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By A. Himsley, E. Byleveld

"With reference to the chemical constraints underlying the ion exchange process for uranium recovery, a generalized view is presented on the actual and the achievable efficiency of the process. The area considered is restricted to acid leach circuits in combination with nitrate, chloride or sulphuric acid elution.A comparison between actual plant results and the chemical requirements shows that:(a) Unless new and better ion exchange resins are developed, no dramatic change in equipment size and resin inventory is""anticipated. (b) Elution efficiency, especially for sulphuric acid, may be improved considerably. More concentrated eluates may beproduced at lower chemical consumption. A possibility of achieving additional purification solely by ion exchange is discussed.IntroductionThis paper presents a generalized view of the actual and the achievable efficiency of the ion exchange processes for urannium recovery. The study is restricted to acid leach circuits in combination with nitrate, chloride or sulphuric acid elution. The ultimate efficiency attainable with ion exchange is dietacted by the chemical reactions underlying the process. The most sophisticated technology cannot change the diffusion rates in the ion exchange resin nor make the uranium loading exceed its equilibrium valueThe design of an ion exchange plant for uranium recovery involves a considerable number of parameters as a result of the wide variety of pregnant solutions produced from different orebodies. Therefore, a generalized approach of the ion exchange process inevitably neglects some parameters which maylead to significant variations in apparently identical situations.The uranium concentration in the pregnant solution, together with its pH, are the principal variables which determine resin loading and residence rime in the ion exchange system. On the elution side, the type of eluant and its concentration will determine the contact time required and the amount of eluant needed to strip the resin. The temperature, the properties of the ion exchange resin, the total dissolved solids in the feed solution and the competing ions are other variables that affect the chemical performance; these, however, may be considered as a correction of the principal parameters if one is interested only in general trends."

Jan 1, 1980

By Mike Dry, Mani Manimaran, Mykolas Gladkovas, Mariam Melashvili, Chris Fleming

Development of a new hydrometallurgical flowsheet requires quantitative description and optimisation of all chemical processes in each step in the process, as well as mass and energy balances across a fully integrated circuit incorporating all the unit operations. This paper covers steps leading to early modelling of a gold processing plant based on a bromine/bromide lixiviant. Research conducted at SGS Lakefield in collaboration with Albemarle provided the data that were used in the development of this model. A previous investigation in this series described the leaching behaviour of various mineral types in Stabilized Bromine reagent. This paper is concerned with the gold recovery operations associated with a conceptual bromine leaching process. The recovery of gold by different types of resin and activated carbon was studied, along with various methods of stripping the gold from the extractant. The circuit is closed by electrolysing the spent leach liquor to oxidize some of the contained bromide back to bromine that would allow recycling the regenerated leach solution back to the leach step in the process.

Jan 1, 2015

By Lorne Sivertson, Peter Kitrredge

"World metallurgical coal imports totalled 110million tonnes in 1978. Of this amount, Japan imported 50 million tonnes, making it by far the largest and most important coking coal market . British Columbia and Alberta exported 12.0 million tonnes of coking coal in 1978, or 11% of the world total. Virtually all of these exports were directed to Japan, making up 22% of total imports.Some observers have suggested that because Japan is almost the exclusive buyer of British Columbia and Alberta metallurgical coal, the benefits of the coal trade may be primarily on the side of the powerful Japanese buyers. Buttressing this suspicion is the fact that Japanese trading companies have taken substantial equity positions in B.C. coal mines, thus presenting the possibility of non-arms-Iength transfer arrangements. There is then at least some evidence to support the hypothesis that Canada's western coal producers receive prices that are less than would prevail in a more competitive market; that is, that they are exploited.This paper produces evidence that Canada's coals are not underpriced in respect to U.S. and world markets. The conclusion is drawn that British Columbia and Alberta metallurgical coals receive prices that are equal to prices known to be competitively determined. This conclusion follows an in-depth analysis of prices, coal qualities and the economic characteristics of all major coals traded in the Japanese market. A by-product of the analysis is an equation capable of predicting the value of any metallurgical coal sold to Japanese buyers, or, for that matter, any buyer. Hopefully, this can be of some use to coal producers in developing their marketing strategies."

