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By Yongbin Yang

Cathodic reduction of oxygen is a process involved in many fields. As is well known, the mechanism of oxygen reduction usually varies considerably with electrode substrates. In this paper, cathodic reduction of oxygen on gold electrode was studied by linear sweep voltammetry with regards to cyanide leaching of gold. As the results shows, the electron transfer number increases as potential shifted negatively and decreases as pH value increases. Besides, the increment of electron transfer number as a function of potential decreases when pH value increases. When pH increases to 13.0, the volt-ampere curve exhibits a relative flat section with currents approximate to the limit current density of a 2e process. By varying dissolved oxygen concentration, the electron transfer number was calculated for pH11.0 at different potentials, the results being 2.387e, 2.732e, 2.982e, and 3.227e at, -0.35V, -0.40V, -0.45V, and 0.50V, respectively. The calculated current densities are in good conformity with measured results.

Jan 1, 2010

By T. V. Swaminathan

Monazite sand is normally processed by, the caustic soda route to produce mixed rare earths chloride, thorium hydroxide and trisodium phosphate. Bulk of the mixed rare earths chloride is used for the preparation of FC catalysts. Recently some of the catalyst producers have shown preference to cerium depleted (lanthanum enriched) rare earths chloride rather than the natural rare earths chloride obtained from monazite. Therefore, a process for producing cerium depleted rare earths chloride, cerium p thorium and uranium from Rare earths + thorium hydroxide obtained by treating monazite based on stepwise hydrochloric acid extraction, was developed in our laboratory. The process involves drying of the mixed rare earths-thorium hydroxide cake obtained by monazite-caustic soda process followed by stepwise extraction of the dried cake with hydrochloric acid under specified conditions.

Jan 1, 1989

By Sutham Niyomwas

The Fe-TiC composite powder was synthesized in situ by carbothermal reduction of ilmenite. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The effects of the reaction temperature (1300 °C - 1500°C) and milling time of precursors on the Fe-TiC conversion and powder morphologies were investigated using XRD and SEM method. The synthesized products showed that composite with iron matrix and titanium carbide as a reinforced phase was formed.

Jan 1, 2006

By Jian Li

Developing the Generation IV nuclear reactor is an international collaborative effort. One of the most promising Gen IV nuclear reactor designs is the supercritical water (SCW) concept, in which the water coolant runs at about 625 oC at the outlet. Under this temperature and high pressure condition, the cooling water is at supercritical state, which poses significant demand for both in-core and out of core materials. High-temperature mechanical properties, corrosion resistance and radiation damage are some of the key challenges. At present, no single commercial material can meet all the requirements of the severe SCWR conditions. Corrosion experiments per-formed under SCW condition yield various kind of corrosion modes, some are very challenging to characterize using conventional techniques. A combination of various advanced characterization techniques proofed to be essential to understand the root cause of materials? degradation.

Jan 1, 2010

By Harumasa Kurokawa

Since the initial start-up, the Toyo Smelter & Refinery has been operating in harmony with the ambient environment, and improvements have been implemented with technologies specifically developed for further protecting the environment. Toyo Smelter & Refinery is now planning to increase the copper production capacity from 280,000 tpy to 450,000 tpy, over a period of several years. In 2003, the first step of this smelter expansion and modernization plan was implemented. The production capacity of the P-S converter was increased dramatically, as it became possible to operate under a ?2 hot-2 blowing? schedule. In 2005, an additional converter will be installed, in order to allow operation under a ?3 hot-2 blowing? schedule. This report will describe the technical improvements on the P-S converters, as well as describe the Toyo expansion program and discuss the technologies applied to the fugitive gas collecting system.

Jan 1, 2005

By José Carlos D?Abreu

The Tecnored process is a new ironmaking technology, developed on a unique approach that combined empirical and theoretical knowledge backed by extensive tests carried out in a dedicated pilot-plant and with close support of universities and research centers. Campaigns in the pilot-plant focused on operate different reactors of different sizes, including a full size slice of the industrial furnace. This approach provided actual conditions to develop the main features of the process such as the internal dimensions, raceway pattern, thermal and gaseous profiles, etc, besides provide reliable data to feed and calibrate a specific mathematical process modeling. This paper presents the first computer model used by the Tecnored technical staff, focusing the behavior of a self reducing agglomerate in the upper shaft of the furnace (zone of solid state reduction). Some results of this model are given and discussed.

