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By Z. D. Hora

Of four main gypsum areas in the province, commercial production has only come from Falkland and the Kootenay and Columbia River valleys of southeast British Columbia. The Windermere deposit in southeast B.C. has been the major producer since /948. Gypsum and anhydrite from the Falkland deposit is used principally in cement-making at Kam/oops. GYPSUM deposits in British Columbia are known from four different areas: the southeast part of the province in the proximity of the Kootenay and Columbia River valleys; Forgetmenot Creek astride the British Columbia - Alberta boundary near Intersection Mountain; Falkland; and O'Connor River north of Haines . To date, commercial production has only come from Falkland and the southeast part of the province. Gypsum deposits of southeast British Columbia occur in the Burnais Formation of Devonian age. Outcrops of gypsum and numerous sinkholes indicating its presence are scattered over large areas of the Stanford Range. Several properties have been examined by industry in both the recent and more distant past. Significant production is reported from only two deposits. The Mayook deposit, active from 1926 to 1929 and from 1947 to 1954, produced approximately 95,000 tonnes of gypsum. The Windermere deposit, which has been active since 1948, is operated by Westrock Industries and has produced more than 6.8 million tonnes of gypsum. The Burnais Formation is composed principally of well bedded, finely 'laminated gypsum but also contains thin lenses of black fetid limestone and dolomite. Part of the Formation consists of breccia with angular carbonate clasts in massive, coarse grained gypsum. In several exposures, the Formation appears 10 be from 200 10 400 m thick, of which more than 75 Industrial Minerals in Canada per cent is gypsum . In the Stanford Range reserves mineable by quarry methods are estimated to be approximately 450 million tonnes.

Jan 1, 1984

By H. C. L. Reemeyer

One of the fundamental trade-offs for copper concentrators is between grinding circuit product size and copper recovery. The capital and operating cost savings and throughput increases for a coarser grind should be evaluated against potential recovery reductions. Other benefits of coarser grinds, such as GHG emissions reductions and favourable effects on tailings and water management should also be considered. This paper assesses the formation of laboratory and pilot test programs, design of process flowsheets, equipment selection, and evaluation methods to determine the most appropriate and economical grind size for a given deposit. The paper will include an evaluation of case studies. INTRODUCTION The majority of the world’s mined copper comes from sulphide deposits, which are mostly processed using crushing, grinding, flotation and dewatering flowsheets to produce copper-bearing concentrates for smelting. Ores must be ground to a sufficiently fine size to achieve an acceptable level of liberation to allow both high recovery of copper and valuable by-product minerals while efficiently rejecting gangue to tailings. Therefore, a key design parameter in process plant design is the grind size of the flotation feed. Copper concentrators use a variety of grind size targets that depend on various factors, including ore mineralogy and the grain sizes of valuable and gangue minerals; the sensitivity of valuable mineral recoveries in the rougher flotation stages to grind size, ore hardness; electricity costs; and mining vs. processing throughput constraints. Typically, copper and by-product recovery increase as grind size is reduced, which can improve revenue, but finer grinds increase power and grinding media operating costs and may have implications for tailings management. This paper explores the trade-offs that should be assessed in determining the optimum grind size, and to answer the question if coarser grinds are worthwhile. METALLURGICAL AND FLOWSHEET FACTORS Recovery-by-size behaviour of sulphide-bearing particles In base metals sulphide flotation, it is typical that flotation recoveries vary by particle size. Metal sulphide particles rendered hydrophobic by collector in intermediate size ranges (e.g. 10 to 100 um) usually show very high recoveries, often approaching 100%. Recovery usually falls away in finer size fractions (<10 um) as fine particles have little inertia and can move around bubbles without colliding and attaching to them. Coarser particles (>100 um) are susceptible to particle-bubble detachment and dropback (Jameson, 2019).

