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By J. Ouellet

The design of hydrostatic liner for a deep potash mine shaft in Saskatchewan poses tremendous technological challenges. Technology has evolved to a point where one could consider a new innovative approach to hydrostatic liner design. But there is still a place for conventional technologies such as cast iron tubbings. As will be discussed in this paper, improvement to manufacturing process, installation procedures and even new materials can bring this technology to an excellent level of performance. With the spur of new projects in the potash industry of Saskatchewan, the authors worked in various shaft liner designs from the conceptual stage through to the construction phase. They were either directly leading the design work on some of these projects or acting as an external reviewer on others. Most of these shaft liner designs involved cast iron tubbing technology and ground freezing. The major challenge in sinking potash shafts in Saskatchewan is to go through a water-bearing ground formation under high pressure, known as the Blairmore or Manville fm. The only proven stabilizing technology for these formations is ground freezing. For a potash shaft, dry shaft conditions are highly desired, so a fully waterproof hydrostatic liner is required. All the existing potash mine shafts in Saskatchewan, except for two with composite steelconcrete lining, used the cast iron tubbing technology. Two new shaft tubbing liners have been constructed recently, one in the Athabasca Basin and one for a potash mine in Saskatchewan. When the authors began working on these new projects, what became quickly evident is that the technological knowhow for designing and constructing tubbing liners was no longer available within Canada and that the past construction methods used to sink tubbing lined shafts was obsolete. The tubbing liner for the shafts sunk in the sixties were designed either by German or British companies. In both of these countries only few tubbing lined shafts were sunk in last 40 years and the technology used in the sixties was not improved. There are only few countries where tubbing is routinely produced and installed: China, Russia, Ukraine and Poland. Out of these countries Poland is the one where this technology is the most advanced. The authors, working in close collaboration with engineers from Poland, attempted to rebuild this knowledge for the mining industry in Canada. This process involved thorough analysis of old technical reports, literature review and study of current polish design and construction practices as well as site visits of existing shafts. Through actual construction experience, some lessons were learned as well as ideas for improvements. In this paper, the authors will present a succinct review of design and procurement process. But, the practical aspects of the construction and installation methodology will be treated with more emphasis, more specifically the practice leading to good liner performance. Some of the poorly understood technical aspects of tubbing installation will be discussed more thoroughly and some currently accepted myths dispelled.

Aug 1, 2013

By Douglas A. Karvonen

"Competition in the world potash market has increased significantly since the late 1970s. The failure of consumption to grow at expected levels has led to industry over-capacity, a situation which is likely to persist at least until 1990. Individual Saskatchewan producers and their offshore marketing company, Canpotex, have responded to this challenge by increasing mining efficiency, developing more cost-effective and reliable transportation systems and establishing innovative financing and market development programs tailored to customers' special needs. Investment in warehouse facilities to serve U.S. customers and exploration of opportunities for intermodal distribution through the Great Lakes and the Mississippi River system have maintained individual producers' position in the highly competitive domestic market.Export sales through Canpotex have been bolstered by utilization of CIDA funds, Exp ort Development Corporation financing guarantees and other innovative payment plans which enable heavily indebted developing countries to maintain the import levels which are necessary for their agricultural development.IntroductionPotash is the general term applied to various potassium salts both natural occurring and commercially derived. The most common of the commercial product s are potassium chloride, potassium sulphate and potassium magnesium sulphate. The potassium content of potash is measured in units of K20 equivalent. The common grades of potassium chloride produced for agriculture average at least 60 0/0 K20 compared with approximately 50% Kp for potassium sulphate and 22% for potassium magnesium sulphate."

Jan 1, 1985

By R. Frank Chiappetta, E. B. Wilson

"The maintenance records for AL-60 airlegs at Falconbridge Ltd. are used to demonstrate some of the procedures for the analysis of such data.The data are not representative of pure failure s of one type or another. In fact, the records are for the undefined pseudo-failures which are usually found in industrial operations. However, because the machines are brought to the shop only when inoperative, the individual recorded components are treated as failures. Manual calculations are conducted to show the analysis of variance (ANO VA) approach to determine whether certain data can be combined; only a limited number of the 206 machines being considered. The manual procedures continue with the weighting of the suspensions; i.e. terminations f or reasons other than the failure of the given component. After the data are sequenced in the proper order, the nature or pattern of the data is determined using the Kolmogorov-Smirnov (KS) test.It is recognized that these manual examples must be replaced by compute r methods 10 process voluminous data of this nature. Such programs are developed and available. However, a program called RELCODE is used in this case to correspond to the manual examples and to take into account the suspensions. These analytical procedures form the basis for those studies required for good maintenance management."

