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By B. Rai

Aluminum is produced by the Hall-Héroult process, which involves passing a current through a molten mixture of alumina dissolved in cryolite (Na3AlF6) to reduce the alumina to aluminum. This process occurs in an electrolytic cell comprising a steel shell lined with a carbon cathode and refractory bricks. After a certain period of operation, the carbon cathode deteriorates and is removed from the cell along with the refractory bricks. These removed materials are referred to as spent pot lining or ?SPL?. Typically, 30 Kg of SPL waste is generated for every ton of Aluminum produced. Globally aluminum smelters produce more than 500,000 tons of SPL each year. Even though SPL has a high fuel value (8000 to 9000 BTU/lb) and contains valuable metals, it is classified as a hazardous material due to its cyanide content and leachable fluorides. Various disposal/recycle techniques have been developed over the years for SPL but none of them is satisfactory. Thus, large quantities of SPL are still being dumped in landfills. In some countries, even the land filling of SPL is not permitted. The safe disposal of SPL thus remains a challenging problem to the aluminum industry and the search continues to find methods of converting SPL into a non-hazardous waste and/or recovering the valuable materials contained in the SPL. We have developed a process to produce hydraulic setting cements (eco-cement) containing a novel fluoride rich cementitious phase, from SPL by an energy efficient, low temperature clinkering route. A raw mix blend of SPL, lime/limestone, calcium sulfate and tailings sands based on a set of design criteria developed by us, is clinkered in a two stage process; 2 hours soak at 800 °C followed by clinkering at 1000 °C for another 2 hours, to produce a soft clinker. The SPL eco-cement is made by grinding the clinker to a fineness of 5000 cm2/g Blaine with 1% by weight borax as a set retarder. A good quality cement having as high as 20 % by weight of SPL in the raw mix (28 % by weight in the cement clinker) is thus produced. The physical properties of the SPL cements are found to be comparable to the Indian standard (IS) specifications for Ordinary Portland Cements (OPC). We have produced the cement in a few Kg batches and tested the reproducibility of results from batch to batch for further scale up. Once commercialized, this process has a potential of converting SPL into value-added cement products. Keywords: cement, spent pot lining, clinkering, fluoride, aluminum, ordinary portland cements

Sep 1, 2012

By M. N. Abdusalyamova

The Republic of Tajikistan has large mercury-antimony deposit. The Republic takes the second place in the countries of the CIS by having antimony recourses or the fourth place in the world. Recently, on the mine bottom horizons the resources of gold were found. Gold in the data ore is submitted as nanosize particles. Results of ores enrichment of bottom horizons of Djijikrut deposit are obtained by a method of flotation. The flow sheet includes the rougher flotation, two scavenging flotation and two cleaner flotation. As a result of enrichment of ore, the mercury-antimony concentrate with the contents of 51.5% of antimony and recovery 90.3% from ore with the content of mercury of 3.5% was received. The investigation of thallium, selenium, and tellurium distributions on products of enrichment was carried out. The most effective reagents are a mixture of oksafore and butyl xanthogenate. While applying this mixture of reagents it is possible to refuse of the use of activator - nitrate lead. The behavior of gold is in details investigated during enrichment. To collective flotation concentrate is extracted only 30% of gold. The basic quantity of gold concentrates in tailings of flotation and is not taken by existing traditional methods. The alternative innovative technology of gold extraction was created. Various methods of roasting of a collective mercury - antimony concentrate oxidizing and reducing are investigated. Vacuum distillation of concentrate allocation in serial sublimates mercury and antimony was designed. In the received calcine concentrates gold. At additional roasting of a calcine up to 900°? concentration of gold makes 30.6 g/t. The offered innovational technology in a complex allows to process ores and concentrates unique mercury-antimony?gold bearing raw material. Keywords: ore, concentrate, flotation, cyanidation, roasting, mercury, antimony, gold

Sep 1, 2012

By A. Boulton

Low molecular weight synthetic polymers substituted with hydroxyl, carboxyl or sulfonate functional groups were used to improve the flotation separation of zinc or copper sulfide minerals from iron sulfide gangue minerals in three massive sulfide ores of different mineral composition. These polymers produced significant improvements in zinc or copper grades as a result of a selective depression of iron sulfide minerals. It was shown that this selectivity was the result of preferential adsorption of the polymer on the surface of the iron sulfide minerals. The different types of interaction between the functional group on the polymers and the sulfide mineral surfaces could explain the trends observed in the flotation results.

