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By N. D. Ilankoon

"The use of thiosulfate as an alternative lixiviant for cyanide to treat complex refractory ores followed by the use of ion exchange resins (IX resins) for gold recovery has become an industrial reality. In this study, polyethylenimine (PEI) coated iron oxide magnetic nanoparticles (MNPs) were used to recover gold from the leaching solutions that consist of calcium thiosulfate, copper and gold. The gold loaded MNPs were easily separated from the solution using an external magnetic field. Proposing a novel adsorbent with characteristically easy solid-liquid separation, to recover gold from synthetic thiosulfate leaching solutions and gold elution and reuse of MNPs were the main objectives of this study. Adsorption isotherm studies revealed that the data fitted both Langmuir and Freundlich isotherm models equally well. The maximum adsorption capacity was 18.5 mg/g at pH 8 and 50?C. According to thermodynamic studies the physisorption process was exothermic and spontaneous. Gold and copper elution, and the regeneration and reuse of the nanoparticles were investigated and promising results were obtained. Different elution systems comprising sulfites, chlorides, glycine, EDTA (ethylenediaminetetraacetic acid) and sodium hydroxide were considered. Among them, EDTA for copper elution and NaOH for gold elution were the most efficient eluants. Regeneration and reuse studies revealed that the MNPs can be used for several cycles without significant performance loss. INTRODUCTION Although cyanidation has been used for gold leaching for more than 100 years, some major drawbacks associated with cyanidation have led to a quest for alternative lixiviants for gold leaching. Cyanide is ineffective in treating carbonaceous refractory ores as gold cyanide complex is adsorbed onto the native carbon in the ore itself known as preg-robbing. On the other hand environmental concerns associated with cyanidation drives the need for environmental friendly alternatives for cyanide. As of today, thiosulfate is known to be the most extensively studied and most promising alternative lixiviant for cyanide in both technical and environmental perspectives (Aylmore and Muir 2001, Oraby 2009)."

Jan 1, 2018

By K. D’Elia, L. D. Ogrel, O. A. Malyshev, T. I. Yushina, I. M. Petrov

"The purpose of this research is to develop enhancements in the mineral processing by flotation methods of nonferrous ores. Currently, 180-190 million tons of ore are processed by flotation in Russia. The annual processing volume of copper-nickel and copper-zinc ores exceeds 20 million tons. In the total volume of processed ores by flotation, non-ferrous ores account for roughly 35% and ores of precious metals for another 15%. The total demand of flotation reagents in Russia in 2016 was estimated at 170,000 tons. Sulfur-based collectors used in the flotation of non-ferrous sulfide ores (typically, xanthates) do not always offer sufficiently high recovery of valuable components.It has been found that reagents like DMIPEC and DK-80 improve the recovery of metals into concentrates. To identify the reasons of that higher recovery, quantum chemical calculations of the mechanism and interaction forces of DMIPEC with non-ferrous sulfides were undertaken by determining the stabilization energy of the resulting chemical complexes. It has been shown that, in the interaction of DMIPEC and DK-80 with the surfaces of sulfide minerals, ethylene and acetylene bonds act as the reaction centers, and the formation of molecular p-complexes is the result of metal-cation interactions with the surface and the flotation reagents.In the flotation of non-ferrous ores, DMIPEC and DK-80 act as selective supplementary collectors with foaming properties, and at a flow rate of 3-35 g/ton, they reduce the flotation time, and increase copper recovery by up to 3.5%, zinc recovery by up to 12%, gold recovery by up to 8-10%, allowing to increase the recovery of valuable components by 1.5-12.0%, basically this kind of reagents nearly double the flotation rate, improve the grade of the concentrate, improve the stability of the flotation process parameters, and reduce the environmental impact of flotation plants."

Jan 1, 2018

By F. Q. Cheng

Despite the successful industrial practice to recovery KCl by flotation, the adsorption state of collectors at KCl salt surfaces is still not fully understood. In this paper, the captive bubble contact angle measurements at KCl and NaCl crystal surfaces in their saturated solutions are reported. The influence of different collectors and their concentration are considered. The results show that both cationic and anionic collectors produce a hydrophobic state at the structure breaking KCl salt sur-face, with finite contact angle values of between 30o and 40o. In contrast, the contact angle at the structure making NaCl salt surface is zero at all collector concentrations, suggesting that no collec-tor adsorption occurs, a supposition that is supported by results from molecular dynamics simulation (MDS). Further, it appears that the presence of surface defects such as edges and corners promote the adsorption of collectors at the KCl surface, and that the flotation is achieved by bubble attachment at the edges/corners of KCl particles with the formation of aeroflocs.

