, J, 2015. Status quo and future evaluations of global rare earth mining (with respect to special rare earth element-industry criteria), in Proceedings Third International Future Mining Conference, pp 21–30 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By K G. van den Boogaart, M Lehmann, U Mueller

Geometallurgical parameters are descriptions of the mineralogy and microstructure of the ore determining its mineralogical and microstructural characteristics. From a conditional geostatistical simulation of such properties, a processing model can compute recovery, equipment usage, processing costs, and thus the monetary value for mining and processing a block with certain processing parameters. The output can be used for optimising mining sequences or finding optimal processing parameters by solving the corresponding stochastic optimisation problem.The approach requires two properties of the simulation not provided by established geostatistical techniques:Many relevant geometallurgical parameters are from non-Euclidean statistical scales such as (mineral) compositions, (grain size) distribution, (grain) geometry, and (stratigraphic type) categorical, which might produce nonsensical values (for example, negative proportions, negative facies probablities, planar grains) when simulated with standard geostatistical techniques.Due to the nonlinearity of processing, the entire conditional distribution of the geometallurgical parameters is relevant, not only its mean and variance. The geostatistical simulation needs to reproduce the joint conditional distributions of all the geometallurgical parameters.The multipoint conditional geostatistical simulation technique discussed here allows for jointly simulating dependent spatial variables from various sample spaces. The technique combines an infill simulation, similar to the one used in multipoint geostatistics, with a new form of distributional regression to estimate conditional distributions of arbitrary scales from different information sources, including training images, training models and observed data. The distributional regression is based on a generalisation of logistic regression and is related to both Bayesian Maximum Entropy geostatistics and high order cumulants.The method ensures that simulated data reside in the set of possible values and honour the characteristics of the joint distribution to be reproduced. The computational effort is substantial, but affordable for a useful application with standard problems: from processing-aware block value prediction and block processing optimisation as shown in the test application to a mathematically completely defined simulated model situation with a complex processing model.CITATION:van den Boogaart, K G, Tolosana-Delgado, R, Lehmann, M and Mueller, U, 2014. On the joint multipoint simulation of discrete and continuous geometallurgical parameters, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 379–388 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By A K. B Opitz, M Becker, J L. Broadhurst

"One of the key drivers of geometallurgy is to define the ore characteristics and their variability to build a geometallurgical model. The inclusion of waste rock properties and their variability is just as important, given that the generation of acid rock drainage (ARD) poses one of the most significant environmental challenges facing the mining industry. Formed through the oxidation of sulfide minerals in the presence of oxygen and water, ARD generation is exacerbated through the regeneration of lixiviates by naturally occurring iron- and sulfur-oxidising micro-organisms. In order to manage the potential risk of ARD pollution, timely, accurate, reliable and robust characterisation and prediction of the ARD potential of waste material is critical from an early stage in the mining process.This study demonstrates the use of the biokinetic-accelerated weathering test developed at the University of Cape Town to characterise the ARD potentials of gold waste rock samples under microbial conditions. These tests are performed in conjunction with standard characterisation tests to provide an indication of the potential for ARD generation under both chemical and biological conditions. Results provided information regarding the relative rates of acid neutralisation and acid generation, with the contribution of specific minerals to the observed behaviour considered through use of a detailed mineralogical assessment. Overall, the addition of the biokinetic test to the current geometallurgical characterisation and prediction toolbox will allow for relatively rapid assessment of the bulk kinetics of ARD generation.CITATION:Opitz, A K B, Becker, M, Broadhurst, J L, Bradshaw, D J and Harrison, S T L, 2016. The Biokinetic Test as a Geometallurgical Indicator for Acid Rock Drainage Potentials, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 183–192 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By D K. Weatherley, A N. Mainza, I Govender, L M. Tavares, M S. Powell

It is understood that rocks do not instantaneously transport along a grinding mill and are consequently not perfectly mixed, but this is conveniently overlooked in mill modelling. A lack of understanding of the transport phenomenon and the difficulty of modelling realistic transport in a complex tumbling system, contribute to this. Visual observation of segregation in AG and SAG mills and measured lag time of mill response to changes in feed provide evidence of the influence of axial transport within mills. Incorporating this lag in dynamic models should underpin dynamic simulation of milling circuits for design and for model-based control. Limitations and errors in predicting the influence of increased power via mill length versus diameter, inability to predict pebble production, and a lack of the differential in residence time across rock sizes and competences, all contribute to inadequate design prediction that can be especially acute for large Autogenous mills. Examples of dramatically under – and overloaded pebble regrind circuits and the inability to predict pebble load in AG milling discouraging the application of this energy-efficient option, point to the need for predictive modelling of breakage by competence linked to transport through and out of mills. Incorporating progress in granular flow and mixing, coupled to computational advances enable models to be based on complex breakage and transport models at high spatial resolution. This allows mechanistic models to simulate thousands of times faster than real time, opening the door to more accurate mill design, including dynamics in process simulation and to live simulation for process control – all with advanced mechanistic models. The value of grasping this opportunity is not easily refuted.

