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By J. Kang

Supercritical fluid extraction (SFE) has became an attractive alternative technology to be a new process to recover metal, of which can be substitute the existing Leaching/Solvent extraction processes. Solvent extraction of metallic ions is a technically important and also well-established process that is used in the chemical and hydrometallurgical industries.1 Solvent extraction techniques use the chelation of metallic ions dissolved in liquid solution with organic ligands. Conventional solvent-extraction technique needs large amount of organic solvents and often creates environmental problems.2 More environment-friendly technology is needed nowadays, and there have been increasing attentions to extract metal ions by SFE. CO2 becomes one of the most notable alternative organic solvents due to its nonflammable, nontoxic, nonpolluting, and relatively inexpensive properties with its moderate critical point (73.8 bar, 31.06 °C). Many works have been reported in metal extraction under the supercritical CO2 (scCO2) solvent.3-5 In this study, to recover cobalt from wastes especially from spent lithium ion battery scrap, we selected two ligands ? Cyanex 272 and DEA (diethylamine) for the metal extraction in scCO2. Cyanex 272 is a commercially available extractant along with its series, Cyanex 301 and Cyanex 302. Smart and coauthors measured the metal extracting abilities of these three extractants, and found that Cyanex 301 and Cyanex 302 extracted metal ions much better than Cyanex 272 in the scCO2 solvent.10 The pH of water contacted with high pressure CO2 (70-200 bar, 25-70 oC) is about 2.8-2.95 based on the calculation and the measurement.6-7 Cyanex 272 is known to be less effective as a metal extractant in this low pH environment compared with other Cyanex series. However, when DEA is added to metal extraction reaction with Cyanex-272, DEA works as a strong base to Cyanex 272 converting Cyanex 272 to a deprotonated form (Figure 1), which results in an easy formation of metal complex and the enhanced extraction rate of metal ion.8 Therefore, the purpose of this paper is the metal extraction from spent lithium ion battery waste using scCO2 with Cyanex 272 and DEA.

Jan 1, 2010

By C. Alexander

Stillwater Mining Company is developing a second underground palladium and platinum mine approximately 21 km (13 miles) west of their existing Nye operation in south central Montana. A 5650 meter (18,550-foot) tunnel is required to gain access to the ore bearing horizon (J-M Reef). Access and primary mine development can be accelerated through the use of two 4.6 meter (15-foot) diameter tunnel boring machines (TBM). One TBM was purchased new while the other was purchased used. Machine specifications, site support facilities, portal/launch chamber construction, TBM assembly, startup and operation are discussed in this paper.

Jan 1, 1999

By Xun Luo, Yi Duan

A field trial of by distributed optical fiber sensing (DOFS) technique was conducted at a longwall coal mine in Australia. This investigation was designed to assess the applicability of DOFS for microseismic monitoring in mining. The experiments used commercially available optic fiber cables, geophones and associated data acquisition instruments – a fiber interrogator and a seismic recorder. The fiber cable was deployed in a 300m deep hole and in trenches of approximately 3.5 km long on the ground surface around and across the longwall panel being mined. The results obtained from the experiments have shown that DOFS is able to acquire microseismic data with quality that is comparable to geophones. It has been proven that DOFS can achieve higher spatial resolution for seismicity sensing and higher accuracy for locating events than a geophone network. These characteristics are particularly useful for using DOFS to monitor ground vibrations associated with ground caving processes and rock fracturing events induced by mining and civil engineering. It was also found that far more additional seismic events were recorded by the fibers than by the geophones. Automated data discrimination and processing methods must be developed in order to utilize DOFS for real-time applications.

Apr 26, 2022

By Thomas P. Meloy

There is much interest in the automation of entire comminution circuits, At the present technological level it is possible to automate a circuit but to date it has not been done, To successfully automate a circuit, a number of problems must be solved. Not all of them are engineering problems. The purpose of this paper is to discuss some of these problems, as certain the implications of these problems and indicate solutions to them. In this paper the term "automation" is used loosely but in the popular sense. Namely, that a plant is automated if a computer is used to control the basic flow of the materials as well as setting the critical parameters in the process. Specifically, the discussion will concern itself with the control of comminution circuits from the dumping of the ore into the primary crusher until the final interface between the comminution circuit and say, the flotation mill in the case of a sulfide ore.

Jan 1, 1965

By W. Blake, J. Whyatt

Sixty years of rock bursting in the Coeur d'Alene district has taught painful lessons and led to a number of practical advances in controlling rock-burst hazards. This paper summarizes these lessons, concentrating on practical measures that have been successfully adopted to reduce hazards. These lessons are explained in the context of district mining history and current understanding of rock-burst phenomena. Overall, the paper provides the practicing mine engineer with an appreciation of rock-burst hazards and an overview of practical measures that can be used to control these hazards in the context of Coeur d'Alene district experience.