Jan 1, 2014

By Sepideh Javanshir

The process of liquid?liquid extraction of gold from chloride solution is complicated by the presence of many variables acting simultaneously in an unknown non-linear fashion for the determination of the final extraction efficiency. In practice, it is quite difficult to develop a model for predicting various properties of such process. Therefore, an alternative approach based on Artificial Neural Network (ANN) is considered to assist in the simulation process. Artificial neural networks (ANN) are powerful tools that can be used to model and investigate various highly complex and non-linear phenomena. This paper presents application of Multi-Layer Perceptions (MLP) to construct relationship that will be employed to develop a quantitative method for the estimation of the extraction efficiency as a function of hydrodynamical parameters such as stirrer speed, [AuCl4]- and DBC concentration, organic and aqueous flow rate. The model is shown to be in excellent agreement with the experimental data (R2 value for training and testing data was 0.9992 and 0.9915 respectively). Therefore, it can be used to optimize the parameters of liquid?liquid gold extraction with dibutyl carbitol (DBC).

Sep 1, 2012

By R. Singh

The present paper deals with the development of flotation based process for enrichment of a lead-zinc sulphide ore from Ganesh-Himal region of Nepal. Detailed characterisation and flotation studies were carried out under varying process conditions. The sample assayed 2.47% Pb with 13.6% Zn. The ore was predominantly made up of spahlerite and pyrite in association with subordinate amounts of galena, minor amounts of pyrrhotite and chalcopyrite. Dolomite was the main gangue. The modal analysis showed the probability of fair liberation of sulphides from gangues around 210 microns but the locking of galena with sphalerite and other sulphides continued to finer sizes. Under the optimum process conditions the rougher lead and zinc recoveries were 96.3% and 90% respectively. Multistage cleanings of rougher products proved helpful in improving the concentrate grade, meeting the required specification. Based on the studies undertake a process flow-sheet for the concentration of the ore to individual lead and zinc concentrates was developed.

Jan 1, 2014

A processing scheme is presented to use one single chemical that has multiple functions to re-duce the use of chemicals and achieve more efficient mineral flotation and solids dewatering. Sti mulisensitive polymers which display hydrophilic/hydrophobic transitions in response to changes in temperature or pH have been found to be useful as such multiple function reagents. They can cause the mineral particles to be either hydrophilic or hydrophobic at one stimuli condition and the opposite at the reverse stimuli condition. Therefore, both particle surface wettability and inter-particle interaction forces are reversibly controllable. When the surface is hydrophilic, particle dispersion is achieved by repulsive inter-particle forces whereas when the surface is hydrophobic, particle aggregation is induced by inter-particle hydrophobic attractive forces. In addition, the hydrophobic surface condition allows for the attachment of particles to bubbles. Flotation and solid settling tests have been conducted with a silica suspension treated with the temperature-sensitive polymer poly (N-isopropyl acrylamide) (PNIPAM). The results indicated that PNIPAM can be used to induce a transition between hydrophilic and hydrophobic surface character at temperature lower or higher than its critical solution temperature (CST around 32oC). Thus, both effective silica dispersion or hydrophobic aggregation and flotation without adding any additional collector have been demonstrated. In tailings treatment, rapid silica settling was obtained with hydrophobic aggregation at temperature above the CST and further sediment consolidation (and water release) occurred at temperature below the CST. Contact angle measurements confirmed the hydrophilic/hydrophobic transition induced by PNIPAM.