Jan 1, 2003

By Kyoungkeun Yoo

A citric acid leaching test after heavy medium separation process was performed to remove the heavy metal contaminat such as Pb, Cu, and Zn from contaminated soil. The lead component was removed from soil by heavy medium separation whereas zinc component shows 0 % - 37.9 % removal ratio with particle size. The citric acid leaching was conducted to remove the remained zinc component. The removal ratio of Zn reached to more than 95 % under the conditions; 10 % in pulp density, 200 rpm in agitation speed, 50 °C, 2 mol/L in citric acid concentration at 2 hrs in leaching time. These results suggest that the heavy medium separation method followed by citric acid leaching is effective for treatment of soil contaminated with various chemical forms of heavy metal. Keywords: metal contaminated soil, citrate, heavy medium separation, zinc

Sep 1, 2012

By N. Jovanovic, A. Vazirizadeh

"The main objective of this study is to find a solution to design a mass flow observer system with the minimum required sensors and maximum observability for a mineral processing plant. The second objective is designing a mass flow observer configuration with high reliability to manage sensor failures. This configuration will provide a robust monitoring system that increases plant availability and process measurement fault detection. Furthermore, the monitoring system is expected to improve process efficiency. In this investigation, the procedure of designing an observer system is presented along with three models to design the sensor network. The advantages and disadvantages of each models are discussed and finally the models result for an industrial case are presented and analyzed. INTRODUCTION The concepts of observability and redundancy of mass flow are directly linked with the ability to solve and estimate the mass flow. There are hundreds of streams in a process plant flowsheet, and for technical and economic reasons it is not possible to measure all mass flows. It is thus important to know for a set of measured streams, which of the unmeasured streams can be estimated. The concept of observability deals with this issue. It is also valuable to know whether a measured mass flow of streams can be estimated even if a sensor fails for some reason. Redundancy deals with this failure question. A stream is said to be observable if it can be estimated by using the measurements and/ or mass conservation equations. Also, a stream is redundant if it is observable even when its measurement is removed. Observability and redundancy analysis can be exploited for adding new measuring instruments. It can also play a useful role in efficient decomposition and data reconciliation problem (Narasimhan and Jordache 1999). The value of an observer system cannot be justified without considering its benefits. This justification is done through evaluation of data reconciliation, gross error detection and improving process performance such as outlined below:"

Jan 1, 2018

By Heramb M. Bal

This paper will underpin the future development of intellectuals having greater understanding of patent law and legislation, IP rights, and innovation. To understand this idea, I present a case study of China?s progress in the last 31 years in the rare earth research, innovation, and simultaneously patents area. Rare earth elements (REE) are at the centre of high technology and are the next wave of world innovation. Much of modern society depends on rare earth elements through their use in computers, lasers, telecommunications, iPods, medical technology, military applications, and so on (Long et al, 2010). The rare earth research, a large research body is being provided by Chinese sources. China devoted three or four university centers to the study of rare earths (Lifton, 2009). These measures are all designed to keep China at the forefront of REE production, materials, technology, and innovation. As a result in the last fifteen years there has been a shift from a US-dominated REE industry patents to Chinese patents. The world must identify strategic areas of rare earth innovation and provide funding to firms and universities that conduct such research. Not only research and innovation is vital but filing patents and preserving IP rights for research and innovation is even more important. We (rest of the world) need a comprehensive strategy to guide the development of patent and IP rights for research and innovation. To achieve this, the development of intellectuals with superior knowledge of patents and IP rights are the future need of minerals industry. Keywords: innovation, rare earth, patent, IP rights