Aug 24, 2022

By J J. Hanhiniemi, M S. Powell

A ‘Variable Blend and Rates’ model is developed for SAG mills which extends upon the JKSimMet® Variable Rates Model. Similarly, a ‘Variable Blend Residence Constrained Perfect Mixing’ Ball Mill model is also introduced, also extending upon the existing JKSimMet® model. These models are used in conjunction with JKSimMet® while employing external technical programs. The technical model is then used to inform an economic model described elsewhere in Hanhiniemi and Powell (2022), which calculate operating and unit costs based on operating conditions, design, and ore characterisation. The SAG and ball mill models include constraints beyond those in the JKSimMet® models. The SAG model constraints include Size Specific Energy (SSE) verification, charge weight limit, and assessment of the impact of media to ore composition in the charge using the SAG Charge SSE Model developed in this paper. The ball mill model includes residence time, volumetric capacity, and SSE verification constraints. These models are applied to Cortez Gold Mine in the processing of two very different ore types and their blends; ‘Horse Canyon’ which is softer in coarser sizes and competent is fine sizes, and ‘Wenban’ which is competent at coarser sizes but softer in fine sizes than Horse Canyon. Horse Canyon also has a finer run-of-mine size distribution then Wenban. The application of the model at this site included undertaking five surveys at varying blends. The behaviours of the blends and individual components is then studied in the SABC circuit. A nonlinearity is observed with throughputs increasing with blending. The newly developed modelling approach captures these responses. Controlled blending based on ore competence-by-size and size distribution was implemented by the site, which then realised significant improvements in throughput without any capital cost (Ntiamoah et al, 2020). The modelling developed in this paper is then compared to existing practice, and the new method was found to provide improved fidelity and utility. A three-dimensional surface is then developed using the model describing the SAG mill throughput capacity at varying conditions (speed-filling) versus varying blend. The change in throughput as a function of only the changing charge composition is presented. The result is nonlinear, and explanations are provided to describe this behaviour.

Aug 24, 2022

By Richards RG, Cross MS

The development of alluvial mining, processing systems and associated gravity separation technology over the last 30 years is largely linked to the mineral sands industry. Attention has been focussed on Australia in these areas of mineral resource development and technological Advancement.

Jan 1, 1986

By H Kundapen, B R. Bolton, H Davies

The Ok Tedi porphyry copper-gold mine is located in the Star Mountains of Western Province, Papua New Guinea. Open-cut mine commenced in 1984 and is due to cease around 2010. The mine produces a total of 88 Mt of waste annually including 58 Mt overburden and 30 Mt tailings, which are discharged directly in to the Ok Tedi River. Mine derived wastes are transported downstream and deposited within the river channel in a variety of bar forms. The prevailing hydrogeological conditions including, velocity, competency, capacity, gradient, grain size and specific gravity, control the deposition and segregation of these sediments. Periodic exposure of the reactive sulfides to oxygen during fluctuations in the river discharge may result in oxidation, localised acid generation and liberation of metals into solution. To evaluate the significance of this issue, Ok Tedi Mining Limited initiated an investigation of the sediments deposited in the upper Ok Tedi River as part of its overall ARD Management Program. The specific objectives were to: evaluate the acid-forming characteristics of identified high sulfide river deposited sediments; characterise geochemically the waters in contact with sulfide-bearing river deposited sediments; map and monitor exposure areas and oxidation depth of deposited potentially acid forming (PAF) sediments; determine the depositional processes controlling sulfide distribution; and assess lag period, oxidation and metal release rates for the sediments. This work included the analysis of sediment and water samples collected on a 50 + 50 metre grid at six gravel/sand bars. The sediment samples were analysed for total sulfur, ANC, NAG, total sulfur and total copper. Water samples were tested for general water quality parameters, sulfate and a suite of dissolved metals including; Al, Ca, Cd, Cu, Fe-sol, K, Mg, Mn, Na, S and Zn. This paper presents the results of these investigations with particular emphasis on the geochemistry of the river sediments and associated contact waters.