Jan 1, 1985

By E. Swartzman

"DURING 1951, experimental cleaning studies on both fines and larger sizes of certain Canadian coals were conducted on a relatively large scale in two pilot plants in the United States, large enough to be considered as small commercial units, and in one commercial plant in Canada.One of the pilot plants was a wet washer of a type which apparently has never been .used in Canada, nor has any Canadian coal been tested in it before. In the other pilot plant and in the commercial plant, dry cleaning equipment was used. The commercial plant is the first of its kind to be employed in Canada, and this type is used only to a limited extent in the United States.Fine-Coal Cleaning ExperimentsTest PlantsHydrotator and Hydrotator-Classifier combination pilot-plant with a capacity of about twenty tons per hour. This is a classifier type washer adapted for cleaning fine coal as well as certain intermediate sizes. The Hydrotator deals with that portion of a coal retained on approximately a 24-mesh Tyler sieve, whereas the Hydrotator-Classifier deals with the minus 24-mesh fines."

Jan 1, 1952

By G. A. Gross

"The Soviet Union has enormous reserves of iron ore in many different kinds of deposits that are widely distributed in this vast land area. The present iron ore industry is based mainly on deposits in Precambrian cherty iron-formation at Krivoy Rog, Kursk and Murmansk. Extensive reserves of both naturally enriched hematite ore and magnetite iron-formation in these areas alone could sup-ply all the domestic ore required for several hundred years.Many contact metasomatic magnetite deposits discovery in recent years in the eastern Ural Mountain belt and east of the Kusnetsov basin in Siberia are being developed, with ore reserves measured in billions of tons. Oolitic limonite-chamosite-siderite ores of Cretaceous and younger age at Kerch on the Black Sea and around the east and southern perimeter of the West Siberian basin constitute some of the largest concentrations of iron in the world. These sedimentary ores are low grade, of poor quality and difficult to beneficiate. Banded jasper magnetite and hematite iron-formation in volcanic rocks of Devonian age in Kazakhstan and along the Mongolian border are of special geoloica1 significance.Iron deposits in the Krivoy Rog and Kursk areas were examined and a large number of geologists discussed their work on deposits in many other parts of the Soviet Union during the writer's seven-week study tour of mines and research institutes in Moscow, Leningrad, Novosibirsk in Siberia and Kiev in the Ukraine. The descriptive geology of iron deposits of useable ore and of marginal material has been well documented in the course of systematic work and a large number of scientists are studying fundamental problems on the origin and treatment of iron ore."

Jan 1, 1967

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988

By D. KEYS, D. E. Gemmell

The portion of the earth's surface covered by peatlands has been conservatively estimated at over 420 million ha (Kivinen and Pakarinen 1980). It is estimated that there are about 170 million ha of peatland in Canada. New Brunswick contains about 140,000 ha. Harvesting of peat for horticultural purposes has been carried out in New Brunsiwck since 1942. This industry, and the potential for using peat for energy purposes, indicated the need for an accurate assessment of the resource. In 1975, therefore, the New Brunswick Department of Natural Resources began a detailed peatland inventory. Assistance from the Canada Department of Regional Economic Expansion permitted acceleration of this program and field work was completed in 1982. Information gathered by the program will form the basis for a management plan for future use of the resource.

Jan 1, 1984

By C. S. Crocker

The Centennial orebody was discovered and named in 1970, Manitoba's centennial year. It is relatively small, about 2 million tons. Strike length varies from 400 to 600 feet and widths from 10 to 60 feet; dip is 75 degrees. Low grade and metal prices demanded low-cost mining, and the mine was developed for conventional sublevel stoping. As the ore lay entirely under a large lake, ground movement had to be avoided and the stopes were to be filled hydraulically. Late in 1973, vertical crater retreat mining was introduced at Inco Limited, Sudbury, to recover pillars between filled stopes. It proved satisfactory and the results were publicized by CIL, who developed the technique. The method seemed to offer some advantages and one stope at Centennial Mine was selected to be mined by VCR while production was maintained from blasthole stopes. The trial stope was safe and showed lower development costs, reduced drilling time, a favourable powder factor and good fragmentation. VCR mining is now an accepted method at HBM&S Co., Ltd., and its use is being extended.