Sep 1, 2012

By Cheng Wei

Fly-ash was used as adsorbent to remove butyl xanthate from aqueous solution in this study. Adsorption kinetics investigation reveals that the adsorption process abides by the Lagergren-second-order Kinetic Model, and fine fly-ash prepared by grinding has a higher second-order adsorption rate as 1.25 g/mg?min and a higher saturated adsorption amount as 10.92mg/g. Four influencing factors as adsorption temperature, solution pH, consumption of fly-ash and adsorption time were investigated. Testing results indicate that butyl xanthate removal rates declines slightly with the temperature increase within the range of 15-50?, increases slightly when pH rises from 7.27 to 8.01 and then declines from 99.65% to 98.25% when pH rises from 8.01 to 11.10. An enhancement of removal rates can be observed by increasing the consumption of the adsorbing agent or prolonging the adsorption time. Thermal desorption was adopted to regenerate the used fly-ash, and test results show that fly-ash possess good regeneration performance and could be used as adsorbent repeatedly with little influence on the adsorption capacity.

Sep 1, 2012

By Dongyun Liang

Process mineralogy focuses on the chemical components and mineral composition of ore, dissemination size of valuable minerals, the occurrence of valuable and detrimental elements as well as the behavior of each mineral in the process. Through determining process mineralogy parameters and analyzing the characteristics of minerals, the results of process mineralogy study can provide mineralogy data for making a reasonable mineral processing technology program and optimizing the process. A detailed process mineralogy study is carried out for a complex rare metal ore in this paper and the results show that niobium mainly exists in the form of ferrocolumbite as well as nioboaeschynite and zirconium primarily occurs as zircon. The valuable minerals including Th-nioboaeschynite, ferrocolumbite, zircon, etc. have the characteristics of fine dissemination size, wide size range, complex chemical composition and variable physical properties, which mean it is a refractory ore. According to the results of mineral composition of ore, chemical composition of minerals, dissemination size of minerals, magnetism ranges of minerals and the distribution of niobium and zirconium, the process of ?desliming-Nb-Zr bulk flotation? is designed for this ore and the niobium-zirconium bulk rough concentrate with the grade of Nb2O5 9.43%, ZrO2 24.95%, Ta2O5 0.36% and the recovery of Nb2O5 77.66%, ZrO2 76.70%, Ta2O5 75.13% to crude ore can be obtained in the whole process closed-circuit test.

Sep 1, 2012

By M. Brozek

The particle settling velocity is the argument of separation in such processes as classification and enrichment in jigs. It characterizes material forwarded to the separation process and belongs to the so-called complex arguments because it is the function of particle density and size. i.e. the function of two simple arguments. The affiliation to a given subset is determined by the values of two mag-nitudes and the distribution of such argument in a sample is the function of distributions of particle density and size. The paper will present a method of determining the distribution of settling velocity in the sample of spherical particles for the turbulent particle motion in which the settling velocity is expressed by the Newton formula. Because it depends on density and size of particle which are random variable of certain distributions, the settling velocity is a random variable. Applying theorems of probability, concerning distributions of function of random variables, the authors will present general formula of probability density function of settling velocity for the turbulent motion and particularly calculate probability density function for Weibull?s forms of frequency functions of particle size and density. Distribution of settling velocity will calculate numerically and perform in graphical form.

