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By G. S. Scott

The Bureau of Mines is engaged in research to assess the hazards associated with the handling, storage, and use of combustible gases, vapors, and. liquids encountered in mines and in industry. As a part of this general pro-gram, numerous limits of flammability and ignition temperatures are being investigated for a wide variety of combustible materials, and methods are being developed to minimize the explosion hazards of these combustibles. The Bureau receives numerous requests for information on the explosion hazards of specified combustible mixtures under various conditions of use. This information circular has been prepared to assist those who may have similar requests. Destined primarily for the layman with a limited technical knowledge of the subject, it considers rather briefly the numerous factors that enter into the general problem of gaseous explosions and their prevention.

Jan 1, 1951

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf as a function of temperature are given in tabular form. Thermodynamic data were compiled for VOSO4, Cr2(SO4)3, MnSO4, FeSO4, Fe2(SO4)3, CoSO4, NiSO4, Cu2SO4, CuSO4, CuO-CuSO4, ZnSO4, and ZnO-2ZnSO4, together with their stable hydrates.

Jan 1, 1982

By Jr. Hill

Laboratory metallurgical treatments of three high-iron bauxite ores from Arkansas were conducted to determine the relative effectiveness of experimental methods for recovering alumina and a commercially acceptable iron concentrate. The standard for evaluating recoveries from experimental processes was the Al2O3 recovery from Bayer digests of the crude ores; recoveries from digestion of the three ores were 74.1, 87.4, and 88.7 percent. Flotation, magnetic separation, or various combinations of digestion, calcination, and reduction-sintering, leaching, and magnetic separation of leach residues failed to produce Al2O3 recoveries as high as the standard. A high-iron-bearing fraction, containing between 68 and 78 percent of the total iron, was produced in a three-phase treatment involving a caustic, lime reduction-sinter of the crude ore, water extraction of Al2O3 from the sinter, and magnetic separation of the leach residue.

Jan 1, 1967

By R. L. Brown, H. G. Berger, E. F. Pohlman

"The Bureau of Mines in cooperation with the American Gas Association investigating the relation of properties of gas oils to the gum-forming properties of carbureted water gas. The present report deals with the effects of operating practice on the composition of the light oils from carbureted water gas. A general outline of the gummy meter problem has been presented in a previous paper.*Carbureted water gas is a mixture roughly of 80 per cent water gas by volume and 20 per cent oil gas. The latter, though small in relative volume, supplies more than half of the heating value of the gas under the present-day standard. Therefore, it is logical that the oil used in the carbureting process and the operating practices involved should be subjected to scientific study. Many investigations***** bearing on the aspects considered in this paper have been carried out in the past."

Oct 1, 1923

By Seth C. Schaefer

The Bureau of Mines studied thermodynamic properties of liquid Al-Si alloys with the high-temperature galvanic cell Al(1)//Al+3(AlC13 in NaCl?KCl)//Al-Si alloy(1). Activities of aluminum and silicon (referred to pure liquid metals) show a pronounced negative deviation from Raoult's law in liquid Al-Si alloys containing 0.9 to 35.2 atomic-percent silicon. Activity coefficients and the properties [?Gi, ?GxS ,?H, ?G, ?Gxs , and ?S] have been derived from the experimental data and are summarized in tables and illustrations.

Jan 1, 1974

By Michael G. Zabetakis

Investigation of gas explosions usually reveals that the combustible gases have come from transmission and storage facilities or from natural gas or oil wells. However, combustible gases such as methane and hydrogen can derive from biological processes. Hazardous situations have been created in the past by the use of abandoned mines for the disposal of sewage and rainwater, by the interconnection of storm and sanitary sewers, by sealing the openings in manhole covers when repaving the roadway over a sanitary sewer, and by the construction of buildings over or near garbage fill areas without adequately providing for the release of combustible gases.

Jan 1, 1962

By W. D. Mcmillan

The Dempsey tract in Washington County, Mo., had a small production of lead-zinc ore from shallow workings. Old dumps from early-day lead mining contain about 25,000 tons of ore averaging about 3 percent combined zinc and lead. Because of the urgent war requirements for lead and zinc, the Dempsey property was examined by Otto Ruhl, formerly an engineer of the Bureau of Mines in August 1942 and selected for further investigation by churn drilling twenty holes totaling 1,309 feet were bored in the fall of 1943. The results of the work are presented in this paper.

Jan 1, 1948

By D. Harrington

Notwithstanding all the effort maa.e to introduce wet drills to prevent dustiness of air of metal-mine workint;s pl2.ces, there has during the pa.st few years arisen in Australia and South Africa an impression that wet drills, in­cluding the Leyner typa, actuali"y cause und..ue quantities of finely divided ore and rock to rise into the air, these fine particles being chiefly attached to · P=i-rticles of fog or spray escc:.ping frow holes using water drills. This fs saia. to have created consternation in the ranks of the min operators who have com­piiei With drastic wet dri llin rf,ubtions, 2nc:i. purchased and operateC1. various types of wet drills at no inconsiderable expeniiture in both money and effort.

