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By G. B. Abaka-Wood, J. Addai-Mensah, W. Skinner

Recently, coal fly ash has become a potential candidate as a secondary resource of rare earth elements (REE). In this investigation, we studied the recovery of REE from fly ash from a commercial power plant. The specific aim was to assess the technical feasibility of recovering REE from the coal fly ash using conventional preconcentration methods, including gravity separation, magnetic separation, and froth flotation. The experimental results revealed that flotation achieved major gains in REE recovery and upgrading. However, during gravity and wet magnetic separation tests, the bulk of REE reported to the tailings. The results showed significant variations in the performance of the various beneficiation methods investigated. This study has confirmed that existing physical separation methods could be used to recover REE from coal fly ash prior to hydrometallurgical and pyrometallurgical processing, although some challenges persist.

Jan 2, 2022

By C. R. S. Needes, M. J. Nicol, G. T. W. Ormrod, N. P. Finkelstein

The industrial application of a dioxide electrode uranium by C. R. S. NEEDES, Ph.D. (London) (Visitor), M. J. NICOL, Ph.D. (Rand) (Visitor), N. P. FINKELSTEIN M.Sc. (Rhodes), Ph.D. (Liverpool) (Fellow), and G. T. W. ORMROD (Visitor) A correlation between the potential of a U02 electrode and the rate of recovery of uranium has been proved in laboratory and plant trials. When the recovery rates change because of variation in the concentrations of Fe(III), Fe(II), SO4 'and H+, a positive correlation is observed. However, an 2- increase in the concentration of phosphate in solution produces an increase in the U02 electrode potential but a decrease in the rate of leaching of U02. The correlation between the U02 electrode potential and the rate of leaching of U02 is then negative. It is concluded that, as a control device, the electrode cannot compete with the platinum electrode for use on certain plants. Nevertheless, the U02 electrode will act as a useful warning device if the total concentration of iron in solution decreases to below a level concomitant with the economic recovery of uranium. Furthermore, because of the positive correlation between the U02 electrode potential and the phosphte concentration, the electrode will also be of value in the detection of an increase in the phosphate level in solution. When it was incorporated in a suitable industrial probe, the electrode was found to be able to withstand the rigours of the leaching conditions in a large pilot-plant pachuca, and only failed after six weeks' operation.

Jan 11, 1975

By R. Castro, R. Gómez, F. Betancourt, M. Moncada

In block cave mining, rock fragmentation is a key parameter that influences the production level design and mine planning. Fragmentation occurs mainly by natural breakage during the caving process and in the draw column. The breakage that occurs within the column is known as secondary fragmentation. Secondary fragmentation has been successfully described using the block caving comminution model, which replicates the fragmentation mechanics between particles under drawn and vertical loads in a draw column. This model is based on a kinetic and population balance approach, in which non-normalized and normalized assumptions can be used depending on material and comminution system behaviour. In this paper, the non-normalized and normalized approaches are applied and compared to laboratory data to determine which assumption should be used for secondary breakage in block caving. Approaches are compared graphically, with the mean square error and the Fisher test with a false-rejection probability of 0.05. Based on a statistical analysis, the results show that the normalized model can be applied to all the rock types tested.