Jan 1, 2006

By Kwong. Kyei-Sing

Gasification is a process that converts a carbon feedstock into synthesis gas (CO+H2). Slagging gasifiers operate at high temperature and pressure and in a corrosive-wear environment from the slag. Cr2O3-based refractory linings are used to protect the steel vessel that comprises the gasifier from the aggressive gasification environment. Increasing service life of the gasifier is one of the keys for wide spread development of this technology. In support of the goals, research on the gasifier atmosphere, the slag chemistry, the interaction of Cr2O3 refractory with different feedstock mixtures (e.g., coal and petcoke) were characterized by post mortem analysis of bricks from service in gasifiers and thermodynamics simulation of the environment. Examples demonstrating how thermodynamic calculations can explain the post mortem results and make predictions of material interactions will be given. Attention is placed on the possibility of Cr+6 in different feedstock mixtures and operating conditions.

Jan 1, 2010

By Eun-young Kim

Electrogenerated chlorine leaching of waste printed circuit boards was investigated in hydrochloric acid solutions. The pulverized printed circuit board contained about 37.6% of metal component, in which copper was about 83.6%. The leaching rate of copper was greatly affected by current density and agitation speed. The leaching of copper up to 98% was achieved at 20 mA/cm2, 50?, 180 minutes, and 600 rpm in 1M HCl solution. Increasing agitation and lowering current density enhanced utilization efficiency of electrogenerated chlorine. Leaching of copper was suppressed at initial stage, while the minor metal elements, such as aluminum, lead, and tin, were dominantly leached out.

Jan 1, 2006

By Hani Henein

Recent innovations in atomization of molten metals have occurred in the area of single fluid atomization. Impulse Atomization (IA), one of the single fluid techniques, provides unique capabilities to study different regimes of atomization in a controlled environment. By changing processing variables, a mono-dispersed distribution of droplets above one millimeter in diameter can be produced. This is accomplished through proper characterization of the forces influencing the process and in particular the flow of melt through the orifice. This paper will discuss the approach and illustrate results with molten aluminum and cobalt.

Jan 1, 2006

By Alberto Oalvez, Lucya Yunus, Pengfii Tan

"Laboratory flotation tests of slow cooled converter slag have showed that 92.5% copper recovery at the copper cut-off grade of 24 - 25 % can be achieved by using a 50:50 ratio of DSP330 and SIBX (sodium isobutyl xanthate) at the natural pH of 7 and with a grinding time of 18.5 minutes. 70ìéç is the P80 achieved at this grinding time. MIBC is the frother and the solid content of the flotation feed was 46%. In the plant trials, two types of collectors at two different feed particle sizes for both the normal and slow cooled slag were operated. The particle size was controlled by the feed rate. The P80 of 75 ìçé at a feed rate between 32 - 36 t/h were tested. The plant trials have demonstrated that the copper recovery in the milling and flotation process of the slow cooled slags was improved by 3%. IntroductionIt is proposed to float the slow cooled converter slag, in the auxiliary circuit of the copper concentrator at Mount Isa, by using the processing conditions identified from several laboratory flotation tests. Among these laboratory tests, one produced a copper recovery of 4 % higher than those achieved from a normal cooled slag with the same slag feed grade and the same copper content (24 - 26 %) in the concentrate. These test conditions were selected for further studies.Laboratory Test Work and Plant TrialsThere has been a lot of work conducted under laboratory and plant conditions [1]. However, the achieved results did not justify their total implementation in the Mount Isa Copper Concentrator. Initially, the lab trials were carried out with slag cooled 100% in air; then it was changed to combined cooling for 12 h with air and 2.5 days with water sprays. The reason for this change was the shortage of space when the slag was cooled 100% in air, as it takes several days to achieve safe temperatures for its removal. The San Manuel Copper Smelter has reported that their slag was left for air cooling in pits for 8 h and then was followed by water cooling for 2-3 days [2]"

Jan 1, 2012

By Marilia S. de Magalhaes

Keywords: sinter, characterization, agglomeration, iron ore Iron ore sinters are the main burden of blast furnaces for pig iron production. The evaluation of these agglomerates is very important due to their properties affect indirectly the productivity and costs of production of the steel industry. In the sintering plants, the standard procedure of sinter assessment has been carried out by particle size control, bulk chemical analyses, tumbler and/or shatter tests and determination of reduction degradation and reducibility indexes. Microscopy techniques have just been applied to characterize sinters produced in pilot conditions, however, these techniques, the classical ones and the less traditional, allow enhancing the industrial sintering process assessment. For investigation of the phases, microstructures and fabric, reflected-light and scanning electron microscopy(backscattered electrons images) were used; for micro analytical chemical examination, energy-dispersive X-ray spectrometry; for Kikuchi patterns registers, electron backscattering diffraction. In addition to the microscopy techniques, the magnetic behavior was depicted by means of magnetic susceptibility measurements. Iron ore sinters are made up by hematite, magnetite, silicoferrite of calcium and aluminium and silicates. These phases develop either during sintering or, in some proportion, represent remnants of ores and fluxes; this is the case of some hematite and Mg-bearing silicate, respectively. From the magnetic susceptibility results, three different behaviors were determined, which are directly related to the magnetiteproportion in the samples. The phase association and proportion, the sintering conditions andthe quality assessment are some features appraised by such procedures, which reveal themagnitude of this proposal in sintering plants.

