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By Stephen D. Cramer

The solubility of methane, carbon dioxide, and oxygen was measured in brines at temperatures from 0° to 300° as part of Federal Bureau of Mines research on the corrosion of metals in high-temperature geothermal and mineral processing environments. Solubilities were measured by the technique of extracting pure gas, dissolved at pressures where Henry's law was applicable, from known volumes of brine. The results were smoothed with respect to temperature. The solubility, expressed in terms of the Henry's law constant, reaches a maximum at temperatures ranging from 60° to 100° C for methane and oxygen, and from 160° to 170° C for carbon dioxide. The Henry's law constant increases, that is, gases are salted out of the brines, in the presence of dissolved salts. Salting-out coefficients are strongly dependent upon temperature. The temperature dependence of the Henry's law constant for geothermal brines is different from that for sodium chloride brines owing to the more complex chemistry of the geothermal brines. The solubility of oxygen and carbon dioxide in brines exposed to air saturated with water vapor and at a total pressure of 760 mm Hg is reported for temperatures from 0° C to the normal boiling point.

Jan 1, 1982

By John Ward Smith

Methods for estimating the amounts of nahcolite, dawsonite, and the sum of these two sodium carbonate minerals from oil-yield assay data are developed and evaluated for Green River Formation oil shales from the saline section of Colorado's Piceance Creek Basin. Derived statistically, these estimation methods depend on the fact that these minerals yield water and gas measured during oil-yield assay. The estimation procedures yield values for nahcolite and nahcolite-plus-dawsonite of sufficient accuracy for stratigraphic plotting and correlation, whereas estimates for dawsonite are more generalized. However, resource estimates and reserve computations for both nahcolite and dawsonite accurate within 10 percent of the real value are readily available by summing the mineral amounts calculated by the procedures presented. These estimation procedures are applicable to oil-yield assay data on core samples from more than 30 coreholes which have penetrated the saline section of the Green River Formation in Colorado.

Jan 1, 1972

By Robert W. Gordon

This report describes the results and conclusions of the further development of a lightweight probe drill for use in anthracite mines. Improvements to the drill previously developed under Contract H0282044 were made and tested at an Eastern Pennsylvania mine. These improvements were: 1. Better hole cleaning due to the development of an air-water mist flushing system. 2. The application of roof drill bits to allow drilling through rock seams and lenses. 3. The development of a quick coupling drill system which reduced total steel change time. 4. Adaptation of a swivel to the drill anchoring system which greatly reduced set-up time between holes. With these improvements the probe drill demonstrated its ability to drill the required 11 holes in one shift. It also gained miner acceptance as a viable underground working tool. The probe drill proved to meet all of the design requirements of portability, low weight drilling controllability, structural integrity and reliability. In addition to its ability to drill the required probe pattern, the probe drill has the capability of drilling long holes. By drilling several holes over 80 feet deep the probe drill has demonstrated a potential for use in robbing pillars and for methane drainage.

Jan 1, 1981

By S. J. Broderick

"INTRODUCTION Dark soils are commonly believed to be better for agricultural purposes than light-color soils. Much of this feeling may be purely psychological, as many persons have unconsciously acquired the habit of associating richness of soil with color light soils, however, may be just as rich in humus and plant foods as the best of the dark soils. A dis-cussion of the manifold attributes that play an important role in soil technology is beyond the scope of this paper, but the color factor will be considered, as it has a particular bearing on some field experiments using coal-mine waste as a darkening medium.It has been established that dark soils absorb more of the sun's radiation, consequently are maintained at a higher temperature than light soils. This physical principle is applied in our daily lives in the choice of clothing. White clotnes in summer are cooler than dark ones. Conversely, dark clothes in winter are warmer than light-color clothing. A decided advantage of dark soils over light soils is the higher average temperature of the former, resulting in an earlier maturing crop. This advance of the maturing season may range from a few days to a month, depending on such factors as climate, crop, and degree of color of the soil. It has been reported that in parts of Russia where the growing season is short, perhaps comparable to that in Pennsylvania and. New York, cotton has been grown successfully on soils originally of light color, but darkened with coal, dusts. The growth of cotton is, accordingly, speeded up a full month. 3/"