Jan 1, 1979

By W. B. Dingle

"IntroductionMANY PAPERS presented on developments in the Canadian Petroleum Industry •during the past few years have commenced with this general sentence: ""The past year has been a record •one for the oil industry in Canada, with new records being set in nearly all phases •of exploration and development ,activity"". This sentence applies equally well to 1951. It is not possible to outline all the details of the broken records in exploration, development, and production but general comparisons can be made. There are several significant developments that have stolen the spotlight during 1951, some of which were foreseen in 1950 and some which were not. Among the high-lights were the following:(1) The greatly •expanded activity in the search for gas, which was touched off by the new Alberta regulations covering gas leases and reservations.(2) The discovery of commercial oil production in the Williston basin of North Dakota and Manitoba, which will have far reaching effects on Canadian oil.(3) The greatly increased activity in northern Alberta, northwestern British Columbia, the southern Northwest Territories, Saskatchewan, and Manitoba.(4) The new discoveries in the general central Alberta area.(5) The granting •of a permit for an oil pipeline to the Pacific coast.(6) The arrival of Western Canadian crude in central Ontario.(7) The number of new refineries completed, commenced, or proposed.(8) The present •and proposed expansion in the petrochemical industry.Most of the remarks made on various exploration and development •activities will refer to Western Canada operations, primarily because the greatest •activity and the most significant developments have been there. Eastern Canada exploration and development operations were at a slightly higher level than in 1950."

Jan 1, 1952

By Scott A. Trebilcock

Nautilus Minerals Inc the world?s leader in exploration and development of deep ocean mineral resources is today focused on the recovery of high grade copper-gold from in seafloor massive sulphide mineralization. These mineralized belts, analogous to land based volcanogenic massive sulphides (VMS) deposits are located near tectonic plate boundaries of the Western Pacific and around the world. Nautilus; first development project is Solwara 1 located in benign waters in Papua New Guinea. Since 2006 the company has completed detailed environmental and geological studies at Solwara 1, culminating in a number of world firsts, including the first Environmental Permit for a deep ocean mineral project and the first NI 43-101 compliant seafloor massive sulphide resource statement. Nautilus has relied heavily on proven deepwater technologies from the oil and gas industry in the design of the first mineral extraction system. Pipeline trenching units, workclass ROVs, deepwater production risers and drill cutting removal systems will all be adapted at Solwara 1. Key contractors to the project have all been selected for their deepwater experience, creativity and determination to launch this new industry. Innovation is at the forefront of Nautilus? success to date. This paper gives an overview of the Solwara 1 development and describes the exploration and production technologies adapted for seafloor mineral extraction.

May 1, 2010

By A. A. Ruitenberg, C. J. Morrissy

"The Lake George antimony deposit comprises a system of stibnite-bearing quartz veins that cut Silurian greywacke and slate. The stibnite-bearing ore zone is in part enveloped by a uraniferous zone.The ore-bearing quartz vein system occupies an easterly striking, gently north-dipping fracture system that cuts across north-northeasterly trending gently southwest-plunging, tight Acadian (early Middle Devonian) folds. This vein system continues at depth into a siliceous skarn zone intruded by altered granite porphyry dykes, which constitute probably a late phase of the Hawkshaw granitoid intrusion to the north.Most of the ore occurs in a northeast-plunging, trough shaped vein structure that formed where the vein system (gently north-dipping) intersects the axial surf ace zone (steeply northwest-dipping) of an Acadian synform. The trough shaped structure resulted from deflection of the fracture zone (containing the vein system) by competent beds.Emplacement of the quartz-stibnite veins was preceded by, and is in part penecontemporaneous with, the formation ofa micaceous-argillaceous alteration halo, which in turn intersects a patchy biotite alteration zone.The hypabyssal intrusions associated with the Lake George deposit probably represent a late phase (early Carboniferousr) of the nearby Hawkshaw intrusive granitoid complex. IntroductionThe Lake George Antimony Mine is situated 40 km southwest of Fredericton and 2.5 kin north of Lake George, New Brunswick (Fig. 1). The mine is owned by Consolidated Durham Mines and Resources Ltd.Shaw (1940) described the early history and development of the mine. In subsequent years, available drill cores were relogged by several geologists. Much new information became available when an extensive diamond drilling program (Kidd , 1970) was started by Consolidated Durham Mines and Resources Ltd. in 1970. A study of the geology and economic potential of the deposit was made by Glover (1973). Abbott and Watson (1975) made a study of the ore mineralogy. Available drill cores were relogged and a preliminary study of the fracture system in the mine was made by G.A. Pierce and A.A. Ruitenberg during 1976. Outcrops in the area sur rounding the mine are extremely sparse.Between 1976 and 1979 the present authors made a detailed study of the mine workings, available drill core and regional structure in the vicinity of the mine, with results set forth in this paper. The regional geologic setting of the deposit, the geometry and structural controls of the ore zones, and the mineral zonation and rock alteration are emphasized."

