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By D McCoy

Titanium feedstocks are the building blocks of the titanium value chain. They can be mined directly, as is the case for ilmenite, leucoxene and rutile, or manufactured from ilmenite by extracting various quantities of non-TiO2 components from the ore by chemical and/or thermal processes.While feedstocks can be grouped into categories of materials with similar characteristics, they are essentially unique products from very different mining locations around the world. In fact, no two feedstocks are exactly the same. As such, the variations between the available feedstocks, in combination with the permutations in processing technologies to turn the feedstocks into titanium pigment or metal, mean that choices between feedstocks are specific to the location in which they are utilised.In this paper, the authors examine the key requirements of titanium feedstocks to the TiO2 pigment and metal sectors. Apart from the well known differences between feedstock choices for the sulfate and chloride process, the more opaque considerations in feedstock sourcing are examined.

Oct 5, 2011

By R Cannings, J Wallace, M McCamley

The mining industry continues to have major disasters (Bingham Canyon, Pike River, Upper Big Branch, Mount Polley and Samarco), which often have a devastating effect on the enterprise, in terms of personnel deaths and injuries, environmental destruction, and financial and reputational loss. These disasters are not imposed from outside the business or organisation, they are almost always a function of loss of control of the management of the organisation’s critical assets and processes that they contain or to which they are exposed.Asset integrity is discussed as an effective response to business risks in order to mitigate, control and recover from loss scenarios that could expose a mining operation to significant property damage and business interruption, or even total loss. Vital to this process is the identification and control of risks to critical assets. Components of a critical asset assurance program are presented for discussion.Formal risk assessment has a longer history in industries other than mining, eg petrochemical, nuclear, military, aviation and space industries. Risk assessment is a structured, proactive approach to understanding and improving risks, as opposed to a reactive ‘fix-it-when-it-breaks’ mentality. Risk assessment techniques were triggered by major public disasters, such as the Flixborough chemical plant disaster (1973), Three Mile Island nuclear plant event (1979) and others.Today, most industries see risk assessment as an inherent part of their business, but do mining sites capture business risks that are related to major loss scenarios, which could have a significant impact on the operation?Does your risk assessment process:- involve a team having the right skill set so that the discussion is both stimulated and technically sound?- use generic assessment when a site-specific assessment is needed?- fail to consider all possible outcomes, including maximum foreseeable loss (MFL)?- fail to identify all hazards and controls associated with a particular activity?- fail to monitor controls effectively?This paper addresses the issues identified by these questions and provides some direction for developing a risk management process where business risk associated with critical asset integrity is integrated with other business and safety and health risk processes to provide a robust method for managing your business. Case studies and common findings from critical asset failures are used to support the need to include critical asset assessments as part of business risk management processes.CITATION:Wallace, J, McCamley, M and Cannings, R, 2016. How robust are your asset integrity management processes? In Proceedings International Mine Management Conference, pp 53-64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By M Noakes

EcoTechnology refers to a series of potential metallurgical processes for complex ores, concentrates, tailings and slags that are all based on an initial chlorination step at low to moderate temperatures probably in a fluid bed chlorinator (FBC). Examples of the research and development (R&D) results are provided in this paper for a high grade Au/Sb Leach Tailings (EcoGold<sub>®</sub> Process), a very refractory sulphide Au concentrate, a refractory gold calcine tailings, a Cu/Au tailings (EcoCopper<sub>®</sub> Process), bulk polymetallic sulphide concentrates and polymetallic sulphide/oxide complex ores (EcoZinc<sub>®</sub> Process and EcoLead<sub>®</sub> Process). R&D on over thirty different ore types has been conducted at a bench scale as discussed. Latterly a dedicated pilot plant was designed and constructed by EcoTech Mining Pty Ltd (EML) and several of the different feed stock results have been confirmed by pilot plant testing. It is planned to scale up to a commercial demonstration plant. To demonstrate the versatility of EcoTechnology, bench and pilot plant test results on five of the projects are used as case studies as follows: Fosterville ‘leach tailing’, VIC; Wiluna flotation concentrate – BIOX Feed, WA; Wiluna calcine facility tailings, WA; Mt Morgan Cu/Au tailings, QLD; Polymetallic sulphide concentrates from Pegmont Deposit, QLD and Polymetallic sulphide/oxide ores from Commonwealth Mine Project, NSW. CITATION: Noakes, M, 2018. Improved recoveries and environmental outcomes from complex ores utilising EcoTechnology, in Proceedings Complex Orebodies Conference 2018, pp 122–123 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