Jan 1, 2003

By C. L. Schneider

The calculation of the liberation spectrum in the product from continuous milling operations is a problem of considerable importance and is difficult to solve because the population balance equation must be integrated in two-dimensional space. Complete solutions require the estimation of a large number of parameters unless a structural model of the ore texture can be used. A very simplified textural model based on the use of the modified Andrews-Mika diagram and the PARGEN simulation of multi-phase particles has been formulated and is used to simulate the behavior of a continuously operating laboratory ball mill. A sensitivity analysis for this mill has been done to show the likely effect of model approximations on the predicted liberation spectrum which will be measured.

Jan 1, 1992

By T. Skodack

This presentation will compare actual work site results for the loading and transport of shot rock for two major tunneling projects in North America. "SCARMAR" (the Canadian subsidiary of S & M Construction) is operating a rail bound Hagglund continuous gathering arm loader in combination with a Hagglund nine car shuttletrain system at the West End of Table Mountain on the B.C. Railway project near Tumbler Ridge, Canada. Al Johnson Construction is operating a Hagglund rubber tired continuous gathering arm loader in combination with haul trucks at the Rocky Mountain Pump Storage Project near Rome, GA. This paper will compare: 1) tunnel and ground conditions, 2) the total work cycle as it relates to mucking and haulage 3) efficiencies and related problems with the two systems 4) mucking and haulage rates 5) operating costs, and 6) recommendations for future large tunnel excavations. Manuscript not received in time for publication.

Jan 1, 1983

By R. G. Reddy

Viscosities of Feo-SiO2 slags were calculated using the previously developed structural based model. An expression was derived using hole theory and the atomic pair model to relate the NO0 and temperature to the viscosity. The deduced equation n=4.9x10-9 T1/2 NO0 exp (E/RT) poise was successfully applied to predict the viscosity of FeO-SiO2 slags in the composition range of 0.1 < XSiO2 < 1 for several temperatures. The calculated data agrees well with the experimental viscosity data.

Jan 1, 1991

By F. W. Jessen

The production of salt through brining operations and the recovery of potash salts by means of solution with water constitute, in large measure, processes which have been used for many years. And although the salt industry has utilized dissolution techniques for years and years it has been only recently that a better understanding of the mechanism of solution has emerged. Greater adaptability of solution mining processes for recovery of valuable salts from ore bodies found at greater and greater depth has resulted in increased adoption of such methods. Because of the high costs of mining in beds of limited thickness, modifications probable when extracting mixed halites, and restrictions (mostly self-imposed) regarding the extent of cavern development to minimize or eliminate subsidence more information is needed on the solution mechanism. It is the purpose of this paper to present the fundamental aspects of the problem of total solution of salts and to point out the developments of certain solution mining techniques.

Jan 1, 1971

By R. J. Hickson

The Grasberg copper-gold deposit was discovered in Spring 1988, just one year prior to the planned closure of Freeport Indonesia&apos;s original Ertsberg open pit copper mine. In spite of Grasberg&apos;s remote location, 600m above the Ertsberg, atop a hitherto inaccessible mountain, Freeport-McMoRan brought their latest open pit mine into production in the last week of 1989, less than two years after discovery. This paper describes the start-up of the operation, highlighting synergies drawn from both the original Ertsberg experiences and the current Freeport Indonesia underground mines.

Jan 1, 1991

By Dai Wang

Stoppings are necessary ventilation control devices for effective air distribution underground. However, one of the major problems underground mining has is that every stopping is a potential leaking source. Since air always flows from a point of high pressure to one of lower pressure, and the total pressure at every point in intake airways is higher than that in the return airways, air will always tend to leak from intake to return (Tien, 1996). In many mines, less than half of the air entering the mine actually gets to the working areas; the rest of it simply short-circuits directly to return airways through leaky stoppings instead (Timko and Thimons, 1983). Leakage through a stopping occurs because of pressure drops across the stopping and available leaky path in stoppings. Empirical equation has been widely used to characterize the relation the amount of leakage and variables that affect leakage. However the use of this equation requires accurate information for constants which are not always readily available. It is the attempt of this paper to derive an equation similar to the Atkinson Equation that can readily be applied to characterize pressure-leakage relationship for any given stopping.

Jan 1, 1998

By Jr. Gambrell

For more cost effective strata control, a fundamental understanding of the behavior of the support system is needed. To assist in this understanding for shield supports, behavior of a four-leg shield design used on a soft floor in an operating longwall system is presented. The shield was constructed having a split base and a split caving shield. Attention is focused on other-than-normal loading on the canopy and its effect on deformation of the lemniscate links. Examples of the typical bending and twisting deformations are given. Schematics of the canopy, caving shield, and lemniscates showing important forces and moments are presented. Approximate minimum values of the forces and moments are calculated. The need for use of more inclusive three-dimensional design techniques is demonstrated.