Nov 1, 2021

1. Book reviews Quantitative texture analysis, edited by H. ,}. Bunge and C. Esling. Deutsche Gesellschaft fur Metallkunde, 1982. 551 pp. Reviewer: L. 1\'1.Matthews Boundary element methods in solid mechanics by S. L. Crouch and A. M. Starfield. Reviewer: J. A. C. Diering World mineral statistics 1976-1980. Produdion,' exports,' imports, by Institute of Geological Sciences. London, Her Majesty's Stationery Office, 1983. £18.00 Reviewer: R. P. King 2. New publications Canadian mines,. perspective from 1982. Mineral Bulletin MR 197. Supply and Services Canada, Hull, Quebec K1A 059, Canada. Copper' s changing cost structure, by Commodities Research Unit Ltd (31 Mount Pleasant, London, WClX OAD, England). Petrology of metamorphic rocks, by M. Suk. New York, Elsevier, 1983. 320 pp. U.S. $68.00. Applied geomorphology, by H. Th. Verstappen. New York, Elsevier, 1983.442 pp. U.S.$95.75. Tin and its uses, no. 137, by the International Tin Research Institute. Greenford, the Institute (Fraser Road, Greenford, Middlesex UB6 7AQ, England), 1983. 3. New journals Mining Science and Technology, edited by C. 0, Brawner and B. N. Whittaker, is to be published quarterly in one volume per year by Elsevier. Aluminium, published monthly by Aluminium -Verlag GmbH, P.O. Box 1207, D-4oo0 Diisseldorf 1, F.R. Germany. DM 690.00 per annum. Rock mechanics The South African Institute of Mining and Metallurgy is to hold two schools on 'Rock Mechanics in Mine Management' at the University of the Witwatersrand, Johannesburg, from 23rd to 27th January, 1984, and from 30th January to 3rd February, 1984. The Federation of Societies of Professional Engineers The Federation of Societies of Professional Engineers (FSPE) has been a member of the World Federation of Engineering Organisations (W FEO) for many years and has regularly sent delegates to the biennial conference of that organisation. Second progress report by ASRET The Professional Engineers Joint Council was estabislhed in 1960 and initially its main fWlction was to represent the interests of engineers. Explosives technology The Center for Explosives Technology Research (CETR) has been established at the New Mexico Institute of Mining and Technology (Tech) in Socorro, New Mexico. International Tunnelling Association A conference entitled 'Ita Tunnels 1984' will be held in Caracas, Venezuela, from 2nd to 7th June, 1984. Automation The IFAC Symposium on Automation for Mineral Resource Development is to he held in Brisbane (Australia) from 9th to nth July, 1985.

Jan 1, 1983

Branch Minutes of the General Meeting held at President Steyn Gold Mine canteen on Wednesday, 10th May, 1978, at 4.00 p.m. Erratum We apologize to Mr J. G. Taylor for the error in one of his qualifications. Bio-engineering monograph The selection of papers presented at the International Bio-engineering Conference at the University of Cape Town organized by the South African Institution of Mechanical Engineers and held in April 1977, and which are appearing in The South African Mechanic al Engineer during April to June this year, will shortly be available in book form. Mathematics The Institute of Mathematics and Its Applications is planning the following conferences and symposia: The Nand F Proposals in Relation to Mathematics, 1st July, 1978: London School of Pharmacy. NIM reports Report no. 1917 The instrumental neutron-activation analysis of granites from the Bushveld Complex. (31st Mar., 1978.) Report no. 1951 Potentialities and limitations of four-parameter equations for the correlation of formation constants of metal-ion complexes in aqueous solution.(15th May, 1978.) Report no. 1963 An evaluation of the methods used at the National Institute for Metallurgy for the analysis of base-metal concentrates. (28th Apr., 1978.) Report no. 1964 The separation, by anion exchange, of noble metals on substituted cellulose. (28th Apr., 1978.) Guide To The Preparation Of Papers For Publication In The Journal Of The South African Institute Of Mining And Metallurgy The following notes have been compiled to assist authors in the preparation of papers for presentation to the Institute and for publication in the Journal.

Jan 1, 1978

By A. G. Journel, CH. Huijbregts

"Centre de Morphologie MathématiqueSpecial problems arise in the evaluation of lateritic-type orebodies (Ni-Co, bauxite) or, more generally, orebodies affected by surface weathering. In this type of orebody, the vertical grade distribution shows, from the hangingwall downwards, a systematic increase followed sometimes by a certain decrease, or vice-versa. These trends appear together with irregular variations from one drill bole to the other.The problem is to characterize a vertical structure that is representative not only of the drill hole but of an entire panel or zone of influence, in order to define mineable thicknesses for given cut-off grades. The vertical grade distribution observed on the drillhole is replaced by a new curve, called 'derive' (drift), which is computed by 'universal kriging'.Once the vertical study is completed, new 'service-variables' are defined in the horizontal plane, such as mineable thickness and the corresponding average grade, economical functions (combination of the grades of several minerals). The local and global estimation of these variables can then be performed by a simple bi-dimensional kriging plan. The global estimation is summed up by several tonnage-cut-off grade curves.The practical valuation according to the above scheme of a New Caledonian lateritic nickel orebody is presented."

