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By Q. Zhang, J. A. Finch

"Sphalerite flotation in the absence of copper activation at moderately alkaline pH has been observed in laboratory studies. An in-plant test of this observation was conducted at Kidd Creek Mine LTD. using a portable minicell flotation circuit. The results confirm that raising the pH causes sphalerite flotation.The testwork with the minicell circuit is described. The circuit, built around 2, 51 cells donated by the Noranda Technology Centre, was funded by Air Liquide and NSERC. It includes a data acquisition system to monitor continuously dissolved oxygen, pH and Pulp potential.INTRODUCTIONFlotation of sphalerite is normally practised by adding CuSO4 as an activator under alkaline pH. Recently there have been a number of laboratory and plant examples of sphalerite flotation without deliberate addition of cu++ ions (Girczys, 1972; Mukherjee, 1976; McTavish, 1980; Marouf et al., 1986; Mielczarski, 1986; Leroux et al., 1987; Palsson and Forssberg, 1989; Sandoval-Caballero et al., 1990; Zhang et al., 1991).In batch tests, with a sample of Pb/Zn ore from Polaris, Leroux et al. (1987) found that sphalerite became floatable after adjusting pH to 9. 5-11: they ruled out natural floatability or the formation of elemental sulphur on the surface but suspected iron hydroxy compounds were responsible. Sandoval-Caballero (1990) conducted a continuous minicell test at Brunswick Mining and obtained a 44 % Zn recovery and 40.5 % Zn grade concentrate without deliberately adding CuS04 at pH= 10.5. With single mineral studies, Zhang et al. (1991) revealed good sphalerite floatability (over 80% recovery) in pH range 8 to 11 and found that this floatability was related to pH, dissolved oxygen (DO) level and Fe++ species present in the system.To explore further the conditions under which sphalerite can float without addition of CuSO4 , a continuous pilot test using minicells was performed at Falconbridge Ltd., Kidd Creek division. The set-up is briefly described (a more detailed description is given elsewhere in these proceedings) with emphasis on the data acquisition system - dissolved oxygen, pulp potential and pH were monitored continuously. Results of testwork investigating pH, CuS04 addition and gas composition are presented."

Jan 1, 1992

By René Lefebvre

Numerical simulations of the physicochemical processes related to acid rock drainage (ARD) in the Sugar Shack South rock pile of the Questa Mine were performed with the TOUGH AMD simulator. The objectives were to 1) identify the main processes responsible for observed present-day conditions, 2) provide an estimate of gas phase humidity transfer, and 3) give a preliminary indication of the potential impact of closure involving the installation of an alluvial soil cover. Modeling results indicated that the mine rock geometry (thin layers placed along steep mountain slopes) favors the onset of strong thermal air convection. Simulations also indicate that resloping the piles would not significantly reduce convection and oxidation. For simulation purposes, a potential cover with the permeability range of a local alluvium was investigated and found to be of questionable effectiveness since its permeability can exceed the value of 3x10-13 m2 required to prevent thermal air convection and reduce ARD.

Nov 1, 2002

By Éric Poulin, Simon Gariépy, Mario Paredes Malca

"While the design of a control strategy depends on the available process knowledge, its implementation depends on the available process information. On-line chemical analyzers are today widely spread in the mineral processing industry. A real-time concentration measurement of chemical components is valuable information that could bring control strategies to whole new levels. However, the use of these measures rarely reaches anything more than process monitoring. The reason is simple: the on-line chemical measurements quality is most of the time insufficient to be directly included in control strategies. The choice is then made to let the critical eye of the engineer or the operator appreciates the measurements before making any decision based on it.Data reconciliation through mass balance is a technique today widely used in the mineral processing industry to increase the accuracy and the reliability of plant data, mainly for accounting and survey analysis purposes. Real-time data reconciliation of on-line measurements appears as a natural coupling of technologies that could bring new process optimization trends. Once overcome the technical difficulties, full valorization of the instrumentation investment could be reached.This paper presents the application of real-time data reconciliation for process control and performance monitoring. It proposes a general approach, discusses challenges and illustrates concepts with industry experiences."

