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By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012

By T. R. Kostecki, J. Hirschi

"Analytical engineering design is based upon a trial-and-error iterative and deterministic process. Within this process, the engineer obtains some estimated values, plugs them into de facto closed-form equations, and receives output, which is expected to be a single number that serves as the basis for the design. This number is typically a factor of safety, or some other equivalent strength-stress ratio. This provides the engineer with a quick and relatively quantitative design methodology. This can create problems however, because in mining applications, the actual in situ system is highly variable, complex and often chaotic, which can lead to potentially incorrect conclusions that result in unsafe designs. A more appropriate and reliable approach is a probabilistic analysis for engineering design. This process is used widely in civil and other engineering disciplines, but is often overlooked for applications in coal mine design. Additionally, it seems the amount of past studies using this approach, especially in coal mine design, are rather limited. Considering how the probabilistic approach can account for uncertainty in parametric values and how unpredictable a mining design can be, the authors believe that this approach has potential in mining. This paper will focus on a summary of past studies related to probabilistic analysis in coal mine pillar design and provide recommendations for future work that could improve design reliability. INTRODUCTIONFeasibility and fundamental design procedures for excavations often start with an assessment of mine openings, pillar design, and the surrounding structure by using a deterministic approach with closedform solutions (ex. Bienawski, Obert-Duvall). These are reliable methods, but designers know that the inputs in these closed-form solutions are estimates at best and do not incorporate any degree of uncertainty. This is therefore not an optimal design procedure.A more appropriate design should incorporate some uncertainty because of the chaotic and variable nature of geology and mining conditions in general. In an attempt to account for uncertainty, a probabilistic approach can be adopted, which accounts for deviations in variables and provides a more optimum design solution. By applying a probabilistic approach, a designer can look at multiple failure scenarios at the same time instead of using the same deterministic design over and over."

Jan 1, 2015

By W. Pietsch

For a number of reasons, solids entering and leaving facilities for the treatment of minerals are becoming increasingly finer. Such materials pose problems throughout processing. Solids featuring small particle sizes tend to dusting, result in losses and segregation, exhibit various storage, transportation, and metering problems, and fine particulate effluents can not be easily captured, used and/or recycled. Sustainable mineral processing must minimize the exploitation of natural resources and avoid the need for disposal of wastes. The first requires the use of lower quality raw materials and upgrading, which typically results in the production of fine grained concentrates, and the latter encourages the recycling of wastes and byproducts or efforts to investigate them as sources for secondary raw materials or other beneficial applications. To overcome the difficulties associated with fine particulate solids, size enlargement by agglomeration is necessary. The resulting products have free flow characteristics, do no longer dust or segregate, and are sized and shaped as required for optimum processing. In addition, agglomerated materials may be engineered to feature desirable structure, composition, and a number of related, improved properties. Such engineering may be applied for the modification of fine run-of-mine and up-graded minerals as well as the production of secondary raw materials from by-products or wastes. By the interdisciplinary application of size enlargement by agglomeration waste-free processing of minerals becomes feasible.

Jan 1, 2004

By K. H. Poulsen, C. J. . Hodgson

Synvolcanic, layered gabbro-anorthosite sills at Rainy Lake, Northwestern Ontario, reflect a combination of igneous processes including fractional crystallization, wall rock assimilation and possibly liquid immiscibility. Chalcopyrite-pyrrhotite mineralization at the base of the Grassy Portage intrusion accumulated by crystallization of a sulphide liquid during cooling. Upward enrichment of Fe and Ti in this intrusion and also in the Bad Vermilion Lake anorthosite complex culminated with the crystallization of lenses of disseminated to massive magnetite+ apatite+ ilmenite+ rutile. Regional low to medium grade metamorphism and accompanying deformation resulted in recrystallization and local remobilization of ore minerals.

