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By D J. Robinson, L L. Kuhar

In-situ recovery (ISR) is accepted and applied across many geographies, and approximately 50% of the world’s uranium is currently extracted by using an ISR method (World Nuclear Association, 2014). The low environmental impact, the elimination of risk for mine workers and the fact that all of the lowest-cost producers of uranium use an ISR approach should raise interest from traditional miners (IAEA, 2014). However, the broader application of ISR to other commodities and mineral systems remains limited. A number of demonstration (experimental) copper projects have been undertaken (Sinclair and Thompson, 2015) with a few copper projects in Arizona being close to demonstration (Florence, 2018 and Gunnison, 2018). Evidence of very few economically operating ISR copper projects can be found (for example, the Russian, Uralgidromed OAO, built by the Russian Copper Company in 2005 and operated as an ISR facility from the Gumeshevskoye deposit (Russia Mining, 2018). A number of gold deposits, particularly paleochannel deposits, have also been considered for ISR, but, to the best of our knowledge, only limited demonstration and no commercial operations have been established, yet (Kuhar et al, 2018 and references therein).CITATION:Robinson, D J and Kuhar, L L, 2018. Extending mine life through application of an in situ recovery approach, in Proceedings Life-of-Mine 2018, pp 56–57 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By M G. Wansbone, R Bhargava

The inferred ground conditions for the proposed mined cross passages at the northern end of the Waterview Connection tunnels consist of an overburden of alluvial and residual soils, with mixed face geology of highly weathered to unweathered extremely weak rock. This paper describes three-dimensional (3D) finite difference analyses undertaken to evaluate the stability of the cross passage headings and to validate the proposed sequence of excavation. The analyses undertaken incorporated the influence of the construction of the mainline tunnels and the breakout opening in the segmental lining for construction of cross passages.The stability analyses were carried out using FLAC3D™, version 4.0 (by Itasca Consulting Group) by progressive reduction of shear strength parameters to obtain a failure condition and estimate a factor of safety. For each step of strength reduction, corresponding increments of displacements of several points on heading faces were monitored. The stability obtained from numerical analyses was compared with analytical solutions. Interpretation of results of drained analyses indicated instability of the upper 2 m of heading face within the highly weathered rock mass. Additional analyses were undertaken by including grouted fibreglass dowels to reinforce the heading face. The results of the additional analyses showed significant reduction in displacements and yielding of ground around the face. The proposed temporary support comprised face reinforcement using grouted fibreglass dowels in conjunction with canopy tubes and perimeter support of steel fibre reinforced shotcrete. The stability of the construction sequence, which was related to the specific requirement of the proposed excavation equipment, was validated.CITATION:Wansbone, M G and Bhargava, R, 2014. Analysis of stability and design of face support for cross passages – Waterview Connection tunnels, Auckland, New?Zealand, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 339–344 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By C D. Pocock

Maintaining catch berm capacity in open pit mines through controlled blasting prevents production delays associated with managing risks associated with wall instability. A method has been developed to quantify the drill hole deviation of presplit holes at Century Mine. Different controlled blasting techniques are used to control wall quality and decrease the risk. The performance of presplit drilling, in terms of deviation from design has been investigated. A methodology has been developed to quantify the drill hole deviation in three dimensions. This methodology was converted into a series of algorithms capable of handling an extensive range of data. The methodology was applied to a case study at Century Mine to evaluate the performance of drilling on two presplit blasts. Overall, 67 drill holes were investigated in the case study. The drill hole deviation was quantified in terms of three parameters: skewness, linearity and drill hole deviation parameter. Methods for quantifying each parameter were developed. Skewness, a measure of the amount of curvature and linearity, was defined as the measure of the consistency of the gradient of the drill hole. Drill hole deviation parameter is defined as the average measured deviation of the surveyed drill hole position from the design position. Acceptable drill hole deviation tolerances for each of the defined parameters were developed by analysing drill hole deviation parameters with respect to implications to catch berm capacity. Verification of the methodology was confirmed through the comparing of the completed drill hole deviation results using both visual inspection and cross analysis for each of the three methods. Holes with an R squared value of less than 0.97 for skewed deviation were classified as having skewed deviation, while holes with a difference in gradient of 3.5 were classified as having linear deviation. The results show that 76 per cent of the drill holes had deviation. Of this, 19 per cent were skewed, 57 per cent had linearity and 12 per cent contained both skewed and linearity deviation.

