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By R. Amelunxen

"The molybdenite associated with copper porphyry ores is generally treated in a flotation circuit consisting of a separation and a cleaning section. In the last few years column flotation cells have replaced the numerous counter-current stages that were previously used in the cleaning section. Despite this, little has been published regarding the number of column cleaning stages required. Therefore a Moly flotation database is assembled with the objective of verifying the existence of a common upgrading profile. This can then be used as a guide in the prediction of the number of stages required to achieve a given concentrate grade.INTRODUCTIONAlthough the first use of Column Flotation was on copper flotation products, the popularity and understanding of their operation was not really achieved until they were widely implemented in Moly circuits in early 1983. The use of columns in Moly plants has since left a legacy of information, both published and unpublished. The data collected since that time has been used primarily used to establish column operating parameters and to determine upgrading potential within the circuit.Byproduct Moly generally occurs with porphyritic copper ores in concentrations less than 0.1% MoS2. As such, piloting a new moly ore to produce, say 5 Kg/Hr MoS2, in a slurry approximately 1 Lt/min (at 10% solids), requires a moly plant feed of about 570 Kg/Hr, which translates to a mill feed rate of 200 to 800 Tonnes per day (depending whether you deal with Chilean or Canadian ores). Piloting Moly for any lower tonnage would reduce the accuracy of the testwork.Thus a need exists to collect operating data in order to establish the existence of process relationships that could be used for feasibility and design purposes.The object of this paper is to expose a preliminary relationship that could be used for the purposes described above and to apply the findings to a preliminary design of a moly cleaning circuit flowsheet."

Jan 1, 1990

By P. Miranda, K. Le, G. Maes, R. Peters

"The Mount Milligan Mine, owned by Thompson Creek Metals Company Inc. (TCM), started operations in September of 2013. It is located between the communities of Fort St. James and Mackenzie and is the first major metal mine to open in British Columbia in 15 years. Based on reserves as of January 1, 2014, it has an estimated 22 year mine life with 2.1 billion pounds of copper and 6 million ounces of gold in reserves. Like all commissioning operations, there have been issues achieving design throughput and recovery due to flow sheet design, equipment failures, control philosophy, and reagent scheme. Efforts to improve overall mill performance include equipment modifications, reagent screening and testing, and grind size testing. Applying these changes to the mill and working closely with the mine has resulted in continuous improvement each month as Mount Milligan looks to achieve the nominal design capacity of 60,000 dry metric tonnes per day in the later part of 2015. Considerable focus is being placed into ensuring size reduction equipment is utilized effectively. Additional modifications and tests are being undertaken to steadily improve processes and alleviate restrictions in the mill. This paper will discuss the start-up and present ramp-up history of Mount Milligan, the current mill processes, and the steps taken to achieve expected production numbers.OPERATION BACKGROUNDMount Milligan is an open-pit copper and gold operation wholly owned and operated by Thompson Creek Metals. It is located approximately 155km northwest of Prince George, British Columbia, between the communities of Mackenzie and Fort St. James. The copper-gold porphyry deposit contains a Measured and Indicated Mineral Resource of 706.7 Mt at 0.18% Cu and 0.33 g/t Au, containing 2.84 billion lb. copper and 7.50 million oz. gold. Mine life is currently estimated at 22.1 years (“Feasibility Update – Mt. Milligan,” 2009). The mill is designed to process 60,000 dry metric tonnes per day and produce 400 dry metric tonnes of concentrate per day averaging 25.5% Cu and 40 ppm Au. Concentrate is delivered by truck and trailer to Mackenzie followed by rail to Vancouver for overseas shipping to various customers.Mount Milligan is considered a “zero discharge” operation meaning no process or surface water will be discharged to the environment. As well, stockpiling is very limited and is only permitted for a short period of time. This scenario presents several unique challenges. Scheduling of ore/waste production must be carefully planned as waste rock is used to build the tailings storage facility (TSF). Reagent selection is also important as persistent chemicals will have a tendency to build up in reclaim water which feeds the process water tank."