Jan 1, 1980

By J. J. Emery

There is an increasing awareness on an international level of the potential for utilizing many wastes and by-products as construction materials. This has resulted in recent major reviews by OECD and RILEM to supplement national activities by agencies such as CANMET, USBM, BRE and LCPC. Much of this international and national work was reported during an International Conference on the use of by-products and wastes in civil engineering held in November 1978 in Paris. Based on participation in the OECD and RILEM reviews, and the Paris conference, developments in waste and byproduct utilization of particular concern to Canada are described. The major technical and economic constraints involved are also reviewed, so that the over-all evaluation reflects important factors such as inherent variability and transport logistics. Areas requiring further research and development are also identified. Particular emphasis is placed on slags, salvaged asphaltic concrete and surplus sulphur. "Due to the rapid development of China's industry, more than a hundred million tons of industrial wastes are generated annually, which occupy lots of land for storing, bring about environmental pollution, obstruct industrial and agricultural production and cause harm to people 's living. Therefore we must utilize them effectively to create wealth for our country. "

Jan 1, 1979

By J. A. Finch

"This paper describes major technical developments in rod mill design and operating practice since its introduction into the North American minerals industry over fifty years ago. The basic operating characteristics of the wet, overflow rod mill are described, and significant operating variables are reviewed in terms of their effects on mill power draw, power efficiency, and practical aspects of circuit operation. Key factors for improving the economic performance of rod milling circuits are identified. IntroductionThis paper summarizes the findings of a detailed review of available technical information on the operation of rod mills. One of the basic problems in historical comminution testwork has been the lack of a standard measure of circuit performance. The Bond Operating Work Index, not introduced until after 1950, has proven of immeasurable value in this regard, but first has to be carefully considered in terms of its utility and limitations. Its prescribed use is described in a later section of this paper.During this review, it became apparent that rod mill performance is generally not well understood. Because of combined interactions, the effects of different operating variables may be difficult to assess, and even at times appear erratic. It is obviously difficult to rationalize plant testwork or circuit adjustments when the results are highly unpredictable. The purposes of this review, therefore, were:a) to establish what basic facts have been learned about rod mill performance;b) to define some genera l guidelines for efficient rod mill design and operation; and,c) to establish a basis for specific recommendations for plant tests or adjustments with minimum risk, and maximum potential for circuit performance improvement."

Jan 1, 1986

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By J. G. Pearson, F. H. MacDougall, A. G. Galley

The difference in age, host rock lithology, alteration and style of mineralization indicates a fundamental difference in the format ion of gold deposits in the Flin Flon and Amisk Lake areas. The Flin Flon area contains early quartz-sulfide-gold veins fo rmed within intermittently active fractures and later plutonic hosted deposits thought to be generated in a porphyry system. In the Amisk Lake area two types of gold occurrences are recognized: I) gold-quartzcarbonate- sulfide veins within or flanking fault zones and 2) structurally and stratigraphical ly controlled zones of dissem inated and vein type sulfide-gold mineralization within extrusive and intrusive rhyolite and dacite porphyries. Both types of deposits are set within supracrustal rocks. are accompanied by intense alteration haloes and were formed prior to the major deformation event suggesting an early, epigenetic hydrothermal origin.

Jan 1, 1986

By Seshadri Seetharaman, Nurni N. Viswanathan, Haijuan Wang

The present work aims at some process modifications in specified metallurgical processes, wherein CO2 can be used successfully as an oxidant for decarburization in steelmaking and applied in some non-ferrous metals production processes. During the decarburization of Cr-containing high alloyed steels, the present researchers investigated the possible use of CO2 instead of Ar-O2 mixture and could successfully decarburize the steel melt without significant loss of alloyed Cr to the slag phase. A mathematical model was developed based on the bubble formation accompanying the chemical reaction: C(molten steel)+ CO2(gas)= 2 CO(gas). The model predictions were tested by laboratory scale (1 kg) experiments carried out in an induction furnace and very good agreement between the model predictions and experimental results were observed. A national project has been sanctioned in China for the implementation of CO2 in decarburization of ferroalloys as well enable the addition of pig iron in the electric arc furnace process when the scrap supply is limited. New processes have been developed for the utilization of CO2 in the case of non-ferrous processes. A novel method of treatment of Al dross by leaching with water and capturing the evolved NH3(formed by the hydrolysis of AlN) has shown very promising results.

