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By J. Bouchard, R. del Villar, A. Vazirizadeh

"Industrial flotation is a continuous and often multistage process, where particles of a given mineral species (usually the targeted one), present in different sizes, encounter a large amount of gas bubbles (normally air) to produce mineral–bubble aggregates, which are removed from the flotation device (cell or column) as a valuable product (concentrate). The bubble content inside the cell is characterized by the prevailing hydrodynamic conditions (known as gas dispersion variables), which in turn are known to influence the flotation performance. Although most researchers and practitioners agree that the relationship between the hydrodynamic variables and flotation performance exists, the lack of an adequate method foronline measuring the average bubble diameter has prevented such studies.The aim of this study is to apply appropriate hydrodynamic variables for flotation kinetic modeling (as a key feature of flotation performance) for a given introduced particle size distribution (PSD). In this regard, experiments were conducted in a laboratory flotation column (5.6 cm internal diameter for a total height of 650 cm), and mixtures of quartz (hydrophilic gangue) and talc (naturally hydrophobic mineral), classified in four different size fractions. The correlation between the flotation rate constant and given hydrodynamic variables were analyzed. Results suggest that the relative importance of hydrodynamic variables for flotation rate modeling depends on the PSD. Finally the suggested hydrodynamic variables for each of the various particle size-classes considered were used to produce single variable models for the flotation rate constant. INTRODUCTIONIndependently of the prevailing flotation conditions, the mechanisms for bubble-particle aggregation and the residence time of the phases inside the device must also be considered. In this regard, one of the most used approaches to represent the overall flotation process is as a pseudo-chemical reaction between a particle and a bubble, whose rate (at a given time) is proportional to the amount of remaining floatable species. The proportionating constant is called the kinetic constant or the flotation rate constant."

Jan 1, 2016

By D. Pérez Escobar

Multiphase steels are quite sensitive to hydrogen embrittlement. Laboratory tests to evaluate this often use electrochemical, charging to introduce hydrogen into the sample, but damage purely caused by hydrogen charging has to be avoided. A ferrite-bainite steel, was charged using various conditions to identify when surface blisters occurred. Samples were also checked for internal, damage by electron microscopy. This study was repeated for three other multiphase steels and pure iron. An HSLA steel, was found to be more resistant whereas pure iron was quite susceptible to internal, hydrogen damage. For al, industrial, steels, cracks concentrated in the middle of the sample were attributed to inclusions and segregations, inherent to production.

Jan 1, 2010

By W. Almdal

"To compete in the ever expanding global market, companies must continuously improve. Benchmarking, a tool that can help determine where the best areas for improvement are, is more than comparing measures, it is comparing how business is carried out and how decisions are made. The key to success is in integrating benchmarking results into the organization, so that those most affected by the results own them and are empowered to use them as a positive change agent. This is a necessary step to achieving substantive change to practices and achieving optimum performance improvement. IntroductionBenchmarking is a powerful tool that can assist in the continuous goal of improvement. Benchmarking is more than comparing productivity rates or unit costs, it is seeking out best practices and assimilating them into a business to provide a positive change agent.Benchmarking is a continuous process - is time consuming, labour intensive, and requires a lot of discipline. There are no easy answers and no easy solutions, just a lot of work. The results, however, are nothing short of spectacular. More and more companies are adopting benchmarking practices because it is a key tool of the learning organization and will become part of the way business is done, part of the way it is managed. Business must change to stay ahead or to get ahead and benchmarking can accelerate the process of business change. Improvements in an organization can happen faster and more effectively with a benchmarking approach."