Iron formation-hosted iron ore deposits account for the majority of current world iron ore production and consist of three classes: unenriched primary iron formation with typically 25 to 45 wt per cent Fe; martite-goethite ore formed by supergene processes, with abundant hydrous iron oxides containing 60 to 63 wt per cent Fe; and high-grade hematite ores thought to be of hypogene or metamorphic origin overprinted by subsequent supergene enrichment with 60 to 68 wt per cent Fe.Individual iron ore deposits range from a few millions of tonnes to over two billion tonnes at >64 wt per cent Fe, although most are within the range of 200 to 500 Mt. In the Hamersley Province of Western Australia, martite-goethite ores are largely developed in the Marra Mamba Iron Formation, although high (>0.08 per cent P) phosphorous mineralisation is also well developed in the stratigraphically higher Brockman Iron Formation. Whilst the vast majority of high-grade microplaty hematite ore is best developed in the Brockman Iron Formation, this paper provides the first textural evidence of locally significant microplaty hematite mineralisation in the Nammuldi Member of the Marra Mamba Iron Formation, in the Chichester Ranges at the Christmas Creek, Cloud Break and Mount Nicholas prospects. Petrographic studies have identified a high-grade Fe texture composed of nanometre scale plates of hematite in mineralised sections of primary microplaty hematite deposits in the Pilbara and elsewhere, well below the normal depth of weathering or dehydration. The population of nanometre to micrometre scale hematite plates is interpreted to represent various stages of nucleation, crystallisation and progressive growth of hematite from the primary ore-forming fluid in areas that were once iron-rich carbonates or silicates in the BIF.

Jan 1, 2005

The long continuing controversy over the Origin of fusain, whether it is a product of primeval forest fires, or of special conditions of weathering (including bacterial decay) of the vegetal debris concerned prior to, burial, has now been extended, to include the possibility that fusain is a product of the coalifaction process subsequent to deposition, so that doubt may reach even to its time of formation.The conflicting views on this point are summarised in the following quotations from two recent publications (my italics in each quotation):1. "Recent observations made in peat and brown coal deposits in Australia, England and Germany strongly suggest that practically all fusain is formed by coalifaction after deposition and 'preliminary compression. In deposits of advanced brown coal rank, it normally takes the shape of pieces of wood compressed parallel to the bedding plane; and some fragments consisting partly of fusain and partly of vitrain exhibit the same amount of compression throughout. This would seem to indicate fusinisation after burial, as hard brittle charcoal would be crushed, or else retain its original irregular shape if strong enough to withstand pressure.In some immature deposits, however, where cover is of a hydrostatic nature rather than a vertical compressionar force, occasional pieces of fusinised wood showing very little flattening are present, but such immature deposits seldom contain the proportion of fusain found in higher rank coals. In view of this, and the possibility of introduction of charcoal into peat deposits, it is felt that a small amount of the fusain in coal may represent wood charred before burial, but most of it almost certaInly originated as a product of fusinisation after burial" (Dulhunty, 1948, p.14).