Jan 1, 2003

By J J. L du Plessis

Escalating energy and electricity costs have become one of the biggest expenditure drivers in mining operations. During the last eight years, energy costs have trebled when expressed as a percentage of total running cost in South African mines. Power consumption on mines is controlled by three main strategies, namely load clipping where energy use is reduced for parts of the day, load shifting where energy use is shifted to other parts of the day, and energy efficiency where energy use is reduced permanently.To reduce the operating costs of ventilating and cooling underground mines continuously, system optimisation studies must be completed. A part of this paper describes methods that can be used to reduce energy usage by optimising cooling and ventilation systems during planning and in existing operations using network simulation models that accurately reflect the current and planned ventilation conditions. These models are used to examine various options for improving the overall ventilation and cooling efficiency. Furthermore, an overview of refrigeration and cooling practices, and ventilation strategies is presented.Ventilation-on-demand and cooling-on-demand strategies have the potential to reduce both the capital and operating costs associated with mine ventilation and cooling systems. In addition, it has been proven that modern strategies and energy-efficient tactics are technically feasible.It is also important that the correct equipment selection is made. This must be based on the best technology with the highest energy efficiency. Where equipment replacement is being considered, energy efficiency must be one of the key decision drivers.In this paper a number of studies were presented and from the experience and the data presented it is clear that a large financial benefit is possible through optimising ventilation and cooling during the planning of mines or within an existing operating mine.CITATION:du Plessis, J J L, 2015. Strategy and tactics implemented to achieve energy-efficient ventilation and cooling of mines, in Proceedings The Australian Mine Ventilation Conference, pp 9–18 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By B J. Wilde

Evaluating the resources and reserves in a mineral deposit requires many interdependent subjective decisions. The decision of stationarity is arguably the most important. This decision includes: the choice of domains that subset the entire deposit, modelling the boundaries of each domain, and understanding and considering the nature of the contacts between domains. Reasonable choices are made in consideration of the geological context, the available data, the goals of the study and the available resources for the study. This paper reviews aspects of the decision of stationarity in modern resource assessment with a focus on quantifying uncertainty and using numerical/statistical tools to help the geomodeller. The use of volume/distance functions to quantify uncertainty in domain limits is particularly important and is presented in detail. The use of contact plots provides help with the continuity of grades across domain boundaries. Realisations are not assembled as a branching combinatorial of all possibilities, but as a set of realisations that provide a measure of uncertainty. This paper amounts to a definition of stationarity for modern resource assessment.

Sep 26, 2011

By D Bradshaw, J R. R de Villiers

The non-stoichiometric sulfide mineral pyrrhotite (Fe(1-x)S), common to many nickel and platinum group element (PGE) ore deposits, occurs in varying crystallographic forms with the different types exhibiting subtly different physical and chemical properties. These differing properties are likely to influence the flotation performance of pyrrhotite, which in the case of PGE operations is actively recovered, whereas in nickel operations pyrrhotite is depressed. In this study, examination of natural pyrrhotite samples from Southern African and Canadian nickel and PGE ore deposits revealed a variety of pyrrhotite compositions in terms of iron content (Fe7S8, Fe9S10, Fe11S12) and solid solution nickel concentration. Pyrrhotite composition was correlated with its mineral association depending on whether non-magnetic pyrrhotite occurred in conjunction with troilite, non-magnetic pyrrhotite occurred as single phase pyrrhotite, magnetic pyrrhotite occurred as single phase pyrrhotite or whether the two phases; magnetic and non-magnetic pyrrhotite co-exist. Subsequent microflotation tests of selected single phase pyrrhotite samples revealed that the non-magnetic pyrrhotite is slightly more floatable than magnetic pyrrhotite. Microflotation tests also showed that varying flotation responses occur between differing magnetic pyrrhotite samples. These differences in flotation performance are postulated to be a result of the effects of varying pyrrhotite crystallography, trace metal content and mineral association on pyrrhotite oxidation, formation of surface species and subsequent adsorption with xanthate collector.