Nov 8, 2011

Silica and limestone fluxing levels in copper smelting slags were studied. Copper concentrates with flux additions were smelted to matte (55.5 per cent Cu) and slag in a pilot scale submerged combustion furnace.Results indicated that oxidic and sulphidic copper levels in slags were minimised with a slag Si02 level of 36 per cent and a SiO2/CaO ratio of 5.5. Total copper losses in slags were 0.6 per cent under these conditions.To produce the desired slag chemistry, additions of bulk silica and limestone to copper concentrates of fluctuating grades were predicted numerically. The method employed the solution of two simultaneous equations, each respectively for silica and limestone calculations.The predicted flux additions were applied in a further series of tests and the resultant stages were found to be satisfactory. The method is applicable to smelting 'operations which employ two flux bins, with weigh feeders, so that slag chemistry may be controlled with the flux/concentrate feed mix.

Jan 1, 1985

By K Katov, S T. Ciutina, J D. Pyke

The development and optimisation of mill discharge trommels, and specifically their screen panels, can be a neglected area in the complex operation of a minerals processing plant. Trommels are often seen as a ‘set and forget’ component of the circuit, even when significant improvements in design are possible. A redesigned trommel and panel arrangement has simplified and added flexibility to the plant shutdown schedule at Kirkland Lake Gold’s Fosterville Gold Mine in Central Victoria.Prior to the trommel redesign, the shutdown frequency was determined by the expected life of trommel panels at 14 weeks. Planning downtime around this item led to higher maintenance costs and wastage in other areas of the plant. This was particularly disruptive with respect to mill lining change-outs, which were forced out of sequence and often changed prematurely. Fosterville Gold engaged Metso Australia Limited to propose a new trommel design that would better suit the site. The new trommel was engineered to balance simplicity with performance, and incorporated the latest in Modular trommel design, modelling and Finite Elemental Analysis (FEA). Modular Panels and Spiral Segments achieve significantly longer life, and allow in-situ panel change outs, flexibility in spiral and dam positioning and an improvement in classification performance. Trommel panel life has significantly increased from 14 to 71 weeks in the trommel’s highest wearing zone. The new design has eliminated some risks to safety by reducing manual labour and lifting requirements during shutdowns. There is greater flexibility with respect to shutdown requirements. The site is no longer at the mercy of trommel panel lifespan, which allows for better optimisation of wear components in the circuit. CITATION:Pyke, J D, Katov, K and Ciutina, S T, 2018. Modular SAG mill discharge trommel for maintenance flexibility and performance, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 613–620 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Colquhoun L

Flooding velocities were measured in a laboratory column (96 mm 4) provided with both bottom and side air entry Packings used were 6 mm glass rings and spheres and -16 +8 mm coke. Results showed that when air was introduced through side nozzles flooding velocities were much higher than those obtained when air was introduced at the bottom of the column. Significance of the results and application to blast furnace flooding is discussed from the viewpoint of assymmetric gas flow.

Jan 1, 1975

By J Vann

The philosophical context of many activities in mine geology can be an important lever in adding value to operations. For mine geologists (including resource and grade control geologists) we argue that the tasks of problem formulation, observation and data collection, interpretation and modelling invoke various philosophical considerations whether the practitioner is aware of them or not.Constructing testable models to explain reality is the definitive aspect of any activity claiming to be ‘scientific’. A primary goal of mining geology is to build models that accurately predict reality to an acceptable degree and these include litho-structural, stratigraphic, grade control, resource or reconciliation models. What’s more, in mine geology we are often able collect additional drill samples or access new underground openings, for example, that can provide relatively rapid feedback on how predictive, and therefore useful, our models are. In this paper, we describe the key philosophical frameworks proposed for conducting scientific investigations, including falsification, the method of multiple working hypotheses and structural concepts of scientific theory. The strengths and weaknesses of these approaches are discussed and an attempt is made to relate them to activities undertaken by mine geologists. Common perceptions of what constitutes the scientific method have been dominated by how scientists do experimental physics and chemistry in particular. There are very important differences in the types of problem confronted in these experimental sciences compared to the ‘historical sciences’, such as geology, where the processes studied are unique and only evidential traces of past events are available. The philosophical implications of attempting to validate numerical geological models, such as resource estimates are also briefly considered.Some practical conclusions are drawn about how mine geology activities can be better implemented if practitioners are cognisant of the importance of philosophical considerations when attempting to gain new knowledge through a scientific investigation. We believe that the implications for creating additional value to a project or operation can be very significant when geology is applied by a practitioner with an understanding of the philosophical basis of the activities we think of as constituting a scientific investigation.Remember that all models are wrong; the practical question is how wrong do they have to be to not be useful? (Box and Draper, 1987, 74 p).The demand that theories be highly falsifiable has the attractive consequence that theories should be clearly stated and precise. If a theory is so vaguely stated that it is not exactly clear what it is claiming, then when tested by observation or experiment it can always be interpreted so as to be consistent with the results of the test. (Chalmers, 1999, 67 p).