Jan 1, 2014

By B. Besa, S. Nalukui

Globally, the demand for mineral products is ever increasing. Extraction of these mineral resources results in the continuous production of a huge volume of waste material, including tailing dumps. The mass of tailings usually exceeds the actual resource and often contains hazardous contaminants. This study investigated the effects of tailings disposal on soil, water, and air quality in the Nampundwe area. Water, soil, and dust samples were collected from different locations in the surrounding communities. The constituents analysed in the samples included copper, cobalt, iron, sulfate, and silica. According to the results obtained, some seepages occurred from the tailings impoundment to the shallow aquifer in the area. However, the general water quality meets the Zambia Environmental Management Agency (ZEMA) statutory limits. Recorded concentrations of sulfate (1500 mg/l), copper (1.5 mg/l), cobalt (1.0 mg/l), iron (2.0 mg/l), and silica were between 0.003 mg/l and 705 mg/l, which is far below ZEMA’s statutory limit. Silica concentration was also evident in the air. The highest concentration recorded was 260 ppcc (particle per cubic centimeter) recorded in July 2019 from the northern direction of the tailings dam. The concentration was below the statutory limit of 350 ppcc. The topsoil from the northern part of the tailings recorded a silica dust concentration of 39.9 ppcc. Iron was evident in the underground soil with a concentration of 8.01 ppcc, cobalt 0.005 ppcc, copper 0.051 ppcc, while sulfate was recorded as 0.41 ppcc.

Oct 9, 2024

By S. A. Lorentz, Y. Xu, C. Theron

The failure of tailings storage facilities (TSFs) results in the discharge of significant quantities of hazardous waste material into the natural environment. Research studies relating to slope instability have identified physical mechanisms such as rainfall-induced erosion, liquefaction, and shear failure as the main triggers. The generation of transient pressure waves and the mobilization of pre-event water in the unsaturated zone have been found to trigger shallow landslides in natural hillslopes. In this paper we review these physical mechanisms, known as groundwater ridging (GWR) and the Lisse effect (LE), from other studies. Previous researchers have explained both these phenomena through field and laboratory observations, numerical modelling, as well as conceptual discussions. These case studies demonstrate the impact of rainfall characteristics on the generation of transient pressure waves that rapidly increase the phreatic surface and change pore water suction. Reference is also made to the influence and behaviour of physical porous medium characteristics on the establishment of a continuous water phase that facilitates the transmission of an induced pressure head. However, previous studies fail to recognize the possibility that the pressure increase in pre-event water through pore air propagation could cause slope instability in tailings dams. The authors suggest that the physical properties and hydraulic behaviour of unsaturated porous tailings media make it susceptible to GWR and the LE, resulting in the creation of a potential failure plane.

Feb 2, 2022

"SAMPLING: THE IMPACT ON COSTS AND DECISION MAKING1. INTRODUCTIONFor years those in the minerals industry have been taking samples to assist them in making decisions; whether they be about investing billions of rand in a new mining operation, or simply whether a truck load of mineralised material should go to the mill or the waste dump, - we need a sample to help us make our decisions. This paper emphasises the importance and significance of sampling as a process, some of the associated technical problems and some of the advantages, especially in the light of traditional approaches that has usually left mine sampling to the least educated and lowest paid individuals on the mine. Perhaps the most important aspect that requires attention is the variability, usually measured in terms of precision, that tends to infect the sampling procedures. Francis Pitard 12 has stated: ""There is no such thing as reliable feasibility studies, unbiased ore grade control, accurate environmental assessments or effective process control, if you cannot identify and minimize the seven (ten) major sources of sampling variability. "" It is these ten sources of sampling variability and the way they arise that are briefly investigated. Variability is measured in terms of variances and rather than being self-compensating, there is good evidence to indicate that they are in fact additive at every step in the sampling and analytical process."

