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By J. Illescas, N. C. Murray

This paper provides an economic comparison and technical evaluation of different approaches for copper recovery from small-scale resources such as historic tails, dumps, pond and pit water as well as acid mine/rock drainage. Factors such as the location, the availability and cost of reagents, power availability and cost and a local market for end product alter the preferred processing technique. A number of scenarios are presented and technologies considered include; solvent extraction, ion exchange, sulphide precipitation, cementation, copper sulphate crystallization, membrane (RO) and copper cathode production.

Jan 1, 2014

By B. I. Whittington

This paper examines the effect of cation type (i.e. NH4+, Na+ and K+) and anion type (i.e. SO42- and C1-) on the extraction of nickel during the pressure acid leaching of a Western Australian laterite ore. The results are compared with testwork conducted with other Western Australian nickel laterite ores and the possible process implications of adding an additive to a plant autoclave are considered. Addition of either (NH4)2SO4, Na2SO4 or K2SO4 increased both the nickel extraction and the acid consumption, provided that the level of additive was not too great. For example, the nickel extraction of 93% increased to above 96% in the presence of additives, but decreased to 94% when, for example, NH4 levels increased from 7 kg/t ore to 21 kg/t ore. The relative stability of the jarosite species formed when additives were present influenced the amount of jarosite in the residue and, hence, both the final free acidity and overall nickel extraction. The use of Cl- versus SO42- salts as additives had little effect on overall nickel extraction or overall free acid values, although the presence of SO42- additives appeared to enhance nickel extraction kinetics over the first 60 minutes of the reaction. In contrast, manganese extraction was enhanced by the presence of Cl- additives.

Jan 1, 2004

By D. Farrish, W. A. Grell

"IntroductionMost base metal mines sell their concentrate to a custom smelter. The two parties concerned therefore draw up a contract which would detail the conditions under which concentrate sales will take place. The contract will identify treatment and marketing charges (including escalations), deductions for metal losses in the smelter, pricing formula, timing of payments, penalties for deleterious elements, etc.An understanding of the smelter contract is important to the mineral processor, for it will determine how he operates the plant to maximize economic return.Description of Contract ClausesUsing copper concentrate as an example, the smelter contract generally contains the following three basic charges:I. Metal Deductions- as the smelting process does not recover all the metal contained;2. A Smelting Charge- expressed per ton of material to cover costs on the bulk material such as receiving, unloading, thawing in winter, sampling, roasting to drive off sulphur, smelting through the matte and blister stages to recover mostof the copper and precious metals;3. A Refining Charge- expressed per pound of copper.The following is a review in some detail of a number of clauses which could be considered typical of a treatment and marketing type of copper concentrate sales contract. Most normal considerations in an agreement could be covered by the following types of clauses.Terminology- covers definitions, units of measurement to be used (e.g. short tons, troy ounces, etc.), currency (Canadian dollars). The term ""unit"" may be defined - l OJo of a ton of concentrate, e.g. one unit of copper means 20 pounds of copper per short ton of concentrate."

Jan 1, 1989

By X. Wu, W. R. Chen, J-G. Legoux, B. R. Marple, E. Irissou

Cold gas dynamic spray (CGDS) has been considered a potential technique to produce the metallic bond coat for TBC applications, because of its fast deposition rate and low deposition temperature. This paper presents the influence of spray processes for bond coat, including air plasma spray, high velocity oxy-fuel, and in particular CGDS, on the oxidation performance of TBCs with a Co-32Ni-21Cr- 8Al-0.5Y (wt.%) bond coat. Oxidation behaviour of the TBCs was evaluated by examining the coating microstructural evolution, TGO growth behaviour, and crack propagation during thermal exposure at 1050°C. The relationship between the TGO growth and crack propagation will be discussed.