Jan 1, 1980

By M. S. Fotheringham

Recognition of the Growing Importance of Iron and Steel Few Canadians have yet become aware that Canada's vast iron ore resources, the greater part of which is only now beginning to be developed, will inevitably have a profound effect on the entire Canadian economy, benefitting in some measure the lives of all Canadians. The great iron mining developments of Ontario, Newfoundland, Quebec, and Labrador are destined to make Canada one of the world's major producers and exporters of this material, on which our industrial civilization is?based. These developments will create new employment, new communities, new transportation facilities, and new investment opportunities. Iron ore is the foundation and the keystone of modern mechanized civilization. The most prosperous nations of the world are the highest per capita consumers of iron and steel, and in these countries the per capita consumption is increasing steadily despite the advent of light metals, plastics, and other competitive materials. Three-quarters of the human race have too little steel -and consequently too little mechanization -to provide for themselves the necessities and comforts of civilized living. Progressively they will demand, and acquire, the machines, the transportation and communication facilities now lacking, and they will win them by making greater use of the world's iron resources. It is the good fortune of this generation that Canada's 'iron age' is just getting well under way.

Jan 1, 1951

By K. Esmaieli

ABSTRACT We conducted a series of numerical experiments to investigate the influence of rock mass foliation on impact-induced damage on ore pass walls. The 2D Particle Flow Code was used to simulate three distinct rock masses surrounding an ore pass, characterized by foliation angles of 60°, 90°, and 120° (clockwise from horizontal). Subsequently, we projected a rock fragment against the ore pass walls at a constant impact angle and velocity. The resulting damage increase

Jan 1, 2014

By R. Augsten, K. K. Feng, K. C. Cheng

"Methane emission and the desorption characteristics of vertical borehole coal samples of Greenhills multiple seams in the vicinity of Elkford, British Columbia were investigated. Three vertical boreholes at depths of 335 m, 380 m and 395 m were drilled along the west wall of an active open pit mine and 44 core samples from various coal seams were obtained for desorption studies.The results are presented in three tables and illustrated with six figures. The methane content was found to increase significantly at depths greater than 200 m. The adsorption equation by Kim and the properties of the coal have been used to predict the methane content and these were compared with the measured values by the direct method.IntroductionThe coalification of plant material in the sedimentary rock produces different ranks of co al and gases of various composition. The gas mixtures are retained in coal beds and rock strata under pressure. The gas content in a coal bed varies considerably depending on the rank of coal and the depth of overburden. The gas content is defined as the volume of gases adsorbed in a unit weight of coal materials. The net amount of gases remaining in a coal seam depends on the difference in the rate of generation of methane by geo-thermal heat and the rate of diffusion of the gases out of the coal bed through sedimentary cover. The major factor that causes the change in rank and the liberation of gases is the temperature, which is governed by the thermal conductivity of sedimentary cover and the heat flux through the underlying rocks. The rate of diffusion of the gases out of the coal is governed by the porosity of the overlying rocks and the degree of fracture. The measured values of gas content in major North American coal beds are from zero up to 24 cm3 per gram of coal(1,2). A gas content of 2.5 to 9 cm3/g is considered ""gassy"" and that of 9 cm3/g or higher is considered ""very gassy"" for underground mining(3). Normally, the gas mixtures released from bituminous coal in Canada contain 90 to 98% methane and the remainder is made up of CO2, N2, 02, H2, He and other hydrocarbons(4)."

