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By J. J. Demeter

A tube-wall reactor with a Raney nickel catalyst deposited on the outer wall of the tube by flame spraying is effective in the practically complete conversion of 3H2+1CO synthesis gas to a high-Btu gas (methane) at an hourly space velocity of 7,000 volumes of gas (NTP) per hour per volume of annular volume. Partially reacted synthesis gas containing an appreciable amount of methane can also be treated in this reactor to increase the heating value to over 900 Btu per cubic foot. Excellent heat removal through the metal wall to a coolant and temperature control were obtained. The heat transfer co-efficient from the catalyst to the coolant was about 275 Btu per hour per square foot per ° F. Synthesis tests were conducted with tubes 1.2 inches in ad by 6 inches long, and 1.3 inches in od by 36 inches long. When operating at a synthesis gas rate of 100 to 120 scfh per square foot of catalyst-coated tube, catalyst life was long enough to realize a catalyst cost for the raw Raney nickel alloy of about 0.3 cent per 1,000 cubic feet of pipeline gas (900 to 950 Btu per scf). Gas recycling at ratios of 1:1 to 3:1 was effective in increasing conversion and in extending the life of the catalyst to about 16 weeks. In cost and in operating characteristics the tube-wall reactor compares favorably with the fluidized-bed and hot-gas-recycle reactor systems for the synthesis of high-Btu gas from H2+CO.

Jan 1, 1967

By J. S. Tosh

An equilibrium study of the system potassium carbonate, potassium bicarbonate, carbon dioxide, and water has been conducted with solutions of 20-, 30-, and 40-percent equivalent potassium carboaate concentrations. These equilibrium data cover the operating range of the hot carbonate scrubbing system for removing carbon dioxide from gas mixtures. Such data are necessary to establish the limits of purification and are used to design absorption and regeneration towers. Values of K in the relationship K = (KHCO3)2/(K2CO3)PCO2 were determined for higher temperatures of 70" to 140° C. and greater concentrations, I 20 to 40 percent, than employed by previous investigators. For the 20- and 30-percent concentrations, K is constant at a given temperature; thus, once K has been determined the equilibrium pressure of carbon dioxide can be calculated for any conversion. Variation of & values with changing conversion was observed with the 40-percent solutions, so that equilibrium calculated pressures are less reliable from average K values.

Jan 1, 1959

By Joseph J. Wallace

1. The Pocahontas No. 3 and Pocahontas No. 6 ere the two most important beds in Mercer County from the standpoint of present production and recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of coal in place, are estimated at 188 million short tons as of January l, 1953. Of this total, 80 million short tons are in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1954

By James C. Barker

Gold placer deposits along the upper Yukon River, in the region between the river villages of Circle and Eagle, were investigated by the Bureau of Mines. The investigation was conducted intermittently between 1976 and 1985 as part of an evaluation of mineral resources on lands proposed for inclusion in the National Park System. At least 230,000 troy ounces (tr oz) of gold has been produced in the region, principally from Woodchopper, Goal, and Fourth of July Greeks. The placers are underlain by, or occur downstream of, early Tertiary sediments that have been deposited in the Eagle Trough. Strike-slip displacement along the Tintina Fault is responsible for creation of the trough and may have been a factor in the formation of the present placers. Placers were found to have a close spatial correlation to certain altered fault lineaments of the Tintina Fault trench. Placer concentrates contain several different textural forms of gold, suggesting multiple origins. Geological studies and a survey of 162 panned concentrates throughout the region indicated previously unreported sites of placer gold, and potential exists for the discovery of additional placer and lode gold. Because of nearly continuous soil and vegetation cover, further evaluation of the region will require subsurface sampling.

Jan 1, 1986

By W. P. Diamond, John C. LaScola, D. M. Hyman

In 1972, the Bureau of Mines developed a direct-method test for measuring the gas content of virgin coal core samples for coal mine health and safety considerations. Since that time, approximately 1,500 coal samples from more than 250 coalbeds in 17 States have been collected for gas content determination. The gas content data, when combined with geologic and engineering studies, can be used as a basis for a preliminary estimate of mine ventilation requirements, and to determine if methane drainage in advance of mining should be considered. The data are also critical in delineating coalbed methane resources and in utilization feasibility studies. This report makes the Bureau's extensive data base of gas content data more readily available to the coal and gas industries. The data are presented in tabular form, alphabetically by coalbed name and by State. The components of the total gas content (lost, desorbed, and residual gas) are given, Location (State and county), sample depth, coalbed or formation name, and coal rank are included for geographic and geologic identification.