Jan 1, 1953

By Lawrie DC

Finely ground beryl was decomposed by mixing with ground limestone and soda ash andheating at 900¦C for,4-6, hours.The sintered material was then crushed and leached by boiling under reflux with 5N sulphuric acid for up to 4 hours. The liquor containing Be, ; Al, . Fe and, other elements as sulphates, was separated from the residue which consisted mainly of silica and gypsum, either' by filtration or by decantation washing.The clarified leach liquor.was first treated to remove Fed}: , by contacting with a primary amine-kerosene solution in2 counter-current stages. The iron free liquor wa,s then passed to a 4-stage counter-current extraction unit where it was con-tacted with 0.5M di-(2 ethyl hexyl), phosphoric acid (EHPA) in kerosene. The'operating conditions were such that at least 99 p'br cent of the Be and only 7' per' cent of the Al- was, extracted The ,B6`= and. Al were ;stripped from the organic phase by sod-ium hydroxide solution of suitable concentration to form soluble "beryllate" and "aluminate" respectively. Most of the Be was subsequently precipTitated a's Bo(OH)2 by-hoating the alkaline solution to 90C, the Al remaining in solution. After filtra-tion and washing, the Bo(OH)2 could be ignited directly to BeO at about 1000 C or used as a feed to further purification stages aimed at producing "nuclear grade" BeO.A small coaAter-current extraction unit was operated con-tinuously using liquor derived from the sintering and leaching stages. Data obtained in batch laboratory tests were confirmed. A product obtained by ignition of the washed "beryllate" precip-itate contained more than'99 per cent BeO.

Jan 1, 1963

By C McIntosh, M Carder, P M. J Durance

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Disseminated, gold-bearing sulfide minerals hosted in sheared, wall rock metasediments and clay alteration zones comprise one of the dominant styles of Palaeozoic orogenic gold mineralisation within the Reefton Goldfield, and is exemplified by OceanaGold’s Globe Mine. This study begins the exploration and characterisation of the gold-arsenic-antimony mineralisation hosted within the dominant lithologies of the Globe-Progress shear zone. The main gold-bearing sulfides are pyrite, arsenopyrite and stibnite. Pyrite and arsenopyrite are not compositionally uniform across the Globe-Progress shear zone. Pyrite from the mineralised greywacke and argillite has higher As contents than pyrite in the host rock and pug breccia. Furthermore, the mineralised greywacke and argillite pyrite are enriched in As from core to rim. The 3D models based on bulk assays reveal a significant correlation in the distribution of Au, As and Sb. The interpolant for Sb envelops those for Au and As, which in turn are very similar to each other in their vertical and lateral extents across the shear zone. This result is consistent with earlier findings that the occurrence of stibnite represents a separate and likely later phase of mineralisation relative to that represented by the formation of disseminated pyrite and arsenopyrite both of which exert a stronger control on the distribution of As.CITATION:Durance, P M J, Christie, A B, McIntosh, C and Carder, M, 2015. The composition of disseminated, gold-bearing sulfides within the three-dimensional framework of bulk Au, As and Sb in the Globe-Progress orogenic gold deposit, Reefton Goldfield, New Zealand, in Proceedings PACRIM 2015 Congress, pp 327–334 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By O Omidi, P D. Katsabanis

The effect of delay time on fragmentation has been discussed for a long period but rarely in a satisfactory and unbiased way. Despite the efforts of many researchers, delay selection for fragmentation improvement or optimisation remains a controversial issue. Large-scale tests have been plagued with scarcity and scatter of observations, while small-scale tests have been associated with boundary effects and energy losses. Theoretical work is often used to produce explanations for available measurements or tries to simplify wave propagation and wave interaction to guide observation and practical work. The present work analyses results obtained from a relatively large number of small-scale experiments in blocks made of grout, and re-analyses results of previous experiments, to conclude on the effect of delay on fragmentation. It is shown that the main contribution of the delay is found in the fragmentation of the larger fragments of the blast, while the small fractions show almost no effect. Samples, where copper liners were used to inhibit penetration of detonation products in the rock mass, showed effect of delay only when short times were used and steady but poor fragmentation when long delays were used. Based on small-scale experiments, it appears that the fragmentation is optimised when a hole fires prior to the radial cracks, produced by the previous hole, reach the free face of the blast. Gas penetration may result in the development of few more fractures that affect the fragmentation of the largest particles of the blast.CITATION:Katsabanis, P D and Omidi, O, 2015. The effect of delay time on fragmentation distribution through small- and medium-scale testing and analysis, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 715–720 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By B Hall