Jan 1, 2014

By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014

By M. Kinnunen

Handling of municipal solid waste (MSW) and control of its potential resources is becoming increasingly important in modern society. The OECD (Organization for Economic Co-operation and Development) average on municipal waste produced in 2003 was that of around 570 kg per inhabitant. In European Union countries around half amount is of MSW landfilled. In Finland still 88% of MSW was landfilled in 2004. Since incineration reduces MSW volume significantly while producing heat energy, it has become one of the most common waste handling techniques. The shortcoming of incineration is however, that incinerated MSW is often not pre-sorted and it produces slags and ashes as side streams from which recovery of metals is difficult. This paper looks into possibilities of scrap metal recovery for recycling from municipal solid waste incineration (MSWI) bottom ash. In order to do that, a flow sheet of physical separation methods was developed and tested with Finnish rotary furnace MSWI bottom ash. In addition, an empirical model for estimation of the recoveries of scrap metals with physical separation methods for treatment of MSWI bottom ash was developed. According to the results of this study, for 1 Mt of incinerated MSW with 30% mass reduction, a minimum resource potential of 100 kt for magnetic metal scrap of roughly 24 % grade and about 19 kt of non-magnetic metal scrap of roughly 65 % grade. In other words, 57 kg magnetic scrap and 12 kg non-magnetic scrap per inhabitant at the mentioned grades, respectively. Although wide variations of parameters affect the MSWI bottom ash quality, it can be said that a considerable amount of metals is drained into MSWI bottom ash. Results of this study show that from MSWI bottom ash significant material streams metal scrap can be reintroduced into the resource cycle which would otherwise be lost.

Jan 1, 2014

By Y. C. Liu

Arsenic bearing copper-gold ores deposit have been found in most areas of China, especially in southwest. Due to the very closed association between arsenic, copper and gold, conventional flotation and cyanide leaching process may not give positive results. An arsenic bearing copper-gold ore in Sichuan province ,with gold grade of 10.12 g/t, 0.6% Cu and 0.14% As, is characterized by superfine grains with -40 microns fraction accounting for 70.9% and the gold enwrapped mainly by pyrite and tennanite accounts for 34.31%. Arsenic in this ore occurs in isomorphism, deposited in tetrahedrite. The ore was processed primarily in two stage flotation to get copper bearing gold concentrate and pyrite bearing gold concentrate respectively, and sequentially processed by leaching. Under the pressure of 300 KPa and 110~115 ?, the copper-gold concentrate was leached by an oxidizing and catalyzing leach agent then copper and gold were separated from each other in leach solution. The pyrite bearing gold concentrate was processed by cyanide leaching with the leach residue as sulfur product. The test results showed that copper recovery was up to 88.89%, gold recovery up to 89.18% and sulfur recovery up to 92.64%.

Jan 1, 2014

By S. H. Morar

Froth flotation is a physico-chemical separation process that takes place in two phases; pulp and froth phase. It is widely recognised as a complex process, due to the range of interactions present within the system. Of critical importance is the role of the froth phase within the system. The pulp kinetics governs the maximum potential recovery within a flotation cell, while the froth phase governs the selectivity via the froth?s stability. Higher froth stability improves recovery at the expense of grade, and lower froth stability improves selectivity. It is well known that the two major factors affecting froth stability are attached particles and solution chemistry. This paper looks at a flotation bank at different froth depth and frother concentrations. The air recovery to the concentrate is determined at each condition and relates the effect of the operating conditions on froth stability and transport to the amount of solids that are recovered to the froth and concentrate by true flotation. The results presented show that, for a given process objective, which in this case was a consistent mass pull profile, depending on the operating conditions, solids recovery in the pulp is affected by the air rate required to maintain the target mass pull. To a smaller extent, the changes in the pulp composition affect down-stream pulp recovery. The variation in solids recovered into the froth drives the froth stability at the start of the flotation bank, while the frother drives the froth stability at the end of the bank. The performance in between these two extreme conditions arises from an interaction of these two effects. The consequences of these interactions can give rise to counter-intuitive responses that can confound efforts to optimise the performance of the bank.

Jan 1, 2014

By T. Damyanov

Spherical grinding media (balls) are the most widely used media for comminution of ores by grinding. A modelling simulation study of the behavior of two grinding media in the grinding process was conducted to determine the possible advantages of the new shape milling bodies called tetraballpebs. Tetraballpebs are in the shape of tetrahedrons with spherical convex walls. A three dimensional CAD model of the mill drum with a diameter of 1200 mm was used. A continuous operating mode was simulated in terms of the 3D contact elements of the model (milling bodies and mill drum). Simulation tests were carried out in a typical grinding mode and at a typical rotational speed of the drum mill (75 per cent of the critical speed in cataracting mode). Studies carried out with both grinding media include equal number of milling bodies with the same weight and volume. Having thus ensured a uniform mass of the grinding media and same number of milling bodies, and constant other conditions and process parameters, conclusions can be drawn about the influence of the shape of the milling bodies on the grinding process. A kinematic analysis of the system using CAE (computer-aided engineering) model parameterization was conducted. The controlled parameters are: ? Power draw; ? Kinetic energy of each milling body; ? Motion of milling bodies inside the drum Keywords: grinding, grinding simulation, balls, tetraballpebs, DEM, CAD-CAE

Sep 1, 2012

By P. Ying

An auxiliary system connected with SEM-EDX for rapid identification of mineral and rock sample has been developed. With the aid of a synthetic spectrum library created, using the compare and match techniques provided by INCA software in EDX the mineral or rock sample names for refer-ence can be given at the same time analyzed.