Jan 1, 2014

By A. Chuma, K. J. Nyembwe, H. Simonsen, J. H. Potgieter

Different concentration techniques were evaluated for preconcentration of a mineral ore at a coarser size to avoid energy and resource wastage. Specifically, the aim was to reduce milling costs and energy required in the beneficiation of tin. In this study, cassiterite (0.17% Sn) was the mineral of interest in a pegmatite ore body associated with quartz (SiO₂ > 60%) and alumina (Al₂O3 > 20%). Three concentration techniques, namely dense media, shaking table, and flotation, coupled with characterization analysis, were used to assess the concentration response. The results confirmed that particle size and mineral liberation impact the separation process. High recovery and grade were obtained with gravity concentration methods (dense media and shaking table) for coarser (+300 to +212 μm) and intermediate (+150 to +53 μm) particle sizes. Lower recovery and grade were identified for much finer sizes (−53 to −38 μm). Flotation produced a high-grade product at a relatively low recovery and appeared to be only applicable to finer grains. Separation efficiency based on Schulz’s equation measured a segregation performance of 74.8% for dense medium separation and 60.7% for the shaking table for the coarse and intermediate particle sizes. Flotation only achieved a separation of 30%–40%. The results suggest that use of dense media separation as a rough preconcentration method prior to further grinding, and the utilization of a more advanced concentration technique for mineral recovery and upgrade, constitute a successful approach to improve process economics.

Apr 14, 2024

By R. Dehghan, M. Zarei, A. Tohry, S. C. Chelgani

Typical depressants for selective reverse flotation of iron oxides from complex silicates do not generally show high levels of efficiency. Therefore, as a hot topic, there are several ongoing investigations in this area. The main aim of this paper is exploring the potential of using humic acid (HA) as a depressant in reverse cationic flotation of hematite from complex silicates. For such a process, the wettability and flotation behaviour of pure minerals (hematite and silicates) was investigated at pH 10 in the presence of HA and cationic collector. Adsorption mechanism of HA on these minerals was measured by zeta-potential and FTIR. Results of flotation tests showed that at the lower concentrations of HA, selective separation of silicates from hematite is beneficial, where the floatability of amphibole was higher than pyroxene. A higher separation efficiency of hematite through reverse flotation was observed in the presence of amphibole, in comparison with the presence of pyroxene. Wettability studies showed that HA has a significant effect on reducing the hydrophobicity of treated minerals with the collector. The adsorption, ZPC and FTIR test results indicated that HA was adsorbed on both silicates and hematite. However, the absorption intensity onto hematite was much higher than silicates. It was found that the adsorption mechanism of HA on hematite takes place through both strong H-bonding and ligand exchange. Keywords: Reverse cationic flotation, humic acid, iron oxide, complex silicates, surface adsorption

Jan 1, 2020

By S. Durapraj, R. T. Masethe, U. Maqina, A. C. Adoko

This study investigates seismicity and rockburst control within the Merensky Reef and UG2 orebody of an intermediate-depth platinum mine located in South Africa's Bushveld Complex. Utilising a mine-wide seismic monitoring system, over 1,900 seismic events were recorded between April 2023 and May 2024, revealing complex seismic patterns driven by mining-induced stress changes. The largest event, with a magnitude of ML 2.0, underscores the seismic risks associated with mining at increasing depths. Key findings include the spatial and temporal variability of seismic events, with high seismic activity observed near pillars and geological structures. A significant portion of events correlated with pillar and foundation failures. Moment tensor analysis identified dominant failure modes, such as stress-driven fracture closures and dynamic pillar failures. To mitigate risks, the study emphasises advanced support system redesign and rockburst risk assessment using the rockburst damage potential (RDP) method. The research highlights the importance of monitoring, geotechnical compliance, and adaptive designs in enhancing safety and reducing seismic hazards in underground mining operations. The study applied the RDP framework, classifying damage across R1 to R5 scales, where most instances fell into low-risk categories (R1 and R3), indicating minor to moderate damage. However, data limitations and the tabular stoping method's complexity led to inconclusive results, highlighting the need for more robust data and customised risk assessment tools. Despite these challenges, the RDP approach provided valuable insights into rockburst mechanisms and the effectiveness of existing support systems.