Jan 1, 1984

By M. Nagamori, A. J. Plumpton

"A low-grade concentrate from the Crevier Township, Quebec, containing 1.8% Ta205 and 13.7% Nb205 was reduced with carbon at 1600°C, and niobium and tantalum were selectively absorbed in liquid iron. To slag off the zirconia-rich gangue, some silica and lime were added as flux. Metallic iron was added in such a way that the combined contents of TaC and NbC did not exceed 20% in the ferroalloy . Up to 95% of the niobium, and up to 80% of the tantalum contained in the concentrate were recovered in the metal. The ferroalloy was ground finely and dissolved in 2 wt % sulphuric acid to leach out iron and silicon preferentially. The insoluble residue consisted principally of NbC and TaC, the calcination of which yielded an enriched concentrate comprising 80% Nb2O5 and 8% Ta2O5. The insoluble residue could also be chlorinated to obtain an impure liquid of Nb2Cl5 and TaCl5. Process variables and their effects are discussed in terms of higher metal recoveries in the smelting.IntroductionPresently, about one-third of the world production of tantalum comes from the pyrometallurgical reprocessing of tin slag, a by-product of tin smelting, containing sometimes 2 to 10% Ta205 and about the same amount of Nb205. Upon heating tin slags with carbon at about 1600°C in an electric furnace, tantalum and niobium oxides are converted to TaC and NbC, which are absorbed by the coexisting phase of molten metallic iron(1,2). The Fe-Nb-Ta-C melts cannot be decarburized by oxidation because of the preferential formation of Nb and Ta oxides over CO gas(3). So, the ferroalloys containing tantalum and niobium carbides are commercially treated by acid-leaching and I or chlorination to eliminate iron and thus permitting the eventual recovery of purified tantalum and niobium oxides(2).Absorbing Ta and Nb carbides in molten iron was first proposed and demonstrated by Zimmerley and Back(4) in 1957 in order to recover selectively tantalum and niobium from lowgrade concentrates. The process was successfully applied to the electric furnace smelting of tin slags by Hunter and Fursmant(5) over a period preceding 1965."

Jan 1, 1985

By John A. Meech, Irene E. Cristoveanu

"The separation of hematite fines (100% - 38 um) from quartz fines (100% -75 um) was investigated using coarse hematite (-212 + 150 um) as a carrier in an oleic acid collector system. Oleic acid additions, per cent coarse additions, combined conditioning time and ferric chloride additions were examined.It was found that carrier flotation is a dominant mechanism for fine hematite recovery at oleic acid levels greater than 200 g/t and coarse additions of 10 per cent. Hetero-aggregation is favoured under conditions of lower levels of oleic acid in the presence of ferric chloride and at conditioning times greater than ten minutes.Ferric chloride acts as a depressant for pre-reagentized coarse hematite at oleic acid levels below 150 g/t. At concentration levels above 500 g/t, ferric chloride interferes significantly with the success of carrier flotation of fine hematite.The sensitivity of carrier flotation to changes in oleic acid addition, ratios of fine and coarse material, conditioning time and the presence of an inorganic electrolyte emphasizes that its application is only suitable when flotation conditions can be stabilized.IntroductionThe production of fine material is unavoidable during the comminution of iron ore . Due to the difficulty of recovering iron from this fine material by various gravity separation methods, flotation can often be a more attractive process producing high-grade material at high recovery. One variation of the flotation process, that can be useful for recovering ultra fine minerals (<10 um) , is known as carrier flotation. This process involves the utilizat ion of coarse particles ( > 150 p.m) which act as flocculation centres to which the fine hematite particles (10 - 40 u.m) become attached and are carried or "" piggy-backed"" into the froth phase."

Jan 1, 1985

By M-d-N. Gagnon, P. Okono, Y. Bergeron

In the mining industry, decisions regarding the type and number of comminution tests to be completed typically rely on geologists? observations and conclusions when studying drill cores. Given that these decisions are based on visual observations, they are essentially approximate and often inaccurate from a comminution viewpoint, causing a sizeable margin of error in estimating characterization test needs. Consequently, companies are often forced to perform more tests than necessary, requiring a significant quantity of material, and accruing significant costs. Recently, a new device, called the Hardness Index Tester (or HIT), was developed, offering users a low cost in-house mechanism for estimating the comminution parameter A*b and the Bond Ball Mill Work Index at any mine site, with potential applications on fragments up to 25 mm from drill core. In late 2016, Agnico Eagle Mines Limited initiated a trial to investigate if having an HIT device installed in a core repository would make it possible to identify the different rock properties more accurately and determine the number and type of comminution tests required. The application of the HIT was not to replace the standard comminution tests, but rather to generate a high number of comminution and geomechanical parameters for the rock mass. Ultimately, the objective would be to determine the uniformity of the rock mass and, therefore, easily distinguish any potentially problematic zones. With this method, the appropriate number of standard tests could be determined, making the HIT not only an excellent complement to the standard laboratory tests, but also an indispensable device for a geometallurgical characterization. This paper presents the results from the HIT trial using samples from the Odyssey Project, which is a Mine Canadian Malartic property.