In feasibility studies the choice of optimum cut-off grade is typically based on an evaluation of tonnage grade curves and manual design of stopes at one or two cut-off grades. In the industry these stope designs are usually based on break-even cut-off grades, but there is little consensus on what cost and price assumptions ought to be included. A new tool for automated stope design has been developed that generates sets of stope shapes for a nominated range of cut-off grades, or depending on the nature of the mineralisation, cut-off values based on net smelter return calculations in the block model. The stope design procedure includes constraints in stope and pillar geometry for the selected mining method and can be used to evaluate sublevel interval and sensitivities to other design parameters in the specific geological and geotechnical environment. These ænested stopesÆ are analogous to ænested pitsÆ in open cut design, and can be used as a key input in the æhill of valueÆ methodology for the evaluation of the optimum cut-off grade in underground design. The results of many consulting studies indicate that a break-even cut-off grade will not be the optimum cut-off grade. A particular benefit of the new stope design tool is that the design rules used to establish stope shapes in the feasibility study can then be used in mine production, in an optimal and repeatable method. This methodology is being advanced in the AMIRA P884 PRIMO project, which is a new research collaboration coordinated by AMIRA International. The project has brought together active research groups in Australia and Canada, with the goal of developing a flexible framework and set of software tools for optimisation in underground mine design.

Jan 1, 2009

Blasting in Norwegian mines is often carried out by contractors who tend to look for the cheapest solution, without concern about fragment quality. The requirementsfor a contractor are usually only related to the maximum size of boulders and the quantity per month. Even when the owners of the mine are responsible for blasting, very little effort is made to optimise the blasting process. This paper presents test methods which were used and results from small-scale and full-scale blasting tests. In the small-scale tests, cubes 500 x 500 x 500 mm of four different rock types were blasted in a chamber, using two types of dynamite explosive. The velocity of detonation (VOD) for the dynamite explosives was 3000 m/s and 6000 m/s respectively. Three cubes of each rock type were blasted with each type of explosive, and a total of six cubes of each rock type was used. The entire muckpile (approximately 350 kg) was- sieved and weighed after each blast and fragments between 8-16 mm were tested for impact values and flakiness. The results of these tests clearly showed improvement in fragmentation the closer the acoustic impedance ratio of the explosive (VOD x density) over the rock (Cp density) was equal to one. The results also showed that the quality of the fragments (in terms of impact values) tends to be better when the cubes are blasted with the high velocity dynamite.

Jan 1, 1995

By McAllister J

Oxygen was in restricted use at Port Kembla until tonnage oxygen became available for steelmaking in the open hearth furnaces. In adopting the new process various modifications to furnace design and operation were necessary and some of these, including increase in roof height and variation in firing and draft control, are discussed.The design of oxygen lances is also discussed and various steelmakingtechniques considered.Steel production increased with oxygen roof lancing-one- furnace producing 8,507 tons in one week-but new problems, such as rate of refractory wear, and disposal of fumes, were created.Design of future open hearth oxygen furnaces is predicted.INTRODUCTIONIn the post-war era, the availability of "tonnage" oxygen caused a major revolution in steelmaking techniques. Various pneumatic processes showed that steel can be madeat a very fast rate and that oxygen steelmaking can be applied to open hearth furnaces. Methods used are surface impingement with roof lances, bath injection with door lances, flame enrichment with fuel firing, mixed gas and oxygen firing, and enrichment of normal combustion air by oxygen injection into the flue systems.Owing to its previous restricted availability and high cost, oxygen was used in rather small quantities in the open hearth furnaces at Australian Iron and Steel Pty. Ltd.(A.I. & S.), Port Kembla, until about the middle of 1960.At that time tonnage oxygen became available and roof lancing commenced on No. 33 furnace at No. 2' open hearth shop.