Jan 1, 2014

By G. S. Zeng

The mechanism of cobalt removal from zinc sulfate solution with zinc dust is still not understood well. The experiments in this paper were carried out by zinc dust from zinc sulfate solution with high cobalt to study the mechanism of cobalt removal. Residues after the cementation process from zinc sulfate solution were analyzed by SEM and Electron probe micro-analysis (EPMA) to investigate the morphology of products. Different temperature will cause different structure of particles. With the increasement of temperature, cobalt removal can be improved considerably. The mechanism of cobalt removal by zinc dust is thought as follows: firstly, the cobalt ion forms Co-Zn alloy with zinc particles, and the reaction reaches equilibrium quickly; secondly, the Co-Zn alloy continues reacting to Co with Co2+, which is the control procedure of the whole reaction.

Jan 1, 2014

Rotor speed is one of the key hydrodynamic parameters in froth-flotation and it plays an important role in bubble-particle attachment. Laboratory scale studies for optimizing the rotor speed to achieve maximum flotation rate constant (K) of quartz, ground by ball mill, are. Purity of quartz was 99.4 percent and d80 of ball mill product was 230 µm. Each size fraction was separately subjected to flotation at three different rotor speeds, namely, 1200, 1000 and 800 rpm, and the flotation rate constant was calculated. The results showed that the flotation rate constant was high at the rotor speed of 1200 rpm. The flotation rate constants achieved at 1200 rpm were 8.676, 8.232, 7.818, 7.248, 7.068 and 6.984 min-1forthesize fractions of +300, -300+250, -250+212, -180+150, -150+125 and -125+106 µm, respectively. Keywords: froth flotation, rotor speed, flotation rate constant, ball mill, quartz

Sep 1, 2012

By Y. Q. He

The dynamic behaviors of the air bubbles in the dense gas-solid fluidized bed have a significant effect on the performance of dry coal separation. The combined method of experimental measurement and numerical simulation were conducted to conduct the research of the mean diameters and rising velocities of the bubbles in the fluidized bed. The calculation models of mean diameter and rising velocity of the single bubble were proposed. The results indicate that the models of the mean diameter raised by Rowe (1976) and the rising velocity raised in this work could be used to predict the bubble dynamic parameters in gas-solid fluidized bed. With the Geldart B type of magnetite powder as the medium solids and while the gas velocity of 1.5Umf=U=2.2Umf, the mean bubble diameter along the bed height is 36mm<Db<45mm, and the mean rising velocity of the single bubble is distributed in 40~65cm/s. The results of experimental measurement, numerical simulation and model predication provide well agreements finally. Based on the uniform fluctuations of air bubbles diameters and their rising velocities, the separation experiments of 50~6mm dry coal using the mixture of 0.3~0.15mm magnetite powder and <1mm fine coal as medium solids were carried out. The results show that the probable error, E is 0.06, which indicates a good separation performance by using the gas-solid fluidized bed. Keywords: dense gas-solid fluidized bed, bubble dynamic behaviors, numerical simulation, separation performance

