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By A. McGrath, M. Trovant, M. Haque

Minimizing energy consumption is a priority for many industrial facilities. Metallurgical and gasification processes produce dirty syngas (CO and H2), which offers the potential for energy recovery. However, syngas handling can pose an explosion risk and even minor leaks can result in poor workplace hygiene. Furthermore, many jurisdictions around the world now discourage wet syngas handling due to limited water availability and secondary pollution. Hatch has developed a 100% positive pressure gas handling system that targets these safety hazards without using fresh water. The implementation of a system for calcium carbide smelters at Qinghai Salt Lake Industry Co. (QSLIC) in China is profiled as a case study.

Jan 1, 2015

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Shigeto Kuroiwa, Eri Takida, Tsuyoshi Hirajima, Masashi Yamane, Yuji Imaizumi, Mitsuru Sawada, Keiko Sasaki

Selective flotation of molybdenite and chalcopyrite using various oxidation treatments (i.e., ozone treatment, hydrogen peroxide, and Fenton-like reagent) was studied in this work. It was found that ozone treatment produced a depressing effect on both minerals, resulting in a lower separation of both minerals. On the other hand, oxidation treatment using hydrogen peroxide (H2O2) and Fenton-like reagent could deliver selective oxidation on chalcopyrite surface and depress its floatability. However, bench-scale copper- molybdenum (Cu-Mo) flotation tests show that oxidation treatment using H2O2 required a higher dosage of H2O2 and a longer treatment time in order to deliver comparable flotation results to that of conventional Cu- Mo flotation using NaHS treatment. On the contrary, Fenton-like reagent could deliver selective Cu-Mo flotation results comparable to that of NaHS treatment at a lower dosage of H2O2 and a shorter conditioning time. Contact angle measurements and X-ray photoelectron spectroscopy (XPS) analysis were employed to understand the depressing mechanism of these oxidation treatments. It was found that the chalcopyrite surface covered by various oxidation products that render the surface hydrophilic. Meanwhile, the surface of molybdenite was slightly oxidized, making the surface remained hydrophobic. INTRODUCTION Molybdenite (MoS2), the main source of molybdenum, is associated with copper sulfide minerals, mainly chalcopyrite (CuFeS2), as a trace mineral. Molybdenite is a valuable mineral and plays an important role in making the copper-molybdenum (Cu-Mo) processing plant economically viable (Laskowski, Castro, & Ramos, 2013). Therefore, it is important to recover molybdenite efficiently and effectively and separate it from copper minerals. Conventional separation of copper and molybdenum minerals is usually carried out in selective Cu- Mo flotation process using a copper depressant (i.e., sodium hydrosulfide (NaHS), Noke’s reagent, or cyanides) (Ansari & Pawlik, 2007; Bulatovic, 2007). However, this process still suffers due to imperfect molybdenum recovery. Moreover, the copper depressants use in this process are toxic and harmful to the environment. As alternative, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, and plasma pre-treatment (United States Patent Office Patent No. US 2559104 A, 1951; Patent No. US2238250 A, 1941; Barzyk, Malysa, & Pomianowski, 1981; Hirajima et al., 2014). However, the oxidation phenomenon and mechanisms are still not clear since detailed surface analyses have not done and the plasma pre-treatment method is facing technical issues for industrial scale application.

