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By Erich U. Petersen

Discussion by Erich U. Petersen Harbuck et al. (1990) present results of research on sulfuric acid leaching of a germanium-gallium ore and shed considerable insight on possible extraction methods for gallium and germanium. However, the presentation does not give sufficient details to evaluate the research, so some of the conclusions may not be as applicable as stated. The objective of this communication is to indicate that relevant and easily obtainable geological and technical information was omitted. Consequently, on this basis, alternative explanations for some of the data are possible. Discussed below are the omission of: • pertinent geological, mineralogical and geochemical literature; • details regarding the determination of germanium concentration in quartz by electron microprobe; and • details on the calculation of the amount of germanium locked in quartz. "These topics are important since the determination of the amount and locus of "unrecoverable, locked germanium" may have an important impact on the economics and methods of germanium extraction and the directions of future research. Harbuck et al. state that "A key to increasing germanium extraction is understanding the mineralogy of the ore." However, only two studies are cited that in some manner describe the mineralogy of the ores. In addition, both of these studies were very preliminary, of limited scope and examined very few

Jan 1, 1993

By P. J. Suardini, S. K. Kawatra

A number of on-stream coal slurry analyzers are presently being developed and commercialized for measuring ash and solids in coal process streams, particularly around flotation circuits. The eventual goal of these efforts is to develop on-line quality control systems for flotation circuits and other fine-coal cleaning operations. As part of this on-line monitoring and control effort, it is important to gain a better understanding of the response of industrial flotation circuits to changing operating conditions. This paper summarizes the results from a detailed sampling program performed at an industrial coal flotation circuit in western Pennsylvania. The testing focused on evaluating the response of the circuit to changes in reagent dosages, operating conditions and feed compositions. The testing indicated that it is desirable to maintain high collector-to-frother ratios to enhance coarse particle flotation. The recovery of fine impurity particles was also proportional to water recovery, due to hydraulic entrainment. Key words: Industrial, Coal, Flotation, Circuit, Reagent, Response.

Jan 1, 1995

By F. G. Miller, M. Polat, S. Chander

Flotation was used to achieve improved separation of magnetite from the float and sink products obtained from heavy medium separation and to reduce the load of the medium cleaning circuit. The investigation was carried out in two successive phases. In the first phase, tests were performed on in-plant samples from the Homer City Coal Perdition plant to determine what effects variables such as medium density, particle size and magnetite source had on the efficiency of the process. In the second phase, the optimum conditions determined in the first phase were used to determine the applicability of the process to other selected coals from central Pennsylvania. It was observed that flotation was very effective in the separation of magnetite from coal. In most of the cases investigated, the magnetite recovery was approximately 99% with a magnetite grade ranging from 95 to 99%. The grade of the magnetite decreased as the ash content of the coal increased and the particle size of the magnetite decreased.

Jan 1, 1994

By D. W. Fuerstenau

The success of industrial flotation separations has been the design of specific chemical schemes for regulating the bulk and the surface chemistry of the system. Highlights of fundamental research on the nature of flotation reagents and their mode of action in flotation, which has been carried on for about the past 65 years, is briefly reviewed.

Jan 1, 1995

By Kenneth N. Han, Peter Mam-soo Kim

The extraction behavior of gold in ammoniacal solutions in the presence of bromine as an oxidant has been studied. The effect of concentration of ammonia, bromine, and pH of the solution on the rate of dissolution of gold was investigated. The dissolution behavior has been analyzed using electrochemical method, and its results were compared with direct leaching tests using gold powder. The overall dissolution of gold in ammoniacal solution containing bromine was found be affected significantly by pH of the solution and the concentration of bromine. The rate expression found in this study has the following form.