Jan 1, 2019

By E. I. Robinsky

"In light of the recurring spills and failures of conventional tailings disposal pond dams, a brief review of the Thickened Tailings Disposal (TTD) system is presented. It is shown that by the process of thickening the tailings to a heavy slurry prior to disposal, it is possible to create a self-supporting deposit of tailings and to eliminate the typical superimposed settling pond. These features, together with the ability to reclaim the disposal area even as mining continues, preclude an ecological disaster. IntroductionMine tailings spills are really not such rare occurrences. They have been happening on many continents, in many countries. Neither Canada nor the United States have been spared. In Ontario, the most recent spill occurred at a closed-down tailings disposal area in Matachewan, in 1991.Such continuing disasters could be avoided if a different approach were taken to the disposal of tailings wastes. The recent failures at the Los Frailes mine in Spain, the Omai mine in Guyana, and the Marcopper mine in the Philippines, will hopefully shake up the industry to consider other methods of disposal. The reason why the failure of a conventional tailings disposal dam is so environmentally disastrous is not the dam itself, but the fact that the dam retains a mass of very loose unconsolidated tailings and a great deal of water, or process fluid1. If the dam fails, the contents liquefy completely as they flow through the breach. In this liquid state, they can flow many miles downstream. If the dam itself were built of tailings material, as is often the case, it too would liquefy and join the flow.The reason the material is so loose in the first place is that it has been discharged into a pond filled with water. The tailings particles drift down through the water, their weight reduced by 50% due to buoyancy, to form a loose structure, like a “house of cards,” or lakebottom mud. It doesn’t take much of a shock to collapse the material into a liquefied state."

Jan 1, 1999

By H. Staton, V. Suontaka, E. Sharifi

"Flotation circuits are typically controlled using on-line elemental assays obtained from the slurry lines. In base metal applications, X-ray fluorescence (XRF) analyzers are the most common instruments for elemental analysis of the slurries. Eagle Mine has been utilizing a Courier XRF Analyzer since 2014. Typically, in XRF analysis, the sampling rate is 10-25 minutes which is good enough for manual process control. In 2018, Eagle Mine upgraded the Courier XRF analyzer with the Rapid Measurement module that is based on reflectance spectroscopy. This option reduces the sampling rate to 10-15 seconds, while maintaining the superior accuracy of the XRF analyzer. This paper presents the results from implementation of Rapid Measurement at Eagle Mine.INTRODUCTION Eagle mine is an underground mine producing nickel and copper concentrates. Eagle Mine is owned by Lundin mining and located in the Upper Peninsula of Michigan, USA. The Humboldt Mill, previously an iron ore processing facility, was refurbished in 2014 and is used to process the ore and produce separate nickel and copper concentrates. Approximately 2,000 metric tonnes of ore is milled per day. Ore is processed using a conventional crushing followed by single stage ball mill and flotation. Nickel and copper concentrate are transported to facilities in North America via rail car. A bulk copper-nickel concentrate is produced by separating the copper and nickel minerals from gangue material by flotation. The copper-nickel bulk concentrate is reground, followed by one stage of cleaning to reject further gangue minerals. The bulk cleaner concentrate is then subjected to a final flotation stage where the copper and nickel minerals are separated from one another through the addition of lime. Final concentrate grades are 14% Ni and 2% Cu in the nickel concentrate and 31% Cu and 0.8% Ni in copper concentrate."

Jan 1, 2019

By Jessica Hurst, Mark Holdsworth, Jeff McKay

"In 2002, Kennecott Utah Copper Copperton Concentrator installed an Expert Control system for optimization of their SAG and Ball milling circuits. The advanced process control has been well received and is utilized well over 95% of the time. In the years since, many lessons have been learned and many advances have been made. Improvements have produced millions of dollars of benefits and have included directly controlling feedrate with complex logic as opposed to using a bearing pressure controller, modifications to how sound is used for control, modifying logic for maximizing asset utilization and using advanced control for automating equipment restart. INTRODUCTIONRio Tinto’s Kennecott Copperton Concentrator produces copper, molybdenum, gold and silver. The mill has 4 SAG mills (SAG 1-3, 34 foot diameter and SAG 4 36 foot diameter), 8 ball mills and copper and molybdenum flotation plants, as seen in Figure 1. The 2010 average data is shown in Table 1.In 2002, a Metso Cisa OCS Expert Control system was installed at Copperton for SAG and Ball mill advanced control. The expert control was first placed on SAG 2; data from the first few weeks compared with operator performance indicated approximately an 11 percent increase in throughput. After full commissioning, the system was gradually refined further by plant personnel to develop key performance indices based on SAG feed size, refinement of the sound setpoint for control of mill speed and throughput, specific rules to help the adjustment of speed based on loss of a feeder, etc. With the addition of the pebble crushing circuit, the expert control began utilizing a model estimation of crushed pebble bin level to help stabilize the impact of returned crushed and uncrushed pebbles on the SAG mills. As the ore and limitations change, it is necessary to evolve the SAG logic to better handle any constraints."