Jan 1, 1994

By A. Osouli, B. Moradi Bajestani

"Increase in permeability of rock mass is vital for both petroleum and geothermal applications. Hydraulic fracturing is a common method to create and increase the permeability for production. Due to the complexity of fracture propagation in a naturally fractured medium, understanding the interaction between hydraulic fracture (HF) and natural fracture (NF) is of great importance to optimize the fracturing process. The possibility of interaction between HF and NF is partly a function of orientation. Various scenarios are predictable for hydraulic fracture regarding the intersection with NF such as being arrested by NF, crossing NF or crossing the fissure while injecting water into it. Different parameters such as geomechanical and geometrical properties of surrounding rock mass, the operational parameters such as injection rate and the angle between created hydraulic fracture and natural fracture (approach angle) can affect the result of hydraulic fracture and natural fracture intersection. In this paper, using a series of flow-coupled Distinct Fracture Network (DFN) simulations, hydraulic fractures were analyzed to investigate the influence of the aforementioned parameters on the hydraulic fracture propagating. Results show that the most significant parameters affecting the interaction of natural and hydraulic fracture are orientation of the intersection as well as injection rate. The interaction and fracture propagation in NF and HF intersections are also studied and discussed in detail.INTRODUCTIONThe hydraulic fracture technology has substantially changed the oil, gas and geothermal industries. With the help of this technology, extraction of fossil resources from tight shale reservoirs will be economical, feasible and sustainable. Due to presence of massive oil and gas trapped in these reservoirs, this technology has been the center of attention for the past 40 years (King, 2012). Hydraulic fracturing is the process in which high pressure water is pumped into shale unconventional reservoirs with low to ultralow permeabilities. With this process paths are created in these mediums for delivering oil and gas to horizontal wellbore and increase the surrounding rock medium permeability. Economical and sustainable stimulation of these tight reservoirs is highly dependable on our understanding in regard to fracture propagation in the highly complex rock medium. Hydraulic fracturing process in rock mediums with preexisting natural fractures is more complex because of the high possibility of Hydraulic Fracture (HF) being arrested or deviated by Natural Fracture (NF). Also, HF and NF intersection can influence the required pumping pressure, injection rate, the outcome of horizontal wellbore and the affected geological underground zones. Since the 1950s, numerous studies have been conducted to predict and plan fracture propagation with the help of modeling and simulation methods. Having a thorough and accurate prediction of fracturing process will not only prevent stimulation of unwanted geological zones or pollution of aquifers, but also will improve the efficiency of the fracturing process. Previously, several studies have been conducted in order to investigate and analyze the interaction of hydraulic fracture and natural fracture (Cottrell, Hosseinpour, & Dershowitz, 2013; Doe, Lacazette, Dershowitz, & Knitter, 2013; Shakib, 2013; Zhang & Jeffrey, 2006)."

Jan 1, 2015

By Robert B. Parsons

"The junior mining company's bank account is depleted, but there are high hopes for the company's property. Where to get the necessary development funds is a common problem facing many juniors.This month, Tax Notes discusses briefly the principal income tax implications of several alternative development plans that are typically available to the junior mining company and its shareholders.IntroductionAt some point in time, many junior exploration companies face a common dilemma-a promising prospect has been proven up and is read y for further development, but alas, the company is flat broke! In this situation, a number of alternatives is available to the company, including the possibility of ""going it alone"" by raising capital through a public offering, or by striking a deal with a ""major"" or some other substantial investor.This article focuses on the latter possibility, and discusses in broad term s the main income tax implications of various arrangements between a typical junior exploration company and a larger public company for the development of a particular property. It will be appreciated that a discussion of other important considerations, such as those pertaining to securities exchange regulation s and company law requirements, is beyond the scope of this article.Jointly Owned CorporationPerhaps the simplest way of dealing with the problem of financing the development of a property is to sell the property outright, pocket the proceeds, and run! Clearly, though, this alternative is unacceptable to most prospectors and developers, who are predictably reluctant to completely relinquish their equity interest in a promising property. An additional strike against such an outright sale is that the sale could trigger an income tax liability. Generally speaking, in the case of a simple sale of a mineral property, for income tax purposes the proceeds are applied to reduce the taxpayer' s unclaimed balance of Canadian development expense (""CDE""), with any unapplied excess being brought into income and taxed at ordinary corporate tax rates."

Jan 1, 1983

By R. O. Grieve

"IntroductionCALEY (1945) and Evans (1950) pointed out that certain instances of convergence between Devonian and Silurian horizons, frequently evident in wells drilled for oil and gas in Ontario, appear to be related to local thinning of salt beds in the Salina formation and they suggested that leaching of the salt beds may have occurred. Exploratory drilling by Imperial Oil Limited since 1945 has brought to light several examples of structures similar to those discussed by Caley and Evans. The writer has had the opportunity to examine cuttings and data from wells which penetrated these structures and the attempt to interpret them in the light of the theory of leaching and subsidence proposed by Landes ( 1945a) to explain the marked brecciation and deformation of Upper Silurian and Middle Devonian sediments which crop out in the Mackinac Straits region of northern Michigan has led to the observations presented in this paper."