Jan 12, 2025

By A. A. Rogozhin, S. I. Anufrieva, A. V. Kurkov

The results of development of technologies for flotation concentration of two types of complex beryllium ores are presented: beryllium-fluorite in apocarbonate metasomatites (Type I) and rare-earthberyllium in feldspar metasomatites (Type II). The researched samples of Type I ores contain a mineral complex that is difficult to separate by fatty acid flotation, including phenakite, bertrandite, fluorite, and carbonate minerals. The ores are characterised by an increased content of fluorite and carbonates. The sample of Type II ore contains such rare-earth minerals as bastnesite and orthite, and a beryllium mineral - cleiophane. The size of individualised grains of cleiophane does not exceed 0.04 mm, which significantly limits the possibility of extracting the mineral into the enrichment concentrates. For the Type I ores, a technological process for the extraction of fluorite using a phosphorus-containing reagent from the class of dialkylphenyl polyethylene glycol esters of phosphoric acid (DAPEGEPhA) has been developed. The use of DAPEGEPhA enables the production of a high-grade fluorite concentrate (95% CaF2). The production of commodity phenakite-bertrandite high-grade (10% BeO) flotation concentrate from the fluorite flotation tailings with using a fatty acid collector is based on binding calcium in the flotation pulp using soda, sodium hydroxide and sodium tripolyphosphate. The use of a combined collector based on fatty acids and DAPEGEPhA made it possible to produce a collective rare-earthberyllium- lithium concentrate with high REE extraction (88%) from the Type II ores. The concentrates obtained are suitable for production of commercial-grade hydrometallurgy products. Keywords: Beryllium ores, flotation, reagents, concentrates, hydrometallurgy products

Jan 1, 2020

1. Book reviews Mining and metallurgical practices in Australasia. Melbourne, Australian Institute of Mining and Metallurgy, 1981. $40 (incl. surface postage). Reviewer: M. G. Atmore Coal mine ground control, by Syd. S. Peng. 1978. Reviewer: C. F. Engelbrecht Sixth Annual International Conference on Coal Gasification, Liquefaction and Conversion to Electricity, July 31 -August 2, 1979. Pittsburgh, School of Engineering of the University of Pittsburgh, 1980. Reviewer: S. T. J. van Rensburg This book is a useful general reference volume on the topics covered provided a great deal of technical detail is not required from it. It consists of 29 papers, which are arranged under 6 headings. Flotation agents and processes. Technology and applications, edited by M. W. Ranney. Park Ridge, D.S.A., 1980. $48. Reviewer: R. P. King 2. New books Project control manual, by Sven R. Red. 250 pp. in loose-leaf binder. U.S. Al47. (Obtainable from the author at Bray Studios, Windsor Road, Windsor SL45 UG, England.) Manganese deposits, by Supriya Roy. London, Academic Press, 1981. 400 pp. Joint preparation for welding (set of overhead-projector transparencies). Abington (England), The Welding Institute, 1980. £34 per set. Electron micrographs of clay minerals, by T. Sudo,S. Shimoda, R. Yotsumoto, and S. Aita. Amsterdam, Elsevier, 1980. 228 pp. Dfl.150. Weld pool chemistry and metallurgy. Abington (England), The Welding Institute, 1980. 357 pp. $27. 3. New journal ...being known as Gliickauf + Translation, at an annual subscription of 396 DM for 24 issues per year. It is available from Verlag Gliickauf GmbR, D-4300 Essen I, P.O. Box 103945, Federal Republic of Germany. 4. Canadian MRI publications During 1980 the Mineral Policy Sector introduced a new series of reports identified by the prefix MRI. These cover internal studies and analytical works on a wide variety of subjects, that for one reason or another, do not reach the publication stream of the regular series yet may be of interest to readers in this 'unpublished form'. Twenty-four such titles are listed below. Exploration planning A series of professional advancement seminars for the mineral industry is to be held at Rhodes University from 12th to 20th August, 1981. The series, entitled 'Economic Guidelines for Exploration Planning', will be conducted by Professor B. W. Mackenzie, and the attendance will be limited to 30 participants. The seminars are intended Seminar on Geostatistics A seminar for mining executives on Geostatistics and Decision Making in the Mining Industry is to be held in Toronto from 23rd to 25th September, 1981. v

