Search Documents

By G. Springer

The identification of lost mineral values in mill tailings frequently requires the inspection of hundreds of thousands to millions of particles. The search of these particles can be made automatic by using an electron microprobe. A standard instrument (Cambridge Mark V) was modified by the addition of stepping motors to advance the specimen stage in a controlled manner. The X-ray Signal is monitored continuously by a computer interfaced to the instrument with an analog-to-digital converter. 400,000 particles of a tailings sample can be scanned in about 3 hours. Particles as small as 2 um and containing as little as 3% of a particular element can be detected.

Jan 1, 1982

By S. K. Varma, Miriam Regalado, Daniel Salas, Erica Corral, Erika Esquivel

"Age hardenable 2014 aluminum alloys and composites containing 0.10 and 0.15 volume fractions of alumina particles (VFAP) have been solutionized at 540 and 550°C for up to 20 hours. The solutionized samples, heat treated for 5 and 20 hours, have been subjected to room temperature rolling until cracking develops. The work hardening curves have been compared to determine the effect of solutionizing time on the rolling characteristics from both hardness and the microstructural evolution points of view. Solutionizing at two different temperatures results in differences in the extent to which the composites can be rolled until fracture. The microstructural characterization by TEM has been performed to understand the room temperature rolling behavior.IntroductionThe effect of solutionizing on the age hardening response of 6061 and 2014 aluminum alloys and composites reinforced with 0.10, 0.15 and 0.20 volume fractions of alumina particles (VFAP) have been reported in the literature [1-4]. A comparison of the monolith and composites indicates that particles promote the aging process through differences in the microstructures in solutionized condition. The first effect of solutionizing is to produce a grain growth process which follows a grain growth law (square of grain diameter as a function of solutionizing time). It appears that it is possible for vacancies to be emitted during grain growth period as they try to minimize the total grain boundary surface area by increasing their diameter. This may be common to both the monolith and the composites. However, the second effect must be exclusively considered for the composites. The particles generate dislocations during the solutionizing process due to the differences in the values of the coefficient of thermal expansion (CTE) between the particles and aluminum base metal. It has been determined [1] that the dislocation density increases with increase in solutionizing time in the composites of 6061 aluminum alloys reinforced with 0.10, 0.15 and 0.20 VFAP. The improved bonding between particles and matrix can give rise to additional generation of dislocations due to curvature effects [1] with the result that the dislocation density continues to increase with increase in solutionizing time even after the CTE effect is considered to have been stabilized."

Jan 1, 1998

By Jerome P. Downey

Technologies developed within the field of extractive metallurgy to recover, concentrate, and purify metals and industrial minerals from ores, have served as the foundation for all of the subsequent environmental remediation, materials recycling, and waste management technologies. This paper discusses the application of classical extractive engineering principles to the development of a thermal process for the recovery of mercury from solid wastes. Process development is presented as a series of logical stages, which begin with a thorough characterization of the site-specific waste, move on to bench and pilot scale testing of the process options, and end with a functional process flowsheet. This paper also presents thermodynamic data on many mercury species of interest to the minerals, power, and chemical industries. These data can be used to model the speciation and recovery of the mercury as a function of various process parameters.