Mar 1, 1922

By L. F. Christianson

The presence of salt in crude petroleum has been known for many years, but recently the percentage of chloride salts of calcium, magnesium, and sodium produced with some crude oils has increased to such an extent that the removal of the salty compounds is imperative for some refiners and their presence causes considerable apprehension for others. The exact reason for this increase of salts is not known definitely, but in all probability a combination of factors contributes to the condition. The most important are acidizing of wells, development of new fields producing crude oils of greater salt content, and the depletion of old fields with an attending increase in the production of emulsified brine. Due to handling

Jan 1, 1938

By L. F. Christianson

The presence of salt in crude petroleum has been known for many years, but recently the percentage of chloride salts of calcium, magnesium, and sodium produced with some crude oils has increased to such an extent that the removal of the salty compounds is imperative for some refiners and their presence causes considerable apprehension for others. The exact reason for this increase of salts is not known definitely, but in all probability a combination of factors contributes to the condition. The most important are acidizing of wells, development of new fields producing crude oils of greater salt content, and the depletion of old fields with an attending increase in the production of emulsified brine. Due to handling

Jan 1, 1938

By V. J. Lynch, A. L. Peyton

"INTRODUCTION AND SUMMARYThe Brewer mine, near Jefferson, Chesterfield County, S.C., was originally operated as a gold mines as late as 1890 this mine was reported to have been one of the large gold producers in the southeast,Occurrence of topaz on the Brewer property was not reported until 1935, when it was discovered by Pardee and Parks. 3/ of the Federal Geological Survey while they were investigating gold deposits in the Piedmont province.During the 1940's the Chemical Engineering Branch of the Tennessee Valley Authority and the Electrotecbnical Laboratory of the Bureau of Mines at Norris, Tenn., investigated topaz from the Brewer mine to determine the possibilities of its use as mullite and for the production of calcium fluoride.From July 1950 through. April 1951 the Bureau of Mines conducted a diamond-drilling project at the Brewer mine to determine the grade and extent of the topaz deposits. Ten diamond-drill holes, totaling 2,344 feet, were completed, and 231 analyses of core samples were made during the course of the project.This report presents factual data relating only to the diamond-drilling project, The placer deposits on the Brewer property were previously investigated by the Federal Geological Survey 4/."

Aug 1, 1953

By R. J. Pokora

This Bureau of Mines report is an applications manual that can be used by the nonmetallic mining industry for guidance in installing noise control materials into crushing and screening plants. These noise control modifications were installed and successfully tested at three operating quarries. This report identifies the major noise sources that can be encountered in crushing and screening plants, and discusses the applicable noise control materials and techniques that a plant operator can utilize on a retrofit basis to reduce equipment noise.

Jan 1, 1984

By Oliver Bowles

"Asbestos" is not the name of a distinct mineral species but is rather a commercial term applied to fibrous varieties of several minerals. The origin and significance of names applied to asbestos by early writers are discussed in the section devoted to sources of supply and terms employed in ancient times. VARIETIES The most useful variety of asbestos is chrysotile, a fibrous serpentine the composition of which is expressed by the formula H4Mg3Si209. Chrysotile is characterized by a strength and flexibility that permit the use of the longer fibers for spinning. The bulk of the world production of both long and short fibers, is of this variety.

Jan 1, 1935

By H. M. Lavender

This paper describing the inclined cut-and-fill, and the semishrinkage methods of mining at the Campbell mine of the Calumet and Arizona Mining Co. at Warren, Ariz., is one of a series being prepared by the United States Bureau of fines on mining methods, practices and costs in the various mining districts in the United States. The major portion of the production from the Bisbee mines of the company is mined by these methods. The total average yearly production for the last two years has been 493,612 tons of 5 per cent copper ore. The average employment in the mining department eras 940 men. With the exception of a small tonnage mined for the high iron and sulphur content, the ore is direct-smelting and is mined for its copper con¬tent and associated gold and silver values.

Jan 1, 1930

By W. K. Overbey

Surface fracture trace density, changes in roof rock type, and topographic unloading due to drainage were mapped for the mining areas located in the Blacksville-Osage, W. Va., quadrangles to investigate their influence on mine roof falls. Using these factors, a technique was developed to predict probable roof fall areas ahead of projected mining operations. As a feasibility test of this proposed technique, areas were delineated where one, two, and all three of these factors were operating to formulate a "potential hazard map" for comparison with roof fall observations that were made. The limited evidence suggests that in combination these factors are reliable predictors of where roof falls are likely to occur. This technique promises to be a useful tool in planning mining operations.