Jan 1, 2010

By J. E. Gill

"THE YEAR 1959 appeared to be a good one in which to attempt a summary of progress in the location and study of sulphide deposits in Canada because a temporary surplus of metals caused prices to fall and many geologists who had been working like beavers were suddenly not so hard pressed. So it was •decided to arrange a Symposium. The response to the call for contributions was excellent and the result is the interesting collection of papers that follow.Activity in the search for massive sulphide deposits has never been as intense as in Canada since 1954. That was the year when the airborne electro-magnetometer first became generally available on a contract basis. These instruments work best on massive sulphide bodies, as do most of the ground electrical survey devices, so much of the new information relates to these. It was decided, therefore, to focus attention in the preparation of symposium papers on such masses. This served also to keep the survey within reasonable limits."

Jan 1, 1960

By J. M. B. Scarborough

This paper deals with measures taken to maintain effective operation of heavy-duty equipment in open-pit mining. at Pine Point, N.W.T., during periods of extreme cold weather. The points covered include equipment modifications designed to improve cold-weather performance, effective lubrication of machinery that is vulnerable to extreme cold and operating procedures designed to prevent equipment damage.

Jan 1, 1966

By J. Kan

In order to determine the recovery functions in an oil sand circuit it is necessary to have more than a minimal determination the mass flows in the network. This over-determination is essential in order to allow for measurements within the flow matrix "to flex" according to an error function. It is then possible to identify the flows and composition at all points with maximum likelihood. These so-called full mappings are not easily obtained. However, in order to obtain an unequivocal determination of all the unit operations recoveries such a balance is needed. When databases are constructed exclusively with coherently balanced sets of data it is possible to obtain a maximally accurate process model by maximizing the probability of correctly identifying the process causality. Indeed, it is doubtful in cases of normal complexity that any sense can be made of data that is not so balanced. Coherent mass energy balancing is a tool developed by mineral processing scientists and engineers. Its rigorous application to oil sands is the subject of this paper. The additional element associated with hydrocarbon requires special considerations. It is shown that at least one currently available mineral processing tool will solve the full-mapping problem for an oil sand operation. Experimental design constraints are discussed in this paper relating to the development of databases for the development of effective process models.

May 1, 2004

By Maxim Martel, Karolan Tremblay

Westwood Mine has experienced several episodes of increased seismic activity. While current geotechnical characterizations such as RMR, GSI, and Q' index can identify the general rock quality and zones at risk of convergence, they fail in identifying zones at risk of seismic activity. Previous research at Westwood Mine has shown a correlation between seismicity and areas with strong rheology contrasts. To characterize this contrast, 300 UCS tests were analyzed with their associated geochemical data, and statistical analysis and regression were performed using IOGAS software to establish a relationship between resistance and geochemistry. UCS-generated data with XRF results were transferred to Leapfrog Geo to create a block model of intact rock strength. This block model dataset was used to perform a competency contrast block model, and back-analysis of specific seismic sectors at Westwood Mine were conducted to validate the model. The purpose is to develop an established geomechanical tool capable in identifying areas with greater seismic risk associated to a change in the rock strength characteristics. By identifying those areas, mitigation measures can be implemented to minimize impact of seismicity on the operation.

Jan 1, 2023

By A. Tabereaux

The reduction of perfluorocarbon (PFC) emissions from aluminum electrolytic cells is a key issue in reducing greenhouse gases at all aluminum smelters, The emission of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) gases during anode effects at smelters can be calculated using two different methods; anode effect-minutes slope and anode effect overvoltage, This work demonstrates that the optimum method depends to a large extent on the type of anode effect kill algorithm utilized at each smelter, CF4 emissions vary widely from aluminum cells depending on the type of anode effect kill method utilized; fast, aggressive anode bridge movements vs. slower, moderate anode bridge movements.