Jan 1, 1986

By W. P. Yant

The hazard to health from contamination of air by a noxious gas depends not only on the potential harmful response attending exposure., but also on the warning properties, which in effect may be termed the "accompanying warning response," This warning may be manifested as an odor, taste, irritation of the eyes, nose, or throat, or perhaps headache, vertigo,, or nausea. These manifestations may be painful and even slightly harmful, but to a much lesser degree than the primary injury of exposure. The warning response mitigates hazards directly in proportion to the degree of intolerability which -accompanies injurious exposure, and accordingly its absence augments hazards. This accounts for the fact that the actual health hazards from a nonodorous or non-irritating gas or vapor of comparatively low toxicity sometimes equal or exceed the hazard from a considerably more toxic substance, but one which possesses a marked odor or produces eye, nose, or throat irritation in advance of harmful exposure. When a substance lacks the properties for giving warning, it is often possible to impart them by the addition of a small amount of another substance which has an exceedingly high warning intensity. The vapors of this substance, commonly termed a "warning agent" or "tracer gas," escape and mingle with the gas or vapor which lacks warning properties and thereby apprises persons of the latter's presence. The amount of the warning agent added is that which will give adequate warning in advance of serious physiological harm from the dangerous gas or vapor.

Jan 1, 1930

By J. H. Heginbotham

As part of the total metallurgical system to recover metals from secondary resources, the Bureau of Mines conducted froth flotation research, using cationic reagents to recover glass from urban refuse. Batch flotation tests showed that high-quality cullet can be obtained from glass-rich aggregates derived from municipal incinerator residues and unburned refuse. This was confirmed by pilot plant operations treating 350 pounds of flotation feed per hour. Aggregates containing 85 to 90 percent glass were wet-ground to minus 20 mesh, deslimed in two stages, and fed to flotation cells. The glass was selectively floated using an amine collector, usually in an amount under 0.2 pound per ton of solids in the feed. The glass concentrates from the rougher cells were cleaned by refloating two or three times. Over 90 percent of the glass in the deslimed feed was recovered in the cleaned concentrates.

Jan 1, 1978

By G. E. McClelland

As part of its mission to assure an adequate domestic supply of metals essential to the Nation's welfare, the U.S. Department of the Interior, Bureau of Mines, investigated a particle agglomeration technique as a means for improving the flow of leaching solution through heaps of clayey or finely crushed, low-grade, gold-silver ores. Bench-and pilot-scale experiments showed that the percolation rate of cyanide leaching solution was markedly enhanced by mixing the ore with a portland cement binder, moistening the mixture, and mechanically agglomerating and aging the feed prior to heap building and leaching. The rate of gold and silver recovery markedly increased because of the increased, uniform percolation of leaching solution through the agglomerated feed. The use of concentrated cyanide solution instead of water during the agglomeration procedure decreased the leaching time required to obtain maximum recovery. Results of bench-and pilot-scale experiments are discussed.

Jan 1, 1981

By Verne S. Mutton, William A. Slivensky, Eric S. Weiss, Kenneth L. Cashdollar, Deepak R. Kohli

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory, cooperated with Tecrete Industries Pty. Ltd. and BHP Australia Coal in a research program to evaluate the strength characteristics and air leakage of four seal and two stopping designs for use in underground coal mines. A fundamental safety research area for NIOSH is to eliminate the occurrence of coal mine explosions or to mitigate their effects. One approach to achieve this goal is to develop new and innovative seal designs that provide increased explosion isolation protection for the mining personnel against ignitions that originate from within the gob or. other worked-out areas of the mine Full-scale seals and stoppings were constructed in the Experimental Mine at Lake Lynn Laboratory near Fairchance, Fayette County, PA. They were ail--leakage tested, then subjected to a series of explosions with average pressure pulses ranging from 25 to 500 kPa (3.5 to 72 psi). Instrumentation measured seal displacement and acceleration as a function of time, providing data to assist in the development of numerical models 1'01- future seal design. All three seals designed with Meshblock wire forlnwo~-k ant1 a lnonolithic shotcrete core withstood the first explosion test, which generated an avcr-age rnaximu~n pressure of - 140 kPa (-20 psi) while maintaining acceptable air leakage rates. These seals I-anged from 175 to 325 mm thick. They included a 2.7-m-high by 325-mm-thick seal that was tesled 27 hr after completion against this - 140-kPa explosion pressure, a special requirement of the test program. This seal survived explosions with pressure pulses up to 300 kPa (43 psi). The 2.3-m-high by 325-mm-thick Meshblock seal survived three explosion tests with overpressures up to 455 kPa (66 psi) and satisfied the air leakage criteria. A I ,200-mm-thick plug seal was constructed of two Gunmesh formwork walls in-filled with shotcrete and a 3,450-kPa (500-psi) strength Aquablend core. This plug seal survived three explosions with pressure pulses ranging 11-om 150 lo 430 kPa (-22 to 62.5 psi) with no measurable postexplosion air leakage. Two Gunmesh stoppings with thicknesses 01' 40 and 75 inln withstood explosion overpressures of 23 and 115 kPa, respectively. Anchoring all seal and stopping designs into the roof, ribs, and floor with steel "rootbolts" provided very effective boundary constraint that is critical to the performanceofstructures subject to explosion overpressures.