Jan 1, 2019

By E. F. Evoy

"The Gunnar uranium deposit was within metasedimentary rocks of the late Archaen Tazin Group. These rocks were intensely altered by albitization so that the immediate host to the ore consisted dominantly of albite, and by the subsequent introduction of calcite. The ore consisted of disseminated pitchblende and uranophane in a pipe-shaped breccia zone. Oxidation of the ore was more intense near surface than at depth, but there was no near-surface enrichment.IntroductionThe Gunnar Mine site is on the tip of Crackingstone Peninsula, on the north shore of Lake Athabasca, Province of Saskatchewan, Canada. The peninsula forms the southern part of the Beaverlodge mining area. The ore consisted of disseminated pitchblende and uranophane in brecciated metasedimentary rocks of the Tazin Group, and the deposit was characterized by extreme albitization and subsequent carbonatization of the host environment.Production from the mine began in 1954 and the ore was depleted by 1963. In that interval the deposit yielded about 5 million tonnes of ore containing about I. 75 kg/tonne U3O8. It was mined initially from an open-pit and subsequently from underground; the open-pit contributed about 55% of total tonnage. Uranium was recovered by atmospheric leaching in sulphuric acid, ion exchange concentration, and precipitation with magnesia.This paper is based on studies made during the productive life of the mine and is concerned primarily with pre-ore alteration of the rocks containing the deposit, and with the ore mineralogy."

Jan 1, 1986

By R. N. W. DiLabio

"In a continuing program of mapping glacial dispersal trains, near-surface till samples were collected down-ice from a copper-silver-gold prospect at Onaman River, Ontario, and down-ice from the past-producing gold district at Oldham, Nova Scotia. The program is designed to aid exploration by illustrating glacial dispersal from various types of known occurrences and by identifying postglacial processes that control drift composition at a detailed scale.Native gold was mined at Oldham from arsenopyrite-bearing saddle reef quartz veins in a dome in Early Paleozoic slates of the Meguma Group. Gold abundances greater than 10 ppb in till form a dispersal train at least 1900 m long. Gold abundances between 40 and 100 ppb occur in clusters up to 600 m down-ice from gold-bearing bedrock. Anomalous arsenic abundances in till form a broad train 1100 m long that is significantly different in shape from the gold train.At Onaman River, subeconomic amounts of Cu-Ag-Au occur in quartz lenses in Archean mafic volcanic rocks. A dispersal train defined by the distribution of mineralized boulders and increased abundances of Cu, Ag and Zn in till extends 600 m down-ice from mineralized bedrock. Gold abundances between 10 and 70 ppb do not define this dispersal train, but occur instead in clusters 300 to 600 m down-ice from mineralized bedrock. In vertical sections in the upper 2 m of copper-rich till, Au abundances vary sympathetically with Ag and Cu levels; however, there seems to be no preferential site of Au enrichment in the mineral portion of the soil profile.Several of the mineralized boulders at Onaman River are richer in Au and Ag than the mineralized bedrock from which they were derived. Although some of the high Au and Ag assays were caused by biased sampling of sulphide-rich portions of the boulders, many were caused by leaching of sulphide minerals from 'the boulders, which left a limonitic boxwork that is enriched in Au and Ag. A few of the Au-rich boulders may have been derived from an unknown bedrock source."

Jan 1, 1982

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By Dharmendr Kumar, Pradip, Beena Rai, Venugopal Tammishetti

"Due to rapid depletion of high grade Indian iron ores, there is a need to utilize low grade fines and slimes. However, these fines and slimes, in their current form, cannot be utilized in steel making due to their high alumina (6-10%) contents. Several beneficiation strategies such as gravity separation, magnetic separation, flotation and selective flocculation are currently being explored for the upgradation of low grade fines and slimes. In our previous work density functional theory simulations were employed to come up with selective flocculants for beneficiation of iron ore slimes. Our simulation results suggested that starch and guar gum are more selective towards iron minerals than other minerals present in the sample. Grinding of iron ore fines becomes necessary in some cases to achieve adequate liberation for removing alumina impurities in Indian iron ores. We have thus investigated effect of grinding of iron ore fines on its selective flocculation-separation.In the present work, we have taken natural iron ore fines from one of the Indian iron ore mines and ground it to -400 mesh (<37 microns) in dry and wet conditions. X-ray diffraction study confirmed the presence of minerals hematite, goethite, gibbsite and kaolinite in the sample. The fine ground samples were used in selective dispersion-flocculation study with corn starch and guar gum flocculants. It is interesting to note that even though the dry and wet ground samples possess almost similar particle size distributions, significant differences were observed in yield and grades of the concentrates thus produced. These differences may be arising due to the coating of alumina containing minerals on iron minerals. We have also studied the effect of addition of dispersant while grinding. Our study suggests that grinding conditions determine the efficiency of the separation process."