May 1, 1940

By D. A. Doughty

The Bureau of Mines developed two methods for determining iron II and iron III in 2- to 5-mg samples of coal using electron paramagnetic resonance (EPR) spectrometry. One method used solid coal samples; the other method used aqueous solutions. The method using solid samples was more simple, technically, but required the use of X-ray fluorescent analysis, or another independent method, for determining total iron in the samples, and the results were subject to some uncertainty. The method using aqueous solutions appeared capable of greater certainty and did not require additional methods of total iron analysis but was more involved procedurally. The coals analyzed were found to contain much more iron II than iron III.

Jan 1, 1973

By William J. Campbell

The Federal Bureau of Mines provided five test materials--amosite, short-and long-fiber chrysotile, crocidolite, and nonfibrous tremo1ite--to the National Institute of Environmental Health Sciences (NIEHS) for studies on the biological effects of orally ingested asbestos-related materials. An inter-agency agreement between the Bureau and NIEHS made possible this program to characterize these test materials. The Bureau in turn received support through contracts with the Ontario Research Foundation for the milling of amosite and crocidolite, and with the University of Maryland for microscopic measurements. The five test materials, which were supplied in quantities of 960 to 1,200 pounds each, were characterized by chemical-instrumental analysis for elemental composition, surface area, density, X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, mineralogy, and particle size analyses. Particle size distributions were emphasized because of the current theories relating adverse biological effects to length-width characteristics of durable elongated particles.

Jan 1, 1980

By Lucia Kuizon

In 1986 and 1987, at the request of the U.S. Forest Service, the U.S. Bureau of Mines studied the Diamond Peak area comprising 183,000 acres in the Challis and Targhee National Forests in order to evaluate its identified mineral resources. More than 3,000 mining claims were located in three mining districts between the years 1882 and 1986. Approximately 230 mining claims in and the 150 claims adjacent to the study area were current in 1986, when Bureau of Land Management mining records were researched for this study. A total of 1,270 samples were collected from these sites (30 were for alluvial placer). Results of the investigation help determine the suitability of the study area for inclusion into the National Wilderness Preservation System. Lead-, silver-, zinc-, copper-, and gold-bearing minerals occur as veins and replacement bodies in shear and fault zones in Precambrian and Paleozoic calcareous Sedimentary rocks that have been complexly folded and faulted. Total production from the three mining districts in the study area was more than 150,000 tons of ore between 1901 and 1982. Approximately 11,600 tons of subeconomic resources consisting of lead, silver, zinc and copper were identified within the area. Over 37,500 tons of lead and zinc subeconomic resources were identified just outside the area. In addition, lead-, silver-, and zinc-mineral resources were identified at 4 mines within 2 miles of the study area. Iron mineral resources were also identified just outside the area.

Jan 1, 1991

By Louis A. Panek

Tests of mine-roof models in a centrifuge show that the suspension effect due to bolting a horizontally bedded mine roof with frictionless surfaces of contact between beds depends principally on the number of bolted beds and their relative flexural rigidities, provided that sufficient bolt tension is exerted to prevent strata separations at the bolt locations. Strata separations tend to occur in the unbolted roof mainly because the beds have unequal thicknesses. "Suspension effect" refers to the transfer of part of the weight of weaker or thinner beds to the flexurally more rigid beds by roof bolts or by any other means. The factors investigated were number of beds in the bolted unit, bed thickness, modulus of elasticity of beds, length of bolts, spacing of bolts across and along the opening, bolt load, and intensity of roof load. The general principles of behavior of the bolted roof beds are explained by an approximate theory. Model test data are used to validate the theory and to obtain an expression for the "suspension efficiency". As the suspension effect actually observed in the models is smaller than that predicted by the approximate theory, the suspension efficiency in general is less than unity. Mathematical expressions are obtained for (1) the change in roof bending stress due to the suspension effect, which is needed for design of a roof-bolting system, (2) the change of roof deflection due to the suspension effect, which may be useful for evaluating the effectiveness of a roof-bolting system, and (3) the bolt load or pre-load that is required to achieve the desired reinforcing effect.