Jan 1, 2012

By Ron Davidson

"The Utility Mine in southeast Saskatchewan is owned by Saskatchewan Power Corporation and operated by Mana/ta Coal Ltd. Up to 3.3 million tonnes of lignite is supplied annually to Saskatchewan Power's Boundary Dam Generating Station. The coal occurs in two predominant seams which are covered by up to 37 metres of saturated fine-grained overburden. Overburden is removed by two draglines working in two pits. Coal is hauled to the mine mouth power station. Comprehensive drainage and reclamation programs are integral parts of the operation. IntroductionThe Utility Mine is owned by Saskatchewan Power Corporation and operated by Manalta Coal Ltd. It is located in southeastern Saskatchewan, approximately 200 km southeast of Regina and 8.5 km southwest of Estevan (Fig. 1). The climate of the Estevan area is semi-arid with long, cool winters and short, hot summers. The mean annual precipitation is 42 cm and the mean summer temperature is 20°C; mean winter temperature is -10°C. The Utility Mine supplies coal to the adjacent Boundary Dam Generating Station. Increases in the station's generating capacity during the past decade have resulted in an extensive expansion program for the Utility Mine. This expansion program, the geological conditions present in the area, and the mining/reclamation operations will be highlighted in the following sections<1.2). History The Estevan area has a long history of coal mining. In the early years, coal was mined via entries into coal seam outcrops along the slopes of the Souris River valley. Surface strip mining was introduced in the late 1920s and progressed to the point where it totally replaced underground mining by the 1950s. Surface mining methods are currently used exclusively by all of the Estevan area operators."

Jan 1, 1985

By The Staff

This is in direct contradiction to the generally accepted philosophy of tube-mill grinding, which is based upon an enormous amount of experiment carried on in different parts of the world. Personally, I have no faith in the reliability of these conclusions of the authors. (Incidentally, the two circuits compared consist of six mills each of which the change in the hook-up is only in the last three mills-in one case, these three mills are in closed circuit and in the other, open or series circuit. Hence the last three mills are alone responsible for the alleged improvement, which means that the improvement in these three mills amounts to at least 18.8 per cent). The value of these figures depends upon the reliability of the work, of the measurements and the calculations of the authors. As very little information is contained in this Addendum concerning the methods of the work and the details of the measurements, it is necessary, in order to form an estimate of this reliability, to study carefully the previous paper published in the July, 1940, BULLETIN(3). Referring to the original paper, the present paper has this to say (bottom of page 379): "Here it may be remarked that we have made more money for Lake Shore digging into and forming the report than in obtaining the figures and data, and so far have never gone back to work on it without a resulting Lake Shore profit". Let me state that I, so far, have never gone back to work on it without finding more discrepancies and inconsistencies and illogical reasoning. In my first contribution to the discussion of the first paper, which discussion was published on page 355 and following, in the July, 1941, BULLETIN, I pointed out discrepancies and inconsistencies and illogical reasoning.

Jan 1, 1942

By M. P. Amsden

"Ecstall Mining Limited, a subsidiary of Texasgulf, Inc., Operates the Kidd Creek Mine, Concentrator and Zinc Plant at Timmins, Ontario. Two different ore types are mined and milled to produce concentrates of copper, zinc, lead and tin. The ores are processed at the Concentrator in three separate individual milling circuits, each with the capacity to treat up to 3500 tons per day. Two circuits treat copper-zinc ore 1t an average combined rate of 6500 tons per day and the third circuit treats 3500 tons per day of silver-lead zinc ore. Conventional crushing, grinding and flotation procedures are followed. The purpose of this paper is to describe Ecstall's experience with rubber mill linings in the grinding circuits.CrushingBoth ores are crushed to minus 6 inches at the Mine and delivered by rail to the Concentrator where they are reduced by secondary and tertiary crushing to minus 5/8 inch.GrindingThe crushed ores are prepared for selective flotation by grinding with rod mills and two stages of ball milling. flotation circuit middling products are reground in regrind mills prior to further treatment. A typical flowsheet of one of the grinding circuits is shown in Figure 1.All the grinding units are Allis-Chalmers Mills. The rod mills are 10 1/2 feet diameter by 16 feet long. Both the primary and secondary ball mills are 12 feet diameter by 18 feet long and all regrind mills are 6 feet diameter by 12 feet long. The primary mills are charged with 1 13/16 inch forged balls. Secondary mills are charged with 1 1/2 inch forged balls and the regrind mills are charged with 1 inch forged balls. All cyclones are Kreb units. The primary cyclones are Dl5B hydrocyclones, the secondary cyclones are D6B hydrocyclones and all regrind cyclones are D6B hydrocyclones."