Jan 1, 2006

By Bill Shand

"Placer Dome - Campbell Mine is a gold mine located at Balmertown in the Red Lake District of North Western Ontario. During the last 50 years, the mine has produced over ten million ounces of gold.A change in ball mill grinding media was made in August 1998 from 1.5” diameter forged balls to 1.5” diameter, 18% chrome balls. This was done to reduce grinding media consumption and to potentially help flotation performance.A marked ball test done in September-October 1999 showed that, of the alloys tested, 18% chrome was the optimum for the ore at Campbell Mine. The test showed that consumption of chrome balls should be 3 times less than forged balls.In December 1999, the ball size was increased from 1.5” to 2” in an effort to reduce the amount of oversize rock discharging from the ball mill. This change in size was successful.Grinding media consumption for the ball mill decreased 73% from 1.20 kg/tonne before the use of chrome balls to 0.327 kg/tonne after the use of chrome balls. This clearly indicates that, for the ore at Campbell Mine, there is significant savings in grinding media by using chrome.Grinding ball costs were reduced by 59% from $O.88/tonne of ore milled to $0.36/tonne of ore milled representing a saving of $298,000 per year. This also clearly indicates that using chrome balls is a benefit at Campbell Mine.Test work to show that chrome grinding media is beneficial to flotation has been inconclusive so far but is still ongoing.No tests have been done to see if there would be a benefit with an even higher chrome percentage in the grinding media. Test work in this area is also planned for the future"

Jan 1, 2001

By Ronald L. Bruening

IBC has developed a cost effective MRT process for the selective extraction and recovery of gold, copper, and a mixture of other base metals from mine leach cyanide solutions. This is a two-stage system in which the gold is first recovered selectively as a high purity salt. The copper is then recovered separately as a sulfate salt. The other base metals are then collected as a cyano anion concentrate. Three different SuperLig® materials are used. The first stage can be used alone on gold leach solutions where copper and other base metals are not a problem. The two or three stage system is used when the base metals build up in the leach solution, resulting in increased costs. The cyanide or cyanide/cyano anion concentrate can be recycled back to the leach solution until the build-up of other salts, etc. becomes too high, or this too can be controlled with a percentage bleed stream.

Oct 1, 2003

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

The world’s first copper electrorefinery started production in 1869 at Burry Port in South Wales. Built within the Pembrey Copper Works which had commenced smelting operations in 1849, the new refinery was based on principles described in the British patents issued to J.B. Elkington in 1865 and 1869. Refining principles and practices pioneered there were key to the foundation of modern electro-refining practice in what is now a dominant international industry producing over 16 Mt of electrical grade copper annually. This paper explores the background to this pioneering application of the new, early 19th century, science of “electro-metallurgy” and examines its links to the contemporary decorative electro-plating industry and to the shortcomings of 19th century fire refining. The beginnings and early years of the Pembrey electrorefinery are briefly discussed in relation to the quality, applications and pyrometallurgy of copper at the time. More than a decade would elapse before the birth of the electrical age: the Pembrey refinery may be seen as one of its vital precursors. Note: This paper was originally published as part of the Copper 2013 proceedings (A.E. Wraith, P.J. Mackey and J. (formerly R.) Protheroe Jones, “Origins of Electrorefining: Birth of the Technology and the World’s First Commercial Electro-Refinery”, paper in Electrorefining, Vol. V, Book 2, (Eds. R. Abel and C. Delgado), Cu 2013 International Conference, pp. 19-33, IIMCh, Santiago, Chile, 2013). It is reproduced here together with a new Appendix and supporting references that lists the year of commencement of the first electrolytic copper refinery by country, 1869 to 1956. It all, the year of the first electrolytic copper refinery established for 15 countries is included. These 15 countries now produce more that 70% of world refined copper (for 2018). INTRODUCTION In the 1840s, the new science of ‘electro-metallurgy’, a term coined by Smee in 1841 (Smee, 1841), was being adapted to the decorative electro-deposition of silver in a thin, bright adherent coating that was evidently equal in appearance to traditional silverware (Williams, 1976). Chief among innovative manufacturers of decorative objects who took up the new art of silver electro-plating was the acclaimed firm of G.R. Elkington and Co. of Birmingham, England. The company, which vigorously developed all aspects of electro-metallurgy for the decorative trade, entered the field of ‘electrotyping’, a technique in which the surface features of a mould are copied on an electro-deposited copper layer which, when stripped off, can be used to reproduce an imprint of the mould. In essence, it is a form of casting by electrodeposition, invented in 1837 independently by Jacobi in Russia (Pavlova, 1968) and Spencer in England (Wyatt, 1851).