Jan 1, 1955

By Qing-hua Tian, Xue-yi Guo, Fei Li

A novel process for the preparation of a-Al2O3 from secondary aluminum dross was studied. Factors including alkali dross ratio, salt dross ratio, smelting temperature, smelting time, leaching temperature, leaching time, and the solid-liquid ratio, which possibly influence the transfer of Al into water were studied, and the feasibility of using seed precipitation as a treatment technology of the leachate was discussed. The optimum condition of the process was determined as: alkali dross ratio 1.3, salt dross ratio 0.7, smelting temperature 500°C, smelting time 60min, leaching temperature 60°C, leaching time 30min, solid-liquid ratio 1:4. The results show that using the seed precipitation method, the leaching of aluminum reaches 92.71%, demonstrating the technique as a feasible and effective treatment technology of the leachate.

Jan 1, 2011

By Mohamed Sassi, I. Kolo, R. L. Sousa, R. K. Abu Al-Rub, Manhal Sirat

"Fractures induced by folds are pivotal in hydrocarbon exploration, ground water transport and harnessing of geothermal energy. This is because of the need to predict and understand fracture propagation in reservoirs which have folded rock formations. Despite its prominence, there is a lack of reliable numerical models for simulating fractures resulting from rock folding. This is partially due to the difficulty involved in fracture modelling. As a contribution to fold-fracture modelling, this work applies a coupled plasticity-damage model to rock fracturing and anticlinal folds. Parametric studies on a single folded layer give insight into the fold formation and behaviour. The anisotropic continuum damage model which considers both tension and compression is formulated using the power damage evolution law. For ease in formulation, strain equivalence hypothesis is adopted whereby the strain is the same for both damaged and undamaged configurations. Lubliner plasticity yield criterion is adopted for plastic deformation. The model is coded in Abaqus user subroutine UMAT and is applicable to quasi-brittle materials.INTRODUCTIONThe understanding of fractures in the earth’s crust helps in the prediction, evaluation and characterization of fractured reservoirs, whether they are petroleum, geothermal or underground water reservoirs. This is partly because reservoir permeability and stability are dependent on fracture properties (Nelson, 2001). To achieve this, various approaches have been developed to analyze reservoir rock fractures. These could be grouped into (a) discrete approaches – where the rock mass is represented by a finite number of well-defined components and (b) continuum approaches – where the mathematical assumption of an infinitesimal element is made (Jing, 2003). Ivanova (Ivanova, 1998) comprehensively studied fracture systems in nature and highlighted folds as one of the major geologic settings that produce fractures. Naturally occurring folds in reservoirs sometimes compound fracture analysis. It might not be clear whether the fractures formed before, during or after rock folding. Fractures formed during the folding process are expected to show stress orientations related to folding and are thus of primary concern in rock folding simulation. It could be argued that there are no numerical models that as"

Jan 1, 2015

By M. G. Lipsett

General Challenges for Mining & Mineral Processing Operations ? Capital-intensive industry ? Ongoing cost pressures ? Remote locations ? Workforce demographics ? Dynamic, unstructured, rugged environment