Jan 1, 1962

In the United States water pollution resulting from mining activities has long been recognized as a major environmental problem Mine drainage pollution results from many types of mining activities and includes both physical (i e , sedimentation) and chemical (i e , acidification, metal contamination, etc ) pollutants Active and abandoned surface and underground mines, mineral processing plants, mine and processing plant waste disposal areas, haulage roads, and tailing ponds are typical sources of mine related water pollution (130) One of the most serious pollution problems arising from mining activities is acid mine drainage resulting from the chemical reaction of sulfide minerals (commonly iron sulfides) and air in the presence of water Acid mine drainage is commonly associated with coal and hard rock mining areas in the United States In general the more serious and extensive acid mine drainage problems exist in the more humid coal regions east of the Mississippi River (11) In 1964 the U S Department of the Interior, Fish and Wildlife Service, reported that acid mine drainage adversely affected fish and wildlife habitat in 9,477 kilometers (5,890 miles) of streams and 6,062 hectares (14,967 acres) of impoundments in 20 states in the United States (64) Of the total affected waters, coal mining operations accounted for 97 percent of the acid mine drainage pollution reported for streams and 93 percent of that reported for impoundments In 1970 more than 19,308 kilometers (12,000 miles) of streams in the United States were reportedly significantly degraded by mining related pollution (130) Of the total affected kilometers, 16,920 kilometers (10,516 miles) or approximately 88 percent were located in the Appalachian coal region (Pennsylvania, West Virginia, Ohio, eastern Kentucky, Tennessee, Maryland, and Alabama) In addition, more than 965 kilometers (600 miles) of streams reportedly were degraded by coal mining in states in the Illinois, Western Interior, and Rocky Mountain coal regions The remaining portion of the stream pollution resulted from the mining of (1) copper (california, Montana, Nevada, New Hampshire, Tennessee, Virginia, and Wyoming), (2) lead and zinc (Colorado, Idaho, Kansas, Missouri, Montana, Oklahoma, and Tennessee), (3) uranium (Rocky Mountain States), (4) iron (Lake Superior iron region), (5) sand and gravel (all states), (6) phosphate (Florida and other states), (7) gold (Alaska), (8) bauxite and barite (Arkansas), and (9) molybdenum, gold, and other metals (Colorado) Abandoned mines and abandoned mine waste disposal areas contribute a large portion of the total pollution resulting from mining activities Numerous abandoned underground mines are located throughout the United States and many are discharging mine drainage pollutants In 1966 the U S Bureau of Mines estimated that more than 88,000 inactive and abandoned underground mines were in existance (126) A listing of these mines by state is presented in Table 1 0-1 More recent estimates indicate that this list is incomplete In Colorado alone there is

Jan 1, 1975

By Robert E. Wood

[The temperature dependency of the low-density thermal conductivity coefficients, ?°T, of nitrogen, 100° to 1,200° K, is correlated with the Keyes' equation, ?T ½ -1 -12/T) WT = aT+ bT 10 The equation ?T,P = ?°T +a[ ]ß represented 509 experimental higher V pressure thermal conductivities in the temperature range 131.2° to 973.15° K for pressures to 500 atmospheres, with a mean absolute deviation of 2.35 percent. This equation was used to compute thermal conductivities of gaseous nitrogen for 47 pressures, 1 to 240 atmospheres, and 110 temperatures, 133° to 740° K, which are common to conditions encountered in Bureau of Mines helium purification processes. Isobaric heat capacities, CP, and viscosities, ?T,P, from previous work were combined with the present thermal conductivities, ?T,P, to compute Prandl1 numbers, C?T P / ?T ,P, of nitrogen. Tabular values of Prandtl num¬bers are presented for 49 pressures, 1 to 240 atmospheres, and 75 temperatures, 133° to 740° K. Estimated uncertainties are ±5 percent in the tabulated thermal conductivities and ±15 percent for the computed Prandtl numbers. However, the uncertainty may rise to ±10 percent for thermal conductivities and to ±30 percent for Prandtl numbers as the critical conditions of nitrogen are approached.]