Jan 1, 2017

By Fred Horne

1N THIS PAPER, the writer proposes to limit his comments to few generalized phases of the subject, based on his personal experience in the midwestern United &apos;States and in one section .of the Coal Branch in Western Alberta. The following statistics are submitted to show the importance that strip mining has assumed in the coal mining industry of the United States. In 1914, 1,281,000 tons of strip coal were produced, amounting to 0.3 per cent of the total production. In 1948, the total was 13~,505,000 tons, representing 23.3 per cent. In 1949, the percentage figure dropped slightly and this can be partially accounted for by the labour disturbances prevalent throughout the year. In 1914, there were 48 power shovels and draglines being used in the stripping of coal; in 1949 there were 3,712, not to mention other types of coal stripping equipment such as bulldozers, tractors and scrapers, rotary excavators, and stackers. At the bituminous coal mines in Western Canada, strip mining was introduced only a few years ago, two of the major reasons for its development being the need for increased production during the war and post-war years and the need to hold the line on increasing production costs, but even in these few years the percentage of strip production has in-creased to such an extent that some mines that, five or six years ago, were producing all their tonnage from underground operations are today obtaining up to 80 per cent of their total output from strip mines.

Jan 1, 1951

By C. D. Anderson, C. G. Anderson, P. R. Taylor

"Rare Earths have become critical for our energy and materials driven society. While primary production must ramp up to fill growing demands, the recycle of these strategic elements must also be initiated. This paper will outline the potentials of and metallurgical technologies employed for Rare Earths recycle from various secondary sources.INTRODUCTIONWhen investigating the recovery of rare earths from secondary sources it is necessary to understand the nature of the sources to be processed. As of 2009, the USGS reports the distribution of rare earths by end use, in decreasing order, was: chemical catalysts 22%, metallurgical applications and alloys 21%, petroleum refining catalysts 14%, automotive catalytic converters 13%, glass polishing and ceramics 9%, rare earth phosphors for computer monitors, lighting, televisions 8%, permanent magnets 7%, electronics 3%, and others 3% (USGS, 2011). Additionally, it is reported that the amount of recycling was quite small and consisted primarily of rare earth magnet scrap, although with the sharp increase in the price of rare earths, and the potential shortage in supply, focus in this area is continually growing. Thus, the opportunities, whether realistic or not, are extremely vast in the recycling of rare earth containing materials. The following subsections will present methods proposed for the recycling of rare earths based on the feed material type.RECYCLING OF RARE EARTH MAGNETSCurrently, investigations are ongoing in the area of recycling production scrap and end-of-life materials in the rare earth magnet industry. The following techniques illustrate potential methods for the recovery of rare earths from secondary RE magnet sources.Recycling of Rare Earth Magnet Sludge by Selective ChlorinationDuring the production of neodymium magnets, a by-product of production is the so called “magnetic sludge”. This by-product contains high amounts of neodymium, thus a process for the recovery of Nd has been proposed. In this process the Nd present is selectively chlorinated/distilled by the addition FeCl2 via the following reactions."

Jan 1, 2012

By Robert M. Hopkins, Craig C. Monahan

A corrosion survey was performed on ten selected H-piles which support a reinforced concrete wharf located at Trepassey, Newfoundland. Approximately 900 thickness measurements were taken at twelve different locations in each off our zones on the steel piles: the splash (atmospheric) zone, the intertidal zone, the low tide zone and the submerged zone. Results show that over the 2o-year life of the wharf, corrosion has been most severe in the splash, low tide and submerged zones with average corrosion rates for the flanges of 6.95, 9.45 and 6.86 mils per year (mpy}, respectively, and average corrosion rates for the webs of 5.13, 4.12 and 3.45 mpy, respectively. Minimal attack was found in the intertidal zone where the average corrosion rate was only 1.66 mpy on the flanges and 1.37 mpy on the webs. Such a pattern of attack is frequently observed f or steel piles partly submerged in seawater. The abnormally low corrosion rate associated with the intertidal zone is generally explained as being due to cathodic protection induced by the high corrosion rate in the adjacent low tide zone. Analysis of the corrosion data obtained for the Trepassey wharf would suggest that this explanation might be incorrect. An alternate hypothesis has been brought forward which better accounts for the extremely low corrosion rate observed in the intertidal zones of these piles.

Jan 1, 1990