Jan 1, 1974

By R. C. Wallace

Since the time when Canada&apos;s East and West were joined by the railway, and communication was established into the interior, settlements grew on the southern fringe of the great Precambrian area that formed the northern protaxis of the continent during its vicissitudes of growth. They clung precariously to the fringe of that ancient land, for the Precambrian is not generous to those who wish to live by the fruits of the soil, except in those limited areas where the Pleistocene ice-sheet has been profuse in its gifts of clay to cover the hard surface of the Precambrian rock. Later settlements spread westwards over the expanse of Cretacean plains that now form the wheatfields of the Canadian West; but there still remained in northern and western Ontario, in eastern and northern Manitoba, a pioneer race, to whom agriculture had attractions only in so far that it provided the wherewithal to lay siege to the riches of the Precambrian. And they had a vision beyond their time. More than they knew, they had seized the fact that for the complete rounding out of Canadian national life, a8 well as for the establishing of the necessary contributions towards the economic stability of Canada and its provinces, an industry in mining sh01.dd be well and truly built in the hinterland of the central provinces. Failing the winning of mineral from the rocks, and timber from the forests, there would remain between the East and the West an enormous barrier of unproductive country which would not only be an incubus to the agricultural people in their struggle for economic liberty, but would effectively, and for all time, remain an un-populated void across which the aspirations of East and West would be unable to unite.

Jan 1, 1924

By Patrick Rennkamp, Wolf-Dieter Trodel, Andy Fearn

"The Jansen shafts are completed using purely mechanical excavation. This paper summarises the geology, a description of the shafts, the method used for excavation and the results achieved along with the challenges encountered and the solutions developed during the project. This experience is now being applied in the next generation machines and shaft sinking processes. This pioneering approach is changing shaft sinking in soft and medium to hard rock. INTRODUCTION The Jansen Mining project located approximately 150 km east of the city Saskatoon is the location of the BHP owned potash mine with an expected mining output of eight million tonnes annually upon completion. Mining contractors DMC Mining Services have used two Herrenknecht Shaft Boring Roadheaders (SBRs) to excavate the two blind shafts with an approximate excavation diameter of ten metres (inner diameter approximately 8.3 m) to depths of -975 and -1005 metres, respectively. The SBRs excavate the rock by a partial-face cutting method, using a transverse cutting drum mounted on a telescopic boom. The excavated rock is then conveyed away from the bench by an innovative pneumatic system and transferred into muck buckets to be hoisted to the surface. No drilling and blasting was done to keep to the BHP philosophy of using only mechanical excavation for this reference project. BHP VISION – MECHANICAL EXCAVATION BHP focused on mechanical excavation at Jansen due to the following perceived benefits: 1.No workers in the excavation chamber (shaft bottom), minimizing the exposure to traditional shaftsinking hazards associated with working in the shaft bottom. 2. Minimal damage to the rock fabric reducing the need for ground support and avoiding potential impact damage to freeze tubes located around the shaft. 3. Accurate excavation diameters with no overbreak, reducing volumes of rock to be removed and replaced with concrete lining."

Jan 1, 2019

By E. P. Cadwell

"Throughout the years Cyanamid has been a supplier of cyanide and a supplier of information to the mining industry. In general, the knowledge of mineralogy is greatly overlooked. Mineral deposits in the Western hemisphere have been exceedingly rich in the past but now they are becoming poorer. In other words, we will have to use our talents to the utmost to extract the precious metals and base metals from these ores. Modifications of some of the mineralogical equipment displayed here belong in the mill.Cyanidation of copper has been one of the main projects in our labs in recent years. De-rimming or de-filming of copper in order to upgrade copper concentrate was the main aspect investigated. A study was made as to how wide spread was the filming of secondary copper on pyrite, and to what extent it affected the copper industry. It was very wide.Often there is no conception as to what the minerals are. One open pit copper producer with a chalcopyrite ore was producing a copper concentrate with a 5% copper value whereas chalcopyrite contains 35% copper. They used primary and secondary grinding and a regrinding section. The ore contained about 8 parts chalcopyrite to one part of other copper minerals. In tests, a 3 1/ 2% copper rougher concentrate, cleaned without regrinding but conditioned with cyanide for a low contact time of 30 seconds produced a 30% copper concentrate with 90% recovery by removal of the film. It was of utmost importance that some quantitative mineralogical analysis be made before flow sheet changes were made. Every man should be trained to do his own microscopic examination in order to get quick answers. The fundamental thing in all mineral dressing is to first of all know the minerals and the mineral associations."