Jan 1, 2019

By P. A. Riveros, W. D. Gould, R. Molnar, D. W. Koren, P. Bédard

This paper reports the results of the field demonstration campaign of a new process for removing and destroying ammonia from mining/ metallurgical effluent solutions. The 50-day campaign was carried out at a uranium plant in Saskatchewan, Canada. The process was developed by adapting and integrating two well established technologies: zeolite adsorption/ elution to extract the ammonia from the effluent stream and to produce a concentrated ammonia eluate; and conversion of the ammonia in the eluate to innocuous nitrogen by applying bacterial nitrification-denitrification (NH3 = > NO3 - => N2). The data show that reasonable target criteria were met, under very challenging operating conditions. Problem areas and possible causes for poor performance are identified. Preliminary and generic cost estimates of the process are also presented.

Jan 1, 2003

By Fidelis T. Suorineni

Rockbursts are a major hazard in deep hard rock underground mining and tunneling. To date a significant number of rockbursts still defy conventional explanations. A review of rockburst case histories in the literature has shown that pillars and tabular excavations under shear loading are prone to rockbursting in situations where they are least expected under conventional knowledge of rockburst causes. Despite the evidence of the effects of shear loading on underground infrastructure, and the frequency of their occurrence, little is known about how this loading mechanism causes such large magnitude events and extensive damage. In this paper analytical and numerical modeling are used to understand the behaviour of pillars and tabular excavations under shear loading. The numerical modelling results show that pillars under shear loading are less confined than their equivalents in loaded in pure compression in the same geologic environment, and are therefore more brittle and weak. For tabular excavations under shear loading, the behaviour depends on whether such excavations are continuous, co-planar or offset with rock bridges. Analytical results based on slit theory show releasable potential energy in tabular excavations increases nonlinearly with excavation half-span. The study results are important for the safe and economic extraction of orebodies under shear loading.

May 1, 2011

By G. S. Dobby, J. A. Finch

"I. INTRODUCTIONA significant development in flotation over the past few years has been the increasing industrial use of flotation columns, primarily in Canada. The column differs dramatically from conventional mechanical flotation machines, both in design end operating philosophy, which has been a principal reason for its slow acceptance by the mineral industry. Boutin, Tremblay and Wheeler (1. 2) developed the concept in the early 1960's and since then plant and laboratory columns have been marketed commercially by Column Flotation Company of Canada Ltd. In 1980-81 at Mines Gaspe, Quebec, three columns replaced 13 conventional cleaners in a molybdenum upgrading circuit, with superior results (3). Since then many of the copper producers in British Columbia have installed columns for copper and molybdenum cleaning, including Gibraltar, Lornex, Highmont and Island Copper. There now appears to be widespread interest in flotation columns.The column is particularly attractive for applications involving multiple cleaning stages and can upgrade In a single stage compared with several stages of mechanical cells. This results in simpler, more controllable circuits. Importantly, the column itself is well suited to computer control. A significant problem, however, has been that of translating laboratory data to plant performance. The purposes of this communication are to address the problem of column scale-up and to describe some of the transport mechanisms of a flotation column, leading to a kinetics based model.A schematic of a flotation column is shown in Figure]. Industrial columns are up to 13 m high and 0.3 to 1.8 m in cross section (either square or circular). Three zones can be identified:a collection zone, with feed entering 2 to 3 m below the top of the column and descending against rising bubbles generated at a gas sparger; a washing zone, where a packed bubble bed is generated by a downward flow of wash water; and a conventional froth (2 - 5 cm thick), the sole purpose of which is particle transport to the launder. The tailings withdrawal at the bottom of the column is controlled at a rate slightly greater than the feed flowrate (called a positive bias).An important element is the washwater, added just below the froth zone. The component of the washwater that flows downward (to make up the bias) is sufficient to prevent coalescence of rising gas bubbles. The packed bubble beg so generated is very efficient at suppressing gangue entrainment to the concentrate."