Jan 1, 2005

By S. W. Asihene, K. Osseo-Asare

The leaching and solution treatment operations used in the ammoniacal treatment of laterites depend on the ability to establish and maintain close stability relations between soluble metal ammine complexes and solid phases such as oxides, hydroxides, basic carbonates, sulfides and ammonium double salts. This paper presents a quantitative treatment of heterogeneous equilibria in ammonia/laterite hydrometallurgical systems, by means of several.types of hydrometallurgical phasedia- grams (e.g., Eh-pH, log [NH3 + NH4+] - pH, log [C02] - pH, log SO42-] - pH, log [Metal] - pH). Dissolution/precipitation phenomena associated with nickel and cobalt recovery and with magnesium scaling are discussed in the context of the phase diagrams.

Jan 1, 1979

By Lynn B. Hales, Randy Ynchausti, Jeffrey D. Mckay

Many consider rougher flotation control to be more of an art than a science. Some have even thought it impossible to make process control decisions and changes without human interaction. Controlling flotation bank pulp levels to maintain consistent pulling rates in the face of changing feed slurry flow rates, varying mineral types, and inconsistent reagent additions can be daunting. However, an advanced supervisory control strategy was installed on the plant floor to control an industrial rougher flotation circuit with little or no operator interaction. Plant staff monitored the flotation circuit under supervisory control and reported benefits of up to 4% improvement in copper recovery above that achieved with an older supervisory control strategy. To accomplish this work, a novel use of instrumentation to solve a flotation bank pulp level control problem was employed, a new implementation approach was used to correct some flaws in the older approach, and careful attention was paid to a few key process control principles. This paper discusses important aspects of these activities.

Jan 1, 2000

By Eric Forssberg, Ming-wei Gao

Four parameters of the Drais stirred ball mitt, i.e., bead load, bead size, flow rate and top feed size have been studied regarding their influence on the specific surface area. A factorially designed scheme was employed for conducting 27 mitting tests. The results show that the bead toad is the most important parameter in terms of increasing the specific surface area with less energy consumption. The bead size is also important. The optimum ratio of bead size to top feed size is found to be 14 to 80, which is much wider than in bat2 milling. The variations in flow rate and top feed size appear to influence the process insignificantly.

Jan 1, 1992

By Jeffery H. Stricklin

Jim Walter Resources operates five underground coal mines with longwall faces in operation in four of the mines. Due to high air velocities (1000-1200 fpm) needed for methane control together with the friability of the coal, dust control on JWR longwalls offers unique challenges. We have tested many innovative measures to reduce respirable dust concentrations on longwalls with varying degrees of success. These measures include the "shearer clearer" system, different drum water spray configurations, sprays on the longwall belt, stageloader and crusher sprays, wetting agents in the spray water system, and homotropal ventilation. Water infusion of deactivated horizontal methane drainage holes in longwall panels is now being evaluated. A study was completed in November 1986 where water was infused into two horizontal de-gas holes. Personal gravimetric samplers were used to measure respirable dust concentrations and showed a significant reduction in the infused zone. A more in depth study will be conducted. This paper will describe the dust control measures presently used on JWR longwalls, give the results of past studies, and discuss new methods proposed to control longwall dust.

Jan 1, 1987

By Anthony D. Hammond

Geographic Information Systems (GIS) are powerful analytical and data display tools for mining industry management, capable of linking spatial features with tabular data and integrating communications across departmental boundaries. This GIS application concentrates in four technical areas of underground mining: ownership and mineral claims; exploration management; production; and mine safety. GIS provides land and exploration managers with the ability to consolidate and archive claim data and to georeference property maps defined in local coordinates into world coordinate systems. It facilitates optimal siting and querying of service installations and refuge chambers relative to production centers. GIS's proximity analysis identifies areas of potential safety concern and points to and maps the shortest routes to emergency exits, facilitating the prompt evacuation of mine personnel.