Jan 1, 1964

By H. Stutchbury

Alberta is labouring, and has laboured, under serious difficulties in the marketing of ?her coals, due to a number of conditions which now obtain, but all of which appear capable of solution, and their elimination would insure a very largely increased market for the vast coal resources of that province. It is perhaps necessary to again mention the fact that 15 per cent of the world&apos;s coal resources are to be found in Alberta; 21 per cent of that of North America; 72 per cent of that of the British Empire, and 87 per cent of that of all Canada. While we talk largely of the great wealth of Canada, the immensity of her vast natural resources, it is axiomatic that the mere presence of any natural product in a country does not in itself constitute wealth for that country, unless these raw materials can find a market, either in their raw state, or by the process of manufacture. There are many factors, however, which enter into the marketing of any commodity. The chief of these, in my opinion, is price competition. High costs of production materially reduce the radius in which any product can be marketed, and this applies particularly to coal. Mining costs in the province of Alberta are necessarily high at the present time, due in a large measure to the ease with which the &apos;gopher hole&apos; mine can be opened with small capital.

Jan 1, 1925

By J. F. K. Brown

WHEN I first received the kind invitation extended to me by the Mining Society of Nova Scotia, I read over very carefully the suggested title-"The importance of long-distance planning and budgetting in modern methods of mining, and the advisability of working to some definite plan". I came to the conclusion that I might as well confess my inability to handle properly such a vast and intricate subject within the scope of any one paper. More properly, I think a round-table discussion should be indulged in-a sort&apos; of symposium carried on in similar fashion to the World Power and Coal Conferences- you know, a committee for this, a committee for that, and, finally, a committee to see what the committees are doing. Weil, your Secretary&apos;s suggestion is just like that- much too comprehensive for any half-hour&apos;s presentation. As a paper, also, it either becomes too general and therefore uninteresting, or i.t descends into detail and describes means and methods to the end desired, which have little attraction because they were designed to meet quite different conditions than those my audience would mentally be considering. Of the two evils facing me, I have chosen the one that sticks to the generalities. Your Secretary&apos;s query almost automatically divides itself into two distinct phases: First, the importance, and second, the advisability, of planning. Let us dwell for the moment on the second, because, if we can prove advisability, that leads to desirability and, finally, to doing. Proving is the difficult part of the little problem. Here was something I, personally and as a mining engineer, had been battling for all my corporate life without being able to prove it to anybody. Then I saw the way out of that. I perceived I could put that little question of advisability on another basis altogether-:put it in the class of "coming- some day- soon" whether you or l or anybody else liked it or not; call it, if you please, mandatory, certain, necessary, enforceable planning. All of which means that the problem of advisability has rather suddenly become the very practical one of "how to do it". Why?

Jan 1, 1937

By E. Goodwin

"Maclaren Forest Products Inc.Lime is commonly used for the neutralization of acid, and the removal of heavy metals in mine waste waters. However, the precipitation of heavy metals as hydroxides must take place under conditions of controlled pH, to produce minimum concentrations of dissolved metals. An account is presented explaining the concepts applied to lime-treatment processes at Bell Mine during the period of a supernatant discharge to Babine Lake; October 18, 1982to January 25, 1983. IntroductionBell Mine of Maclaren Forest Products Inc., Babine Mining Division, an open-pit copper mine, is located on Newman Peninsula, Babine Lake approximately 65 kilometres northeast of the town of Smithers, British Columbia (Fig. 1).A depressed market for copper metal in 1982 forced a management decision to suspend operations at the mine for an indefinite period from October 3 I, 1982. For some time prior to the mine closing date, mine management was concerned about the increasing level of supernatant in the tailings pond , and its possible effects on the stability of the dam when cycloning of mill tailings ceased. Consideration of these potential hazards led to an application being filed with the Provincial Waste Management for a permit to discharge the excess water to Babine Lake. This large lake, an important link with several significant salmon spawning sites, is a major contributor to the British Columbia commercial fishing industry. Jurisdiction for the environmental affairs in the area is shared by the Department of Fisheries and Oceans, the Environmental Protection Service, and the Provincial Waste Management Branch. These agencies were directly concerned in the formulation of discharge permit following joint consultation, and exchange of information with the company on environmental concerns. An approval was finally granted to discharge approximately 1,000,000 cubic metres of supernatant from the tailings impoundment at Bell Mine into Hagan Arm, Babine Lake from October 18, 1982 with a daily discharge not to exceed 9000 cubic metres. Provisions were made that a particular discharge procedure be followed, and that the company would be responsible for setting up a sampling and monitoring program to safeguard the quality of the effluent."