Jan 1, 2014

By Auhin Kumar Maparu

Metal oxide nano-particles are used as additives in various industrial applications such as pigments in paints, additives in adhesives, plastics, cosmetics, functional coatings, personal care and health care products, for antibacterial applications and more recently in heat transfer applications. In most of these applications, usually dry nano-particle powders are added to the formulations. However, often it becomes difficult to achieve a uniform and stable dispersion of nano-particles in the given formulation. Thus, a scalable and commercially viable process for in-situ production of stable nano-particles suspensions in the desired medium will certainly be more beneficial. Ultra-fine grinding in high energy mills (planetary mill, stirred media mill) has been used to produce fine particles (sub-micron size). However, in order to obtain nano-particles (particle size <100 nm), the choice of appropriate dispersant and solvent is crucial, since freshly generated nano-particles tend to agglomerate due to their high surface reactivity. We have employed molecular modeling (MM) based selection methodology to arrive at the most suitable solvent?dispersant combination for preparation of the given metal oxide nano-particles. Molecular modeling techniques are employed to compute the interaction energy of a given dispersant with surface of the metal oxide particles in the presence of the dispersion medium. The interaction energy helps identify a dispersant that has strong affinity for the metal oxide surfaces allowing for strong dispersant adsorption and hence a more stable dispersion. For example, in case of aqueous nano-titania suspensions, poly-carboxylic acids like citric acid provide better dispersion than mono-carboxylic acids like lauric acid, mysristic acid, and oleic acid. While in non-aqueous medium like ethanol, p-hydroxybenzoic acid and glycerol trioleate perform better. The suspension is produced in-situ by ultra-fine grinding of the metal oxide powder in the presence of the selected dispersant and dispersion medium in a planetary ball mill. By careful selection of various process parameters such as percent loading of powder, jar filling, grinding media to powder ratio, time and amount of dispersant addition, both aqueous and non-aqueous suspensions of metal oxide nano-particles with average particle size less than 100 nm are produced. The aqueous suspensions of alumina and titania produced in presence of citric acid dispersant exhibit median particle size of 83 and 62 nm, respectively. These suspensions have been found to be stable for nearly 3 years. The nano-particles thus produced are used in the preparation of nano-fluids?advance heat transfer liquids, which show enhanced heat transfer capabilities and unaltered stability and performance even after several heating-cooling cycles. The nano-particles are also utilized for making efficient photo catalysts, which are found to be highly effective under sunlight. Keywords: stability, nano-fluid, milling, grinding, thermal conductivity, nanocoolant, photocatalyst

Sep 1, 2012

By V. I. Lakshmanan

The growing concerns on process efficiency, escalating operating and capital costs along with environmental and social concerns of using conventional technology for extracting gold and titanium dioxide demand an in-depth understanding of the fundamentals and a broader understanding of the various process steps involved. This will allow development of efficient process flowsheet for product recovery and compliance with regulatory guidelines. This paper will discuss our recent developments in mineral processing and hydrometallurgical technologies to recover gold and titanium dioxide from a wide range of feed materials including ores, concentrates and tailings.

Sep 1, 2012

By M. Saghaeian, R. Hejazi, M. Farahani, M. Dehghani, A. Tohry

"Wet tailing dams of iron ore processing plants typically contain a significant amount of valuable minerals. In more recent years, due to the increase in iron’s prices and technological innovations, as well as the low energy consumption which required for processing of materials from tailings, dams can consider as potential valuable deposits. However, the production of iron concentrate from tailings is usually complicated where the high moisture content of the material, the high clay content and the presence of chemicals of processing such as flocculants, acids and flotation reagents, all make materials highly sticky which can be easily swollen. In the present paper, the optimization of operational parameters to recover ultrafine hematite iron ore from the wet tailings dams of the Chador-malu iron ore mine was investigated. The optimization of operational parameters, showed that with modification of the washing unit components for slurry making, the challenge of constraints from feeding the plant could be overcome. To decrease the magnetite content in the tail stream of the medium intensity magnetic separation (MIMS) and subsequently increase the efficiency, the orifice of the cleaner tail flow exit pipe was changed from 7 inches to 3 inch and yoke angle changed from 14 to 8 degrees. These changes increased mass yield by 3% and decreased the magnetite content in the final tailings to 1.2%. By recirculating the cleaner SLons of final tailings within the circuit, the solid percentage of the feed to rougher SLons decreased to around 15%, and as a result the matrices were not overloaded that easily, and mass yield increased to about 13% from 7%. All the above mentioned optimizations were achieved without significantly affecting the concentrate Fe grade."