Jan 1, 1984

By R. L. Bruening, N. E. Izatt, S. R. Izatt

The need for selective metal separations has increased as the mining industry encounters more complex ore bodies and demand for higher performance end products expands. The Molecular Recognition Technology (MRT) process uses highly selective SuperLig® resins to remove desired metals from a variety of solutions in the mining and metals processing and recovery industries. MRT separation processes efficiently produce high purity metal products. In this paper, applications of MRT to metal recovery at mg/L to multiple g/L concentration levels are presented and discussed. Specific examples in the precious metal, nickel, cobalt, zinc, copper, and rare earth industries are given.

Jan 1, 2014

By A Frydrychewicz, J. Mirza, J. Lipkowski

The objective of this work was to understand the mechanisms of action of additives, such as thiourea, that enhance gold leaching in thiosulfate solution. The leaching reaction and surface passivation were investigated using linear sweep voltammetry. Leaching currents were determined using analysis of current-potential curves and the mixed potential theory. The gold-electrolyte interface was further characterized with surface enhanced Raman spectroscopy. The results show how thiourea prevents formation of oxysulfur compounds, which passivate the gold surface. Other molecules such as 3- m ercaptopropionic acid and L-cysteine were also studied as possible additives to prevent passive layer formation.

Jan 1, 2011

By Joseph Bradley

THROUGHOUT this article, minerals used in the paint industry are designated 'pigments'. They may be classified in two groups: (1) Pigments which are used in the state in which they occur in nature, requiring only mechanical preparation. (2) Pigments which require heating or chemical treatment before use, in order to obtain from them a product of the desired quality or shade of colour. They may be further classified according to colour, as follows: White Pigments .-These include calcium carbonate (chalk, marble), gypsum and alabaster, kaolin-or china-clay, and magnesia. However, the white pigments most extensively used are compounds prepared chemically from minerals containing lead, zinc, titanium, and antimony. The white pigments are of particular importance because, not only are they used by themselves, but they also serve as adjuncts to other colours for the production of special shades. Yellow Pigments.-These are mainly naturally occurring ferric hydroxides, as limonite and bog iron ore, or similar. compounds prepared artificially. Brown Pigments .-Pigments of this group are distinguished for their beauty and depth of colour, and many of them are used in the finest of paintings. Familiar names are sienna, umber, and Vandyke brown. They are for the most part ferric hydroxides, containing varying amounts of water; but the group also includes a manganese brown, which consists chiefly of a mixture of oxide and hydroxide of manganese. Red Pigments.-Chief among this group is ferric oxide, known under various trade-names, such as Canadian red, Persian red, etc., and also the much prized and somewhat rare vermilion. The pigment used is either naturally occurring hematite, de-hydrated limonite, or artificially produced red ferric oxide.

Jan 1, 1937

By Clemens Kuhnert

"Nickelhütte Aue GmbH is specialized in the recycling of waste materials containing non-ferrous metals. We treat nickel, copper, cobalt, vanadium, molybdenum and precious metal containing materials like spent catalysts, ashes, dusts, grindings, liquids, slurries and sludge's as long as they contain one or a combination of the above mentioned metals. In our pyrometallurgical works we produce non-ferrous metal concentrates suitable for further treatment in our hydrometallurgical plant where we refine Ni-, Cu-, Co- and V-chemicals. Our production is based on synergy effects due to the combination of pyro- and hydro-metallurgy. As an example we can mention our heat recovery system and internal recycling of by-products. Furthermore, the use of alternative fuels instead of fossil fuels contributes to the economic and environ-mentally friendly treatment system.INTRODUCTION Nickelhütte Aue GmbH (NHA) can look back on nearly 400 years of tradition as a pyrometallurgical works and recycling company. The existence since its foundation in 1635 as a blue dye works shows responsible and successful action in the past. Therefore, we see highest customer service, minimization of interferences with nature by closing material cycles and maximized health and occupational safety protection by avoiding injuries and diseases, still as our future duties. These duties are evaluated and monitored by an integrated management system that meets the standards of DIN EN ISO 9001, 14001, 50001 and BS OHSAS 18001. We commit ourselves to the observance of all juridical and customized demands. The management and the department managers perceive their model function. We require responsible action from all employees. To protect the continuity of our enterprise, we will also perform in future continuous improvement of products and their quality, as well as steady progress in the areas of environment protection, health protection and industrial safety. Equally the effectiveness and propriety of the management system is checked and developed regularly. In order to obtain the objectives resulting from this policy, our company determines activities and measures by involving all employees."