Jan 1, 2016

By Y. Mudryk, D. Paudyal, K. A. Gschneidner, V. K. Pecharsky, M. Khan

"Rare earth intermetallic compounds are utilized commercially as magnetic and battery materials, electron gun electrodes, etc. Several of these intermetallics will be briefly discussed. There are many other rare earth intermetallic compounds which are not utilized industrially but have unusual properties which are of fundamental interest and may have future technological applications. Several of these materials are discussed as well.INTRODUCTIONTens of thousands of rare earth intermetallic compounds exist, but physical properties (primarily their magnetic behaviors), other than their crystal structures have been measured for only a small percentage of these materials. Among these are the commercially important compounds: Nd2Fe14B, and the SmCo5 – Sm2Co17 family – well known high strength permanent magnets; (Tb0.3Dy0.7)Fe2, Terfenol-D, a giant magnetostrictive material; LaNi5Hx a critical component of the rechargeable Ni metal hydride batteries; and LaB6 an electron emitter. There are, however, many other intermetallic compounds which are not utilized industrially, but none-the-less, exhibit interesting, and sometimes, exotic physical properties which are of fundamental interest and may have some future technological significance. These include: the giant magnetocaloric effect compounds Gd5Si2Ge2 and La(Fe13-xSix)Hy; the RCu and RAg families of ductile intermetallics; the mixed intra-lanthanide (R,R')Al2 compounds in which magnetic transitions disappear and reappear as one R is substituted for by R'; and GdNi which exhibits large dilations along two crystallographic directions and a larger contraction in the third direction at the Curie temperature resulting in zero volume change as GdNi orders magnetically via a second order phase transition.COMMERCIALLY IMPORTANT INTERMETALLICSNdFeB Permanent MagnetsThe Nd2Fe14B permanent magnets were discovered in 1984 independently in the USA and Japan. It is a ferromagnet and with proper heat treatment and processing Nd2Fe14B is the strongest near room temperature permanent magnetic material known today. This intermetallic compound is utilized as a permanent magnet in many applications, such as electric motors (e.g. the modern automobile contains up to 35 electric motors), spindles for computer hard disc drives, microphones and speaker magnets for cell phones and other audio equipment, direct drive wind turbines, actuators, and Magnetic Resonance Imaging (MRI) units. There are two kinds of NdFeB permanent magnets – bonded and sintered. The bonded magnets have a lower magnetic strength than the sintered magnet. The highest strength magnets are obtained by small substitutions of Dy (up to a maximum of 10%) for Nd, because Dy can significantly increase the coercivity and thus the energy product (a measure of the magnetic strength or hardness). The bonded magnets account for about 12% of the NdFeB market (~82 metric kt per year, containing ~20 kt/a of Nd). The NdFeB permanent magnet market is growing at a rate of about 15% per year. (Burzo & Kirchmayr, 1989; Kobayashi & Hirosawa, 2001; Coey, 2011)."

Jan 1, 2012

By K. C. Corin, Z. G. Song, J. Y. Liu, M. W. Zhang, State Key Laboratory of Mineral Processing-BGRIMM, J. G. Wiese