Jan 1, 1986

By F. Goodarzi

"The nature and distribution of the inorganic components and the concentration of certain environmentally sensitive elements, such as, As, Sb, B, Hr, Cd, CI, F, Mo, Pb, S, and Se, or elements detrimental to the utilization by industry such as B, Na, P and S are very important in determining coal quality. The concentration of elements in coal is controlled by the following factors: (1) frequency of occurrence of partings; (2) nature and habit of occurrence of minerals in coal; (3) environment of coal deposition; (4)rank; (5) geological setting; and (6) weathering.Selective mining of coal can reduce the input of undesirable elements such as As and S by eliminating the part of the seam which is enriched in these elements. IntroductionCoal is a sedimentary rock of plant origin and consists of two components: an inorganic component (minerals) which is formed by influx of clastic sediments into the coal-forming environment and also by activities of groundwater, and an organic component (macerals) which is formed from plant debris deposited in the original coal-forming environment. However, coal is a generic term with a broad range of utilization characteristics. A coal that is attractive for use in one market - such as generation of electricity (combustion) - may not necessarily be acceptable for use in another, such as for production of coke (Davis, 1978).The elements in coal are associated with both macerals and minerals. The elements associated with coal macerals, such as C, H and N are termed elements with organic affInities. The concentration of elements with organic affmities (including B, Br, CI, F, I, S, and Mg) often decrease with increasing ash content of coal (Nicholls, 1968; and Finkehnan,1982). FIgure 1 shows such a trend for chlorine. Some of these elements may also be incorporated in coal maceral as very fine mineral grains (Finkelman, 1982). The elements with organic affmities are often volatilized during combustion and carbonization of coal and emitted in the vapour phase. Emission of some of these elements (C, 0, Br, N and S) is of major environmental concern (Lim, 1979)."

Jan 1, 1994

By J. Mizera, B. Adamczyk-Cieslak, K. J. Kurzydlowski, A. Dobkowska

"AZ31 is the one of the most popular magnesium alloy using in the modern industry. It is well known, that compared with steel, magnesium alloys posse better properties, such as light mass, high specific strength or thermal conductivity. It should be noted that their application is limited by poor corrosion resistance. In this work the corrosion behavior of AZ31 magnesium alloy as cast and after heat treatment were described with the use of testing in neutral salt spray atmosphere.To characterise corrosion resistance and describe layers built on the surface it was necessary to do the metallographic observations with the use of optical microscopy. After that influence of heat treatment for AZ31 corrosion resistance was examined. Measurements were conducted by electrochemical impedance spectroscopy (EIS) and by neutral salt spray tests in artificial atmosphere. Surface and cross section morphology after removal of corrosion products were observed with the use of scanning electron microscopy (SEM).The weight loss measurements show that there is no significant difference between alloys as cast and with following heat treatment.INTRODUCTIONMagnesium and magnesium alloys are popular in modern industry because of the low density and good formability. Magnesium alloys are described by few properties which have got significant influence for their application in transportation and electronics industries (Feliu & Liorente, 2015). Their wide application is limited by poor corrosion resistance. As it is well known Mg is one of the chemically most active metal. Corrosion resistance of Mg alloys depends on several factors, such as impurities, chemical composition or working conditions (Cheng, Qin, Wang, & Zhang, 2009). That all causes that there are many different ways to find well defined and good solution of magnesium alloys processing to improve their corrosion resistance.There are many different versions about the influence of aluminum on the corrosion resistance of magnesium alloy. It is known that intermetallic compounds such as Mg17Al12 due to ß-phase content plays the minor role for corrosion resistance. It is proved ß-phase acts as cathode and it has good ability to build passive layer in broad pH ranges. However it should be noted that mentioned behavior depend on size and distributions of ß-phase in the microstructure (Singh, Singh, & Das, 2015)."