Jan 1, 2017

By S. Hosseinpour

Chromate conversion coatings (CCCs) are usually applied to these alloys to enhance their resistance to localized corrosion and to improve paint adhesion. The special properties of these coatings such as their low electrical contact resistance (ECR) make them suitable for satellites. This study is aimed to develop advanced CCCs with the proper appearance, morphologies and surface roughness and to evaluate their role on the ECR and thermo physical properties on hardened aluminium alloy of Alclad-7075-T6. Coating characterization was performed by means of scanning electron microscope (SEM) and atomic force microscope (AFM). ECR of coatings were measured by special laboratory designed instrument and a and c were measured by Emissometer and Reflectometer respectively. In addition, corrosion performance of the CCC-coated alloys was determined by 168 hr exposing to salt-spray testing in accordance with ASTM-B117. The results of accomplished experiments on the developed CCCs in this study have been agreeable concerning available acceptability criteria for satellite surfaces.

Jan 1, 2007

By C. Dragusanu, J. Sims, J. Connolly

Based on a statistical analysis of the categorical and numerical data from the established geological model, a geochemical classification of mineralization has been shown to be objective in nature and correlated to the envisioned metal extraction process. Multivariate chemical classification has the potential to discriminate within a combined response from different types of alteration and metal abundances. Distinct domains of chemical response determined by clustering analysis were used as a validating criterion for a geologically driven metallurgical testing program. The groups established are spatially linked to the geological process responsible for their genesis, providing clarity in geometallurgical and resource modeling.

Jan 1, 2011

By F. J. Hrach, K. P. Flynn, P. J. Miranda

"ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (300 µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. Separation results are presented for selected industrial mineral sources. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.INTRODUCTIONThe lack of access to fresh water is becoming a major factor affecting the feasibility of mining projects around the world. According to Hubert Fleming, former global director for Hatch Water, “Of all the mining projects in the world that have either been stopped or slowed down over the past year, it has been, in almost 100% of the cases, a result of water, either directly or indirectly” (Blin et al., 2013). Dry mineral processing methods offer a solution to this looming problem."

Jan 1, 2016

By D. Ofstie, B. Kargutkar

BIM, or Building Information Modeling, is transforming the way metallurgical facilities are built, operated and maintained. BIM provides a digital representation of the facility, complete with all physical and functional characteristics - enabling collaborative planning, concurrent design, construction simulation, sustainable operations and predictive maintenance through a connected information model. Building on experience gained in other industries, Hatch is aggressively applying the BIM process to the mining & minerals processing industry to address inefficiencies inherent in traditional document-based information management. Intelligent 3D models support real-time quantity forecasting and cost trending by commodity type and construction work package. By linking procurement and schedule data, material availability and constructability reviews are visualized to verify construction critical path, ensure work front safety and minimize craft downtime. The BIM digital information model connects engineering, construction, commissioning and vendor data, aiding timely asset-centric handover to plant operating and maintenance systems.

Jan 1, 2015

By W. E. Oching, M. M. Ghomshei

Attracting and retaining workers in mining industry has become an uphill battle to many mining companies. As workers with significant experience retire, it is getting more difficult to attract not only new workers but also top talent to the mining industry to replace professionals exiting the workforce. To make matters worse, students’ enrolment in the post-secondary mining programs in Canada and USA is continuously declining year after year for reasons not directly linked to job market. This raises a question of how can the future needs of mining be met? This paper focuses on avenues for collaboration of industry and educational institutions to meet the current and future needs of mining. It provides effective approaches that mining institutes can engage with program advisory committees, role of the mining industry in supporting both faculty and students, how to harness the benefits of diverse workforce in the country and use of innovative technologies to attract young workers in mining. This work presents Human Resources (HR) professionals with tools that they can use to hire and retain skilled workers with strong interest to work in the mining industry. It also provides HR professionals with an opportunity to re-evaluate their restructuring practices during economic downturns as they reduce number of employees on temporary or permanent basis. The paper stresses the need of working together of the mining stakeholders including mining industry, academic institutions, First Nations’ communities and provincial(state) and federal governments to meet the current and future demands of mining as the industry experiences shortage of labour and low students’ enrolment in post-secondary mining programs. It is shown that mining educational institutes can enhance their programs and recruitments through establishing a better communication with all stakeholders. This communication can be facilitated by creating a national advisory board, to work with all mining programs at the national level for sustainable mining.