Jan 1, 1971

By W. S. Landers

In contrast to the large fund of information available on the carbonizing properties of Eastern U.S. coals, the experimental data available for most Western U.S. and foreign coals are meager. To supply some self-consistent data, the Bureau of Mines conducted 220 low-temperature carbonization assay tests at 500° C. in a laboratory-scale carbonization apparatus. The results are included in this report. The U.S. coals tested are from Alaska, Arizona, Colorado, Illinois, Montana, New Mexico, North Dakota, Pennsylvania, Ohio, Texas, Utah, and Wyoming. Assays were also made on coals from Canada, Ecuador, France, Greece, India, Mexico, the Philippine Islands, Thailand, and Yugoslavia. In addition, one assay of pine sawdust and one assay of a peat from Ireland are reported. Prediction equations were developed relating the yield of products of carbonization obtained at 500° C. in the assay unit to the proximate and ultimate analyses of the coals. The equations for predicting the yields of tar plus light oil, char, and gas, and the heating value of the gas, are considered good, each equation having a multiple correlation coefficient of 0.90 or higher. The equation predicting volume of gas obtained upon carbonization is considered as fair, with a multiple correlation coefficient of 0.84. A reproducibility study of the assay made on 10 replicate samples of a subbituminous coal indicated that the standard deviation of the individual products was 0.31 percent or less.

Jan 1, 1961

By A. J. Kraemer

The Bureau of Mines for a number of years has been carrying on an investigation of properties of crude oils from producing fields in the United States and has published a series of reports on different fields, including oil fields of Texas3. Production Data The Spindletop field was discovered in 1901 when the pay sand was found at deaths of about 800 feet. During the following twenty-five years a number of attempts were made to find a deep productive sand. All attempts sere failures until a roll drilled by the Yount Lee Oil Company found oil late in 1925. An intensive drilling campaign began at once, and the production of the Spindletop field increased to a daily average of 93,217 barrels in September, 1926; the present production is estimated at 66,000 barrels doily. Tile following table taken from the Oil and Gas Journal for February 10, 1927, shows the daily average and the total production by ninths for 1926.

Jan 1, 1927

By Eric B. Sansone

The Federal Coal Mine Health and Safety Act of 1969 requires coal mine operators to sample accurately the amount of respirable dust in the mine atmosphere. A technique approved for such sampling employs a 10 mm nylon cyclone followed by a membrane filter (nominal pore size ????= 5 µm) and a pump. The pump is required to provide a flow rate of 2.0 ± 0.1 liters per minute. Calibrations have yielded a range of flow rates (1.4 to 2.8 1pm) at which the cyclone should be operated to remove the non-respirable portion of the dust. The purpose of this project was to evaluate the performance of the 10 mm nylon cyclone at flow rates of 1.8 and 2.0 1pm using a polydisperse coal dust aerosol. The penetration characteristics of the cyclone were to be compared to the United States Atomic Energy Commission's respirable dust standard. The effect of relative humidity on cyclone penetration characteristics was also to be observed.

Jan 1, 1973

By C. W. Smith

The Bureau of Mines conducted laboratory-scale beneficiation tests on a sample of corundum gneiss from Montana to devise a method for beneficiating corundum for use as a substitute for refractory-grade bauxite. A flotation process utilizing petroleum sulfonate as the collector in an acid circuit was devised. Results showed that two flotation schemes each produced a concentrate exceeding the national stockpile specifications for calcined bauxite. From a feed containing 28 pct corundum concentrates containing up to 92.5 pct alumina (A1203) were produced with a corundum recovery of 78.5 pct.