Jan 1, 1985

By A. Wright, P. Lacombe, R. del Villar, D. Hodouin, C. Sepulveda

"The data acquisition from industrial plants is a fundamental step for process modelling in process optimization, process analysis and automatic control.The introduction, some years ago, of modern distributed control and data acquisition systems in concentrators imposes a new approach in designing experimental schemes for data acquisition campaigns and new criteria for the treatment of the obtained discrete information.This paper presents the methodology applied to sample a zinc flotation circuit at Les Mines Selbaie, Joutel, PQ. Values of 85 process variables were obtained form the Distributed Control and Data Acquisition System (Bailey Network 90) and transferred to the DOS environment. Another 11 variables (flowrates and valve positions) were directly sampled using an IBM-PC compatible computer equipped with a data acquisition card and a signal processing circuit.All variables, under the vector form, were processed in the PC-MATLAB environment to either filter or eliminate the non-linear disturbances and noises, producing useful data for model development. The filtering algorithms are also presented.INTRODUCTIONProcess control does not need to be justified. Whether manual or automatic, any processing plant requires some form of control to accomplish its main objectives: a good quality product and a target throughput. Process control of mineral processing plants has steadily evolved from manual control, where the operator skills and/or experience play an important role, to some level of automatic control, usually considered better, as less human subjectivity is involved, at least when actions have to be taken.The design of these control systems requires the knowledge of the dynamics of the process it is deemed to control. Process modelling is therefore an essential step in the assessment and the design of a control strategy. The choice of model will depend on the available resources and manpower."

Jan 1, 1991

By Kym Runge, Emmy Manlapig

"The objective of an industrial flotation circuit is to separate valuable minerals from non-valuable minerals utilising differences in their flotation recovery rate. Regrinding and reagent addition are particle modification processes which are employed within these circuits to maximise the flotation selectivity of one mineral with respect to the others present in the ore feeding the process.Batch test nodal analysis, or the ability to compare floatability through mathematical combination of laboratory batch flotation test results, is a powerful technique for assessing the effectiveness of particle modification processes on ore floatability in industrial flotation circuits.In this paper, the use of nodal analysis is demonstrated within an industrial flotation circuit. It is used to show that regrinding and staged reagent addition within Teck Cominco’s Red Dog zinc retreatment circuit is beneficial to pulp flotation selectivity. Optimisation of these processes could potentially improve the zinc recovery within the circuit. Lime addition, which is periodically employed to depress pyrite in the circuit, was found to depress sphalerite in preference to pyrite and to result in poorer metallurgical performance in the circuit.INTRODUCTIONThe objective of an industrial flotation circuit is to separate valuable minerals from non-valuable minerals utilising differences in their flotation recovery rate.Different minerals can only be effectively separated using flotation if they are sufficiently liberated from each other (i.e. do not co-exist within the same particles) and have a sufficient difference in surface hydrophobicity. Size reduction processes and chemical addition are utilised before and within a flotation circuit to achieve sufficient particle liberation and to maximise differences in mineral hydrophobicity. In effect, the objective of these processes is to maximise the flotation selectivity of one mineral with respect to the others present in the ore feeding the process."

Jan 1, 2004

By S. Rajeswari, D. Gopi

"Pitting corrosion inhibition of 304 stainless steel (SS) in groundwater with a ternary inhibitor mixture (phosphonic acid + bivalent cation + various surfactants) was studied with different environmental variables such as temperature, pH, dissolved oxygen and chloride ions. Critical pitting potential and corrosion potential were calculated for these test media using electrochemical techniques. Under the tested condition, the localized corrosion resistance of 304 SS was determined and the results are discussed. IntroductionPitting corrosion of metals and alloys is a major cause of failure in chemical processing desalination plants, scrubber for flue gas desulphurization (FGD) plants, water storage tanks and pipelines, petroleum refineries, etc.Heat exchangers and condensers in inland thermal and nuclear powerplants utilize groundwater as a coolant, but materials of construction are generally prone to localized corrosion.Localized corrosion attack can be initiated when the passive film on the metal is disrupted. The presence of certain aggressive anions such as chlorides (Cl-) can migrate to the actively corroding area and stabilize pitting corrosion. Attention has been focussed on improving the resistance of stainless steel against localizedcorrosion in aqueous environments.One of the most accepted methods of avoiding corrosion is by the addition of chemicals (inhibitors). Over the past two decades, some phosphonic acids have been explored due to their good corrosion inhibition efficiency and low toxicity (Fang et al., 1993; Karman et al., 1998; Rajendran et al., 1998; Gopi and Rajeswari, 2000a). Bivalent cations like Zn2+ are often applied as additives to inhibit the metal dissolution (Sekine and Hirakawa, 1986; Aruna Bahadur, 1998)."