Jan 1, 2005

By X. T. Feng, Y. H. Hatzor, Y. Tal, G. Yagoda-Biran

"When studying jointed rock mass deformation around underground openings it is of great importance to model correctly the excavation sequence during the numerical simulation. This is because for effective arching mechanism to develop in the roof minute block displacements must take place and some of the available discontinuities shear strength must be mobilized. If from the beginning of the simulation the underground opening already exists in the numerical model, block displacements into the excavation space will initiate and develop from time zero, before the initial stresses in the model have attained their actual initial level in the field. These initial block displacements are therefore artificial and exist only in the numerical model, not in the physical reality, and may lead to erroneous assessment of the stability of the designed structure, typically on the conservative side. We have introduced sequence excavation capabilities both in the numerical manifold (NMM) and the discontinuous deformation analysis (DDA) methods and show here the advantages of this modification using three different case studies, each illuminating a different aspect of this enhancement.We begin with the 25 meter deep 2000 year old underground Zedekiah limestone quarry below the old city of Jerusalem, Israel, which is still standing today unsupported with a free span of 40 m. We show that when the opening exists from the beginning of the numerical simulation the required friction angle for roof stability is 25 degrees, whereas when the opening is removed after all stresses and displacements in the model have been stabilized the required friction angle for stability is only 15 degrees.We then model the excavation sequence of a tunnel model representing a 2500 meter deep research tunnel in the Jinping hydroelectric project, China, in order to determine the in situ stress field at this depth by a grid search inversion of displacement data obtained using the sliding micrometer technology in the course of tunnel excavation. Thus we are able to constrain the in situ stress field at these depths where standard in situ stress measurement procedures are extremely difficult to execute properly.Finally, we use sequence excavation modeling capability to find the total height of the expected loosening zone around tunnels excavated through columnar jointed basalts which pose a great engineering challenge because of the characteristic dense network of slender prismatic blocks that transect the opening at a steep inclination. We use MPBX data obtained during excavation of a deep tunnel through such a rock mass to validate our numerical results and show that application of standard empirical guidelines for dimensioning rock bolt reinforcement in such rock masses may in fact result in very un-conservative design because existing empirical approaches typically ignore the anisotropic nature of the structure of such rock masses which, as we show, plays a very significant role in determination of the extent, shape, and geometry of the loosening zone around the opening."

Jan 1, 2015

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By G. R. Parslow

U, Fe, Mn, Ni, Cu, Zn and Co data for the sediment in both Key and Seahorse lakes, which overlie portions of known economic uranium deposits in the region, are presented. With the exception of U, Fe and Mn, the elemental distributions can be considered anomalous, in a statistical sense, in both lakes. The U values are of particular interest in that Key Lake is not anomalous, whereas Seahorse Lake is markedly anomalous. Tentative correlations made with background data from other surveys in an attempt to differentiate between anomalous and background values indicate that deviations from linearity in a distribution, and not absolute mean or maximum values, are indicative of anomalous samples within the distribution.

Jan 1, 1979

By D. B. Apel

As depths to the ore bodies keep increasing around the globe, the problem how to deal with the increasing temperature of undisturbed rock mass becomes very important. In extreme cases the rock temperature at the bottom of the mine could raise up to 80 °C. In deep mines, geothermal heat is considered as the primary heat load contributor, which accounts for 50?90% of the total heat load depending on different geological conditions. Thus the geothermal heat control in underground mines is the most important and demanding issue to ensure a suitable working environment. In this study, expanded perlite aggregate (EPA) was incorporated as a lightweight substitute for sand. Five mixtures were prepared using 0, 25, 50, 75 and 100% replacement ratios of sand by EPA. These, mixtures were tested in the laboratory for both the insulating and strength properties of the developed shotcrete. The goal of this research was not only to develop shotcrete which would exhibit good insulating properties but also which would exhibit strength properties similar to the regular shotcrete. This paper not only reports the results of the laboratory tests but also discusses the output of numerical model which was performed to evaluate the benefits of using the insulating shotcrete in reducing the cooling costs at hot underground mines.