Jan 1, 2015

By J. Basi, D. F. Rucker

"A review of historic operating practices of the heap leach pads at the Los Filos Mine, Mexico, revealed periods of restricted cyanide addition, reduced leach time, and insufficient irrigation flow. These issues all led to the buildup of partially leached recoverable gold inventory within the leach pads. Drawing down this inventory represented an opportunity to bring value forward. This paper outlines the strategic initiatives which were implemented as efforts to accelerate the inventory drawdown, including geophysical mapping and pressure injection.INTRODUCTION Los Filos is a heap-leach operation located in the Guerrero gold belt in southern Mexico. Operational and hydraulic challenges at the Los Filos Mine have led to a buildup of gold in inventory within the leach pads. Operationally, periods of restricted reagent addition, reduced leach time, and insufficient irrigation flow have compounded over the last eight years, and resulted in significant inventory growth. Hydraulically, the leach pad has issues with low permeability and solution channeling due to the fines and clay content of the ore. The leach pad is storing high-grade pregnant leach solution (PLS) as perched aquifers above areas that are compacted and difficult to drain. These operational and hydraulic challenges made it particularly difficult to spatially predict the precise locations of the inventory build-up. Fortunately, the challenges at Los Filos are not unique to the mine, and others have taken steps elsewhere to reduce metal inventory through a program that targets areas for inventory drawdown. For example, Ghorbani et al. (2016) noted that a method of injecting barren reagent solutions, applied directly to specific areas of a leach pad to reduce inventory, was presented by Wan and Brierley (1997) and Wan (1997). Seal (2004; 2007), Seal and Jung (2005), and Seal et al. (2012) have put the injection methodology into practice in Nevada and Colorado gold mines with a technology called Hydro-Jex®. The goal of Hydro-Jex has been to supply reagents at a high pressure over a short duration, followed by periodical low pressure rinse periods to remove leached metal and resupply fresh reagent to the ore."

Jan 1, 2017

By Tim Watson

Andacollo Hypogene Project ?Overview Project description: Sulphide copper concentrator Throughput:55,000 tpd Location: Approximately 50 km from La Serena Elevation: Approximately 1,000 m ASL Start feasibility study: July 2005 Start of construction: May 2007 Construction completion: December 2009 Final cost(1,2,3):435 Million US $ (1) Excludes third party costs, 220 kV power line (2) Cost is based on a Chilean Peso to US Dollar foreign exchange rate of 535 to 1 (3) Does not include US$40.3 million for the Elqui River Pipeline Project or US$8.0 million for the stock pile cover

May 1, 2010

By William F. Caley, A. MacKinnon, P. W. Kingston

"The purpose of this paper is to identify a number of currently available opportunities for exploration and/or mine development in the industrial minerals field in southeastern Ontario. The paper is not intended as a complete review of the industrial minerals industry in southeastern Ontario, but highlights what are seen by the authors as areas where there are immediate opportunities for investment and growth.Traditional exploration targets in the Grenville Supergroup in southeastern Ontario have been vein-hosted gold deposits, industrial minerals, and base metals. In recent years, emphasis has increasingly shifted to industrial minerals, in response to changing technologies in the minerals-consuming manufacturing industries, and to an increasing awareness of the industrial mineral potential in this area.This paper examines the resurgence of interest in exploring for and developing a wide variety of industrial minerals, and it examines the work the Ontario Ministry of Northern Development and Mines has done under the current Canada-Ontario Mineral Development Agreement. Specific development opportunities are identified in various commodity areas. Use oj the industrial minerals wollastonite and nepheline as substitutes for fluorspar in the formulation of synthetic steelmaking slags is also discussed."