Jan 1, 2002

By R. L. Grayson, S. Yuan

A stochastic model for evaluating the impact of the reliability and maintainability of shovels and trucks on the operational effectiveness of shovel-truck mining systems is presented. In the model, the Markov modeling technique is used to analyze the operating status of a shovel-truck mining system. Then, simulation is used to study the productivity of a shovel-truck system in a particular state. Finally, the relationship between the effectiveness of a shovel-truck system in terms of productivity and the reliability and maintainability of equipment is established. This relationship may be very useful to mine managers in making decisions in surface mining (e.g., regarding production process control, equipment replacement, and maintenance planning). A quantitative study is given to demonstrate how the reliability and maintainability of equipment affect the system effectiveness and how to pinpoint the parameter that has the most significant effect on the system effectiveness. The quantitative study indicated that in order to improve the system effectiveness significantly, the reliability and maintainability of the equipment need to be improved simultaneously.

Jan 1, 1995

By Marie-Antoinette Dziurla, Barrie Johnson, Åsa Kolmert

Acidophilic bacteria are well known for their role in accelerating the oxidative dissolution of sulfide minds, such as pyrite. Other acidophiles, however, are able to catalyze dissimilatory reductive reactions. Bacteria that reduce ferric iron to ferrous, and sulfate to sulfide, were isolated from ARD-impacted environments and immobilised onto porous beads made of recycled glass. Column bioreactors containing colonized beads were constructed and peacolated with synthetic and actual ARD, and evaluated for their capacities to promote iron or sulfate reduction, and pH amelioration. Iron reduction did not require strictly anoxic conditions in bioreactors, and rates of up to 800 mg Fe3+ reduced/(l*day) were achieved, with a conversion efficiency of up to 98%. Using mixed populations of acidophilic fungi and iron-reducing bacteria, the bioreactors were capable of promoting iron reduction using paper pulp as sole carbon and energy source. Reduction of sulfate in pack bed bioreactors was observed with acidic wastewaters of pH 3 and above, though average rates of 300 mg sulfate reduced/(l*/day) were less than those recorded for circum-neutral pH systems. Bioremediation of ferric iron-rich ARD was assessed using coupled iron-reducing and sulfate reducing bioreactors.

Jan 1, 2000

By W. P. Diamond, A. C. Smith, J. A. Organiscak, T. P. Mucho

The U.S. Bureau of Mines examined bleederless ventilation practices to evaluate their use as a spontaneous combustion control measure in U. S. coal mines. Results indicate that restricting airflow into mined-out areas (bleederless ventilation) is recognized worldwide as a spontaneous combustion control measure. However, ventilation practices commonly used to limit airflow to mined-out areas are not easily applicable to United States mining conditions, systems, experience and regulations. The types of bleederless ventilation systems used throughout the world and the spontaneous combustion risks associated with these systems are discussed. Primary design considerations for bleederless ventilation consist of the interaction of ventilation practices, methane drainage, ground control, seal construction and mine monitoring. Technological improvements needed for U.S. application of bleededess ventilation are also discussed.

Jan 1, 1995

By R. Hogg, T. F. Dumm

With increasing interest in the physical cleaning of fine coal, there is a need for extension of the sink-float analysis procedure to finer sizes. Problems arise, however, in ensuring complete dispersion of the particles in the heavy liquids. A procedure has been developed in which surfactants are wed as dispersing agents, and solids concentration is minimized (using a simple formula to estimate the minimum weight needed for statistical reliability). Using centrifuges to increase separation rates and subsieve particle size analysis of the specific gravity fractions, a complete size-specific gravity distribution can be obtained. Analyses have been performed on coal samples as fine as - 10 µm.

Jan 1, 1987

By J. Bigu

Use has been made of several theoretical models to predict radiation levels in underground uranium mines. The models used are the Evans model, the Thomas-Epps mine model, the isolated mine model, the mine tunnel with no air flow and the mine tunnel with air flow (Beckman and Holub). Calculations based on the above models have been extended to include thoron gas and its progeny, a common occurrence in some Canadian uranium mines. Theoretical predictions include radon and thoron progenies WLs and concentrations, and some ratios of great practical interest. The main differences between the models are pointed out and comparison is made with experimental data gathered during the last three years in several Canadian underground uranium mines.