Aug 1, 2013

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By P. C. Parsons, G. C. Milligan

"IN FIELD WORK in the Cape Breton Highlands, which are heavily covered with vegetation, it is necessary to run traverses along the valleys of small brooks. We encountered difficulty in closing such traverses, and the following technique was developed to solve this problem. It has been tested in the field for four seasons by several people, and found to be simple, efficient and more accurate than any other compass-and-pace system of which we are aware. So far as we can find, the technique has not been described previously. It may be of use to others.The Cape Breton Highlands of Nova Scotia consist of hills of old intrusive and metamorphosed sedimentary rocks protruding up to 1,000 feet above the general level of the younger sediments which underlie the valleys. The flat hill-tops are the remnants of a plateau; drainage off the edge of this plateau has produced many small steep brooks. They occupy valleys which are up to 800 feet deep, and V-shaped in cross section, with steep sides covered by mixed conifers and hardwoods. The stream at the bottom is rarely more than a few feet wide, with a negligible meander belt, but with many bends, rapids and falls. Visibility along the stream, in consequence, is rarely more than a few hundred feet, and in many places much less.It was found impractical to map the streams by the method of meander lines, as described in many standard surveying texts and hand-books. The limited visibility, and the numerous bends of the brooks, necessitated many corners. Every corner introduces errors. To 'close' a survey with 40 or 50 such corners proved either very time-consuming or impossible. In most cases, however, the general direction of a valley may be obtained from an aerial photograph, or by direct observation, and this became the basis of the method adopted."

Jan 1, 1971

By Hector Monette

"AFTER SPENDING a lifetime in the mining industry it is normal that one should be concerned with the future of his profession, especially if he is directly responsible for the education and formation of future mining engineers. It is not necessary to insist on the importance of mining for Canada and for the entire world to prove the necessity of the Mining Engineer. A statement was made by Zay Jeffries, former vicepresident of General Electric Co., and here I quote: ""Even though minerals without man are of no moment, man would not be man as we know him without minerals ... ""minerals are as essential to the life of social man as food is to man himself"". This certainly expresses magnificently the purpose of the mining profession. These are the reasons why I have accepted to present my views on the future of the Mining Engineer. If I express some concern it is not because I feel that there is any danger for the profession to disappear; men will always respond to a challenge and this can be found in the extraction of minerals as well as in any other field of human endeavour. However, the first big question concerns the competitive position of Canada in the world of mining. To be made available to Canadians and to the rest of the world, all this tremendous potential mineral wealth that our country has been so generously endowed with by nature must be gained from the earth's crust at a competitive cost. Otherwise it will never become ore and will have no value. Let us not forget that although minerals are discovered, mines are not found but are made. So let us be more efficient mine makers. To accomplish this end, it is the duty of the different responsible organizations at all levels - be they governmental, para-governmental, public or private institutions - to do their utmost to assure the profitable development of our mineral wealth. The University has an all-important role to play in preparing all the specialists required by this intricate machine that mining is. All the different disciplines of engineering, health, social and -managerial sciences are needed for the good functioning of the mining industry. Although they are all essential, some will play a more important role as a member of the structure. In this discussion it is the role of the most important member, the mining engineer, who is actually responsible for the extraction of the minerals from the earth's crust that must be established. From this we will then be able to analyse his responsibilities and try to suggest the mining engineering program most suitable to prepare this engineer for his future role."

Jan 1, 1972

By Donald F. MacDonald

THE cement plant nearest to Nova Scotia is not far from Montreal. Cement is a heavy product which, because of its relatively low value, cannot stand a high freight charge without unduly enhancing its cost. This is one reason why cement costs are high in Nova Scotia. The regular retail price per bag (8772 lb.) in Antigonish is 85 cents, which would be $3.40 per Canadian barrel of 350 pounds, or $3.65 per American barrel of 376 pounds.It is said that the lowest wholesale price in Halifax is 65 cents per sack, which would be $2.60 per Canadian barrel or about $2.80 per American barrel. According to U.S. Bureau of Mines statistics, the average factory price for cement in 1937 was $1.48 per American barrel, which is practically the same as the value per barrel indicated in Dominion statistics for the Canadian output during that year. The difference between $3.40 and $1.48 is $1.92. It is evident that the average user of cement in the Mari-times pays a stiff premium because Maritime cement raw materials have not been developed. Rock-wool, the manufacture of which is rapidly increasing in Ontario and the United States, is much needed for building insulation in the cold climate of Nova Scotia.