Jan 1, 2023

By J. L. Wilson

"Many modern concentrators with VSD driven SAG mills still rely on the control room operator to manually adjust the speed in reaction to increasing bearing pressure. All too often, the problem with this strategy is by the time the operator reacts with a sudden speed increase, the SAG Mill is likely already on its way to loading up. To assist the new operators, the SAG Mill at B2Gold’s Fekola Mine in Mali needed a robust control that could handle load changes and unmeasured disturbances with minimal operator intervention. With modern Distributed Control Systems (DCS) powerful enough to run advanced control, they often have Model Predictive Control (MPC) blocks built in or available as an “add-on” license, and thus MPC can be readily implemented within the modern concentrator with a relatively low added capital cost. This paper discusses an implementation of two single output MPC controllers to control the SAG Mill at Fekola. This was implemented using the existing signals and advanced control blocks available to the installed DCS.INTRODUCTION Many modern concentrators with VSD driven SAG mills still rely on the control room operator to manually adjust the speed in reaction to increasing bearing pressure. All too often, the problem with this strategy is that by the time the operator reacts with a sudden speed increase, the SAG Mill is likely already on its way to loading up. The next step the operator may take may be to cut back the feed rate, or production until the SAG is once again stable. With this sudden reaction comes an abrupt change in SAG rotational speed and power consumption that sends a surge of material down the circuit as the mill suddenly ejects more pulp. Furthermore, choosing a higher rotational speed can lead to higher than normal liner wear as the cataract overshoots the toe of the charge and impacts the liners. After start-up at B2Gold’s Fekola Gold Mine in 2017, the SAG mill was being controlled manually. The SAG rotational speed was adjusted manually by the operator in step changes depending on whether the SAG bearing pressure was increasing, decreasing or stable. During this time of manual control, the SAG fresh feed rate was also adjusted to a tonnage setpoint with a PID controller. Generally, the SAG fresh feed rate setpoint was kept at a target value, but then the feed rate was throttled back if the SAG mill or grinding circuit showed signs of overloading. The extra challenges were that the operators had limited experience and were concurrently learning how the plant operated. Also, they were also occupied with managing situations in the rest of the plant. Often their attention was drawn away from the SAG mill and during that time, the SAG Mill would load up before they could react."

Jan 1, 2019

By D. Sagara, V. G. Makhado

"A model based control strategy was implemented at Loulo Gold Mine in Mali, to stabilise the thickener underflow stream density. This stream acts as the feed to the leaching circuit. pH control of the leaching circuit was integrated with the model-based controller due to slow process dynamics that are not suited to PID control. The controller performance was quantified over a period of 6 months, and was compared to the performance before implementation. The model based controller reduced process variability for both thickener underflow density and pH considerably, and resulted in a reduction in flocculant and lime consumption of 9.32 and 6.55%, respectively. INTRODUCTION Reagent consumption in gold processing plants significantly contributes to the total operational costs. In a typical Carbon-in-pulp (CIP) circuit, the reagent consumption associated with leaching, adsorption, elution and regeneration contribute to approximately 15% of the total operational costs (Stange, 1999). At Loulo Gold Mine, the reagent consumption associated with leaching, adsorption, elution and regeneration contributes to 6% of the total operational costs. As such, a reduction in reagent consumption will present a significant opportunity for savings on operating expenditure. Variability in feed ore characteristics results in continuous changes in steady state operating regions, which presents process control challenges as a result of the long residence times in some of the process units associated with gold processing plants. Overdosing often occurs in the presence of process variability to ensure safe operation and to maintain recovery targets. As a means of reducing reagent consumption and accounting for significant changes in the feed to gold plants, some of the plants have resorted to improving their process control strategies around their circuits. This paper focuses on the implementation of a model predictive based controller at Loulo Gold Mine on their thickener and Carbon-in-leach (CIL) tank to: •,stabilise the thickener underflow density, and •,the CIL tank pH."