Jan 1, 2015

By Joe Pease

"The demand for minerals and metals is increasing. Head grades of ore bodies are dropping. Remaining ores are becoming finer grained, more complex, and more logistically challenging. Mineral processing – in particular comminution – already consumes a huge amount of energy. But in 20 years’ time, it will require about six times as much energy as today to meet the world’s mineral demand.Unless we do something different.As minerals professionals, it is our job to find that “something different”. The world is relying on us. Of course, we must look for new breakthrough technologies and techniques. We must find them, and we will find them – most likely in surprising areas.But what if we also already know how to make 30-50% improvements to efficiency? Just by using existing technologies, by applying modern analytical techniques, by custom designing our plants, by applying manufacturing principles, by breaking down our management silos between disciplines.The thing is, industry professionals already know this. Yet – in spite of a lot of intelligent people trying very hard – we just can’t seem to make it happen.This discussion considers why, despite our best efforts, we don’t get the best out of what we already have. Why we are wasting energy and money. Once we understand why, we can set about unlocking that value and improving industry productivity and energy efficiency. We will discuss the role that professionals and volunteer professional organisations like CMP and CEEC can play in catalysing the changes."

Jan 1, 2015

By David Seaman, J-P Franzidis, Emmy Manlapig

"A new device has been developed to directly measure the bubble loading of particle-bubble aggregates in industrial flotation machines, both mechanical flotation cells as well as flotation column cells. The bubble loading of aggregates allows for in-depth analysis of the operating performance of a flotation machine in terms of both pulp/collection zone and froth zone performance. This paper presents the methodology along with an example showing the excellent reproducibility of the device and an analysis of different operating conditions of the device itself.The device has been used to investigate the froth selectivity of attached particles. Simultaneous measurements were made using a different froth recovery measurement technique in the same flotation cell. A comparison of these techniques shows that in this case, particles are selectively detached from bubbles at or near the pulp-froth interface.INTRODUCTIONA flotation cell can be considered to operate in two distinct phases or zones; namely the pulp or collection phase and the froth phase. The pulp zone is responsible for the formation of hydrophobic particle-bubble aggregates, whilst the froth phase is responsible for the separation of these aggregates from surrounding suspended hydrophobic and hydrophilic particles. Thus, the froth phase is the grade determining phase in flotation. A measurement of the bubble load (the mass of particles attached to air bubbles in units of mass/volume) will enable the analysis of the performance of both the collection zone at creating bubble-particle aggregates and also the froth zone at separating these aggregates from surrounding pulp.A measure of froth zone performance that has been used extensively in flotation research is the Froth Recovery, Rf, of a particular system. Froth recovery is defined as the mass of particles collected in the concentrate launder by true flotation as a fraction of the mass of particles entering the froth phase. The measurement of bubble load allows for this term to be calculated easily, rather than having to go through the laborious task of, for example, changing froth depths to determine this performance criterion (Contini et al., 1988; Vera et al., 1999b; Feteris et al., 1987)."

Jan 1, 2004

By E. A. Lowe, A. F. Bellamy, J. W. Smith

"In the autumn of 1977 Bethlehem management initiated feasibility studies on recovery of by-product molybdenum from concentrate produced at the existing Highland Valley mining operation. Over the fall and winter months test work was carried forward concurrent with design, flowsheet, equipment specification and cost studies. The decision was made to go ahead with a 200 ton-per-day treatment plant. Construction started in early 1978 and progressed to an initial start-up stage in mid-June. Full operational status was reached in August 1978. Operational results through August 1979 are presented. INTRODUCTIONBethlehem Copper Corporation operates a 20,000 ton-per-day Open Pit Mine and Flotation Plant located in the Highland Valley, some 30 air miles Southwest of Kamloops and 20 miles Southeast of Ashcroft, B.C.Two open pits are worked; the Iona Pit with limited reserves of higher Mo content, and the lower grade, more extensive Jersey Pit. Upwards of 150 tons per day of bornite-chalcopyrite bulk concentrate is produced, ranging 0.25% to 1.5% in molybdenum grade depending on the area mined."