Jan 1, 2003

By Carlos Schvezov, Eliana Agaliotis, Alicia E. Ares, Mario Rosenberger

"The interaction between a solidification front and a spherical particle was modeled and simulated in order to study the phenomenon of ""pushing"". Finite element methods were employed in axisymetric domains. The drag force is calculated from the calculated fluid flow field and the repulsion force is the Lifshitz-Van der Waal force. The thermal field is decoupled from the force field. The model is applied to a metallic matrix containing particles with similar, lower or higher thermal conductivities than the matrix, resulting in planar, convex and concave interface shapes, respectively.The results show that the critical velocities for pushing for concave and convex interfaces are about one order of magnitude larger and one order of magnitude lower than the critical velocity for flat interfaces, respectively. The simulated results were in very good agreement with reported experimental results.IntroductionThe solidification interface of materials containing spherical particles in some cases can push the particle ahead the interface. This phenomenon generally occurs during the solidification of different materials such as, metallic alloys containing native particles, metal matrix composites containing particles or fibers as reinforcements and crystallization of semiconductor, optical, optoelectronic or biological materials. In all cases the interaction strongly determines the distribution of particles and the resulting physical and physic-chemical properties of the resulting material. The phenomenon has been investigated for many years both experimentally and by mathematical modeling [1-21]. The process is complex due to the variety of phenomena involved during pushing. In all cases, the physical problem depends on the properties, nature, and morphology of the interacting media; the particle, melt and solid; and external fields such as gravity, thermal and electromagnetic fields."

Jan 1, 2012

By Michael F. Kitto

The production of sulphuric acid at base metals smelters is predominantly an involuntary activity and now comprises approximately 17% of all-forms sulphur supply in world terms. The majority of elemental sulphur is also produced involuntarily in response to environmental regulations regarding emissions from hydrocarbon processing plants. The paper examines the points of similarity and difference in the sulphur and smelter acid markets, and reviews their interactions. The reasons for the merchant acid market collapse of 1993 are analyzed, and the prospects of a recurrence are considered.

Jan 1, 1996

By C. M. Egert, S. Rajic

"We have developed a monolithic micro-spectrometer suitable for a variety of sensing applications including industrial process monitoring. The device consists of a solid structure with a volume less than 6 cubic centimeters. All optical components of the spectrometer including two aspheric mirrors, a diffraction grating, and entrance and exit surfaces are fabricated onto the surface of the structure. All light paths are internally contained within the structure. The result is a small, rugged spectroscopic sensor ideally suited for use as a process monitor. Due to its monolithic nature the device requires no post-fabrication alignment; nor can it be knocked out of alignment during use. Although many materials and thus wavelength regions were possible, the prototype device discussed here was produced in PMMA by precision diamond turning. However, lower cost manufacturing approaches involving injection molding are under development to produce an affordable sensor.Due to its rugged monolithic design, small footprint, and low cost the monolithic micro-spectrometer is ideally suited for distributed monitoring applications often required for industrial processes. It is expected that modified versions of this sensor designs will be required for specific applications so as to maximize the performance and resolution over the operating range. For example, the prototype device described here operates over a wavelength range of 500 nm to 1000 nm. The performance of this device as a real-time surface monitoring sensor will be discussed in detail. Our approach of using wavelength dependant scattering resulted in the reduction to practice of a miniature, monolithic, rugged, low-cost, micro-instrument in a sensor sized package. The process sensor applications community has been faced by the cost versus performance issue. Simple go/no-go sensors are typically inexpensive but they provide very limited and sometimes dubious data. Scaled down traditional instruments offer very good measurand information but are typically cost prohibitive, fragile, and still relatively large. This work will bridge the gap between these two extreme sensing alternatives."

Jan 1, 1997

By Kenneth L. Reid

The Mineral Resources Research Center at the University of Minnesota has recently installed a QEM*SEM system (Quantitative E.valuation of Materials using Scanning Electron Microscopy) to aid in detailed mineralogical evaluation of potential mineral resource developments in Minnesota and to provide services to the North American mineral industry. A primary application for the unit is to serve the Minnesota taconite industry by providing mineralogical analysis of ores and concentrator products. Minnesota taconite ores contain fine-grained magnetite in a quartz matrix. The ores undergo several size-reduction/magnetic-separation steps to produce a final concentrate with approximately 75% passing 325 mesh and containing about 5% gangue. The paper describes a typical taconite concentrator flowsheet and reports some preliminary results of the applications of QEM*SEM particle image maps and cumulative yield liberation data to samples from selected points in the concentrator circuit.