Jan 1, 1973

By John O. Atkins

[Experiments were conducted by the Bureau of Mines on five types of simuated lunar rock (dacite, tholeiitic basalt, vesicular basalt, pumice, and uluth Gabbro) to study the effects of various simulated lunar environments n their strength and deformational properties. Specimens were tested in an ltrahigh vacuum (UHV) system at pressures ranging from atmospheric down to 0-11 torr and at temperatures of -130°, 20°, and 135° C. All tests were onducted with a servocontrolled testing machine. Rock specimens tested at 0° C in UHV exhibited significantly higher compressive strength and Young's odulus than those tested at 20° C in atmospheric pressure. The magnitudes f increase are related to the porosities and permeabilities of the rock pecimens; high porosity and permeability allow better outgassing and thus nprove surface cleanliness in UHV. The compressive strength generally ncreases but Young's modulus decreases as test environments change from 20° C i UHV to 135° C in UHV. No significant difference was observed in the iysical properties measured at 20° C in LTV and -130° C in UHV. Anisotropy i strength and Young's modulus exist both in UHV and at atmospheric condi¬'.ons with the same symmetry pattern. The orientations of the principal axes iy, however, change from the atmospheric to UHV condition. The results idicate that rock fragmentation in lunar environment will require more ergy than that at 20° C in atomospheric pressure.]

Jan 1, 1974

By S. B. Levin

The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States and Alaska since 1939. During the fall of 1942, the Bureau of Mines put down nine diamond-drill holes at the Cape Rosier zinc-copper-lead mine in Hancock County, Maine, that aggregated 2,883 feet of bore. These holes supplemented 13 holes, aggregating. 5,501 feet, put down on the property about 2 years earlier by the St. Joseph Lead Co. Veins of mixed sulfides were intersected in 15 of the holes drilled. Beneficiation tests were made on samples of ore obtained from old dumps. Zinc-copper-lead sulfides occur at the Cape Rosier mine as lenses in a zone of altered agglomerate beneath and between a series of diorite sills. The mineralized zone strikes F. 17° E. and dips southeast. Between July 1881 and September 1883 the mine produced about 10,000 tons of ore reported to have contained 20 percent zinc, 2.8 percent copper, and some lead. The crude ore was hand-sorted, and some. 3,000 tons were reported shipped.

Jan 1, 1948

By D. A. Larson

This is the second in a series of Bureau of Mines reports which de-scribe experiments designed to devise an efficient, economic mechanical fragmentation technique for hard rock. The previous study described the development of the ripper cutting technique to successfully cut hard rock with 3-to 6-in-wide drag cutters. This study was conducted to test the ripper cutting technique at full scale using 9-in-wide drag cutters. The experiments were conducted with a special test device that cut shallow, 6-by 6-ft openings in 9,200-lbf/in2 compressive-strength concrete blocks. The tests showed that ripper cutting can excavate large-scale openings of the type required by the mining industry at a production rate that outperforms the conventional drill-blast technique. Moreover, the system can produce openings of various sizes and shapes, is simple to oper-ate and maintain, and produces very little dust or noise during operation. The system appears to meet all of the criteria for a successful hard-rock mining machine.

Jan 1, 1987

By R. H. Lien

The Bureau of Mines developed a flue gas desulfurization process as part of its goal of minimizing the undesirable environmental impacts associated with energy and mineral-processing plants. The modified citrate process involves absorption of sulfur dioxide (S02) in a buffered citric acid solution. The S02-loaded solution is regenerated by countercurrent contact with steam in a packed tower. The wet S02 product is then dried and can be liquefied or further processed to make sulfuric acid. Test data from process investigation unit studies are presented. Material balances, flowsheets, and cost estimates are given for recovering S02 from copper smelter reverberatory gas, lead smelter sintering machine tail gas, and power-plant stack gas. Operating cost estimates show the process will add $0.04 per pound of copper, $0.01 per pound of lead, and $0.015 per kwhr to the cost of the respective operations. These costs could be substantially reduced if a source of waste heat was avail-able to provide the process steam requirements.

Jan 1, 1982

By F. J. Wiebelt

Production of small tonnages of asbestos has been reported from 18 California counties; 16 additional counties have occurrences of asbestos. The counties in the northern part of California that have had a recorded production are: Alameda, Amador, Calaveras, Contra Costa, E1 Dorado, Napa, Nevada, Placer, Shasta, Siskiyou, Trinity, and Tuolumne. No deposit in the State has maintained consistent production. Serpentinized peridotites (potential chrysotile-bearing rocks) are widely distributed in the coast ranges, Klamath Mountains, and western foothills of the Sierra Nevada.

Jan 1, 1958