Jan 1, 1980

By D. A. Trotter, G. J. Goddard

"This paper describes a method of deciding on various design parameters for a sublevel caving layout. Layout design curves are obtained from the output of a computer optimization program. The program uses mathematical relationships derived from the theory of gravity flow of material to optimize the large number of interdependent design variables which are involved.IntroductionIn the design of an efficient sublevel caving mining system, a large number of interrelated variables need to be considered. Although many papers discuss individual variables, very little exists in the literature to show how these variables interact to achieve optimum results. This can lead to trial and error in sublevel caving design, which can prove costly, particularly because sublevel caving is a mining method which requires integration with sublevels above and below. With no pillars being left, experimental stopes cannot be isolated for study. Unfortunately, the complexity of layout design and the costs associated with trial and error have caused many planning engineers to choose more tried and tested mining methods.Sublevel caving works best to extract low-value ore surrounded by incompetent rock. All phases of the mining method can be highly mechanized, allowing low operating costs and high production rates. Good safety records are achieved, as workers are always in 'good' ground and the method is regular, making it comparable to an industrial process."

Jan 1, 1981

By Rick Wilkins

The stability of steep embankments is a major safety issue in open pit mining, highway passes, and earth filled dams. A failure in any one of these situations could mean a loss of very expensive equipment, a long term inconvenience, and more importantly, a loss of life. These possible catastrophes could be avoided by installing a reliable real time monitoring system. Robotic total stations (RTSs) give one possible cost effective solution to creating a near real time monitoring system. Repeated surveys at predetermined time intervals can automatically generate warnings if slope movements exceed a preset tolerance level. The variation in atmospheric refraction, combined with possible instabilities in reference targets, can make a monitoring system based on RTSs produce false alarms. A methodology has been developed at the Canadian Centre for Geodetic Engineering (CCGE) for reducing these systematic error effects. The methodology has been realized in the creation of a software package that has been successfully implemented at large earthen dams in California and at an open pit mine operation in British Columbia.

May 1, 2002

By I. Campbell, P. C. Jones, E. G. Potter, R. P. Taylor

"The Cobalt embayment is a large domain of Paleoproterozoic clastic sedimentary rocks that unconformably overlies the Archean Abitibi greenstone belt. Regionally extensive sills and dikes of Nipissing diabase, emplaced circa 2219 Ma, occur throughout the embayment and are the preferential host to gold-bearing polymetallic vein systems on the Merico-Ethel property, near the northeastern margin of the Cobalt embayment. These gold-bearing, polymetallic veins are predominantly east-west-trending, steeply dipping, discordant calcite- quartz vein systems that formed close to the time of crystallization (within ~15 m.y., based on Pb-Pb ages) of the Nipissing diabase. The ore mineralogy is complex in character, typically comprising sulfides, arsenides, native metals (gold and silver), and specular hematite, preferentially concentrated along the interface between silicate and calcite gangue. A simplified sequence of mineral deposition in the veins is: (1) "Early-stage" pyrite ± chalcopyrite hosted in quartz ± chlorite gangue; (2) "Main-stage" polymetallic (Cu + Co + As + Ag + Au + Bi ± Pb ± Ni ± U) sulfides, arsenides, and native metals hosted in calcite gangue; and (3) "Late-stage" calcite flooding ± galena. Wall-rock alteration in Nipissing diabase is restricted to narrow (<5 cm) haloes of calcite-chloriteepidote- bearing assemblages, whereas a weak alteration halo of specular hematite, calcite, and allanite-epidote has been observed in the surrounding sedimentary rocks. In terms of their age, geology, mineralogy, paragenesis, and morphology, the gold-bearing vein systems at Merico-Ethel closely resemble the silver-sulfarsenide vein deposits of the historic Cobalt and Gowganda mining camps. These observations indicate that the Au-bearing veins are variants of the Ag-vein systems and as such, have a common genesis belt. L’Échancrure de Cobalt est un large domaine de roches sédimentaires clastiques d’âge Paléoprotérozoïque qui reposent en discordance sur la ceinture de roches vertes d’Abitibi d’âge Archéen. La Diabase de Nipissing, mise en place vers 2219 Ma et qui constitue un réseau de sills et de dykes d’importance régionale, est présente dans l’ensemble de l’échancrure et constitue la roche-hôte principale des systèmes de veines aurifères-polymétalliques de la propriété Merico-Ethel, près de la bordure nord-est de l’Échancrure de Cobalt. Ces veines à minéralisation aurifère et polymétallique constituent un système de veines de calcite-quartz sécantes d’orientation principalement est-ouest et à pendage fort qui se sont formées peu de temps après la cristallisation de la Diabase de Nipissing (à ~15 Ma près, d’après les âges Pb-Pb). La minéralogie de la minéralisation est complexe; elle consiste typiquement en sulfures, en arséniures, en métaux natifs (or et argent) et en hématite spéculaire, préférentiellement concentrés à l’interface entre les silicates et la gangue de calcite. La séquence de déposition simplifiée des minéraux dans les veines est : (1) «Stade précoce» pyrite ± chalcopyrite encaissés dans une gangue de quartz ± chlorite; (2) "Stade principal" sulfures polymétalliques (Cu + Co + As + Ag + Au + Bi ± Pb ± Ni ± U), arséniures, et métaux natifs dans une gangue de calcite; et (3) "Stade tardif" calcite massive ± galène. L’altération pénétrative de la Diabase de Nipissing est confinée à des halos étroits (<5 cm) présentant des assemblages marquées par la présence de calcite-chlorite-épidote, tandis qu’un faible halo d’altération en hématite spéculaire, calcite et en allanite-épidote est noté dans les roches sédimentaires environnantes. De par leur âge, leur géologie, leur minéralogie leur paragenèse et leur morphologie, les systèmes de veines aurifères de Merico-Ethel ressemblent beaucoup aux gîtes filoniens d’argent-sulfoarséniures des camps miniers historiques de Cobalt et de Gowganda. Ces observations indiquent que ces veines aurifères constituent une variante des systèmes des veines argentifères et qu’elles partagent"