Jan 1, 1981

By P. C. Pistorius, M. P. Maphutha, J. D. Steenkamp

Advanced high-strength steels (AHSS) are sophisticated materials being developed by the steel industry to mitigate challenges related to the performance of motor vehicles. To meet the requirements of AHSS, the ferromanganese alloys (FeMn) utilized in the production of the steel are required to contain acceptable levels of unwanted impurities, i.e. P, S, N, H, and C. The focus of the current study was to investigate dephosphorization of ferromanganese to produce a low-P alloy that could be effectively utilized in the production of AHSS. The study involved conducting laboratory-scale testwork to study the efficiency of CaO-based slag systems to dephosphorize FeMn alloys. The addition of Na2O, CaF2, and BaO to MnO-CaO-SiO2 slag was considered. The test work was carried out in a 25 kW induction furnace at temperatures of 1350°C, 1400°C, and 1450°C. The P partition coefficient (Lp) remained small at <1, which is an indication that dephosphorization had not been achieved. The baseline slag, comprising 40%CaO-40%SiO2-20%MnO, reported higher Lp values. Addition of Na2O and CaF2 did not show any further benefit. Substituting half of the CaO by BaO, resulted in similar Lp values to those of the baseline slag under conditions of 1350°C and 1450°C at 30 minutes. In summary, based on the Lp values obtained, the conditions investigated with the CaO-based slags appeared to have been unfavourable for dephosphorization of FeMn alloys, as most of this impurity element remained in the alloy.

Sep 1, 2021

By Ri McCrindle

"Analytical Chemistry is moving rapidly towards a concept where technicians have to do no more than press a button and print the result from an instrument that is a featureless ""black box"". In this environment we must ask how much traditional &apos;&apos;wet chemistry"" is still required for undergraduate students.Methods that can be fully automated will become increasingly important. An example of such a method is that of the slurry nebulisation and ICP-OES analysis of precious metal concentrate. Grinding the sample and adding Triton X100 as dispersant, complete analysis time is in the order of 90 min as apposed to the traditional Carius tube method which could take as long as 24 h. For most of the elements studied, the results using ""in-house"" reference material for calibration and as samples as well were within the 95% confidence level. Elements of low concentration in the sample (As, Bi and Se) were not within that level."

Jan 1, 2014

By J. A. Maritz, D. F. Malan

Pillar strength is affected by pillar shape, but this has largely been ignored in past research studies. Bord-and-pillar layouts are typically designed using empirical strength equations developed for square pillars. Owing to the poor quality of pillar cutting, many hard-rock pillars have an irregular shape and it is not clear how this affects pillar strength. Furthermore, the strength of rectangular pillars in comparison with square pillars is also difficult to quantify. The ‘perimeter rule’ is widely adopted for rectangular pillars, but its applicability for pillars with irregular shapes has never been tested. We used numerical modelling in this study to investigate the effect of pillar shape on strength. An analytical limit equilibrium model of a square and a strip pillar also provided useful insights. For slender pillars, the strength of a long rib pillar is essentially similar to that of a square pillar. In contrast, for rib pillars with a large width to height ratio, there is a substantial increase in strength. The study found that the perimeter rule should not be used for irregularly shaped pillars. Displacement discontinuity modelling, using a limit equilibrium approach, is proposed as an alternative to determine the strength of these pillars.

May 3, 2023

By F. W. Petersen

The Conference Minerals & Materials &apos;96 was held in Somerset West, South Africa, from 31st July to 2nd August, 1996. It was organized by the Universities of Stellenbosch and Cape Town, the Cape Technikon, and the Western Cape Branch of The South African institute of Mining and Metallurgy (SAIMM). The three-day Conference was attended by 180 delegates, representing countries such as Australia, South Africa, United Kingdom, Finland, Sweden, Germany, Poland, Zambia, and Zimbabwe. The programme and associated exhibition were well organized, and each of the delegates received two volumes of proceedings containing the 77 papers presented at the Conference.