Jan 1, 2005

By Tianjiao Luo

Some literatures discussed on how to recycle the various reagent, but the discussion on how to reuse the waste liquid directly is very little. How to reuse the waste liquid directly was researched in this paper. Firstly, the waste liquid should be filtrated to remove the impurity; then some quantity of H2O2 solution was dripped into the waste liquid to pretreat it; finally, CuSO4solution was added into the treated waste liquid and the pH was adjusted to about 12, then some HCHO solution was added into the waste liquid, in which the treated carbon fiber can be plated. The morphology and composition of coatings were investigated by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS), the deposition rate was mensurated by the way of dissolution. The results indicated that, the plating effect was basically identical with new plating solution, and the solution is stable, and the plating rate is still about 0.8µm/h, and the copper coating is even and combines closely with carbon fiber. According to this way, the waste liquid can be reuse 5~7 times.

Jan 1, 2006

By Carlos Maurício Fontes Vieira

In the present work a ceramic body, fabricated using a mixture of clays and sand, for roofing tiles, produced in Campos dos Goytacazes, north of the State of Rio de Janeiro in Brazil, was characterized. Characterization was performed by X-ray diffraction, thermo analysis, chemical analysis, particle size distribution determination and plasticity. In addition, technological properties related to water absorption, linear shrinkage and flexural rupture strength were determined in samples fired at 700, 900 and 1100oC. The results showed that the investigated ceramic body has satisfactory plasticity and presents a refractory behavior during firing due to the predominantly kaolinitic nature of the clays.

Jan 1, 2006

By Vasil Kopaleishvili

The bainitic Fe-C-Si alloys with optimum content of retained austenite serve as ?containers? for storing of hydrogen. Both the vacancies of fcc lattice and the possibility of forming hydrides of silicon and other alloying elements will be used. The idea is based on our scientific hypothesis. There is the silicon threshold (Si=0,50%) in "Fe-Si" system and Fe-C bainitic alloys, above which it causes self-organized phenomena: sudden increase of hydrogen solubility and amount of retained austenite in the alloy after ??ß transformation, formation of two supersaturated solid solutions <a??r>, "rejuvenation? and its reverse process. Rapprochement of iron atoms when Si=0,50%, causes appearance of new covalent forces where uncompensated electrons of 3d-subshell are involved and it provokes synergetic phenomena. They ?free? silicon atoms from the previous bonds. After that silicon itself becomes a getter of hydrogen using vacancies (14) of 3P2(6)d0(10) subshell and it results in sudden increase of hydrogen solubility in metal. Simultaneously sudden decrease of iron activity takes place. That in its turn ?releases? the carbon. Thus, its redistribution, controlling the bainitic transformation, is hastened. It stipulates for creation of ?brittle bainite" B[a(C,H)+?r(C,H)] after ??ß transformation. While weathering of metal, "rejuvenating", hydrogen diffuses in ?islets? of retained austenite and ?relaxed bainite? (B[(C)+?r(C,H+H)]) is obtained. When heating austenite ?(C,H) is obtained, and after cooling ?brittle bainite? is obtained, etc. Presented scientific hypothesis explains the available experimental facts ("rejuvenation? and its reverse process, graphitization, weldability, forming of flakes, reaching high strength, etc.) in a new manner, as well as, gives real opportunity for creating of new trends in many fields, e.g. iron based HAA. Provisional data having been obtained are encouraging.

Jan 1, 2006

By Masaki Imamura

A novel hydrometallurgical process for copper concentrate treatment has been developed by Niihama Research Laboratories of Sumitomo Metal Mining Co., Ltd. The process has numerous advantages with respect to the operational and environmental aspects. For example, copper is leached effectively from chalcopyrite concentrates by chlorine gas under atmospheric pressure. The copper in the leach solution is then separated from iron and silver by solvent extraction and undergoes electrowinning for its recovery as a highly pure copper metal; this does not require any further purification. Moreover, iron metal can be produced from the purified raffinate by electrowinning without generating a large volume of goethite or hematite, which are solid wastes generated due to iron rejection in common hydrometallurgical processes. This process can also realize the efficient recovery of precious metals. The results of batch testing and continuous-operation testing are presented in this paper.

Jan 1, 2006

By M. N. H. Khan

CSIRO has been experimenting with supersonic flows as a method of rapidly quenching metallic vapours. Cooling rates above 106 °C/s have been achieved. The supersonic flow conditions are achieved by adiabatic expansion of the vapour through a Laval nozzle into a vacuum chamber. This paper will describe the basic physics of the process, outlining computer fluid dynamic (CFD) modelling of flow in the nozzle, the effects of different flow conditions on the condensation process and discuss the practical design issues associated with operating supersonic nozzles. Results obtained from a CFD model of the nozzle, which compared two methods of incorporating condensation, showed that inclusion of condensation substantially changes the conditions in the nozzle. Most noticeably, the effect of condensation produces a region in the nozzle where the temperature remains almost constant.