Jan 1, 1962

By K L. Silversides

Shales form distinctive peaks in natural gamma downhole logs, which are used to manually identify the location of ore boundaries. These shales form important lithology markers that can potentially be automatically identified using Gaussian processes. This approach is trialled using data from a typical iron ore mine in Western Australia which contains the Marra Mamba sequence of the Hamersley province.The method uses Gaussian processes (GPs) with a single length scale squared exponential covariance function. A library of 8 m sections, where natural gamma measurements were taken at 10 cm intervals down the hole, was used to train the GP model. This library was iteratively improved and was tested using natural gamma logs that were not included in the library. Areas that were misclassified or were not clearly classifi ed were added to the library. The new library was then used to train the model and improve the results. The trials used a double gamma peak from the NS3 and NS4 shales at the boundary between the Newman 1 and Newman 2 ore zonesin the Newman member and the AS1 and AS2 shales at the base of the West Angelas member. The results show that both boundaries can be identifi ed with an accuracy of over 99 per cent. The classification has the highest accuracy on undeformed shales. This method provides a fast, accurate and objective identifi cation of shale and ore boundaries and can potentially replace the current manual detection.

Jul 11, 2011

This paper is intended to continue the subject in the light of recent work, from where it was left at the conclusion of the discussion on the excellent paper by the late Mr. Noel Haszard. The position then obtaining is briefly summarised below:-The points which received general agreement at that time were:-'(1) That the gold occurs, probably in an elemental form, in a state of very fine division in the pyrite.(2) That the aim in roasting of Kalgoorlie flotation concentrates should be to obtain the maximum porosity possible. The gold tellurides were amenable to treatment with either a' solution of high lime and cyanide strength combined with fine grinding, or bybromocyanidation without re-grinding.(3) That a low roasting temperature is essential during the elimination of the first atom of sulphur, if the final calcine is to give a good extraction by cyanidation.(4) Even with the best temperature conditions of roasting then determined, and after a period of cyanidation of the calcines until no further extraction was obtainable, the lowest calcine residues obtainable were equivalent to approximately 1·8 dwts. per long ton, based on an original concentrate of pure pyrite.There was some division of opinion at the time as to whether the temperature of the later stages of roasting was significant, and also as to the reason why the initial roasting temperatures had so marked an effect.

Jan 1, 1939

It is a very great privilege for me to be able to address you tonight and I am deeply sensible of the honour which has been done me. I am equally sensible of the inadequacy of my training for the position of President of your Institute.May I say at once what a very great pleasure it is to have so many members from the mainland States visiting us here in Tasmania. We do hope that you will find pleasure and profit in your stay.Since the Annual Conference is always held in the vicinity of one or other of the great mining fields, it has become the practice for the Presidential address to review the history of the particular field and t(j) indicate its place in the economic structure of the country.I propose to follow this practice and to try and present to you a short picture of thÇ mineral industry as it has existed in Tasmania. None of the information is new it is available in diverse and remote geological reports and in publications such as Witham's Western Tasmania and the more recent Peaks of Lyell. The last composite approach was written twenty years ago by P. B. Nye and published as a Geological Survey Bulletin.I have enjoyed preparing this address because on occasion I find it refreshing to look back and see what was known and what was accomplished in the days when the going was a little tougher than it is now, and to speculate upon the reasons that drove men to do what they did. I shall therefore discuss the search for minerals in this State; the discoveries over the years; the elation with which the new fields are greeted; the disappointments attending some of them; the mines that have come and gone; and the...

Jan 1, 1958

By E de N, B H. Usher, F D. I Hodgson

Due to the haphazard application of static tests in South Africa, several methods and interpretations have been followed. This has resulted in confusion amongst practitioners and regulators in the use and validity of these methods. Research was done over a two-year period to define standardised methods and interpretation of results. This included laboratory testing and continuous consultation with all interested parties throughout the country. The research yielded a modified ABA, based on several existing methods. The methodology includes AP determination using hydrogen peroxide, and an analysis of the supernatant by ICP. This has the advantage of not only registering reactive sulfur, but also provides the NAG pH, that enhances the interpretation and QC of the tests. Analysis of the supernatant provides an indication of heavy metal solubilisation, should acid conditions arise. One hundred and seventeen samples were compared to Leco S analyses and provided a good correlation. The Leco values were slightly elevated due to the reporting of total S as opposed to æreactive SÆ. The NP method deviates from the usual methodology, in that H2SO4 is used (to provide a field analogy) and the fact that a 24-hour stabilisation period is allowed before back-titration. The latter modification appears to prevent psuedo-buffering by transient phases. These methods have also been tested for repeatability and prove to be robust. A very simple macro-driven spreadsheet, æABACUSÆ, was also developed. This spreadsheet allows the entry of basic data and provides a detailed interpretation and graphical display of typical ABA data. In cases where drill holes are used, the Pennsylvanian approach of volume calculation can also be done with ABACUS. The results of the research have been distributed to interested parties in South Africa and it is hoped that these methods and their application will find widespread acceptance.