Jan 8, 1999

By Earl L. Phillips

The Bureau of Mines conducted laboratory tests on samples of pozzolanic-cement concrete to develop a low-strength backfill. Results show that support costs can be lowered by replacing a portion of the portland cement in mine backfill with pozzolan (fly ash) and lime. Unconfined compression tests on various ratios of fly ash to cement in 84 samples produced compressive-strength curves that can be used to estimate the best backfill mix for any mine.

Jan 1, 1981

By R. Blickensderfer

Test equipment that simulated frictional impacts between coal-cutter bits and mineral inclusions at a coal face during operation of a continuous coal mining machine was used by the Bureau of Mines in the laboratory to study the incendivity of impacts between various rocks, metals, and hard-metal alloys in an explosive mixture of air-7 pct natural gas. Quartzitic sandstone was found to be the most incendive of several rocks tested. Limestone concretions from a coal seam, known locally as "sulfur balls," sparked furiously but were not incendive. Among the metals tested, the type of steel used in commercial coal-cutter tools was the most incendive material tested. A l7-4PH stainless steel was less incendive and appears to be the most promising high-strength steel alloy, reasonably economical, for use in coal-cutter bits. Some hard-metal alloys, primarily titanium and zirconium diboride composites, were also evaluated as possible replacements for the conventional cobalt-bonded tungsten carbide used in the tip of coal-cutter bits. The metal-bonded diborides were generally less inc endive but more brittle than the conventional tungsten carbide. Carbonitride coatings on tool bits were also tested but found to have no advantage. The source of ignition during frictional impact between metal and rock was studied. Immediately after impact, a yellow flash was observed and a smear of metal near its melting point occurred on the rock. This hotspot on the rock, rather than the yellow flash or sparks or metal fragments, was observed to be the cause of the ignition.

Jan 1, 1974

By J. Schlocker

The present emergency has greatly stimulated interest in the light metals - aluminum and magnesium - owing to their extensive use in airplane construction. The $63,000,000 plant being erected in the Las Vegas Valley by Basic Magnesium, Inc., under the auspices of the Defense Plant Corporation,

Jan 1, 1942

By W. P. Diamond, B. M. Bench, C. M. McCulloch

This Bureau of Mines report describes photolineaments obtained from stereoscopic examination of vertical aerial photographs and by the Ronchi grating study of aerial photoindex sheets. The photolineaments are compared with the trends of oriented fracture systems procured by measuring the compass direction of joints in bedrock. The relative reliability of the methods is shown, and the results are presented in graphical, tabular, and written form. Analyses of field measurements of strikes of bedrock joints in the project area indicate for the most part two intersecting sets of major joints oriented N 76° W - N 15° E, and N 57° W - N 27° E. The analyses of lineaments determined by stereoscopic examination of aerial photographs show dominant trends of lineament zones of weakness to be an average of N 65° W - N 20°E. Analysis of lineaments found by Ronchi grid viewing of aerial photoindex sheets indicate dominant trends of N 70° W - N 27° E. The three methods give similar findings and verify the work of previous authors. The Ronchi grid method is a useful guide, but it cannot be substituted for the two more painstaking methods.

Jan 1, 1977

By John Nagy

Limited experiments in the laboratory with specimens of mine rock from a Virginia bituminous coal mine indicate that natural gas-air mixtures can be ignited by sparks generated by rubbing friction of sandstone against sand-stone, shale against sandstone, sandstone against (roof-bolt) steel, and shale against steel. Such sparks, generated during a roof fall, may have initiated a recent gas explosion in this Virginia mine, although this cannot be stated with certainty. No ignitions of gas were produced by sparks or heat generated by impact friction between mine rocks or steel, during tension breaks of roof bolts, or by pull tests of roof bolts through their washers and roof plate. However, this negative result of limited experiments does not preclude the possibility of gas being ignited by these conditions.

Jan 1, 1960

By Oliver Bowles

[In an endeavor to promote greater efficiency in the lime industry, the United States Bureau of Mines is preparing a series of preliminary reports dealing with particular problems of the industry. Through the circulation of these reports, it is hoped that sufficient interest may develop among lime-plant operators to prompt them to discuss with the bureau their our experiences with these problems. By such an interchange of ideas, it is believed that conclusion may be reached which will be of practical benefit to try entire industry. The first report, "Stripping problems it Limestone quarries of the Shenondoah Valley", Serial No. 2401, was issued during October, 1922. This report t is the second of the series. It is hoped that may operators will contribute additions to the information now at hand.]