Jan 1, 2003

By B. G. Hunt, E. J. Kwasney, W. P. Campbell, S. L. Gertsman

"AbstractIn the separation of lead and zinc concentrates from the ore from Cominco's Sullivan mine at Kimberley, • B.C., an iron sulphide concentrate is also produced, some of which is roasted to provide sulphuric add for the manufacture of phosphate fertilizer. The iron oxide calcine from the roaster is potentially a valuable raw material for the production of pig iron and steel. To evaluate this material, six tons of .pig iron was produced from it in an experimental 75 k.w. electric furnace at Trail. The pig iron alone, and also in varying proportions with structural steel scrap and commercial pig iron, was used in the production of basic electric furnace steel at the Mines Branch Laboratories, Ottawa. Details are given of the steel making and fabrication procedure, of the visual and microscopic examination, and of the extensive series of tests on the steel produced. The steel produced using Cominco .pig iron in the charge showed normal working properties in all tests carried out.IntroductionTHIS PAPER describes (a) experimental work by The Consolidated Mining and Smelting Company of Canada, Limited ( Cominco), at Trail on the production of pig iron .from Sullivan iron concentrates, and (b) a joint laboratory investigation by Cominco and the Mines Branch, Department of Mines and Technical Surveys, Ottawa, to determine the feasibility of making a satisfactory steel from this pig iron."

Jan 1, 1955

By J. Kazakoff

"The success of gold recovery at the Jolu gold mill depends on many variables. The most important ones are the people, the ore body, plant design parameters, equipment selection and cost control. This paper will briefly hiqhlight the above, the main focus, however will be on the gravity gold circuit.The gravity circuit requires judicious operator attention in order to operate properly. In return the circuit gives immediate visual results for mill peopleIntroductionThe development of the Jolu property to the production stage was carried out quickly, efficiently and economically. The property became a gold producer ahead of schedule and under budget.The Jolu property is a joint venture between International Mahogany Corp., a 70% partner, and Corona Corporation, a 30% partner. Corona Corporation operates the Jolu Gold Mine, located 140 kilometers north of LaRonge and 520 kilometers north of Saskatoon."

Jan 1, 1990

DynoMiner APS Delivery Systems Overview ? New Design of DynoMiner APS-M2 ? Stand alone or attach to Cargo type 10,000 lb (4536 kg) emulsion bins. ? Hose reel w/200-ft (61-m) by 1-inch I.D (25-mm) hose capacity, power rewind. ? Increased water and trace capacity. ? Hose reel and gassing offered as options. ? New Flow Meter ? DN-100: aluminum body, UHMWPE rotors. ? Will be offered as an option. ? APS Nomenclature ? Proposed changes ? DynoMiner APS and APS-M1 to become DynoMiner APS Drifter ? DynoMiner APS-M2 to become DynoMiner APS Stoper. ? Both to have optional gassing / flow metering.

May 1, 2004

By Karl Marquis

La Mine Mouska exploite depuis deux ans certains blocs de réserve à l?aide de la méthode long trou. Même si, à priori, la méthode long trou semble rentable, le contrôle de la dilution ainsi que le respect d?un échéancier serré s?avèrent primordiaux afin que cette méthode d?exploitation puisse être justifiable économiquement. La présentation suivante fera la comparaison économique entre cette méthode et celle de chambre-magasin.