Jan 1, 2016

By Lin Li, Ahmad Ghahremaninezhad

"In this paper, the electrochemical behavior of ferric and ferrous couple on the pyrite surface was studied by application of the chronoamperometry technique in an acidic solution at room temperatures and atmospheric pressure. The effects of the pyrite origin, ferric and ferrous ions concentration on the electron transfer kinetics of Fe3+/Fe2+ reaction were probed. Tafel behavior of all the test conditions were developed. The results showed that the ferric-ferrous reaction on pyrite electrodes with different origins have a common mechanism, despite different reaction kinetics. The exchange current densities of the redox reaction have the same magnitude of about 10-5 A·cm-2, which is far lower than the value reported for the gold and platinum electrodes, but larger than that of the chalcopyrite electrode. The cathodic transfer coefficients are between 0.4 and 0.5, while the anodic transfer coefficients appear unusual with the lowest value being 0.23. It was also demonstrated that an increase of one order of magnitude of iron concentration has no clear effect on the exchange current density and cathodic transfer coefficients of Fe3+/Fe2+ redox reaction.INTRODUCTIONPyrite, FeS2, is mostly considered as a gangue mineral which frequently coexists with valuable minerals and metals, such as gold, copper and nickel. Its separation from valuable minerals can be a costly process (Chandra & Gerson, 2010). In refractory gold ores, the fine gold particles are locked inside the pyrite structure. Oxidative leaching of pyrite is a hydrometallurgical method to destroy the structure of pyrite and expose the fine gold particles to the cyanide solution in the downstream cyanidation circuit. Pyrite oxidative leaching can be achieved by oxidation of pyrite via oxygen and ferric ion(McKibben & Barnes, 1986). In fact, pyrite oxidation by oxygen and ferric is a significant source of acid mine drainage(AMD), which adversely causes serious environmental problems(V. P. Evangelou, 1995).The pyrite oxidation mechanism is accomplished in three consecutive steps: (i) pyrite is oxidized by oxygen and ferrous ion formation (Eq. 1); (ii) ferrous oxidation by oxygen and ferric ion formation (Eq. 2); (iii) pyrite oxidation by means of ferric ions (Eq. 3). Hence, both oxygen and ferric participate in the pyrite oxidation process (Moses & Herman, 1991):"

Jan 1, 2016

By D. R. Schmitt, N. Ong, R. S. Kofman

Shales and mudstones comprise about 75% of all the sedimentary rocks. In, particular, organic rich shales are considered as a petroleum source rock and more recently with the advent of hydraulic fracturing technology to be a reservoir in their own right. In this sense, the aforesaid motivates our work with laboratory measurements of elastic properties of these geologic materials, which are known to be anisotropic. As such, assuming Vertical Transverse Isotropy (VTI) symmetry, the dynamic and static moduli of a series of cores from various geological formations in Alberta, Canada are simultaneously investigated as a function of confining pressure using the ultrasonic pulse transmission method and strain gages. Dynamic moduli were obtained from ultrasonic P- and S-wave velocities measured on a prism cut with faces perpendicular, parallel and oblique to the assumed vertical axis of symmetry. Static moduli were calculated from strain-stress curves obtained along the directions perpendicular and parallel to the assumed axis of symmetry as well. Velocity measurements show that samples are highly anisotropic, but that the pressure-dependent behaviour of the wave speeds differs. VP(90°) and VSH(90°) both with layer parallel propagation and polarizations change little with pressure while VP(0°) and VS(0°) (both with layer perpendicular propagation) display significant nonlinear responses particularly at pressures < 25 MPa. These characters transfer to the derived full set of elastic constants. In order to effect a proper comparison of the dynamic and static moduli, we convert the dynamic elastic constanst to linear compressibilities pependicular (Kdyn1) and parallel (Kdyn3) which are directly comparable to the static tangent compressibiities obtained by differentiation of the observed strains. Both sets highlight the anisotorpic nature of the material but most interestingly Kdyn1 _ Ksta1 but Kdyn3 > Ksta3 by nearly 40% for one of the samples. The other samples measured respond similarly suggesting that conceptually the structure of such materials could be considered to be constructed of alternating stiff or compliant layers. This finding has implications in the response of the formation to stress particularly during hydraulic fracturing and the interpreation of acoustic logs in providing appropriate measures of elastic properties for engineering purposes.