Jan 1, 1988

By Hans von Michaelis

There has been a renaissance in gold and silver extraction and recovery that has taken place over the last fifteen years, since the price of gold was freed from the $3510~ level. Despite major advances in such areas as carbon adsorption processes for gold recovery, refractory gold ore treatment, crushing and grinding, process control, etc., there still remain several gold and silver mineral processing frontiers. Frontiers related to environmental management present significant challenges especially in the USA. More than ever it is appropriate to optimize total economics by adopting a "systems approach" that integrates mining, mineral processing and environmental management.

Jan 1, 1993

By S. Ellor

The development of models of INCO's Copper Cliff operations using a computer spreadsheet program is discussed. Empirically developed metallurgical relationships were utilised. The paper concentrates on models of the pyrometallurgical processes but discusses applications such as optimisation of operating parameters, evaluation of feed changes and custom or recycle materials processing. The models were initially developed using a spreadsheet program on a personal computer. The requirements of plant engineers and process operators for significant increases in operating speed led to the transformation of some of the modules. The paper is presented in two parts: 1. The development of the modules using a spreadsheet. 2. The transformation of a module into a high speed tool for process control. The application of the technique to other pyrometallurgical processes is discussed.

Jan 1, 1992

By Neil E. Izatt

The use of Molecular Recognition Technology (MRT), a selective separations technology using specifically designed ligands, has been established as an effective process for removal of metal ions found in many hydrometallurgical, chemical, and wastewater streams. The MRT process has been proven to be highly efficient and effective for indium extraction and recovery from zinc acid leach, electrolyte, chemical process and waste streams. A high percentage of the indium is recovered in a solid product format. MRT has also proven effective for germanium extraction and recovery from similar feed streams. This paper provides the indium and germanium metal recovery flow sheets and analytical results of the metal load and recovery steps.

Jan 1, 2006

By C. J. Beyke

Slags and/or mattes from three secondary lead producers were studied as part of an effort to develop treatment methods for these lead-bearing residues. Each company used a somewhat different production process. Company A used a reverberatory furnace followed by a blast furnace. Company B used only a blast furnace. Company C used both a reverberatory and a blast furnace, and the scrap material was desulfurized with sodium carbonate prior to smelting. The slag matrix produced from sulfur-bearing scrap consisted mainly of iron-calcium silicates; the slag from desulfurized material was similar, but also contained sodium. In all the slags most lead was present in metallic form, often alloyed with tin, antimony, arsenic, and/or iron. Slag from Company B contained the most alloying elements, often as discrete subparticles within the lead droplets. Mattes were produced at Companies A and B; predominant phases were pyrrhotite and magnetite, while lead was present in metallic form and as galena.

Jan 1, 1995

By A. L. Davies

The MTDATA computer software package consists of a rigorous implementation of an algorithm for calculating chemical phase equilibria by the technique of Gibbs free energy minimization and a database of the thermochemical properties of common materials, such as slags, mattes, metals, gases and aqueous solutions. We have used MTDATA to contribute to our understanding of the chemical reactions occurring in several specific unit operations of the Kennecott Utah Copper Garfield Smelter. The following two examples illustrate the range of environments to which the method is applicable. Calculation of the liquidus phase relations of the FSF fayalite and FCF calcium ferrite slags helped in the early diagnosis of several operating problems. Calculation of the deportment of fluorine between the FSF offgas and the FSG scrubber liquor helped in the identification of operating conditions under which significant hydrogen fluoride concentrations could be introduced to the contact section of the acid plant. Without the painstaking assessment of solution phase properties undertaken over many years, these calculations would not be possible.