Jan 1, 2009

By R. G. Burn

"A brief outline will be given of the concept of risk and its implications with regard to investment in exploration. The relationship between risk and decisions under uncertainty will be examined as a prelude to identifying those factors which contribute to exploration risks:consideration of the effects of corporate objectives (e.g. survival, expansion, diversification) on exploration strategy and ultimately on success or failure, exploration and mining as an investment (the relationship between risk and reward) and the desired return on investment; exploration odds, funding levels, staying power, financial exposure and the concept of gambler&apos;s ruin;origins of uncertainty in exploration decision-making-man-made risks and natural hazards; the nature of introduced constraints at each exploration decision stage and their effect on the rate of success;improving the chances of success and the invest reduction of risk through sound exploration strategy, effective project generation and efficient target detection capabilities."

Jan 1, 1984

By R. L. Bruening, J. B. Dale, N. E. Izatt, S. R. Izatt

IBC Advanced Technologies&apos; Molecular Recognition Technology (MRT) SuperLig® products selectively and rapidly bind with target metal ions to remove them from solution. The MRT process can produce a high purity separation product of maximum added value at low cost. This paper discusses applications for MRT in the gold industry, including recovery of gold and silver as well as metal contaminants from various process and recycle streams.

Jan 1, 2011

By T. Hadley, E. Catovic

"Northern Minerals Limited’s (ASX: NTU) flagship project is the Browns Range Rare Earth Project (the Project) located in Western Australia, consisting of a number of deposits with high value, heavy rare earth elements, in particular yttrium, terbium, and dysprosium. The deposits are dominated by xenotime mineralisation, which occurs within hydrothermal silicified and hematitic breccias. The Company delivered an initial JORC compliant resource estimate for the Project at the end of 2012 of 10,500 t of contained total rare earth oxides (TREO), which was increased to 28,084t of contained TREO in October 2013 and further enlarged to 47,997 t of contained TREO in February 2014. Concurrent with the growth of the Project resource base, significant progress has been made in developing the metallurgical process for the beneficiation and extraction of rare earth elements (REE’s) from the xenotime mineralisation. Development of the beneficiation circuit evaluated several process options and selected whole-ore flotation and magnetic separation, followed by flotation (hybrid circuit) as the two preferred flowsheets to pilot, following encouraging results on the bench of 83% and 86% recovery to a 20% TREO mineral concentrate respectively. Several downstream hydrometallurgical extraction flowsheets were evaluated. However, the following two preferred process flowsheets were ultimately selected for further detailed investigation during the prefeasibility study: 1. Sulphation bake, water leach, purification, oxalate precipitation, and/or calcination to produce a mixed RE oxide; 2. Sulphation bake, water leach, phosphate precipitation, caustic conversion, HCl leach, and oxalate precipitation to produce a mixed RE oxalate. Excellent heavy rare earth oxide (HREO) extractions (~ 90%) from beneficiation concentrates were achieved on the bench for both circuits, however flowsheet 1 was ultimately selected as the preferred flowsheet to pilot due to lower capital and operating cost. A mixed rare earth oxalate (42% TREO) or oxide (92% TREO) can be produced with low levels of Th and U of 3 ppm and 6 ppm respectively."

Jan 1, 2014