Jan 1, 2017

By I. Murray, N. Geoffroy

"Buried pipelines, tanks and other similar equipment are almost always present on large scale industrial sites, including in the oil and gas fields. However, as the proverb “out of sight, out of mind” suggests, it is easy to overlook proper maintenance procedures and simply assume that corrosion protection measures in place are working correctly. Unfortunately, this is not always the case, leading to significant environmental damage and loss of production. This paper describes several cases from various industries where buried equipment failed because of corrosion, sometimes with catastrophic results. It also presents various strategies, based on experience and new research, to help predict and prevent damage to underground metallic structures.INTRODUCTION Metallic underground structures are extremely common in industrial and commercial settings for numerous reasons. Burying pipes, tanks, wires and other similar equipment has numerous advantages: it provides significant protection from mechanical damage, frees up ground space that can be used for other purposes, requires little to no support structure and is generally more esthetically pleasing. However, this last benefit can also be considered the most significant disadvantage of underground equipment: becoming invisible and forgotten. While every engineer is aware of the importance of preventive maintenance, it is also human nature to somewhat forget about equipment that is hard to inspect and assume that everything is fine. This is unfortunately not always the case and failures in industrial settings can have extremely serious consequences. While economic aspects immediately come to mind (loss of production, cleanup cost, etc.), failure of underground equipment also results in an environmental and therefore public relations nightmare, especially in the oil and gas field. Leaks that would have been considered negligible in the past can now make national headlines and perfect reliability, while probably impossible to achieve, is now the goal of most companies. While environmental damage (real or perceived) is most often associated with leaks in the oil and gas industry, it can also affect the mining world. For example, the authors have worked on a project where a buried slurry pipeline had ruptured in the ground, causing a release of perfectly inert tailings. While the economic loss was low, the leak was reported in local media and caused a public relations problem."

Jan 1, 2017

By M. Gagné, F. E. Goodwin

The mining industry represents a significant investment in infrastructure of which steel plays a key role. Many structures in a mine are made of steel including shaft structures (buntons, station steelwork and headgear); stope structures (roof supports, pipe hangers); haulageway structures (ore transfer stations, electrical stubbies); and surface structures (plant buildings, tank supports, pipe gantries, conveyor belts, stacks, stockpile structures, stairways and railings). Maintenance of structural components can often be difficult because of the environment, including those where corrosive fumes persist, or limited access, such as in shafts where access is limited, or to short maintenance shifts or where limited working space is available. Thus a cost-efficient, long-lasting and maintenance-free protection system for steel should be specified. Galvanizing provides the required high-quality, long-term corrosion protection to steel. Galvanizing provides protection in two ways, first as a physical barrier to corrosion and secondly by means of cathodic or sacrificial protection that is unique to zinc. The dual nature of corrosion protection provided by galvanizing significantly extends the service life of steel even in the most challenging environments. The unique corrosion protection properties provided by galvanized steel will be highlighted with global mining application case studies.