Jan 1, 2018

By Ashok Kumar, Subhadra Sen Dr. Rashmi Kumari, D. P. Chakraborty, Ajay kumar Gupta

The blast furnace coke quality depends on the characteristics of coal blend, pre-carbonization techniques adopted such as stamping, vibro-compaction etc., and coking conditions. Of the above, coal blend plays a significant role in the production of quality coke. Furthermore, the quality of the blend depends on the quality of individual coals and their interaction making up the blend. During transportation and stockpiling, coal is in contact with air for periods of time that sometimes may exceed several months. During this time, reaction with oxygen in the presence of water, sunlight and possibly elevated temperatures may take place. The resulting weathered coal suffers some alteration in its technological properties, which in turn affects coke quality for Blast Furnace operation adversely. In this work, two coals belong two prime hard coking and hard coking categories, namely Illawarra & Tahmoor, were selected and kept in a separate stock pile for a period of 120 days. These coals were characterized in terms of proximate, rheological & petrography properties at a regular frequency. This report summarizes the impact of weathering on the coking behaviour of these two coals in terms of properties as mentioned above. However, the rate of loss depends on coal rank and storage conditions. This has been seen through this study that the loss depends on coal rank and storage conditions. Deterioration of rheological and petrographic properties were seen higher for low-rank coals, like in this study Tahmoor, which is a low rank coal, compared to Illawarra showed higher degree of coking property degradation within the same time period under identical environmental conditions. Low-rank coal deteriorates at a faster rate because low-rank coal is dominated by free radicals that easily react with oxygen, resulting in the creation of various carbonyl groups and weathered vitrinite. Based on the results obtained in this study, size of stock piles for different qualities of coals to be maintained, at a specific time, can be determined and recommended, so that target coke quality is always achieved.

Jan 1, 2018

By Q. J. Liu

The flotation circuit and the reagents of the all-sliming flotation about low grade and hard operation on zinc oxide ore are researched in the paper. The results indicated that there are many types of zinc minerals in this ore, and the composition is very complex. They include hemimorphite, smithsonite, hydrozincite and so on. The ore is seriously sliming. In light of the ore properties, three kinds of flowsheets have tested. They are gravity concentration (cleaning tables), flotation, combined process of gravity concentration and flotation. The test showed that the recovery of zinc is only 17.08% in the gravity separation. In combined process of gravity separation and flotation, the recovery of zinc concentrate is close to 70%. But the flow-sheet is complex and hard to control in the production. The floatation circuit is feasible. In the test, it pay attention to investigate the new combined reagent which is used in selective all?sliming flotation process. The effects of slime are eliminated by the multi-loop treatment of middling. In flotation, the final recovery of concentrate is 88.76%; the grade is 29.50%. The recovery of physical ore is 93%; and the recovery of -10mm fraction is more than 65%.

Jan 1, 2014

By Nilmara Dias, Maria Margarida Martins, Maria Teresa Carvalho

"The heavy residual fraction of the mechanical and biological treatment (MBT) plants treating undifferentiated municipal solid waste is mostly composed by inert materials, such as glass, stones, ceramics and brick. Glass, appearing in significant grade and amount, is not recycled today due to the high content in the other materials, mainly stones. All these materials have approximately the same density but stones have significantly different shape from other materials particles. In this paper it is presented the research developed to eliminate stones appearing in the fine fraction (2.8-8 mm) of the MBT plants heavy residual fraction (MBTr) using a shaking table operated in dry conditions. Two different samples from two different MBT plants were used. Firstly, the samples were characterized (materials content and particle size analysis). Then, laboratory work was carried out to optimize the operation of the shaking table, by changing the machine parameters, deck slope and movement frequency. The study showed that it is possible to upgrade the product in glass. The best results, obtained with one single stage of processing, were 82% content in glass with 84% in recovery, in the glass concentrate, when the coarser fraction (-8+5.6 mm) of one of the MBT plants was used. With the intermediate particle size fraction (-5.6 + 4mm), the glass concentrate attained 74% content in glass with 91% recovery."