By J. A. Finch, J. Vergouw

"Flotation selectivity becomes progressively more difficult to achieve with decreasing particle size. One of the possible problems is agglomeration, i.e. particles clustering together. One mechanism derives from the surface charge all particles develop in water. Agglomeration driven by surface charge is known as coagulation. One form is coagulation between particles of two different minerals of opposite charge. Another is coagulation between particles of the same mineral when conditions are such that the charge approaches zero.The paper describes the method of measuring charge and a new automated settling technique for measuring agglomeration. The phenomena are illustrated with galena and pyrite. Methods of assessing the importance of agglomeration in the plant environment are still to be developed.IntroductionFine particles can agglomerate (i.e. adhere to each other) under certain conditions. This is counter-productive for any physical separation process, including flotation. One cause of agglomeration derives from the surface charge that all particles develop in water. Agglomeration due to surface charge effects is referred to as coagulation. There are two forms of coagulation. If the surface charge is brought to near zero then the force of repulsion is lost and particles coagulate. This usually applies to particles of one mineral type and the technical tenn is homocoagulation. On the other hand, if two particles have opposite charge there is an attractive force. Since the particles in this case are usually different minerals this is known as heterocoagulation.Both types of coagulation can cause minerals to be misplaced. In the case of heterocoagulation this is fairly obvious. One example that may be familiar is slime coating (fines of one mineral coating larger particles of another) But even homocoagulation can be a problem an agglomerate of the same mineral particles can entrap particles of another mineral."

Jan 1, 1997

By Scott Martin

This paper will discuss the challenges currently facing the mining industry. By sharing experiences gained in the CIM Leading in Mining Course, I will highlight what’s working, what’s not, what are the challenges, what are the concerns, what are the opportunities, what needs to happen. Specifically, I will discuss what is currently happening with leadership and leadership development in members’ own organizations, what skill sets are important to develop in different hierarchical groups and how comprehensive leadership courses like the leading in Mining course can help improve leadership within individuals and the industry. Leadership development is a process not an event.

Jan 1, 2014

By P. W. Godbehere

"INTRODUCTIONMagnetic mill linings have been developed from an invention by Mr. Bertil Brandt, the originator of the Skega rubber lining. The OREBED magnetic mill lining is a concept in which rubber covered strontium ferrite permanent magnets are arranged on the inside wall of a mill shell so that they attract magnetically susceptible material be it ore, media or tramp, to form a protective layer over the magnets and to serve as an operating surface with indefinite life.Noranda Mines Ltd. through its associate Norcast Division of Noranda Metal Industries formed a joint venture with the inventors to market magnetic mill linings in North America. For the past twelve months trials have been undertaken in conjunction with Orebed Inc. to test and develop these linings for grinding mill applications at the Horne Concentrator. Two independent milling circuits are currently being operated, one treating a siliceous gold ore and the other a copper slag.This paper presents the results of the magnetic lining test programme to date."