Jan 1, 2006

By Vijaya Thangavelu

Biological leaching of low-grade nickel laterite is based on a non-traditional leaching of oxide minerals using heterotrophic micro-organisms. The organisms solubilise metals by excreting organic acids; these acids then form complexes with heavy metals. High salinity of water supplies and soils in the vicinity of nickel laterite ore bodies is a major abiotic stress to fungi and represents a major challenge in the application of bioleaching process in-situ. Salinity exposes fungi cells to Na+ toxicity and osmotic stress. This study examined the salt tolerance development of Aspergillus foetidus based on gradual acclimatization of organism, its salt threshold and the salinity effect on its metabolism. The biological leaching of weathered saprolite ore with the resulting halotolerant organism under saline conditions was assessed. It was observed that salinity stress affected the organism?s growth and energy utilization

Jan 1, 2006

The purpose of this study was to investigate the immobilization as a host for metallic pollutants (Cr, Cu, Pb, and Zn) by ettringite phase. Ettringite phase is produced through hydration reaction of calcium aluminate with gypsum. From the XRD patterns, it is known that the distance between spaces in 010 planes in ettringite crystal increase with an increase of ionic radius of heavy metal except Pb; no big difference is shown. For this reason, the d-value of 010 planes in ettringite crystal increased with the substitution of Cr, Cu and Zn having a big Al ironic radius. But in case of Pb, because the substitution occurred at calcium site, it does not influence to increase d-value of 010 planes.

Jan 1, 2006

By Liu Wei

In order to make clear the dissolving characteristic of the chrysocolla (CuSiO3?H2O) in the ammonia-ammonium chloride solution, a thermodynamic model of the chrysocolla (CuSiO3?H2O)-ammonia- ammonium chloride-water system is established using the exponential computation method based on both mass balance and charge balance equations. The equation group of the thermodynamic model is solved by the MATLAB Soft on PC. The condition which is favorable for dissolving high concentration of copper in solution is making out. The stable area of chrysocolla (CuSiO3?H2O) and the condition of chrysocolla (CuSiO3?H2O) converting to atacamite (Cu(OH)1.5Cl0.5) is also studied. A group of experiments are designed to validate the veracity of the results of the thermodynamic calculation.

Jan 1, 2010

By Donald Voit

"The reaction between zirconia/zircon, coke, and chlorine involves a slow reaction between the coke and the zirconia/zircon and a fast reaction with chlorine. Because of the fast chlorine reaction, the reaction rate for zirconia/zircon is nearly independent of chlorine concentration for most conditions. The reaction between zirconia/zircon and coke is particle size controlled and related to the degree of physical contact between the zirconia/zircon and the coke. Since particle-particle contact is critical, compaction of finely ground coke and zirconia/zircon produces the highest reaction rates. Uncompacted, coarse coke and zirconia/zircon has the slowest reaction behavior with static bed tests.SummaryZirconia reacts with chlorine in the presence of carbon to form zirconium tetrachloride, carbon monoxide, and carbon dioxide. A similar reaction occurs with zirconium silicate with the additional formation of silicon tetrachloride. The reaction rate depends primarily on temperature and the intimacy of contact between the zirconia and the coke. The reaction is multi-stepped with a slow reaction between coke and zirconia to form an intermediate that reacts rapidly with chlorine, causing the order of the reaction for chlorine to be near zero. Chlorination rates in the range of 1 µmole/hr/cm2 are seen for fluid bed reactors. Plug flow, and static bed reactors have reaction rates of the order of 1 mmole/hr/cm2, where the area is based on the zircon surface area in plug flow and fluid bed reactors and the boat cross sectional area in a static bed. Chlorination rates measured in zirconia/coke briquettes are higher with rates as high as 400 mmole/hr/cm2 reported. High chlorine diffusion resistance, not accounted for in the analysis of experimental results, has led to a lot of confusion in the literature interpretation of chlorination data.In general coke and zirconia/zircon particle size, coke and zirconia/zircon intimacy, coke to zirconia/zircon ratio, chlorine concentration, and temperature are important variables for chlorination. Decreasing the coke and zirconia/zircon particle size generally increase the reaction rate. The coke to zirconia/zircon ratio affects the reaction in a more complex way. Increasing the chlorine concentration generally increases the reaction rate, but the effect appears to be more related to the concentration dependency of diffusion than to its role in the kinetics. The reaction rate increases with temperature but the exact behavior is complicated by temperature effects on diffusion."

Jan 1, 2011