May 1, 2008

By F. Duan, J. Pfarr, J. M. Goris

"The U.S. Bureau of Mines, in cooperation with the Homestake Mining Co. and the University of Utah, is conducting a field demonstration to evaluate the behaviour of rock masses supported with cable bolts. One of two rock masses being studied is supported with both conventional and birdcage cables. This rock mass is located between the 6500 and 6650 levels of the 45-48N stope, 21 ledge. The second rock mass is the hanging wall of the D-limb stope between the 3500 and 3650 levels near the Ross Shaft and is supported with conventional cables. The primary objectives of the project are to monitor the behaviour of the two rock masses during mining using extensometers and cable support strain gauges, after which the rock will be modelled using the finite-element code UTAH III. Field data will be used to verify the modelling. In addition, a comparison between the effectiveness of conventional and birdcage cables will be made.45-48N StopeThe 45-48N stope is located in the 21 ledge between the 6500 and 6650 levels and contains about 233 000 short tons of mineable ore. The orebody lies within the Homestake Formation and is very irregular being approximately 200 ft long and 75 ft wide. Between the 6500 and 6650 levels, it dips from 35 degrees to 60 degrees east with a near-vertical plunge to the south. Mineralization is characterized by arsenopyrite and pyrrhotite with minor gold. The contact between the Homestake and the overlying Ellison Formation creates a plane of weakness along localized graphitic layers. The footwall dips at approximately 60 degrees but between 100 ft and 120 ft above the 6650 level , the hanging wall flattens to almost 20 degrees causing a significant mining problem."

Jan 1, 1991

By Roger C. Parsons

"The problems presented by ice formation and interference with processes, structures and mechanical operations in the mining industry can be expected to increase sharply as more of our mineraI needs are supplied from the far north. A process of rapid ice destruction is presented which lends itself to the effective removal or penetration of ice. Suggestions are offered for applying the system to problems related to mining activity in cold environments. The system can be readily adapted to large-scale operation, the reactant components being transported in crystalline form and volatilized on site.IntroductionThe number of operational mines in northern environments, relative to the number of mines in the temperate zone, will increase in the years ahead. This is not surprising, because:(a) in the past, those mines closest to centres of commerce had minimum transport charges and hence were more economic to develop;(b) great centres of commerce were far removed from northern environments;(c) the exhaustion of ores and lowering of grades in temperate zones now offset to some degree the extra transport costs applied to northern ores;(d) the abundance of excess energy in the north in the form of oil, gas and hydropower attracts mining as a means to justify its development; (e) assuming that the frequency of mineral occurrence north of the 52° N latitude is no different than south of it, there are many deposits waiting to be developed.As a result of current and projected activity in northern environments, we are faced today, and will be increasingly so in the future, with mining problems rarely encountered before-problems related to below-freezing temperatures. Engineering activity in permafrost regions will increase as new mining ventures are developed north of the 52° N latitude, roughly coinciding with the -1.1 ° C isotherm in Labrador, the upper temperature boundary for permafrost."

Jan 1, 1982

By S. Zakaria

"Inco's Automated Haulage Truck System (AHT) is a revolutionary automatic guided vehicle that performs all load, haul and dump operations without human intervention. The high level of sophistication and the short period it has been in operation has only allowed a select few Inco personnel to become familiar with the ART operation and maintenance. As an aid to operations an expert system using the knowledge gained from the experienced specialists was implemented in the field.The AHT operating and maintenance assistance expert system will reason through the information given, arrive at conclusions and give advice to operations, technical and management personnel. It will provide comprehensive real-time troubleshooting assistance for the hydraulic, electrical and mechanical subsystems of the ART. The ART expert system has many benefits to Inco which include increased skill levels of ART operations and maintenance personnel, reduction in ART downtime, standardization of troubleshooting procedures and reduction in ART operating and maintenance costs. In the future, the expert system application will be linked to SCADA (Supervisory Control and Data Acquisition), maintenance and statistical software to display current and historical trends of variables from a centralized historical database. As well, a wide variety of features will be integrated into the system including AutoCad drawings, graphics, photographs, voice and video capabilities."

Jan 1, 1994

By G. Barbery, P. Dauphin

"In order to obtain reproducible and reproducible results in batch flotation, researchers have tried various approaches, from normalized testing, to modifying existing cells, and even designing new machines. The paper reviews the basic concepts that must be fulfilled in a laboratory flotation machine, and present the FLOTOMATEC design, which results from five years of testing and development. In addition to providing accurate measurements of air flowrate, power consumption, agitation speed, the cell eliminates most operator induced errors. Results of experiments comparing FLOTOMATEC to a conventional cell, as well as reproducibility tests are given. Introduction The use of batch flotation machines in mineral processing research and development is very common. These machines have been used for many years without almost any change in their design, instrumentation or automation. Various authors since Raffinot (1960) have criticized the available designs, especially with respect to the large errors that are introduced by the manual mode of operation. Barbery et al. (1986) have presented a review of the problems involved in laboratory testing in flotation research.Batch laboratory machines should have the following characteristics:"