Jan 1, 1939

By C. H. Hopper, D. R. Derry, H. S. McGowan

"The property of Matachewan Consolidated Mines is in the Matachewan area on the west side of Montreal river. It lies in the western extension of the Kirkland Lake sedimentary belt. The first discovery of gold on the property was made by S. Otisse, in 1916. The property was taken over by Ventures, Limited, in 1933 and production commenced in late 1934. To date (December 31st, 1947) it has amounted to 2,308,800 tons, from which gold and silver to the value of $9,567,600 has been recovered. The mill is currently treating 650 tons of ore a day.GENERAL GEOLOGYThe deposits lie close to the south contact of a belt of sediments striking in a general east-west direction. The sediments, presumed to be of Timiskaming age, consist of light buff arkose and greywacke, containing small pebbles. The Keewatin volcanic rocks to the south are andesites or basalts with cuff and agglomerate bands developed especially near the contact with the sediments. The lavas and sediments are overlain by relatively flat-lying sediments of the Cobalt series to the south and west of the mine, but these later sediments are not involved in the mineralization under discussion. The Keewatin lavas and Timiskaming sediments are intruded by dykes and lenses of red syenite porphyry that have approximately the same strike and dip as the invaded rocks. Later diabase dykes, apparently post-ore, run in a north-south direction and cut all rocks except the Cobalt series.OREBODIESThe gold-bearing mineralization forms bodies of two different types: (1) Within the volcanic rocks irregular orebodies with limited vertical extent. These consist of a series of flat-dipping quartz stringers and adjacent lavas and /or cuffs fractured, bleached, and mineralized with pyrite and gold. They are higher grade than the second type (average about 0.16 oz. gold a ton) and formed the main source of ore for the first 5 years of production. They are described in more detail than can be given here in an article by C. H. Hopper (4). More recent work on deeper levels has failed so far to find orebodies of comparable grade, though low-grade mineralization of a similar type does occur on the projected rake of the main group of the 'basalt type' of orebodies."

Jan 1, 1954

By H. Chaouki

The aim of this work is to simulate the forming process of a green anode. For this purpose, a nonlinear compressible viscoelastic constitutive law is presented. The concept of natural reference configuration is considered. Within an isothermal thermodynamic framework, a Helmholtz free energy is proposed to take into account the nonlinear compressible deformation process occurring between natural reference configuration and current configuration. A dissipation potential is introduced in order to characterize the irreversible aspect of compaction process. Thus, the constitutive law is formulated through two equations: 1) an expression of Cauchy stress tensor and 2) a differential equation characterizing the evolution of the natural reference configuration. Material parameters are assumed to be a function of the bulk density. This allows capturing the micro-mechanical phenomena within the chosen macroscopic approach. An experimental study based on compaction tests is carried out in order to characterize the mechanical behaviour of the anode paste. A user's material VUMAT subroutine for finite element dynamic explicit analysis has been developed and implemented in the ABAQUS commercial software. To evaluate the model predictive capability, numerical simulations of the compaction forming process of anode paste were performed. Simulation results show that the constitutive law predicts the experimental trends and gives interesting physical responses. This constitutes a first step toward making a benchmark with experimental results on the forming process of anode paste.

Jan 1, 2011

By A. J. Makoka, B. C. Qi

Reliable monitoring of corrosion is vitally important in the combat against corrosion and over the last two decades the interpretation of electrochemical noise has received considerable attention as a means to discriminate between different types of corrosion. To this end, many different analytical methods have been proposed, such as power spectral density analysis and analysis via various other stochastic criteria. However, although many corrosion systems are nonlinear and therefore not readily interpretable by the abovementioned analytical approaches, few studies in the analysis of electrochemical noise to date have exploited advances made in the analysis of nonlinear systems. In this paper, the use of phase space methods to analyze and detect change in corrosion systems via electrochemical noise is considered. In particular, the electrochemical noise data are used to reconstruct trajectories in the so-called phase space of the system and changes in the topology of these trajectories or attractors as represented by correlation dimension curves are consequently interpreted as an indication of change in the dynamics of the system.

Jan 1, 2005