Jan 1, 2015

By A. Manouchehrian, M. Cai

"Rockburst, which often occurs around underground openings in highly stressed hard rocks, is a sudden and violent unstable rock failure and is associated with energy release. Rockburst is very dangerous to workers and mining equipment, and it has been a major concern for deep underground construction and mining. Before excavation, rocks are loaded under a true-triaxial condition. Upon excavation, the rocks at the excavation boundaries are loaded in the maximum principal stress direction and unloaded in the minimum principal stress direction and this provides a necessary condition for unstable rock failure to occur. Understanding rock behavior under true-triaxial unloading condition is critical for developing measures to control unstable rock failure in underground construction.In this article, an explicit FEM tool is used to simulate rock behavior under true-triaxial unloading condition, with a focus on analyzing stable and unstable failure and the released energy during failure. Firstly, a uniaxial compression test was simulated. The results indicated that the adopted numerical tool was able to simulate stable and unstable failure by varying the Loading System Stiffness (LSS). In this research, Loading System Reaction Intensity (LSRI) was proposed as an indicator to identify stable and unstable failure. Secondly, unstable rock failure under true-triaxial unloading condition was simulated. A rock specimen was loaded in three directions; the lateral pressures (s3 and s2) were kept constant and the vertical stress (s1) was increased to a pre-defined stress. The specimen was suddenly unloaded in the minimum principal stress direction (s3) and loading in the s1 direction was continued until failure occurred. Different LSS values were considered and the results showed that the LSS influenced the failure mode; a soft loading system resulted in more violent failure and released more energy than that in a stiff loading system. The influence of specimen height to width ratio on rock failure was also investigated. It was found that failure in taller specimens was more violent than that in shorter specimens. Insights gained from the simulation are useful for better understanding of the influencing factors on the released kinetic energy during unstable rock failure and to find means to control rockburst damage in engineering practice."

Jan 1, 2015

By B. Westin, G. Voicu, C. Daoust

Orogenic gold deposits represent a major class of deposits that are found in various rock types of various ages. Those deposits show a strong structural control that usually complicates their interpretation at the regional and deposit scales. The Rosebel Gold district located in Surinam (South America) is hosted in a Paleoproterozoic greenstone belt of the Guiana Shield, and has been recently classified as one of those orogenic gold deposits. The gold district comprises eight distinct deposits located along three different structural trends and within different rock types. The mineralization is undefonned and shows a strong structural control characteristic of orogenic gold deposits. All the deposits of the Rosebel Gold district have been subject to a detailed structural analysis that has led to the elaboration of a new structural model for the whole gold district, which is now differing considerably from the previous models. This characterization had direct implications at three different scales. 1- While the older models were considering some areas of the property as gold-barren, the new structural model has led to recent exploration campaigns which have revealed positive results. 2- At the deposit scale, the comprehension of the various vein systems and of the folding of the host rocks has helped the establishment of optimized drilling campaigns. 3- At the mining scale, the comprehension of the architecture of the veins helps for the elaboration of optimized mining method. This study thus shows that the structural analysis of orogenic gold deposits is critical, and should be a priority for exploration and production in any mine.

Jan 1, 2011

By Binbin Luo, Northeastern University, Chuanyao Sun, Jie Liu, Yimin Zhu, Yanjun Li

"A series of new type collectors a-bromo-saturated fatty acids, CH3(CH2)5CHBrCOOH (a-BHA), CH3(CH2)7CHBrCOOH (a-BDA), CH3(CH2)9CHBrCOOH (a-BLA), CH3(CH2)11CHBrCOOH (a-BMA) were synthesized from saturated fatty acids and bromine by solvent-free method (Hell-Volhard-Zelinski reaction) in laboratory. The micro-flotation tests of quartz mineral were conducted at a relatively low temperature of 15 °C. The adsorption mechanism of such collectors on quartz mineral surface were established by zeta potential measurements, in conjunction with the results of quartz micro-flotation tests. The flotation results showed that the collecting ability is in the order of a-BMA > a-BLA > a-BDA > a-BHA for the flotation of quartz mineral, which also demonstrating that the a-bromo-saturated fatty acids (a-BFAs) are new selective collectors for reverse flotation to remove quartz mineral from iron ores at a relatively low temperature.INTRODUCTIONThe requirement of higher pulp temperature to maintain the activity of fatty acid anionic collectors which have been widely applied in technological process of iron ores reverse flotation lead to a great deal of energy consumption.The purpose of this paper is to synthesize a new modified collector with carbon chains from eight to fourteen atoms, with strong electronegativity bromine atom introduced into a-carbon position to improve the activity and solubility of the reagent so that it can be adopted at a comparatively low pulp temperature. The collecting performances of these new collectors on quartz surface were studied, and the structure - properties were discussed in light of zeta potential measurements and quantum chemistry calculations."

Jan 1, 2016