Jan 1, 2015

By N. Molaei, E. R. Bobicki

The continued demand for mineral products, coupled with the depletion of high-grade ore resources, has led to the mining of lower grade ores, which often require fine grinding to achieve mineral liberation. Regrinding of low-grade ores results in the production of fine gangue mineral solids and produces vast quantities of fluid fine tailings which are difficult to separate from water, particularly if they are composed of clay minerals. Organic synthetic polymers and inorganic salts have been widely applied in flocculation of colloidal suspensions in the treatment of mining tailings. However, there are growing concerns regarding their impact on the environment and human health. Recently, extracellular biopolymer flocculants or bioflocculants have attracted much attention as alternative reagents. In this study, much effort has been devoted to considering the effectiveness of protein and polysaccharide-based biopolymers for the dewatering of clay slurries. The interaction between kaolinite and illite clays and biopolymers was investigated via settling tests at pH 7 and 10. Zeta potential measurements were also conducted as a complementary technique. Results showed that protamine and lysozyme protein- based biopolymers were generally the more effective bioflocculants. Pectin, a polysaccharide-based biopolymer, showed a dispersing effect and has the potential to be used as a dispersant and/or depressant for clay minerals in froth flotation. INTRODUCTION With the depletion of high-grade ore resources, the need for mining of low-grade ores has increased over the past few decades (Bourgès-Gastaud, Stoltz, Dolez, Blond, & Touze-Foltz, 2014; Chen, Walshe, Fru, Ciborowski, & Weisener, 2013; C. Wang, Harbottle, Liu, & Xu, 2014). Low-grade ores often require fine grinding and contain clay minerals, leading to the generation of fluid fine tailings (FFT). It is a challenging process to separate suspended clay particles from water (Craciun, Manaila, & Stelescu, 2013; Dompierre, Lindsay, Cruz-Hernández, & Halferdahl, 2016; Kasperski & Mikula, 2011; Mercier et al., 2012). Clay minerals form stable dispersions in water due to their anisotropic nature, non-spherical morphology and colloidal size (Lagaly & Ziesmer, 2003; Olphen, 1977). The difficulty in separating clay minerals from water has led to the accumulation of vast quantities of FFT in oil sands, phosphate, copper and nickel operations, representing a huge liability for mining companies (Chen et al., 2013; Mercier et al., 2012)

Jan 1, 2019

By L. J. Surges, C. Bazin, D. Hodouin

"A kinetic model was developed for the conditioning and flotation processes of an industrial lead concentrate dezincing circuit. The models were incorporated into a flowsheet simulator. Simulation results demonstrate the advantages of split conditioning of coarse and fine particles and the potential of this approach for the production of the heuristics required for the development of intelligent control strategies.The conditioning model relates the proportions of activated and hydrophobic surfaces and residual reagent concentrations to activator and collector reagent flowrates. The model accounts for the solids and water flowrates, and for the solids grade and size distribution. The flotation model uses the predicted proportion of hydrophobic mineral surface, the aeration rate and the froth depth to estimate cell, bank and circuit performances. IntroductionFlotation has been the object of modelling and simulation studies for more than two decades. The process is usually modelled as a kinetic one in which the particle flotation rate constants are key parameters. Rate constants are related to the operating variables (pH, reagent flowrates, aeration rate, etc), however these relationships are seldom established in the literature.In spite of the large amount of literature on flotation modelling and simulation, few papers deal with the interaction between flotation rate constants and operating variables. This important gap, which was identified in the early seventies by Woodburn (l970), still exists. One of the first attempts to include operating conditions in a flotation simulator was made by King (l973), who explicitly introduced the aeration rate into an air bubble loading model. Lynch et al. (1981) used an empirical model to relate the proportion of slow floating particles to the ratio of collector per ton of ore. Such empirical relationships are difficult to calibrate and cumbersome to use when an activator and a collector are added to slurries in which particle size distribution and surface characteristics are changing. Eascur and Herbst (l982) relate in a fundamental way the mineral flotation rate constants to the aeration rate, froth depth, agitation and frother concentration, however the model does not account for reagent flowrates. Niemi et al. (1982) have proposed a model for the conditioning of minerals and included it into a conventional flotation simulator."

Jan 1, 1988