Jan 1, 1999

By Kunihiko Takeda, Kimio Imaizumi, Tsuyoshi Arai

"The study on the preparation of mono-dispersed liquid droplet was performed using ultrasonic as one of the steps of producing the perfectly mono-dispersed particle. The ultrasonic system was a 33.6kHz ultrasonic generator, an amplifier, an electric distortion element, and a bolted Langevin type horn installed in .a cell. For the first time, a liquid pillar under a nozzle of the cell ·was stably formed. Then, dense and coarse parts were alternatively constructed by oscillating the wavelength of the ultrasonic.· The diameter of those liquid droplets were found to be· perfectly uniform, therefore, it was measured by ""multiplex photography"" using a synchronized stroboscope with the ultrasonic.- From the results, more than 30,000 of perfectly uniform liquid droplets in 1 second were observed by this method.IntroductionRecently, research on the control of physical form is done in various fields of industry. Some examples are the processing technology of the minute compound material of micro-machines and integrated circuits, and the form control of molecule size like catalysts. There is a need for such material to take on various forms in correspondence to its use. ""Form control"" as used in this study will indicate ""research on physical chemistry factors which determine the size of the material"" and will refer to the contour uniformity of comparatively little particles. A well-known method of preparing particles is to spout a mist of liquid and slurry from a nozzle l) 2). Particles for metals, catalysts and food have been prepared by this method. In this case, although an approximate particle diameter can be decided by controlling the nozzle diameter and the violent outflow velocity, it is not easy to completely control ·the contour and to prepare a particle with uniform diameter. ·However, the preparation of perfectly uniform particles is necessary for solders for the adhesion of electronic wiring 3), ion exchange resins4), catalysts and so on. Large quantities of fine particles and super-fine particles are generated when manufactured in the usual way. Large quantities of these fine· particles and super-fine particles have polluted the internal and external' environments of factories. The products yield' ·decreases, also. From such a background, this study examines the preparation of perfectly uniform particles that could be· collected -100% as products. Recently, NASA has succeeded in the preparation of perfectly uniform particles in zero gravity 5). But the preparation of 'perfectly uniform particles by this method is difficult, and it can not be used in general industry"

Jan 1, 2000

By E. M. Alcântara

This paper describes some aspects about the relationship between copper electrorefining addition reagents and the hydrogen in the cathode. The conditions of electrorefining were studied by factorial design methods. The advantages of this technique are reduction in the number of tests, well organized experiments; improvement in productivity and reliability of results. The dosage of the two main addition agents, glue and thiourea, were varied simultaneously and compared with the hydrogen content in the cathode. The influence of these factors, as well their interactions were analyzed by statistical methods denominated ANOVA (Analysis of Variance). The increase of thiourea quantities, within of levels studied, influenced significantly at 95% confidence in the hydrogen content in copper cathode.

Jan 1, 1999

By Yousef Mohassab, Hong Yong Sohn, Mohamed Elzohiery

As part of the development of a novel flash ironmaking process at the University of Utah, a labscale flash reactor was used to produce iron directly from iron oxide concentrate. This work tested the feasibility of the novel flash ironmaking process using the partial combustion of hydrogen as fuel and reductant. In this flash reactor, the energy required to reduce concentrate particles was obtained from the internal combustion of hydrogen and oxygen with complementary energy from electrical resistance heating to compensate for the heat loss. After the reaction shaft was electrically pre-heated, hydrogen and oxygen streams produced a non-premixed flame inside the reaction shaft. Various conditions such as flame configuration, flame power, positions of concentrate feeding ports, excess hydrogen amount and residence time were tested. More than 90% reduction of magnetite or hematite was achieved at temperatures as low as 1175 oC with < 100% excess hydrogen in <10 s of residence time.

Jan 1, 2016

By Fumiatsu Sato

In recent years, an increasing number of urban soil contamination cases have been found during redevelopment of former factory sites. Hydroclassification technique, separating heavily contaminated fine soil particles from contaminated sites, is one of the economical remediation techniques for contaminated soil by heavy metals, but the separated fine soil particles are generally landfilled because of the difficulty in removing strongly adsorbed heavy metals on them. In the previous study, the authors have investigated the mechanism and the optimum condition of chlorination-volatilization technique to eliminate heavy metals from inorganic waste and found it was needed to heat up around 1273K. In this paper, a new remediation technique for lead contaminated fine soil particles is proposed. This technique is composed of chlorination and subsequent warm water extraction. In the chlorination step, water-insoluble lead complex is chlorinated to be water-soluble lead chloride without volatilization, by heating the soils with MgCl2-CaCl2-KCl salt mixture at relatively low temperature. By subsequent warm water extraction, lead chloride is leached out. Effects of chlorination conditions, such as time, temperature, composition of the salt and added salt ratio, on lead behavior were investigated. It was proved that lead concentration could be reduced below Japanese environmental standard.