Oct 1, 2001

By G. Papachristodoulou, O. Trass

"Performance data for both wet and dry grinding of materials have been obtained in this novel, planetary ring-roller mill over wide ranges or operating conditions. The Szego mill consists of a stationary cylindrical shell inside which grooved, radially mobile rollers rotate, driven by a central shaft. The mill has several internal design variables such as number, diameter and length of rollers as well as size, shape and pitch oi helical grooves. It is compact, has a high specific capacity, modest power consumption, and can grind many materials down to ultrafine powders. Illustrative data on product fineness and mill power consumption are given along with results from studies on grinding kinetics.INTRODUCTIONThe extensive use and importance of grinding as a unit operation, coupled with the rather low energy efficiency of conventional equipment provide a challenging incentive to investigate novel methods of comminution. Yet, most current development work is taking place in mill performance modelling and optimization, or with various detailed improvements rather than in the field of new equipment development.This paper is a report on the development of a ring-roller mill invented by the late L.L. Szego which embodies several novel concepts. The mill has a broad range of applications, may be operated wet or dry, and can grind materials down to ultrafine sizes with modest energy consumption. It has been developed by General Comminution Inc. in close cooperation with the University of Toronto."

Jan 1, 1986

By Andrea M. Ouchi

A major focus of ground control research presently being conducted by the Geomechanics Group in the University of British Columbia Mining Engineering Department is to incorporate weak rock masses (RMR76 less than 50) into existing empirical design relationships. An emphasis is being placed upon the updated span design curve/critical span graph originally developed at UBC. The original database has been augmented by mapping of one mine in Montana and of several mines within the Carlin and Getchell Trends of Nevada. In addition, a neural network analysis has been performed and modifications of the span design curves at the lower RMR76 range have been made. The common factor in all the above mentioned mines is a weak back and/or walls. In most cases, the ore zone is the weakest rock unit and must be dealt with to safely extract the mineral bearing rock. This work attempts to provide rock mechanic tools that will enable a mine operator to make economic decisions that will also ensure a safe working environment.

May 1, 2004

By Phil Thwaites

"The mining industry uses many types of mineral and metallurgical plants to produce saleable product from ore mined. Plant design history has left current operations with a mixture of manual operation and various forms of automated process controls. Consequently, we typically see high variability in the continuous operations together with a shortfall in the attainment of full capacity, or higher utilization of consumables.At a level of best practice, “Operational Performance Excellence” focuses on process control, using automation and control systems to deliver process optimization. This more sophisticated delivery is a great deal more difficult than the first stage of equipment selection / installation. It includes the appropriate selection of the right instrumentation, control system, key process knowledge, individuals with a solid control engineering background/experience, and the essential backing/ support of the operations management team together leading to higher value delivery. Robust solutions can be realized, considerably minimizing process variation, thus leading to process optimization. This approach results in an easier, efficient and safer process while providing considerable returns for the plant owners.How variable are your processes, and do you maintain optimized process performance with dedicated resources, modern instrumentation, ‘best practice’ control systems and performance monitoring tools? In this lecture, these questions and their possible answers are discussed.357"

Jan 1, 2013

By M. J. Fairweather

"The development of means to maximize the selectivity between galena and sphalerite in lead zinc ores is extremely important to the lead-zinc industry. Two challenging studies recently undertaken by Cominco will be reviewed. The first required an unusually fine grind to achieve liberation between galena and sphalerite. The second contained partially altered galena which resulted in unusual early activation of sphalerite under normal flotation conditions. Means by which lead and zinc separation were optimized in these two ores will be discussed.There are two important factors in the separation of minerals by froth flotation: particle size distribution (grind) and pulp chemistry. Pulp chemistry includes a number of factors including pH, Eh, collector type and concentration, inorganic depressants, organic depressants and activators.Grind is important for two reasons. A sufficiently fine grind is required to optimize liberation. However, if the mineral dissemination is too fine, mineral selectivity in the flotation process is impaired. Due to the hydrodynamic constraints of conventional mechanical flotation cells, flotation works best over the single decade size range between 10 and 100 microns. The majority of new ores treated by Cominco until relatively recently were comparatively simple. The major factor in their treatment was defining optimum grind size. Accordingly, the focus within mineral processing at Cominco was on grind and supporting liberation studies. The relationships between grind, liberation and flotation response are intuitively easy to understand. An idealized relationship is shown in the first figure."

Jan 1, 1991