Aug 22, 2011

By L J. Strachan, O J. Hawes, S W. Crossen, R C. Roberts

The Albany Conglomerate is a widespread geological unit found in northern areas of Auckland, New Zealand. It has previously been described as part of the early Miocene Waitemata Group which underlies most of Auckland. Much of the Waitemata Group comprises weak interbedded sandstones and mudstones, but also includes conspicuous conglomeratic units such as the Albany Conglomerate. The Albany Conglomerate comprises a well-cemented mixture of hard pebbles, cobbles and boulders of igneous and metamorphic derivation in lenticular beds. A number of tunnelling projects are planned for the near future in Auckland. Recent experience has shown that the variable features associated with the Albany Conglomerate can make selecting appropriate construction methods very challenging. This paper explores the engineering geological and sedimentological features of the Albany Conglomerate with respect to other conglomerates within the Waitemata Group and the potential implications on tunnelling projects in Auckland. Consideration is given to the extent of proposed geotechnical investigations and the production of geotechnical baseline reports.CITATION:Roberts, R C, Hawes, O J, Crossen, S W and Strachan, L J, 2014. Underground construction challenges associated with the Albany Conglomerate in Auckland, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 195–202 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By M J. Pejovic, I Miljanovic, A Milutinovic4, T Benovic, A Petrovski

The paper presents a model of a multigrade monitoring-management structure for support to decision making and management in real and extended time in mineral processing (MP). The model was created as a result of a long-lasting research, design and development of mining, computer integrated monitoring-management systems. Apart from the general explanations, the authorsÆ state in the introduction that efficiency of a system for support to decision-making and management in mineral processing is more difficult to achieve by conventional approaches, than by the fuzzy logic approach. Starting from the multiphase structure of process flows in MP, the following are process and monitoring-management oriented graphs. The graphs served as a foundation of the multigrade hierarchical fuzzy model for support to decision making and management in MP. Following the example of the monitoring-management system of the æRudnikÆ mine flotation plant, fuzzy logic implementation was shown. The key conclusions of the paper are that fuzzyfication of layers of the decision making and management model has full justification due to the complexity and dynamics of mineral processing processes, complications and often insurmountable difficulties concerning the precise description of real systems by conventional mathematical tools, variability of external influences, and the (general) non-linearity of the MP processes management criteria functions.

Sep 26, 2011

By D B, M A. Sares, D W. Coulter, D C. Peters

This presentation discusses NASA-funded research on the ability of hyperspectral remote sensing to map diagnostic acid rock drainage (ARD) mineralogy that adversely affects water quality within watershed and to determine the relative contributions of natural ARD sources of metals and acidity to that drainage. Ground-based reflectance spectroscopy, combined with water chemistry, is used to identify mineralogical and chemical variations throughout a watershed. Integrated with hyperspectral data acquired from airborne remote sensing platforms, such as the NASA Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, a methodology has been developed that should improve environmental assessments and tracking of impacts on and from drainages. Phase I of this project focuses on a drainage basin (Lake Creek), tributary to the upper Arkansas River in central Colorado, which is impacted by natural acid rock drainage from areas of high-sulfide hydrothermal alteration. This project builds upon research and inventory efforts by the Colorado Geological Survey (CGS) to identify hydrothermal alteration that is the primary source or is contributing to acidic and toxic drainage in Colorado. This presentation will cover ground and airborne hyperspectral remote sensing techniques and results and water analyses for seasonal high-flow and low-flow conditions in Lake Creek. Identifying correlations between mineralogy, especially mineralogy that can be identified through airborne remote sensing, and water chemistry is a key focus of this project. Of particular interest are low-pH iron phases such as jarosite, ferrihydrite, schwertmannite, copiapite, and transitional amorphous phases as well as AlOH phases from higher, although still acidic, pH environments which are observed to mix with the iron precipitates within the streams draining from the hydrothermal systems. Drainage in the Lake Creek watershed derives from the Grizzly Peak caldera (Oligocene), which exhibits extensive hydrothermal alteration. Alteration types include silicic, quartz-sericite, quartz-sericite-pyrite, advanced argillic, and argillic. By understanding the chemistry of a naturally impacted drainage and its relationship to the surrounding geology, the project goal is to allow more efficient and complete identification of such sources in mineralised terranes through remote sensing technology.