"In the present study effect of grinding media on flotation of two mineral systems have been investigated, viz. sulphide minerals (including a pure chalcopyrite and pyrite mineral, and two different base metal sulphide ores), and oxide minerals (quartz, hematite and cassiterite). It was shown that mild steel media milling produced lower recoveries in the case of chalcopyrite and pyrite, as compared to the case of milling using ceramic media. For oxide minerals, the effects of using mild steel media as opposed to ceramic media were not as significant as was for the sulphides, although, after mild steel milling, at acidic pHs their recoveries were significantly reduced. For two base metal sulphide ores, viz. Nkomati and Dexing ores, the differences resulting from different milling media , although marginal, were opposite for each of these ores.For oxide minerals XPS showed that oxides and hydroxides of iron (e.g. FeOOH) adsorbed on the surfaces of the minerals. In the case of the Nkomati ore, adding Fe2+ or F3+ ions after milling with chrome steel media resulted in reduced talc (gangue) recovery, but increased water recovery and reduced concentrate grades. Further investigations are currently in progress to examine the Fe ions effect on the talc surfaces and froth properties.INTRODUCTIONGrinding of ores is necessary to liberate the valuable minerals from its gangues to allow for their selective recovery during mineral processing such as flotation. The grinding process inevitably involves contact of the ores with the surface of the grinding device and the grinding media. Accompanied by grinding, several phenomena can occur including the grinding medium wear, formation of precipitated species on the ore surfaces, chemical reaction, galvanic effects, changes in the Eh of solution, etc. There is a considerable body of literature on the differences observed in the flotation of various ores after milling using various grinding media. Laboratory studies have used balls or rods made from mild steel, ceramic, stainless steel or chrome steel to investigate the effects of different grinding media on mineral flotation. It is found that the interactions between the ore and the grinding environment can affect flotation separation of sulphide (Wei and Sandenbergh, 2007; Bruckard, 2011), oxide (He et al., 2014) and carbonate minerals (Song, 2009 and 2010). For example, mild steel milling produces relatively high concentrations of Fe ions in the pulp, affecting the recoveries of minerals compared to the case of ceramic media. On the other hand, the stainless steel media or chrome media are reported to be beneficial to the recovery of sulphides, when compared to the cases of using mild or carbon steel media (Rey and Formanek, 1960; Peng et al., 2003a,b; Huang and Grano, 2006; Bruckard, 2011). It is not clear, however, whether these Fe ions may affect the surface properties of the minerals involved or the general pulp/froth behaviour and hence their floatability. In addition, in the study of an low-S PGE ore carried out by Miettunen et al. (2012), forged media grinding in the CO2 atmosphere led to the highest Pt and Pd grades and recoveries, but the high chrome grinding media gave lower flotation recoveries than those using the forged media."

Jan 1, 2016

By Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

A thermodynamic description of the equilibrium in liquid and gas phases under specific conditions of refractory gold pressure oxidation was generated using the HKF theory. The gold behavior was considered at 190-225°C in the presence of 1-100 mg/L of chloride ion, and under oxidationreduction potential (ORP) of +700 to +1030 mV. The calculations show that the predominant form of gold(I) occurrence is [AuOH]° compared to [AuCl2]?. High ORP favors the formation of [AuCl4]? as a predominant form of gold(III). It is noted that this complex is responsible for the gold losses buildup during POX. Laboratory test results for double refractory concentrate POX are shown. The combined negative effect of (i) organic carbon of the concentrate and (ii) dissolved chlorides in POX slurry on gold recovery is demonstrated. The effects of carbonate blending to the POX feed concentrate and incomplete oxidation of sulfides on POX performance were studied. The pilot tests results of continuous pressure oxidation are also shown and generally confirm the laboratory results and theoretic dependencies. A comparison of the experimental data with the results of thermodynamic calculations is made. As a result of current research, an effective process for POX treatment of carbonaceous sulfide concentrates in the presence of chlorides was developed.

Jan 1, 2014

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By J-F. Béland, N. Parson

Aluminum extrusions are widely used for automotive crash management systems due to their superior specific energy absorption capabilities, as compared to steel. The Al-Mg-Si alloy series can be readily extruded into complex multi-hollow profiles, as required in crash systems, and can be used to target a range of desired strength levels. This paper focuses on the development of an axial crush test protocol and evaluation of the crush performance of common 6XXX series alloys for a variety of tempers. The observed crush behaviour is then compared to tensile test results.