Jan 1, 2014

By V. V. Ramarao

Grinding and flotation operations deliver better-optimized performance when they are monitored and controlled in terms of the minerals they process rather than as elemental assays that we usually refer to. Mesh of grind (MoG), liberation, floatability, grade and recovery etc. are more directly related with the minerals and their characteristics rather than the elemental assays. Hence, online analyzers only provide the status for the grade and recovery of metals and not the direction for the enhanced performance. Central Research and Development Laboratory (CRDL) and Rampura Agucha Mine (RAM) mill section of Hindustan Zinc Limited (HZL) jointly undertook various survey campaigns in the grinding and flotation process streams. Grinding circuit surveys involved systematic collection of representative samples from different grinding circuit streams under stabilized conditions for monitoring particle size and process mineralogy details across individual grinding circuit. Flotation survey campaigns included study of fort-nightly / monthly composites of un-ground flotation feed, lead concentrate, lead tailing, zinc concentrate and final tailing samples for size distribution details in the 150 ? 38 micron range, chemical analysis and mineral characterization through optical microscope. This work details the investigations results and their implications on beneficiation performance. Grinding circuit survey campaigns supported the task for modifying the originally installed configuration of hydrocyclones, to limit recovery losses due to excess grinding of soft galena and related silver minerals. Flotation plant surveys helped in adjusting flotation circuit process parameters to reduce loss of liberated and floatable galena and sphalerite grains into their respective tailing streams. Keywords: grinding circuits, survey campaign, hydrocyclones, mineral liberation and locking, lead-zinc ore beneficiation operation

Sep 1, 2012

By W. Yao, M. L. Li, R. Cui

"The purpose of this research is providing a flotation process for recovery of lead in lead silver residues from a zinc smelting plant with a new hydroximic acid collector (HOC). The collecting ability and reaction mechanisms of HOC were investigated based on pure mineral flotation tests and analysis of zeta potential. The pure anglesite flotation tests showed that HOC has a good collecting ability for anglesite. Zeta potential measurements proved that HOC adsorbed on anglesite surface physically and chemically. The lead-silver residues in a zinc smelting plant with lead grade about 17.5% was used as raw material for flotation tests. The results showed that under the conditions of pH adjusting agent lime 500g/t, inhibitors sodium silicate 2000g/t, collector HOC 1500g/t, frother alcohol oil 75g/t, the grade of the lead concentrate can be reach 47.18% and the recovery was 76.39% by one roughing-one scavenging-three cleaning and middles back to the flow-sheet in turn after the lead-silver residues were washed by two stages of cleaning-filtration.INTRODUCTION Nowadays, with the increasing exploitation of natural mineral resources, more and more secondary resources should be researched and used for the valuable metals. Hydrometallurgical zinc leaching residues, which contain a considerable amount of zinc, lead, silver and other minor valuable constituents, is a typical and abundant secondary resources (Zhang et al., 2011). A huge quantity of zinc leaching residues (ZLR) had been produced per year (Jiang et al., 2017).This residues not only occupy precious land but also threaten the environment because of the dissolved heavy metals especially in rainy days (Han et al., 2014). Consequently, it is urgent to develop an effective and clean method to dispose this residues which can benefit not only in economical but also in environmental (Jha et al., 2001)."