Jan 1, 2003

By P Velletri, N Gaylard

The management of wear surfaces in mining operations has remained largely unchanged since the inception of mining. Sacrificial wear liners are installed on the inside of chutes, hoppers and other equipment used to transfer bulk ore to protect the asset from abrasive wear caused by the flow of material. These liners are generally replaced at fixed intervals which may be determined based on historical wear rates or may be driven by other maintenance requirements for that asset. This approach does not always yield satisfactory results, especially for critical assets where the impact of downtime on production can be substantial. For such assets, a condition-based maintenance strategy has the potential to significantly increase productivity and reduce the total cost of ownership associated with the asset. However, for such a strategy to be successful, timely information on the actual condition (remaining thickness) of the wear liners is essential. This paper describes the development and implementation of a wear monitoring system that can be used to remotely and continuously report on remaining liner material thickness in real time. It details some of the challenges that were overcome when developing the system, including the design of a patented thickness measuring system that can be used in a variety of liner materials and is tolerant to the presence of ore on the wear surface. The paper also explains how a cloud-based approach enables data from the wear sensors to be integrated into external systems such as a data historian, which has been demonstrated through a collaborative project with one of the largest iron ore producers in the Pilbara. This ability to combine real time liner thickness information with other data sources, such as throughput, provides the foundation for the transition to a condition-based maintenance strategy.

Nov 8, 2021

In most mining operations the ore undergoes several processes such as drilling, blasting, loading, hauling, crushing, grinding and liberation to become the final salable product. Drilling and blasting is an important step in this process chain and itÆs results such as fragmentation, muckpile shape and looseness, dilution, damage and rock softening effect the efficiency of downstream processes. The value created per ton of broken ore is the difference between the price it commands when sold as the final product and the cost to produce it. Traditionally, the total process in the mining industry is classified into two groups as mining and milling. These are managed as separate cost centres inspite of the interdependency. Each process has a budget and production target and emphasis is usually on maximising production (tons) and minimising cost rather than the overall profitability of the whole business unit. The efficiency of each process is considered to be satisfactory as long as they are within budget and meet the production targets. The mine and mill managers usually try to optimise each process independently rather than the entire process. This paper discusses the potential pitfalls of decreasing the drilling and blasting cost per ton of broken rock without considering its impact on downstream processes. It introduces a holistic approach to blast optimisation by identifying and measuring the leverage that blast results have on different downstream processes and then optimising the blast design to achieve the results that maximise the overall profitability rather than just minimising the drilling and blasting costs. This paper demonstrates the benefits of such a holistic approach to blasting based on computer model simulations and field studies from metal and open cut coal mining.

Jan 1, 2001

By M Boon, M Franklin

This paper outlines the journey of cultural maturation and management system development at the Mt Rawdon (MRO) gold mine from its acquisition by Evolution Mining Limited (Evolution) in late 2011 to 2016.Evolution embarked upon a series of projects that aimed to improve the operational consistency and implementation of change on-site, while leveraging off the existing strengths of the operation. This document describes the gaps that were identified, the processes used to close them, and the resulting cultural change and production outcomes, with a specific focus on how to optimise the culture at any mining operation.MRO had a history of four owners in less than three years when it became a key asset of Evolution. The site leadership team (SLT) decided to influence the culture at MRO by reviewing and upgrading the existing management processes.The first priority was to improve transparency and collaboration at the SLT level, followed by improving competency in project management. The next phase was to strengthen the internal communication using a deliberately designed network of meetings, communication screens and other initiatives. Once there was some traction, the focus moved toward increasing production volume and decreasing cost per unit by improving short-term planning and execution capability. Together with other initiatives, this resulted in improved collaboration between all functions, which in turn netted over 37 per cent mining production uplift.Following solid success, a process of prioritisation and alignment management was implemented. This supported the ‘Mine to Mill one operation’ ideal and allowed the SLT to decide month-by-month what actions were to be prioritised. These priorities incorporated production realities and longer term imperatives of the balanced business plan.Much of this work was completed during a period of declining gold prices and a relentlessly strong Australian dollar, making it difficult to justify spending money on improvement projects. This work proved critical for the operation’s long-term survival.CITATION:Boon, M and Franklin, M, 2016. Improving consistency of delivery at Mt Rawdon Operation, in Proceedings International Mine Management Conference, pp 305-320 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By Thomas MJ