Jan 1, 2008

By D J. Bradshaw, E M. Wightman, B Newcombe

Flash flotation plays an integral role in many of the gold and sulfide mineral concentrators around the world, and yet despite this widespread use, very little information on this unit process is available in the published literature. For operations to maximise the performance of their flash flotation circuits, understanding how these cells operate, the nature of the particles they target and how to predict whether a flash flotation cell should be used on a specific ore type is of vital importance. This paper provides a summary of the key findings of a large flash flotation research project based in the operating environment of a refractory gold concentrator. The influence of key flotation performance criteria including gas dispersion, residence time and particle segregation within the cell will be discussed and recommendations for process improvements will be made throughout. The nature of the particles within the flash cell will be examined, as will the impact on the type of particles that are passed to downstream processes when the flash flotation cell is taken off-line. The development of a laboratory method to determine whether an ore is suitable to undergo the flash flotation process is also presented for its potential to aid in flow sheet development and optimisation for new ores.CITATION:Newcombe, B, Bradshaw, D J and Wightman, E M, 2012. Into the belly of the flash à Insights into the mechanisms at work within a flash flotation cell, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 163-170 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By J Masliyah, Z Xu

The largest oil sand deposit in the world is located in Alberta, Canada, with a total proven reserve of 2.5 trillion barrels of oil. The water based extraction process is currently being used in commercial operations to recover bitumen by flotation from oil sand ores. A recognised challenge in bitumen extraction is the reduced bitumen recovery when processing ores containing high fines content or æweatheredÆ oil sand ores, collectively known as poor processing ores. Inspired by demonstrated success of using kerosene as collectors in coal flotation, an innovative idea of using oily bubbles (air bubbles coated with a thin layer of oil or solvent) was tested to improve bitumen flotation recovery from poor processing ores. In this study, dynamic contact angle of air bubbles or oily bubbles on bitumen and induction time of bitumen-oily bubble attachment in water were measured to justify the use of oily bubbles in bitumen recovery from poor processing ores. The type of oil or solvents, including kerosene, toluene and naphtha, used in generating oily bubbles showed a marginal effect on the contact angle values, similar to the values measured with air bubbles. However, the spreading of an air bubble was found to be much slower than that of oily bubbles on a bitumen surface. The induction time for oily bubble-bitumen attachment was found to be much shorter than that for corresponding air bubble-bitumen attachment in the process water from poor processing ores. The reduced induction time for kerosene-coated air bubble-bitumen attachment correlates well with the improved bitumen recovery from poor processing ores using kerosene-coated oily bubble flotation technology.

Jan 1, 2005

By L Dzinza, K C. Corin, M Tadie

The recycling of process water comes with increased electrolyte concentrations that affect water quality, which may in turn affect the flotation performance of valuable minerals (Hirajima et al, 2016). Electrolytes such as Ca2+, SO4 2- , Mg2+ and S2O3 2- have been surmised to have an impact on the action of flotation reagents such as collectors (Ikumapayi et al, 2012). Xanthate collectors are known to play a significant role in imparting hydrophobicity on mineral surfaces to enhance their flotation. The interaction between minerals and xanthates is well known to be electrochemical in nature. Such redox processes may be elucidated by electrochemical techniques. Since the mechanisms involving the interactions between electrolytes in process water with sulfide minerals and the subsequent adsorption kinetics of collectors are not well understood, this study therefore aims to provide fundamental knowledge to unpack the mechanisms involved when electrolytes interact with Platinum Group Minerals (PGMs) and how these interactions may affect xanthate adsorption. The interaction of sodium iso-butyl xanthate (SIBX) in the presence of electrolytes at increasing ionic strength was investigated by rest potential measurements, to explain the impact of electrolytes on the adsorption of SIBX on PGMs in the flotation process. Rest potential measurements for PdTe2 and PdS were conducted in an air saturated 0.05 M di-sodium tetraborate decahydrate solution, in the absence and presence of SIBX and electrolytes. It was found that the existence of sulfide and telluride on palladium affects the mechanisms in which electrolytes interact with Pd mineral surfaces. An increase in the ionic strength of Na2S2O3, CaCl2 and MgCl2, increased the interaction between the salts and PdS, thus decreasing the extent to which SIBX interacted with PdS. An increase in ionic strength for Na2S2O3 increased the interaction between Na2S2O3 and PdTe2 and therefore decreased the extent to which SIBX interacted with PdTe2. Other salts investigated in this study increased the rate of oxidation of PdTe2 with an increase in ionic strength thereby enhancing the interaction of SIBX and PdTe2. This study has shown that mineral type, electrolyte type and concentration all have an impact on the mechanisms that result in the adsorption of SIBX on PGMs.

Aug 24, 2022