Jan 1, 1990

By Bror Nyman

Wide settlers are a way to decrease the linear velocities of advancing liquid phases. It has, however, been found unnecessary to risk a proper settler performance by building shallow settlers in order to avoid a so-called interface turbulence due to a too big difference between the linear velocities of the organic and the aqueous phase. This conclusion has been reached from tests using a large transparent settler model, where the behaviour of a clean interface between two advancing liquids has been investigated. Also in a more realistic case, making an organic in aqueous or an aqueous in organic dispersion to move between the liquid phases, no obstacle has been found to use a somewhat more deep and correspondingly ore slowly t10wing aqueous phase. Based on above findings, support can be given to a new trend to build the settlers slightly deeper than what has been typical for the so-called low-profile design. In this way, it is much easier to avoid an excessive air introduction and other severe difficulties, like those caused by crud moving from one stage to another. It is further shown, how gravity can be used to slow down and distribute a dispersion being fed into a settler of a VSF unit. Entrainment levels have been found to be reduced by a careful design of primary dispersion distributors and picket fences of the settler. Finally, it is demonstrated, how outlets from the side of the settler can be used to simplity interstage pumping and to decrease the rotation speed of any pumping device.

Jan 1, 1996

By I. E. Odom

The rare magnesium-lithium clay mineral hectorite occurs at many places in the McDermitt caldera of Nevada-Oregon. Commercial development of several high purity deposits began in 1986. The hectorite was precipitated in a lake environment formed after collapse of the McDermitt caldera. Hectorite beds and lenses are associated with volcaniclastic sediments, limestones, dolomites, zeolites and locally sandy bentonites. The high purity deposits appear to be associated with hydrothermal areas. The hectorite consists of extremely small flake-shaped crystals, and Ca is the predominant exchangeable ion. Its color ranges from white to light green. Commercial uses developed to date include high brightness magnesium aluminum silicate products, organophilic clays, pulp retention, and ceramics. The MAS is used as a suspending agent, binder, stabilizer and thixotrope in aqueous solutions for cosmetics, household cleaners, pharmaceuticals and miscellaneous industrial applications. Organoclays are used in printing inks and paints.

Jan 1, 1992

By A. Khan

The effect of sulfur dioxide on collectorless and collector induced flotation of chalcopyrite was studied by cyclic voltammetry on a rotating disc electrode. Contact angle measurements were made to determine the effect of sulfur dioxide concentration and electrochemical treatment. The benefits of sulfur dioxide in enhancing the selectivity of separating chalcopyrite from complex sulfide ores are discussed.

Jan 1, 1996

Laboratory tests were conducted in a full-scale continuous miner test gallery to evaluate resulting dust levels for changes in face airflow, spray water quantity and pressure, and mining height. The minimum and maximum values tested for each parameter were as follows: airflows between 1.42 and 6.14 m3/sec, water flows between 56.8 and 132.5 lpm, nozzles pressures between 413 and 1379 kPa, and mining heights between 1.52 and 2.74 m. Each of these parameters were evaluated for four common spray system designs. Respirable dust samples were collected in the operator&apos;s cab on the miner and in the immediate return. Second-order polynomial models were used to represent expected dust levels and multiple stepwise regression was used to identify significant control parameters for inclusion in the models. Separate models were developed for dust levels at the operator and return locations and for each individual spray system. Interaction between control parameters and curvature effects were found in most models. The analysis indicated that at the operator location, airflow and mining height had the most significant impact on respirable dust levels. In the return, airflow and water pressure were typically the most significant parameters. The models developed for each spray system design can be used by mine operators to guide application of control parameters for a variety of operating conditions and mining heights.

Jan 1, 1994

By C. C. Muir

At the outset, I believe reference should be made to comparatively recent world developments in copper which have an important bearing upon the Canadian position. COPPER SITUATION No one can doubt the marked change for the better compared with not so long ago when less than adequate attention was paid to marketing and to uses of the metal. I need not show you graphs of world copper prices, which except for relatively brief periods and war conditions were, until about three years ago, not unlike the topography of the Canadian Rockies. There remain, of course, some non-industry factors who yearn for the old days of "roller-coaster" copper prices.

Jan 1, 1964

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By K. T. Valsaraj

The separation process called solvent sublation for the removal of two hydrophobic compounds (penta-and tri-chlorophenols) from the aqueous phase is discussed. A steady state mathematical model for the process is discussed. The process was conducted in a continuous countercurrent mode. The underlying mechanisms, theory and experimental details on the effects of process variables on removal efficiency are reported.

Jan 1, 1992

By H. EI-shall

The conventional beneficiation scheme for Florida phosphates involves reverse flotation with an intermediatory acid scrubbing step. A single reagent flotation process, using fatty acids or amine as the collector, would eliminate the scrubbing step along with the other flotation step. This can not only simplify the process flowsheet, but also result in reduced reagent costs. The potential of single reagent flotation of Florida phosphates using fatty acids as the collector was examined in this study.

Jan 1, 1993