The Cannington silver-lead-zinc deposit is located at latitude 21¦ 52' 9" South, longitude 140¦ 55' 10"" East, on the south-eastern margin of the Proterozoic Mount Isa Block (Figure 1), 135 kilometres south-east of Cloncurry. Access is via a graded shire road for 80 kilometres south from the small pastoral community of McKinlay.REGIONALThe deposit is hosted by the Proterozoic Soldiers Cap Group within the Mount Isa Block Eastern Succession. South of the Cloncurry Beardsmore et al (1988) have grouped part of the Eastern Succession stratigraphy intothe Fullarton River and Soldiers Cap groups (1760-1740 million years) which together make up the Maronan Super Group. This is an apparently conformable sequence 10 kilometres thick and consists of metamorphosed sediments and volcanics with intrusive amphibolite bodies.The Maronan Super Group has experienced a complex history of deformation with up to six events having been recognized. The stratigraphy trends broadly north-south and is predominantly characterized by tight, upright isoclinal fold structures.

Jan 1, 1993

The procedure used for Truck Maintenance is described systematically in this paper. Emphasis is given to manpower required, work facilities, daily maintenance and oil sampling procedure. Scheduled Preventative Maintenance Service, Electrical Service, Component Change, Truck Overhaul and Outside Contractors are also discussed. The system used, achieves the required results with an average haul truck availability in 1981 of 87.9 per cent. INTRODUCTION Situated on the Island of Bougainville, in Papua New Guinea, the Bougainville Copper mine nestles in a valley near the crest of the Crown Prince Range, between 600 m and 980 m above sea level. The mine is serviced by two towns, Arawa - an open town on the Coast and Panguna at the Mine Site. Currently Bougainville Copper operates an open pit mine removing an average of 198 000 dry metric tonnes of material per day (115 000 tonnes ore and 83 000 tonnes of waste) with a fleet of electric shovels and 154 tonne electric haul trucks.

Jan 1, 1982

By Davies K. E

Several nuclear techniques have been assessed for application to online conveyor belt analysis of oil yield from Rundle oil shale. The most favourable technique is neutron inelastic scattering which determines the total carbon content of bulk shale samples. Correlations of chemical laboratory assays for 540 Rundle oil shale samples show that oil yield can be predicted from total carbon to within 11 litre/tonne.Laboratory experimental work on 17 bulk samples of Rundle oil shale indicated that carbon and oil yield can be determined to within 0.6 wt per cent and 9 litre/tonne, respectively, using the neutron inelastic scatter technique. A practical neutron inelastic scatter gauge for application on a 23 mm thick reinforced conveyor belt could consist of a 5 curie 241 Am-Be neutron source and a 150 mm diameter x 100 mm thick Nal(TI) detector. With this gauge, the analysis time to achieve a counting statistical error of 6 litre/tonne should be about five minutes.

Jan 1, 1985

By M S. Fenzel

Increased environmental regulations and pressures have created changing and new demands for tailings management strategies in a variety of mining applications. Critical among these items is the disposal of tailings as the pursuit of increased yields and lower costs have driven the application of different process technologies. With a number of technologies having a niche application focus, the belt filter press has been utilised for decades as a cost-effective and versatile option for dewatering different types of mineral tailings and other waste process streams. One of the critical advantages of the belt filter press is the technology’s ability to adapt and work in numerous plant designs, operating conditions and applications. As permitting and disposal options have become more stringent, plant designers, operators and equipment suppliers must develop comprehensive and site-specific economic, design and process evaluation techniques to ensure proper equipment selection and system design for belt filter presses or any other dewatering technologies. This paper will explore these techniques in relation to belt filter presses (with reference to other technologies) in a variety of different applications, along with other considerations to ensure a successful tailings dewatering system and disposal design. Summaries of equipment performance characteristics, operating and maintenance strategies and optimisation techniques will also be addressed in conjunction with the belt filter press’s adaptability to different plant designs and the resulting tailings characteristics.CITATION:Fenzel, M S, 2015. Analysis and adaptability of belt filter presses and other technologies for tailings dewatering over a range of mineral processes, plant designs, conditions, regions and operating philosophies, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 35–44 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