Jan 1, 1922

By Robert S. Sanford

"INTRODUCTION AND SUMMARYThis paper is one of a series recently undertaken by the Mining Branch, Bureau of Mines, College Park, Md., to describe current practice in hauling ore and waste by truck at various mines.Heavy-duty ore trucks are replacing railroads at many large open-cut mines and even at a few underground mines. Recently a few mines have been equipped with trucks for transporting ore to a central point, from which conveyor belts move the ore out of the mine. This paper deals only with truck haulage methods and costs.The requirements for efficient low-cost truck haulage are good trucks designed for heavy loads, adequate truck maintenance, smooth roads, and well-trained truck drivers.A correct balance must be maintained between the primary crusher capacity, the number of shovels loading ore, and the number of trucks hauling ore.The cost of tires is important. Tire companies are manufacturing better tires. Mining companies are prolonging the life of tires by building better roads and maintaining correct tire pressure.The trend is toward heavier equipment. In 1949 it cost $0.0925 a long ton to haul ore and waste with a 15-ton truck and $0.0743 a long ton with a 22-ton truck.When trucks are properly maintained, hauling costs do not increase with the age of the trucks. During 1948 it cost $0.1118 per long ton to haul with the four oldest 15-ton trucks and $0.1130 per long ton to haul with the four newest 15-ton trucks, two of which were purchased in 1945 and two in 1947.The weighted ayerage cost of hauling a long ton of ore to the crusher and waste to the dump has been reduced from $0.1159 in 1948 to $0.087 in 1949."

Oct 1, 1950

By M. W. Von Bernewitz

Corduroy is used for saving gold in small Land large milling plants throughout the world. Investigations by the Metallurgical Division of the Bureau of Mine indicate that corduroy blankets, used with or without a trap or jig in the mill classifier circuit, often are effective in concentrating gold and sulfides, especially if the gold does not amalgamate readily and if not enough sulfides are present to warrant the use of a shaking table, flotation cells, or cyanide plant. Most cold-mining countries include several or many small miner, that produce siliceous ores low in sulfides and gold, which can easily be amalgamated or caught in traps or jigs or on corduroy and shaking tables. At these mines the ore is crushed by stamps or bill mills, and the flow sheets include plates, flotation cells, and cyanide treatment, yet probably nearly as much of the pair minerals may be recovered by the less expensive plant. A well-known western maker of mine and mill equipment asserts, as the result of considerable observation of installed plants, that old and other valuable minerals should be caught as soon as they have been released by a mill, end recommends jigs to do this. A supplier of corduroy has informed us that at some mines this material is being replaced by jigs that catch gold as fine as 400-mesh. But for the small operator, inexpensive equipment such as a corduroy table may be better adapted and give a good recovery of gold and associated minerals.

Jan 1, 1939

By Sidney Katell

An estimated capital investment of $76,499,800 will be required for a plant designed and built to produce 90 million standard cubic feet per day (std.c.f.d.) of synthetic pipeline gas through Lurgi gasification of bituminous char. This investment figure does not include the pretreatment plant, the cost of which is assumed to be reflected in the cost of the char fed to the gasification system. Shift conversion, C02 removal, and methanation are required after gasification in the Lurgi unit to make a gas suitable for pipeline transmission. Capital investment data are based upon equipment costs, January 1959. Based on a 90-percent or 330-day operating year, the operating cost before profit and Federal taxes with the char price as a variable will amount to the following: [ ]

Jan 1, 1959

By Paul M. Tyler

Graphite is chemically identical with diamond, both being crystallized allotropic forms of carbon. Graphite obviously differs greatly from diamond in physical properties and is easily recognized by its blackness, its softness (1 to 2 on Mohs' scale), and its slick feel when rubbed between the fingers. Strictly speaking, all graphite is crystalline, but grades in which the individual grains cannot be distinguished with the naked eye are commercially classed as amorphous. Natural mixtures of the two varieties occur in all proportions, and the classification of a given sample as "amorphous" or "crystalline" graphite is based largely upon trade practice. Until recently different varieties of vegetable or animal charcoal, lamp black, soot, gas carbon, and coal ware considered strictly amorphous, but modern examination by X-ray methods indicates that even these materials possess the same internal crystalline structure as graphite, differences in physical properties being perhaps explained by porosity or presence of combined hydrogen or other impurities.

Jan 1, 1941

By Stephen Utter

This report summarizes the procedure and results of an investigation to determine the stresses in the rock around an underground opening in the Climax molybdenum mine, Climax, Colo. This study is part of an overall investigation conducted by the Bureau of Mines to determine the stresses induced by block-caving mining. The purpose of this study is to obtain estimates of the magnitudes and directions of the principal stresses, the location of the maximum stress concentrations, and the effect of topography on the stresses.

Jan 1, 1962