Jan 1, 2006

By C. R. Bennett

The first phase in the design, development and implementation of a comprehensive computational model of a copper stockpile leach process is presented. The model accounts for transport phenomena through the stockpile, reaction kinetics for the important mineral species, oxygen and bacterial effects on the leach reactions, plus heat, energy and acid balances for the overall leach process. The paper describes the formulation of the leach process model and its implementation in PHYSICA+, a computational fluid dynamic (CFD) software environment. The model draws on a number of phenomena to represent the competing physical and chemical features active in the process model. The phenomena are essentially represented by a three-phase (solid-liquid-gas) multi-component transport system; novel algorithms and procedures are required to solve the model equations, including a methodology for dealing with multiple chemical species with different reaction rates in ore represented by multiple particle size fractions. Some initial validation results and application simulations are shown to illustrate the potential of the model.

Jan 1, 2003

By C. E. Hunt

Since the turn of the century, copper-nickel sulphide ores have been processed at the Sudbury, Ontario operations of INCO Limited, currently the largest integrated mining, milling, smelting and refining complex in the free world. Through the years operational, ecomomic, social and legislative changes have dictated the need for research and development directed at mitigating the impact of existing operations on the surrounding natural environment and also the reclamation of areas affected by earlier mining activities. Approximately one hundred years of mining history and the current annual processing of some 12 million tons of ore presents significant challenges with respect to waste disposal, liquid effluent treatment and land reclamation, particularly in light of rapidly evolving environmental regulations&apos; and controls within the Province of Ontario.

Jan 1, 1992

By B. J. Beaudry

The effect of various levels of purity of the rare earth fluorides and the calcium reductant used to prepare rare earth metals were determined. Metals which have low melting points such as La, Ce, Pr and Nd are not purified by distillation or sublimation. Impurities in the reactants remain as contaminants in these metals. Gd, Tb, Y and Lu which have slightly higher vapor pressures at their melting points than the first four metals are usually distilled to remove the Ta or W impurity introduced by the crucible and are purified slightly with respect to 0 and N by distillation. Rare earth metals that have high vapor pressures such as Sc, Dy, Ho and Er can be purified with respect to 0, N, C, as well as Ta or W by sublimation. The most volatile rare earth metals Sm, Eu, Tm and Yb are readily purified by sublimation and are usually prepared by a reduction-distillation process directly from the oxide. The importance of each step of the processes in determining the final purity of the individual rare earth metals is discussed.

Jan 1, 1989

By A. D. Besser

The world production of lead has been growing continuously and reached over 7 million tonnes in 2005. At the same time, the structure of lead consumption has changed: the use of lead compounds to liquid fuel has been virtually terminated; the proportion of lead for manufacture of lead-acid batteries has been growing and reached 76.7% of the overall world production of this metal. This has taken place against the background of increasingly stringent environmental norms and environmental legislation. This is due to the lack of an alternative for lead in manufacture of local power sources. A solution to the problem of meeting the industrial demand for lead with simultaneous reduction in the primary lead production is in recycling. A large amount of batteries manufactured worldwide and their short life cycle, as well as the positive economics and a possibility to comply with the environmental requirements encourage the development of secondary lead production. Currently, over 60% of the world demand for lead is met due to recycling. The current situation with collection, transportation, storage and processing of spent lead-acid batteries has been analyzed in this paper. Examples are given to illustrate technological and equipment solutions and trends for improvement of secondary lead production discussed.

Jan 1, 2006