Autocompression and virgin rock tempera ture have a marked influence on the ventilation of the lower levels at North Broken Hill Limited N.S.W. To maintain comfortable working temp- eratures without penalty to working hours, increase in airflow or the cooling of the work area is necessary. The use of refrigerated air cooling is discussed. Ventilation of underground mining opera tions at North Broken Hill Limited is accomplished by downcasting air through No.3 shaft, the main operating shaft, 1581 m deep, with additional air through No.1 shaft (542 m) 2 and No.2 shaft (978 m), both no longer opera- tional shafts. Air is upcasted through No.3 ventilation shaft which is 4.9 m diameter and concrete lined, from the No.28 level (1140 m) to the surface. On the surface level of this shaft is a horizontally mounted Richardson 4800 mm diameter single stage axial flow fan with adjustable pitch rotor blades.

Jan 1, 1977

By R A. Pax, B Cornish

"Although it is well known and easily experienced that the feed size distribution influences the throughput and stability of operation of a semi-autogenous grinding (SAG) mill, the details are poorly understood since it is often only the input and output measurements that are used to identify unfavourable in-mill conditions. Load cells and power monitoring are sometimes used but are generally poor indicators of the mechanisms that lead to such unwanted conditions.At the MMG Century operation a 12-microphone array around the SAG mill using non-contact acoustic measurement methodology has been used to diagnose the in-mill conditions to facilitate improved throughput and stability of operation. Use of acoustic measurement and control has provided a demonstrated increased throughput of at least 20 per cent as well as improved stabilisation of the mill. Since the information derived from the acoustic noise from a mill allows discrimination of the behaviour of the steel balls and the rock, a number of in-mill conditions can be identified with signals that include toe and shoulder angles, water holdup and the ball to rock ratio.Feed size variations, measured online with an imaging system, have been used to determine their effect on the internal charge behaviour. It has been found that circumferential segregation of steel balls and rock occurs as well as poor mixing of large rocks. Both of these effects are not conducive to optimal breakage rates of different size fractions. Longitudinal segregation effects also occur. This paper presents and discusses these results and illustrates how the new acoustic knowledge can be used to manage and improve mill operation and stability.Citation:Pax, R and Cornish, B, 2016. Understanding Size Effects of Semi-autogenous Grinding (SAG) Mill Operation as a Pathway to Solving Feed Disturbances - Case Study using the MMG Century SAG Mill, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 321–330 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By R Dunne, D Yan

In flotation where a bulk flotation concentrate is produced or a gangue sulfide such as pyrite contaminates a concentrate, residual collector has to be removed from the sulfide surfaces to allow selective separation in a subsequent flotation step. Depending on the sulfide mineral, the main species that needs to be removed when using a xanthate collector is either a metal xanthate or dixanthogen. For the identification of surface species, specific solvents may be used to remove each species û metal xanthates are known to be soluble in acetone whilst dixanthogens are known to be soluble in non-polar solvents such as diethyl ether. Xanthates break down with time, temperature and pH into various decomposition products. The major decomposition product is dixanthogen which can aid flotation but other products such as perxanthate and carbon disulfide can have an adverse effect on flotation. Various analytical techniques can be employed to monitor the formation of decomposition products on the surface of the mineral and in solution. The best of these is ultraviolet spectroscopy as it has diagnostic peaks for decomposition product determination. In this work two approaches were taken to understand the relationship between the flotation of a chalcopyrite and pyrite from an ore containing these two minerals. One approach was to remove the xanthate species with an organic solvent and then use ultraviolet spectroscopy to determine the concentration of dissolved species. The second method involved measuring xanthate decomposition in solution by measuring the residual xanthate concentration using ultraviolet spectroscopy. These experiments confirmed the species adsorb at the surface of the mineral and how these species affect the recovery and grade of the valuable mineral. In both cases pH and temperature were varied and two xanthate collectors (SEX and PAX) were used to study these relationships. These relationships could be applied to industrial flotation systems and allow for more accurate determination of optimal xanthate dosage and hence save on reagent costs.

Jan 1, 2005