Jan 1, 2018

By Chandra Sekhar Gahan

The present study aimed to investigate the depyritization of coal using iron oxidizing and sulphur oxidizing acidophilic chemolithotrophic microorganisms in an iron free 9K growth medium at varying pulp densities. Three different coal samples used in the shake flask study from three different countries such as domestic anthracite (Korean), Indonesian and Chinese lignite. Experiments were carried out in batch at a controlled temperature of 35 °C and varied pulp densities of 8%, 10% and 12% (w/v) with a working volume of 100 ml containing 10 ml of microbial inoculum and 90 ml of the iron free 9K growth medium. Coal samples were crushed and ground to fine size fractions <100 microns by attrition mill wet grinding. The progress in the experiments were followed by the regular measurements of pH, redox potential, viable planktonic cell count, residual Fe2+ ion concentration, amount of acid addition and amount of slaked lime addition. The pyritic sulfur removal percentage varied between 90-95% with highest sulfur removal with China coal (95%) followed by Korean Coal (93-94%) and slightly lower level for Indonesia coal (90%). However the pyrite oxidation was highest for Korean coal ranging between 78-80% followed by a similar level of pyrite oxidation of 50-61% for the Chinese and Indonesian coal. It was found that 10-12% pulp density would be fairly feasible for all the different coals tested leading to an economical process. Another benefit from this study is the iron free 9K growth medium, which will reduce the operation cost and overall it?s an environment friendly process.

Sep 1, 2012

By Jim Pae Lem

This study investigates the mode of occurrence of uranium in a copper concentrate from the Prominent Hill mine. Mineralogical and liberation studies of a high grade Cu concentrate (monthly composite) containing uranium (U) were undertaken using QEM-Scan in combination with QXRD and ICP-MS. The study aimed at determining in what form U was recovered, and by which mechanisms. The deportment of U was studied in 3 size fractions; +20µm, -20+8µm and -8µm. QEM-Scan analysis showed that uranium was present as U(Cu)-silicates, U-silicates, UPbOx/FeOx or traces of UThOx and UTiOx, with the U-silicates present across the size fractions. The association of uranium bearing minerals with copper sulphides varied across the size ranges. Interestingly, most of the U (46% by weight) was distributed in the finest fraction (-8µm), in which the deportment of Cu was low (6%). Over 40% of the U mineralisation in the -8µm was liberated. In terms of the floatation response, while recovery of the uranium minerals as a result of their association with copper sulphides (as composite particles) was evident, recovery of UPbOx locked in hydrophilic haematite in the +20µm size fraction suggests, that other mechanisms (e.g. Inadvertent activation by Pb from radioactive U decay) are possible. Furthermore, the high amount of fine liberated U bearing particles in the concentrate points at entrainment as another major mechanism for uranium recovery, and therefore, a target for process optimisation.

Sep 1, 2012

By K. Anand Rao

Extensive exploration for uranium metal by the Department of Atomic Energy in India led to the discovery of new carbonate host rock uranium deposits Tummalapalle and Gogi, which are located in southern part of India. Alkaline leaching at elevated temperature and pressure using autoclave is the central unit process in the overall strategy for extraction of uranium from these new ore deposits. Autoclave leaching is affected largely by intrinsic nature of the ore and by the process variables and the equipment settings. In order to understand such a complex process and also to be able to predict the process performance under randomly (ore grade, uranium mineralogy, gangue mineralogy etc.) and consciously perturbed variable settings (partial pressure of oxygen, temperature, concentration of leachant, stirring speed and time), sound and robust mathematical models are needed with analytical and/or numerical solutions. Present investigation attempts to develop a variant of kinetic correlation based on shrinking core model for batch alkaline leaching process in an autoclave. The leaching model incorporates particle size distribution according to popular Gates-Gaudin-Schuhmann equation, rather than assuming a single mean size for all the particles participating in the leaching reaction. Kinetic experimental data generated in autoclave leaching of Gogi uranium ore was used to evaluate various constants of the model developed. The ore sample used for experiments assayed 0.21 per cent U3O8. The partial pressure of oxygen was varied between 0.15 to 6.5 atm, temperature from 343 K to 438 K, concentration of sodium carbonate leachant in the range 0.47 g mol/L to 0.94 g mol/L, and the stirring speed from 573 rev/min to 900 rev/min in the experiments. The goodness of fit of the leaching process model is found to be >0.95. Morphological studies carried out on leached and unleached particulate matter using Scanning Electron Microscopy with Energy Dispersive X ray analyses are included in the present study.

Sep 1, 2012