Jan 1, 1996

By J. D. Zhou, F. Yang, X. G. Bi

"In this investigation, the phosphorus distribution ratios in the CaF2 system and B2O3 system dephosphorization slags for high-phosphorus hot metal pretreatment were measured by an indirect method under laboratory conditions. Firstly, the phosphorus distribution ratio between liquid slag and solid iron was measured, and then the phosphorus distribution ratio between liquid slag and hot metal was calculated. Phosphorus capacity was calculated in terms of the composition and optical basicity of the slag. Dephosphorization slag was also studied by scanning electron microscopy, energy dispersive analysis, and X-ray diffraction analysis. The experimental results show that the phosphorus capacity of the B2O3 slag system is much greater than that of the CaF2 system. It is demonstrated thatB2O3 can completely replace CaF2 as fluxing agent for high-phosphorus hot metal pretreatment. With CaF2 as fluxing agent, the phosphorus capacity increases with increasing CaO content in the slag, but the phosphorus distribution ratio decreases. B2O3, when used as fluxing agent, can react with high melting point phases such as 2CaO·SiO2 and 3CaO·P2O5 in the slag to form new phases with low melting points such as 11CaO·B2O3.4SiO2, 2CaO·B2O3.SiO2, and Ca9.93(P5.84B0.16O24) (B0.67O1.79), thereby acting as a fluxing agent. When the ratio of w(B2O3)/w(CaO) is 0.16, the phosphorus distribution ratio reaches its maximum value, that is, the dephosphorization ability of the slag is at its maximum. IntroductionAs international iron ore prices continue to rise, the development of China's steel industry is facing a lot of pressure. Against this background, development and utilization of domestic high-phosphorus iron ore resources is particularly important. When highphosphorus iron ore is used in ironmaking, the phosphorus content in the hot metal can reach 0.35% or more, and the hot metal must be pretreated. For hot metal with 0.08–0.10% dissolved phosphorus, the traditional hot metal dephosphorization pretreatment technologies are relatively mature. However, when using these methods to dephosphorize hot metal containing 0.35% P or more, the amount of dephosphorization slag can reach 100–150 kg per ton of hot metal. Furthermore, the traditional dephosphorization methods require the addition of large amounts of CaF2 as fluxing agent, and this results in high fluoride levels in the dephosphorization slag. The fluorine in the slag can partially dissolve in water and thereby causes high fluoride concentration in the water and soil. Once the fluoride is absorbed by humans or animals, it can result in toxic effects on the central nervous system and myocardium. In addition, fluoride can accumulate in the environment, and thereby pose a health risk to animals and humans through the food chain (Li, 2007; Liu, Wang, and Dong, 2011, Diao, 2013). The objective of this research is to replace CaF2 with B2O3 as fluxing agent while achieving the expected goals of hot metal pretreatment."

Jan 1, 2016

By K. Wu, L. Li, D. W. Zhou, J. W. Yu

The presence of a fractured water-conducting zone (FWCZ) is of significant importance for the safety of underground mining under water bodies. When a coal mining area is covered with a thick layer of alluvial soil, the height, width, and distribution pattern of the FWCZ in the area shows unique features. The internal mechanism by which thick alluvial soil affects the FWCZ is still unknown. Using the Huainan coal mining area (HCMA) in China as a case study, we investigated the impact of thick alluvial soil on the height, width, and distribution pattern of the FWCZ through numerical simulation using the distinct element method, theoretical derivation, and data validation. The results indicate that a thick layer of alluvial soil inhibits the FWCZ height and increases the FWCZ lateral width. When the soil-to-rock ratio is greater than a certain value (the numerical result in this study is 15:18), the FWCZ height and width are affected by the thick alluvium significantly, and the thick alluvial soil alters the shape of the FWCZ from tall and thin to short and wide. The load exerted by the alluvial soil transfers downward to influence the FWCZ; however, this process is obstructed by the hard strata in the bedrock. Therefore, the vertical and lateral change trends show a similar step pattern. Our results can provide a basis for accurate calculation of the FWCZ height in mining areas with thick alluvial soil, to mitigate mine water hazards and increase the safety of underground mining in coal mines covered with a thick alluvium layer. Moreover, reducing the FWCZ height can help extend the upper extraction limit in coal mines covered with a thick alluvium layer, which reduces the thickness of the impermeable coal pillar and increases coal production.

Jan 1, 2016