Jan 1, 1990

By Stephen D. Butt

Presentation Outline Overview of abandoned mine workings problem. Outline project phases and major outcomes. ? Phase 1 ? Assessment of current imaging technology ? Phase 2 ? Prototype technology development. ? Phase 3 ? Proof of concept ? Montague Gold Mines field trials. Research status - summary of ongoing and future work.

Apr 1, 2005

By Bruce W. Downing, Philip G. Claridge

"The availability of environmental data is a major concern in the development of an exploration project through the permitting and feasibility stages. The collection of these data should ideally start very early in a major exploration program. Although a large proportion of the environmental data can also be used for exploration purposes, (e.g. stream-sediment, soil, and rock analyses), environmental sampling will rarely have been initiated at an early date. For the Windy Craggy project, a major environmental concern is the potential for generation of acid rock drainage from waste-rock piles. The project is reviewed with respect to the environment of the deposit, deposit geology, mineralization and reserves, the sequence of exploration activities to the present, the potential for the development of acid rock drainage, the geochemistry and water quality, and the integration of exploration and environmental databases and their application to environmental planning. IntroductionIn the classical sense of exploration of a mineral deposit, the efforts throughout exploration are routinely directed at confirming the existence of the deposit and defining its extent, grade and continuity. Environmental issues are usually tackled separately, possibly by different personnel at a later date. When that is the case, an opportunity is lost to build, from an early date , a comprehensive database that (I) will satisfy the needs of conventional exploration and environmental monitoring, and (2) is usable as a predictive tool for environmental impact assessment.The concept of environmental geochemistry is not complex. The availability of environmental data is a major concern in the development of an exploration project to the feasibility and permitting stages. The collection of data should ideally start very early in any major exploration program. In many cases a significant proportion of the geochemical exploration data gathered early in the life of a project will also be used later for environmental purposes (e.g. stream-sediment, water, soil, and rock analyses). Rarely, however, will the data gathered in a geochemical exploration program provide information as complete as that attainable if environmental objectives had been considered in scoping the work.A knowledge both of local and regional geochemical processes can lead to a better understanding of environmental impacts. This understanding is the basis upon which good environmental management practices may be built. Geddes Resources Limited has undertaken a major study of the natural environment in the Windy Craggy area which includes geology, surface and underground waters, soils, stream sediments, glaciers and geomorphology (Geddes Resources Limited, 1990). This paper deals with the building and integration of the exploration and environmental databases."

Jan 1, 1993

By M. R. Hudec, M. A. Nikolinakou, P. B. Flemings

"We model the shale response to the large deformations associated with salt bodies, and we identify the implications of the stress changes for hydrocarbon exploration. We employ both the static and evolutionary approach, and show that while the static one can model actual geologic geometries, only the evolutionary approach can provide a detailed description of the stress history of shales, which is essential for predicting stress, porosity, and pore pressure and, more generally, for understanding Earth processes related to salt-hydrocarbon systems.INTRODUCTIONDuring the last two decades, understanding the stress, material behavior, and pore pressure in shales around salt bodies has become increasingly important. The energy industry routinely drills near salt (Beltrão, Sombra, Lage, Fagundes Netto, & Henriques, 2009; Meyer, Zarra, Rains, Meltz, & Hall, 2005; Seymour, Rae, Peden, & Ormston, 1993), because a significant number of hydrocarbon reservoirs around the world are found in layers dipping away from salt diapirs.Salt is a viscous material that cannot sustain deviatoric stresses. Under differential loading it flows, changes shape, and eventually relaxes to an isostatic stress state (Urai & Spiers, 2007). Therefore, emplacement of a salt body and its viscous relaxation process may cause significant deformation of the surrounding sediments, perturb their state of stress and create local overpressures (Dusseault, Maury, Sanfilippo, & Santarelli, 2004; Seymour et al., 1993). As a result, drilling near salt is particularly challenging, and problems leading to additional expense or even abandonment are common (Bradley, 1978; Dusseault et al., 2004; Meyer et al., 2005; Seymour et al., 1993; Willson et al., 2003).Historically, salt and the evolution of its cross section to the present day geometry have been studied using kinematic restorations (Rowan & Ratliff, 2012). This approach aims to explain the present geologic section through a sequence of plausible past sections; however, it does not model the constitutive response of the wall rocks, hence it cannot provide any prediction on their state of stress. Similarly, largestrain numerical studies (Albertz & Beaumont, 2010; Chemia, Schmeling, & Koyi, 2009; Goteti, Ings, & Beaumont, 2012; Gradmann, Beaumont, & Albertz, 2009) have focused on the rheological evolution of salt systems without modeling the geomechanical response of the sediments."