Jan 1, 2015

By L. Lorio, B. Hilscher, P. Nayak, N. Yoon

"Mining has been a staple to technological advancement ever since the dawn of time. By harnessing the different physical and chemical properties that each mining commodity brings to the table, more and more innovation is developed and manufactured. As these non-renewable resources continue to be extracted, the industry as a whole faces a challenge in finding the next economical deposit as well as declining grade at the current operations. By means of pre-concentration, ore sorting aims to separate the barren material from the valuable ore to reduce energy consumption and tailings generation, while increasing the feed grade, concentrate grade, mill recovery, and revenue. In addition, ore sorting allows the modification of deposit geometallurgy in order to allow the creation of an optimal mill feed. This paper evaluates the applicability and challenges of ore sorting by utilizing the results from four different mines, and reviews them in detail. The mines include one underground and three open pit mines that are precious metal operations. In order to understand the applicability of ore sorting in these operations, initial rock-by-rock test results and different types of assays (atomic adsorption [AA], inductively coupled plasma [ICP], and fire assay) are utilized. Using the assay results, the grade recovery curves for ore sorting are generated and they are further improved by using and developing an ore sorting algorithm, which is discussed in this paper. The application and evaluation of ore sorting in greenfield and brownfield properties will also be discussed. The state of the art ore sorting technologies for both rock-by-rock and bulk sorting are also reviewed in this paper. The future technologies on the horizon, including different combinations of sensors, are explained. The sorting technologies include X-ray transmission (XRT), X-ray fluorescence (XRF), colour, infrared, electromagnetic, and laser induced breakdown spectroscopy (LIBS)."

Jan 1, 2017

By Bob Drew, Goran Vukovic, Bojan Zivanovic, Klaus Gamweger

Reaction bath temperature is a major factor in processing liquid metals and in many applications where a balance between process duration and temperature has to be found to run a procedure efficiently. Also extremes of temperature can decrease the output of a process if too cold or even make it impossible, conversely overheating can be detrimental to both the product and furnace integrity. With the help of the new online temperature measurement system very accurate monitoring of the process is possible in contrast to the current routine practice where the temperature is measured periodically with dip thermocouples. The system works with a digital, fiber optic pyrometer, which is embedded in a refractory housing. Installation in the lining is possible below liquid level as nitrogen is blown to keep the system open and to ensure continuous sight from the optical head of the pyrometer to the molten metal through the tuyere. This permanent temperature measurement gives optimal process control with the potential of taking appropriate actions at an early stage enabling proactive process control. Therefore energy savings and even process endpoint detections can be realized.

Jan 1, 2015

By K. Svens, M. Lahtinen, L. Lehtinen

"Outotec&apos;s direct leaching process is an atmospheric leaching process for sulphidiczinc concentrates. The direct leaching process, based on special leaching reactors developed by Outokumpu and leaching know-how, is the most economical way to produce electrolytic zinc. The newest industrial-scale application of Outotec&apos;s direct leaching process will be started up in 2008 in China at Zhuzhou smelter. The process isintegrated to the existing production plant, replacing part of the old production facilities by modern technology and increasing the production capacity significantly. The process equipment supplied by Outotec includes also tailor-made reactors designed on the basisof the work and experience of Outotec Research Centre."

Jan 1, 2008

By Jean-Marc Simard, Richard Genest

"La mine Agnico-Eagle, localisée près de Joutel, a été découverte en 1962 par le forage d'anomalies électromagnétiques. Exploitée à partir de 1974, elle a déjà produit près de 30 tonnes d’or à partir de 2 puits, le puits Eagle et le puits Telbel, distants de 1,3 km.Le gisement est situé entre le sommet du complexe volcanique de Joutel, à dominante felsique, et la base de l'ensemble sédimentaire de la rivière Harricana. Ces deux unités ont une extension régionale; elles sont orientées NW-SE avec une polarité NE et des pendages subverticaux. Une faille majeure, la faille Harricana, passe de façon subconcordante au contact de ces deux ensembles.La minéralisation aurifère, de 2 à 5 m d’épaisseur moyenne, est liée a une zone carbonatée, comprise entre des tufs felsiques, argilites et sédiments chimiques (éponte inferieure) et des argilites carbonatées (éponte supérieure). Le minerai est constitué habituellement de 20% de fine pyrite disséminée. L’or est en fines particules associées directement à ces grains de pyrite de texture cataclastique.Deux modelés ont été for mules jusqu' a présent pour expliquer la genèse du gisement: une thèse syngenetique (Barnett et a/.1982) et une thèse épigénétique (Wyman et al. 1986). Cette dernière apparalt comme la plus probable du fait de la présence de la minéralisation dans les zones cisaillées a carbonates secondaires et pyrite cataclastique."