Jan 1, 1981

By K. Fuenkajorn, J. J. K. Daeme

Ring tension tests have been conducted on 229 mm (9 in) diameter disks of Grande basaltic andesite and Pomona basalt with various center hole sizes in order to study the relationship between ring tensile strength and relative hole radius (hole radius/disk radius). The tensile strength, [ ] decreases as the relative hole radius, [ ] increases. A power equation, [ ] where C and R represent the coefficients of strength and shape, respectively, adequately represents the ring tensile strength as a function of relative hole radius over the range investigated. This equation can be used to distinguish the effect of the hole size from the strength results, to predict the tensile strength of a ring sample containing arbitrary hole sizes, and to approximate the critical relative hole radius of the material tested.

Jan 1, 1986

By R. M. Carland, F. F. Aplan

The ion-exchange capabilities of natural zeolites from the western United States, representing the species chabazite, clinoptilolite, erionite and mordenite, have been studied because of their potential use in environmental remediation and in hydrometallurgical processes. These raw zeolite samples were found to contain Na+, K+, Ca+2 and Mg+2 as exchangeable cations, and all of these, with the exception of Na+, were found to seriously interfere with the exchange of Cu+2 from solution. Placing these zeolites in the Na+ form was found to increase their cation-exchange capacity, often massively. In addition, the elution of Cu+2 from the Na+ pre-exchanged zeolite is greatly facilitated when the deleterious K+, Ca+2 and Mg+2 have been largely expelled. The relative influence of these deleterious ions on the uptake and elution of Cu+2 was determined.

Jan 1, 1996

By C. B. Alcock

The control of high temperature processes requires the ability to measure significant variables during operations. With increasing automatic computerized control there is need for sensors which can provide on-line chemical analyses of all phases present in a reactor without the necessity to withdraw samples from the high temperature reaction zone. Probes using electrochemical cells and conductivity measuring devices have provided the answers to some of these problems, notably the measurement of oxygen in liquid metals, and similar potential systems based on the same fundamental principles for the analysis of non-metallic and metallic elements appear feasible. In this discussion, the state-of-the-art in chemical sensors will be discussed in terms of the potential materials of construction, and, in some cases, the limitations of upper temperature at which some promising systems can, at present, be applied. It is concluded that a new phase of basic research could improve the outlook substantially by providing solutions for some problems in chemical sensors which are now well-defined.

Jan 1, 1990

By Donald D. Haas

This presentation will discuss a mine owner's evaluation to utilize a contract miner in the development and production of gold properties. I will address both the quantitative and subjective aspects of the evaluation process. The quantitative aspects include cost evaluation, capital preservation, acquisition and disposal of new and used equipment, administrative costs, recruiting and training, and organizing a staff and craft labor force. The subjective areas of this discussion include corporate philosophy, administrative concerns, contractor competence, loss of owner control, operating flexibility, financing assistance, recruiting and training program utilization and risk reduction. The evaluation of alternatives provides a system for comparing, on a cost basis, an owner/operator system vs. a system using a contract miner. The supplement provides a concept on how a contract miner may be the cost effective system to be utilized.

Jan 1, 1989

By T. M. Barton, M. Gauna, A. A. Campoli

Coal mine bumps, the violent failures of overstressed coal, present a safety hazard to miners when longwall mining is conducted in deep, bump-prone coal mines. Two different longwall gate entry systems were evaluated in a southern Appalachian coal mine located in the Pocahontas No. 3 coalbed under approximately 610 m (2000 ft) of overburden that included a massive sandstone member. Both gate entry systems employed a center abutment pillar flanked by yield pillars. The original design used a 24.4-m (80 ft) square abutment pillar, while the new design employed a 36.6-m x 54.9-m (120 ft x 180 ft) abutment pillar. Rock mechanics instrumentation data analysis and in-mine observations indicated that this increase in abutment pillar size significantly decreased bump potential. The new design in worst-case conditions increased effective bearing area 62%, with only a 9% increase in gate entry system width, and eliminated face bumps that were experienced with the original gate entry design.

Jan 1, 1993