Sep 1, 2012

By M. Surracco, M. C. Tilocca

"Mineral comminution is often a costly process which also requires high level of energy. In the course of the studies carried out by the researchers of the Department of Civil-Environmental Engineering and Architecture at the University of Cagliari, aiming at the optimization of the reduction processes, it has been experimented, among of others, the effects of high-speed water jets on minerals grinding. As far as coal is concerned, some of the solutions initially adopted are presented in this paper, which essentially relied on the water jet power only, with secondary use of mechanical actions, to reach the most modern solutions that envisage the use of mechanical energy, normally used in traditional grinding machines, in synergy with hydraulic energy transferred by water jet.INTRODUCTION Mineral comminution can be rather expensive and demand a high-energy consumption, especially for fine sizes (Austin, 1979). Further interesting perspectives in this area may be offered by comminution means aided by high pressure water jets (Ciccu 2007), whose crushing potential is currently used for several operations such as cutting different materials, rock digging and industrial cleaning. The crushing action of water jets may induce a traction stress in materials where substances of a mineral nature, especially if characterised by permeable porosity, oppose a minor resistance (Griffith, 1920). The first solutions to this purpose essentially relied on the sole energy of water jets, with a secondary use of mechanical actions (Ciccu, 1993). Results were encouraging, despite the high values of specific energy for the low capacity of treatment. However, due to the difficulty in making the techniques mainly based on hydraulic energy practically applicable to solids comminution a solution was experimented, with some interesting results, consisting in the combination of mechanical energy, normally used in traditional grinding devices, with hydraulic energy transferred through water jets, in a synergic relationship (Ciccu, 1998; Tilocca, 2016)."

Jan 1, 2018

By U. M. J. Boin, W. L. Dalmijn, T. P. R. de Jong

"This paper explores the complex interrelationship between the resource cycle, recycling and metal production as a function of economics, environmental legislation, and product design. It is argued that central to optimising this resource cycle lies the control in particular of physical separation plants by the application of advanced sensor technology and sorting equipment, as well as suitable control and sampling algorithms supported by optimising mass balance models.Metals are produced through a long chain of processes. For primary resources, metals production goes through mining, mineral processing, ore smelting, conversion and refining steps or via low temperature hydrometallurgical processes, or a combination of both pyro- and hydrometallurgical operations. For the recycling of resources, metals are separated and recovered from metal scrap, which plays an increasingly important role in the world. Metals after being produced, either from primary or recycling resources, have to be further refined or manufactured into various types of alloys and finally shaped into different products for the end-users. Since the end-user discards products the contained materials find their way back into the resource cycle as scrap. Therefore, controlling the metallurgical reactors also controls, in a much broader sense, the material quality in the complete metals cycle, from the production phase, to the end-use phase, up to the recycling phase (Reuter et al., 2003). The recycling phase includes separation of materials into saleable intermediate products, which are reintroduced into the production phase as a recycling resource. Therefore, the metallurgical processes in each unit operation in the metals production and processing chain have to be controlled, so as to achieve optimal performance of high product quality, low energy and materials consumption, and low environmental impact."

Jan 1, 2003

By P. N. Mohan Das, K. Harikrishna Bhat

"The major ilmenite reserves are located in India at Chavara (CH), Manavalakurichi ( MK) and Chatrapur, Orissa (OR). India stands first in terms of ilmenite reserves, which are estimated to be 278 million tonnes out of which, 142 million tonnes are processable. Mineralo-chemical analysis shows that Chavara ilmenite is the most weathered one with about 60% TiO2 while Chatrapur is the least weathered with about 50% TiO2. Co-existence of ilmenite with pseudorutile, rutile and haematite is observed in substantially varying amounts in the three deposits. It is observed that the tropical weathering rather than the source rock difference has apparently played an important role in imparting major compositional and structural dissimilarities among ilmenites in different places.In processing of ilmenite through the Becher process, aeration rusting of pre-reduced ilmenite is found to be the rate limiting step thus, affecting the productivity of the process. Investigations have proved that the addition of some organic compounds such as glyoxal, sucrose etc., to the system accelerates the reaction to such an extent that the rusting time has been reduced to less than half.A new route of processing ilmenite for synthetic rutile has also been developed in which, ilmenite is carbothermally reduced and then processed through plasma route. The slag thus obtained is processed further to get high-grade synthetic rutile, metallic iron and high purity iron oxide. The process has been scaled up in a continuous moving bed plasma reactor. It is technologically and economically more viable where, all the iron values are recovered as salable byproducts. This paper describes the salient features of the technologies developed for the beneficiation of ilmenite to synthetic rutile."

Jan 1, 2003

By P. Vijay Kumar

Phosphate minerals are conventionally concentrated by flotation process using soap or soap- light diesel oil emulsion as collector. Some plants use detergents such as sodium petroleum sulfonate or alfa olefin sulfonate to enhance efficiency of soap flotation. It is reported that urea a known hydrotrope enhances flotation efficiency of soap as efficiently as alfa olefin sulfonate or linear alkyl benzene sulfonate at bench scale tests. In the present study tri sodium citrate also a known hydrotrope is tested as promoter in the flotation of phosphate mineral from Eshidiya ore.

Sep 1, 2012

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimisation.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003