Jan 1, 1990

By T. Gerritsen, R. MacRosty, R. Pula, P. Gebski, W. L. Ying

Furnace run-outs can cause extended furnace downtime for repair, while leaks or more severe failures in the cooling system can lead to brick hydration or in severe cases, steam explosions. These incidents can result in lost production, damage to equipment, injuries and casualties. To prevent such incidents, reliable and accurate techniques to monitor the critical components of the furnace such as refractory lining, furnace structure, taphole integrity and main water circuits are required. This paper describes several advanced methods that have been developed to assess the condition of furnace integrity, refractory lining, tapholes and cooling water circuits.

Jan 1, 2015

By L. Trytten, S. Bass, P. Nawrocki, J. Mercer

The Sherritt Fort Site nickel refinery and fertilizer plant has been operating continuously since 1954. The ammonia leach process uses ammonia and sulphuric acid, producing nickel and cobalt and an ammonium sulphate byproduct. One of the features of an ammonium sulphate based process is the aggressive nature of ammonium sulphate to concrete and structural steel. After six decades of operation, portions of the structural steel and concrete at the Sherritt facility have become degraded. Infrastructure replacement programs started in earnest more than a decade ago with pipe racks and electrical infrastructure, and have now progressed into building steel. Replacing and repairing this infrastructure within the tight constraints of an operating plant poses several difficult challenges. This paper will outline the approach taken to accomplish this difficult work, and discuss key learnings from the ongoing program.

Jan 1, 2015

By A. Khan, C. Ciriello

The purpose of this paper is to demonstrate the value of constraint modelling in optimization of mineral processing systems. This will be achieved by first understanding the overall concept of variation and constraints present in any system. Next, the value of using a Constraint Model in optimization is demonstrated through comparison of business cases. The benefit of understanding the severity of constraints and movement of the bottleneck within a mineral processing system will be understood through the use of a case study. Paper will conclude with a summary of all optimization benefits that utilization of a constraint model can bring.

Jan 1, 2015

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

A pre-flotation process of the Kupferschiefer ore with only frothers produces a concentrate enriched in carbonaceous matter and tailings for further upgrading steps. A partial removal of easy-to-float components of the feed before the main enrichments steps by flotation (rougher, scavenger) improves overall efficiency of separation of valuable elements from the ore. Since the types and doses of frother used for pre-flotation effect the process, the aim of this study was to determine the influence of selected frothers on the efficiency and selectivity of the Kupferschiefer ore processed by KGHM Polska Miedz S.A. A series of pre-flotation tests in the presence of different poly(propylene glycols) ethers, poly(ethylene glycols) ethers and aliphatic alcohols were conducted. The obtained results indicated that the types and doses of frother determine the flotation selectivity of copper and total organic carbon. The evaluation of the pre-flotation process was based on the analysis of selectivity parameters calculated from the recoveryrecovery Fuerstenau upgrading curves as well as the values of copper and organic carbon grades in the flotation products. It was shown that pre-flotation performed in the laboratory scale using a suitable frother provides higher overall flotation selectivity of organic carbon with lower overall flotation recovery of copper in comparison to flotation without the pre-flotation step. Thus, the pre-flotation process improves the quality and quantity of the final concentrates produced from the Kupferschiefer ore.

Jan 1, 2016