Jan 1, 1989

?Introduction to the Delphi Group ?Why is carbon important to your organization ?Key elements of a carbon management strategy ?Inventory ?Risk & opportunity scan ?Mitigation options and financial mechanisms ?Identify targets and develop policy ?Communication and improvement ?Manage for success

May 1, 2009

By Edgar L. Horner

"The objectives of the Wabush Mines tailings stabilization program are to control dust Ii/t-off and to rehabilitate the disposal area. The evolution of the program started with test plots in 1970, these being continued and expanded upon through 1974. In 1976, a 35-acre vegetation field trial was attempted and failed, part of the failure being attributed to lack of adequate equipment. Subsequently, equipment was purchased and during the summer of 1979-80 extensive areas were treated. The program was also expanded to include the evaluation of chemical and water spray stabilization versus vegetation in areas where shorter-term control is required. In addition, during the summers of 1979-80, spruce bog material was spread over about 100 acres and seeded.The approach to reclamation by vegetation at Wabush is one of soil building. Work to this point indicates that iron ore tailings can be converted to a soil capable of supporting plants. Plans for the Wabush tailings disposal area should make dust lift-off from inactive tailings areas negligible within the next few years."

Jan 1, 1981

By V. I. Peresypkin, A. Y. Lein, N. S. Bortnikov, Yu. A. Bogdanov

"Abstract - The lipid component in hydrothermal deposits of the Logachev vent field, at 14°45_N of the Mid-Atlantic Ridge (MAR) and Broken Spur vent field, at 29°N of the MAR, was studied. Biochemical, gas chromatographic (GS), and molecular mass methods (GC-MS) research established the mixed nature of the organic matter (OM) including phytoplanktonogenous, chemosynthesized lipids, and lipids of questionable origin. Specific local conditions around the sulfide ores of the black smokers (absence of free oxygen and presence of reduced copper, which prevents OM degradation) facilitate the preservation of biogenic material, including bacteria. The main differences between the lipid compositions of the hydrothermal deposits of these two vent fields relate to the variable nature of hydrothermal circulation systems.At the 14°45_N vent field, high-temperature hydrothermal fields are forming due to the reaction of sea water with upper mantle ultrabasic rocks during serpentinization (a deep hydrothermal circulation system). High pressure and temperature (>400°C), a reducing environment and the presence of various metal oxides are favorable for the abiogenic synthesis of CH4 and oil hydrocarbons (HC). At the Broken Spur vent field, hydrothermal deposits are forming above axial crust magma chambers due to the interaction of sea water and basalts (an axial hydrothermal circulation system). Abiogenic synthesis of HC also occurs in this situation, but to a considerably lesser extent."

Jan 1, 1999

By John O. Marsden

Technology development and innovation has played a crucial role in the copper industry throughout history. The effective development and implementation of new technologies allows mankind to produce copper at progressively lower cost of production at a given feed grade and mineral type. This progress serves to counteract cost escalation over time and, depending on the magnitude of the cost benefit, allows ore cut off grades to be reduced thereby improving the availability, accessibility and utilization of mineral resources. The development of step change technologies that can offer >$0.15/lb total cost benefits provides a significant opportunity for producers to achieve competitive advantage, but it has been argued that rapid dissemination of technology makes such competitive advantage unsustainable over time. This paper presents the results of a recent study that evaluates a number of historical and emerging step change technology case studies in the copper industry and quantifies the associated cost benefits for users, the impact on the production cost curve, and the duration of such cost benefits for various categories of implementers: first mover, fast follower, conservative followers and laggards. The results provide a compelling case for major, mid-tier and emerging copper producers to invest in technology development initiatives if they wish to achieve and sustain competitive advantage over the long term. INTRODUCTION AND BACKGROUND A key issue for mining companies is how much time, effort and cost to spend on research and technology development (R&TD). The economic drivers for technology development and implementation are poorly understood in our industry and the business case is clouded by some notable and well-publicized failures (McNulty, 1998). Mining companies are in business to deliver financial returns to investors. This means delivering short term results on a quarter-by-quarter reporting basis as well as sustaining and growing the company to retain and reward a sustainable longer term investor base. The cyclical nature of the commodity metal markets makes it challenging to maintain investment in research and step change technology development: Mining companies must manage through the highs and the lows of price cycles, typically ranging from 5-15 years in length. The discounted cash flow approach to investment evaluation results in weak financial justification for R&TD expenditures. A clear and compelling rationale to support longer term investment in research and step change technology implementation is required.