Jan 1, 1983

By K. Parameswaran, A. Veek, A. Fernandez, P. Safe

ASARCO LLC (Asarco) Hayden Copper smelter, in Hayden, Arizona, has operated continuously (except for minor labor and economic curtailments) since 1912. The current plant configuration comprises INCO flash smelting, Peirce Smith (P-S) converting and fire refining/anode casting. In order to comply with the U.S. Environmental Protection Agency (EPA) 1-hour National Ambient Air Quality Standards (NAAQS) for sulfur dioxide promulgated in June 2010, the Hayden smelter had to increase overall sulfur fixation from approximately 95 % to 99+ %, requiring a retrofit of the existing converter department and upgrade of associated emissions controls systems. The Converter Retrofit Project (CRP) involved replacing the five existing 13’ diameter Peirce-Smith converters (2 blowing, 2 hot standby) with three new 15’ diameter Peirce- Smith converters (1 blowing, 1 hot standby) to allow for more effective process gas capture using the existing acid plant contact section. Significant upgrades were made to the acid plant wet gas cleaning section and converter primary gas handling system to improve capture performance, reliability, and sludge handling. In addition, a new tertiary gas capture system was installed to further minimize fugitive emissions from the converter aisle. The existing furnace tapping ventilation ESP was replaced with a new baghouse to enable at least 50% SO2 removal using high-surface-area dry lime injection, which was also implemented on the existing converter secondary gas baghouse system. The first two converters and all gas handling system improvements were started up in April 2018, and the third converter was brought online in November 2018. This paper presents the regulatory context; genesis and rationale for CRP; detailed description of the project; challenges during commissioning; system improvements implemented, and design considerations made, and systems performance and process optimization achieved since startup.

Jan 1, 2019

By Jamie King

This paper describes the use of dynamic scheduling and discrete event control to provide coordinated control of multiple automated vehicles. In the past decade there have been significant advances in the field of robotics for underground mining. As this trend progresses toward a realization of a completely automated underground mine the need for a central control system, capable of providing coordination for multiple vehicles in a semistructured environment, becomes more evident. In the past year general research into multi-robot coordination has been applied to the underground mining scenario and demonstrated in a scaled model underground mine in a laboratory setting. This system shows significant potential to be adopted into a full-scale implementation for mine wide automation.

May 1, 2001

By N. Behnood

"This paper describes how material selection, quality assurance, and failure investigation play important roles in the efficiency and safety of mining and metallurgical operations.INTRODUCTION Material selection, quality assurance, and failure investigation are all complementary elements of materials engineering in the application of materials technology for failure prevention. Based on commodity price increase of 300% between 2002 to 2013 [1] and increased cost ofcapital projects and operation, equipment failure, which in some cases causes complete shutdown of the operation, becomes a vital importance in mining and metallurgical plants. The following sections present a number of examples from many failure cases experienced by the author during his three decades of work as a materials engineer in the mining industry."

Jan 1, 2015

By Mark G. Lafontaine

Underground 802.11 wireless communications has become widely adopted for automation and communication purposes but maximizing the wireless signal presents many obstacles given the harsh environment as well as the presence of materials and conditions that can reduce signal propagation. Changes in elevations and curvatures in ramp to drift transitions also affect the wireless signal. Based on the requirements of wireless applications such as voice, data, or location tracking, the wireless site survey is the key tool for measuring and predicting signal strength and signal-to-noise ratio. These readings help determine the maximum distance between access points in order to sustain an overlapping wireless signal where required. This paper describes the methodology and tools used for measuring 802.11 wireless signal strength in an underground mine environment in Northern Ontario. The physical characteristics of the mine and the actual recorded wireless signal data will be presented in order for the audience to gain an understanding of the factors that affect signal throughput. Antenna selection used for the site survey will also be discussed as it played a key role in propagating the wireless signal.

May 1, 2013

By Vincent Roy

Numerous on going activities at the Daniel-Johnson Dam : ? Surveillance / monitoring ; ? Structural investigations & evaluation ; ? Injection work ; ? Crack mapping ; ? Instrumentation management (drawings & inventory) ; ? Drainage system state ; ? Foundation evaluation

Aug 1, 2013

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003