Jan 1, 2003

By M Grigorescu, S Crimp, J H. Hodgkinson, P Kokic, W Jin

Mines are typically located in remote, inhospitable locations and movement of materials between site, processor and port are often at risk from extreme weather events. Mining companies have recorded multiple supply chain, production and logistics delays caused by climatic events. Recent analyses of extreme temperature and rainfall events (90th and 99th percentile values) for 1960 to 1985 and 1986 highlighted regionalised increases in the frequency and intensity of extremes. The trajectory of this change is likely to be maintained (IPCC, 2014) in regions where increases have occurred historically, suggesting that some parts of the industry may be faced with management challenges beyond current experience (Hodgkinson et al, 2010; Loechel, Hodgkinson and Moffat, 2012). Reliance on historical data to plan for extremes (such as scheduling production downtime to reduce impact) will become increasingly ineffective as the data become less representative of future conditions. Importantly, mine site remediation and closure management need to consider the future climate to ensure rehabilitation is sustainable under changing conditions.Vulnerability assessments and risk-reducing adaptation will become more common as the industry reaches to secure both a mine’s longevity and the industry’s reputation as shareholders and clients become less tolerant of repeated or prolonged interruptions (Hodgkinson, Hobday and Pinkard, 2014). Climate-resilient new mines may be planned using site planning tools combined with knowledge of future climate scenarios. Scenario tools are valuable for developing a gated risk management approach to reducing climate-risk during a mine’s life, through to the rehabilitation process and for managing care and maintenance or closed mines.CITATION:Hodgkinson, J H, Crimp, S, Jin, W, Kokic, P and Grigorescu, M, 2016. Life-of-mine planning tools for a changing climate – intuitive, interrogative, iterative, in Proceedings Life-of-Mine 2016 Conference, pp 71–74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By C B. Valentin

It is acknowledged that the analysis of iron ores using X-ray fluorescence (XRF) for major and minor elements is best carried out on fusion discs. This method of sample preparation eliminates mineral and particle size effects which can lead to biased results when using pressed powder pellets. However, the fusion disc method is costly as it requires a high capital investment in platinumware, requires experienced operators and uses expensive fluxes. Also, the dilution effect complicates the analysis of trace elements. For many applications, such as exploration and mining control, the method of XRF analysis of iron ores by pressed powder pellet probably provides data of adequate quality. Kumba Iron Ore, an iron ore producer in South Africa, recognises this and carries out most analyses of iron ore by pressed powder pellet and uses the automated fusion method mainly for certification of in-house calibration standards and quality control (QC) samples that are used for validation of pressed powder pellet method purposes. Automated fusion is also used for analysing the composite export shipping samples. All the other exploration, production, despatching and plant operation samples are done by the pressed powder pellet method. Automation of sample preparation procedures should improve the quality of data for pressed powder pellets. To compare the precision of the three methods of sample preparation and XRF analysis, 20 aliquots of a QC standard were prepared and analysed by each procedure/preparation method. The results and statistical data on the most important elements, Fe, K2O and P, are as shown later in Table 2.Clearly the precision is best for the auto prepared fusion discs, as expected, and worst for the manually prepared pressed powder pellets. However, the data generated from the auto prepared pressed powder pellets compare remarkably well against those from the auto prepared fusion discs.