Jan 1, 2019

By Z. Pilecki

This work concerns the identification of weak zones in the structure of a rock mass endangered by outburst of gases and rocks in the Rudna copper ore mine at greater depths (approximately 1200 m). A special methodology has been undertaken for the recognition of that threat in the wake of an outburst in the mine in 2009. No similar phenomena have been previously recorded in KGHM Polska Miedz copper ore mines. The research described in this paper was carried out in the new part of the deposit prepared for mining. Geophysical methods were used: seismic tomography and borehole ground penetrating radar (BGPR), along with particular identifications using geological engineering methods. In the researched area, Permian layers of sandstone and shale clay (Weissliegendes formation) and of Zechstein dolomite (top of Rotliegend formation) and anhydrite occur in the copper ore deposit. The rock layers are characterized by variable thickness and intensity of mineralization, varying internal structure, and local fracturing containing different gases and water. It is assumed that accumulation of gases occurs in the tectonically fractured dolomite. The study was focused on the recognition of the structure and properties of the dolomite layer lying directly within the roof of excavations. The first tests were performed with seismic tomography for the recognition of anomalous changes in the elastic properties of the rock mass. The results of these studies were used to design a control borehole for a detailed geological engineering assessment and BGPR surveys with 100MHz antennas. Seismic tomography enabled the identification of changes in Pwave and S-wave velocity, the Vp/Vs ratio, dynamic Poisson's ratio and dynamic Young's modulus. It was clear that seismic anomalies required verification by other methods. The BGPR survey was performed in a specially designed borehole, passing through the selected seismic anomalies. While the borehole was being drilled, the outflow of gases was identified, with varying amounts of CH4, CO2, and H2S detected, as well as water outflow. The results of BGPR confirmed the location of a reservoir of water and gases, about 30 m in length, found in layer of dolomite. The direct cause of the BGPR anomaly was assumed to be intensive fracturing, a greater content of clay material in the dolomite, and the presence of water in the fractured zone. The BGPR image was correlated with information on lithology, fracturing based on the RQD index and additional information acquired during drilling about water and gases surveys and other symptoms. The achieved results also showed a very strong correlation between the location of the zone containing gases and water and the anomalous S-wave velocity and field of dynamic Poisson?s ratio, and to a lesser extent other seismic parameters. It was found that the other measured seismic anomalies may be of the same nature as those identified in the control borehole and accordingly will require the implementation of detailed identification. The performed tests have also shown the usefulness of geophysical methods to identify geodynamic hazards under the geological and mining conditions of the copper ore deposit in the Rudna mine.

Aug 1, 2013

By Robert B. Parsons

"One of the disadvantages of the federal government's idea of ""taxation by consultation"" is that it seems to take longer to enact new legislation. The proposed new rules for taxing automobile benefits is one example. Here is a ball which has been batted around between government and the public several times and still has not come down to earth. Fasten your seatbelts, there may be more to come. IntroductionThe draft legislation released on April 13 contains the details of the government's current proposals on car expenses and benefits. They differ significantly from the last announced position. Finance Minister Wilson has indicated that the release in draft form will provide an opportunity for the Commons Standing Committee on Finance and Economic Affairs (the Blenkarn committee) and other interested persons to comment before the legislation is introduced in Parliament. Accordingly, there may yet be revisions.Notwithstanding the prospect of further changes, the proposed rules generally come into force in 1988. While taxpayers may welcome some of these changes, particularly the increase in the tax-exempt allowance, many must be frustrated that, at this late date, the rules for the current taxation year are not yet finalized."

Jan 1, 1988

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016