Jan 1, 1987

By A. B. Coates

During the last three years the use of ethylene glycol dinitrate4 (E.G.D.) as at low-freeze (L.F.) agent in place of nitropolyglycerin has become common in the manufacture of explosives of the dynamite type. The usual proportion of D. G. D. in the explosive "oil" is 25 per cent; the remainder, 75 per cant, is regular nitroglycerin. These proportions were probably selected as a continuation of the practice of 25 per cent nitropolyglycerin and 75 per cent regular nitroglycerin.

Jan 1, 1929

By Jeffrey Shawn Peterson

The testing procedures of the U.S. Mine Safety and Health Administration specify that intrinsic safety acceptance tests be conducted using a standard tungsten-cadmium electrode configuration in the break- flash apparatus. However, in realistic mining environments, other materials may be more likely sources of sparking. Information defining the probability of spark ignition between common materials such as aluminum, brass, copper, lead, tin, cold-rolled steel, and stainless steel is of more practical value in determining ignition hazards. The U.S. Bureau of Mines has completed an investigation of the influence of material on the ignition probability using the breakflash apparatus. By comparing ignition currents or ignition voltages corresponding to a probability of one ignition per thousand sparks to those found previously for cadmium, a margin of safety may be estimated for each material. This report presents the results of an investigation into the influence of disk electrode material on the probability of ignition.

Jan 1, 1992

By J. G. Stuart, A. W. Cipkins, R. H. Thompson

Preliminary safe distances for blasting wiring from typical electromagnetic sources are presented. The distances are for underground coal mines and electromagnetic sources in the frequency range below 10 MHz. The distances are based on measurements performed at 3 locations in each of 3 coal mines. The measurement apparatus, measurement procedure, measurement results and the rationale used in the calculation of the safe distances are all described. The safe distances presented are dependent on the measurement results and their interpretation. More measurements are clearly necessary to establish the validity of the suggested distances.

Jan 1, 1985

By W. E. Dennis

"INTRODUCTION The strategic importance of zinc warranted investigation of the Silver Eagle zinc prospect, which was first examined by an engineer 3/ of the Bureau of Mines in January 1943.From October 12, 1943, to March 16, 1944, the Bureau explored the deposit by trenching, core drilling, and sampling to establish the amount and grade of ore and to test for the presence of sulfide-ore minerals at depth.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director."

Oct 1, 1946

By I. O. Salyer

This research was conducted with the objective of suppressing the respirable dust in coal mines by foam application. A formulation was developed for making a water-based, high-expansion, and limited stability foam. A horizontal boring machine was used as a laboratory coal mining model for generating coal dust. A modified laboratory foam generator was built. Foam was applied directly to the point at which dust was being formed by the cutter of the boring machine working against a block of coal. Coal dust was sampled with an impinger and analyzed for the particle count and particle size distribution. Coal dust suppression test results on freshly generated dust have demonstrated very clearly that in laboratory scale experiments over 90% of the respirable coal dust can be suppressed by foam. These tests were run when initial coal du t concentrations were 10 and 70 million particles per cubic foot (mppcf).

Jan 1, 1970

By B. H. Eccleston

Experimental data were obtained from two medium-duty diesel engines derated to qualify for use in underground mines. Gaseous and particulate emissions from these engines were measured and results provide information on the effect of exhaust treatment devices on the emissions. The devices in the study were a catalyst, a particulate trap, and an exhaust gas cooler of the water scrubber type. Emission levels of carbon monoxide and hydrocarbons were observed to be very low in comparison with emission levels of comparable engines in full-rated operation. Oxides of nitrogen and benzo(a)pyrene content of the exhaust also were found to be somewhat low in comparison with previous findings. For particulate reduction, the combination of a particulate trap and a scrubber was observed to be the most effective combination tried; in some cases, over 60 pct particulate reduction was effected by the trap-scrubber combination.

Jan 1, 1981