Jan 1, 2007

By C Aldrich

In this paper, the use of topology preserving projections (Sammon maps) and neural networks are considered as a basis for the construction of multivariate statistical process control charts for a semi-autogenous grinding circuit on a gold plant. Comminution circuits are often operated in a quasi-steady state mode, where the mills tend to move rapidly from one state to another. This makes them difficult to monitor by conventional means designed for continuous steady state processes. As a first step, process data reflecting normal operating conditions are mapped with SammonÆs algorithm. Only one feature is extracted at a time and each mapping is captured by a neural network model to allow online application. Reverse neural network models are used to reconstruct the data prior to the extraction of subsequent features from the data residuals. The ensemble of neural network models can then be used for both fault detection and identification. The approach compared favourable with both linear and non-linear principal component models. It was able to detect two simulated fault conditions both with a reliability of 100 per cent, as opposed to 57.8 per cent and 95.2 per cent detected by an approach based on the use of linear principal component analysis and 84.1 per cent and 98.0 per cent detected by an approach based on non-linear principal components extracted with auto-associative neural networks.

Jan 1, 2007

Mispah form (FAO: Lithosol) soil contaminated with >380 000 mg kg-1 creosote was co-composted with sewage sludge and poultry manure for a period of 19 months. The soil was mixed in a ratio of 1:1 (v/v) with wood chips to improve aeration. The soil-wood chips mixture was then mixed in a ratio of four soil-wood chips mixture: one compost material (sewage sludge or poultry manure). Compost heaps were set up in triplicate on wood palettes overlaid with double layers of nylon straw bags. Control experiments, which contained the contaminated soil-wood chips mixture without sewage sludge or poultry manure were set up in triplicate. Moisture, temperature, pH, ash content, C:N ratio of the compost and the creosote concentration of the soil was monitored monthly. The concentration of selected creosote components in the soil was also determined at the end of the incubation period. Temperature was observed to rise to about 60¦C in the poultry manure and about 58¦C in the sewage sludge within two months of incubation, while temperature in the control fluctuated between 15¦C and 35¦C throughout the incubation period. Creosote concentration in the control was reduced by 17 per cent at the end of the incubation period while concentration of creosote in the sewage sludge and poultry manure compost was reduced by about 99 per cent. The percentage rate of creosote reduction in the poultry manure compost was initially lower than observed in the sewage sludge compost. However, the reduction rate became similar towards the end of the treatment period. The concentrations of selected creosote components were reduced by about 100 per cent within the same period. Respiration of compost microorganisms and counts of microbial populations showed that microbial activity correlated with reduction in creosote concentration.

Jan 1, 2004

By B Brattli

The dispersion pattern of heavy metals in soil and water is a consequence of complex geophysical and geochemical processes. Metal release from mining sites and subsequent migration occur primarily through acid mine drainage and erosion of waste and tailings dumps. Water plays a significant role in heavy metal mobilisation. Whilst it acts as a storage buffer for the pollutants, it is also the medium in which most of the reactions take place, and is undoubtedly the most significant transport vector in the pollution process. The intrinsic properties of the acidic drainage such as chemical composition, speciation of key mineral components, redox potential and pH are master variables controlling metal release, transport, deposition, reactivity and availability to biota. The mobility of heavy metals is strongly increased by acidification from acid mine drainage, and the discharge of these metals into the receiving waters results in numerous physical, chemical and biological responses in which the environment can affect the metal and vice versa. The result is an overwhelming number of association/dissociation, substitution, adsorption/desorption reactions, giving rise to a complex migration pattern. The attempt to understand and describe the dispersion pattern of heavy metals is complicated by the nature and level of interaction between the geochemical and hydrodynamic processes that generate and control the movement of the pollutants in the geosphere. Transport models which can be used to predict the behaviour of metal pollutants in a natural environment are still in the initial phases of development and their application to real life situations is limited. The Biochemical Cycle adds another dimension to the mobility of heavy metals. Metals form an important component of the food chain for man and plants. Biological uptake of metals from the bedrock and soil by organisms can result in migration paths very difficult to follow. Biodegradation or assimilation is just a tip of the iceberg.

Jan 1, 2003