Jan 1, 2015

By B. K. Gorain

"The Air-Metabisulfite (AMBS) process has been developed to treat complex copper, molybdenum and precious metals (gold, silver) bearing ores using brackish and sea water. This process was able to produce significantly better copper concentrate grades and higher recovery than possible using conventional lime and/or cyanide based processes for certain complex ores with high sulphide gangue minerals. The AMBS technology in now used commercially following a rigorous evaluation process emanating from laboratory curiosity to plant applications. In addition, many projects have embraced this technology at a feasibility level involving various complex ore bodies.This paper presents a summary of the findings from testing the AMBS technology on various ores types. Experiences gained from this successful development from bench to piloting and then to plant applications are also presented in this paper.INTRODUCTIONProcessing of sulphide copper, molybdenum and precious metal ores typically involves flotation of copper bearing minerals while depressing non-sulphide and other non-copper sulphide minerals such as pyrite, pyrrhotite and sometimes arsenopyrite. Though in many precious metal ores, the values are in these sulphide minerals as well. The conventional method employed in the industry to produce a saleable copper concentrate requires depression of these non-copper sulphide minerals using an alkaline pH above 9.5, though 10.5 to 11.5 is more common. Alkalinity is controlled by the addition of a pH modifier. Lime is normally employed as a pH modifier due to its relatively low cost; however, the costs associated with adding lime can be significant and the effectiveness of lime as a depressant could be drastically reduced when the process water supplied to the flotation circuit contains high level of dissolved salts. In some cases, a small amount of cyanide is used along with lime to depress non-copper sulphide minerals especially when its proportion to copper sulphide minerals in the ore is higher than three."

Jan 1, 2016

By Carlos Rebolledo, Nelson Parra

Arsenic is an unresolved problem in the mining industry considering the fact that most of the new copper deposits have high arsenic contents; stricter environmental restrictions for handling, transporting and processing complex materials are expected and stable abatement of arsenic is not extensively applied. In 2018 Chile produced 24.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly associated with production of concentrates that will also contain more arsenic. China has set an import benchmark of maximum 0.5% for arsenic content in copper concentrates and this value is expected to be more restrictive in the future. On the first day of 2018 China banned the importation of scrap. Blending practice has been a business option, but it is not sustainable in the future, as “normal” copper concentrates become less and less clean. By the end of 2018, Chile formulated new regulations, increasing the capture of SO2 and arsenic to 95%. In order to comply with these regulations Chilean smelters had to make large invest large amounts of money. Disposing of arsenic as a stable residue is a pending issue. EcoMetales is a 100% subsidiary of Codelco and provides the mining industry with environmental solutions. It has a plant near Calama in Chile that treats flue dust from smelters, refinery effluents and acid solutions from acid plants. EcoMetales is fully committed to contributing to the solution to the arsenic problem. Currently we are developing four main projects: 1) Concentrates treatment. A PLCC project considering the treatment of 200 ktpy of copper concentrates with arsenic from the northern district of Codelco; 2) EPAS DET project considering the treatment of 700 m3/d of weak acid solution with arsenic from the of El Teniente devision of the Codelco acid plant; 3) Borras project, considering the recovery of valuable metals (Cu, Ag, Ge, Pb) from the flue dust leaching plant; 4) Tailings project, considering the recovery of metal values from tailings. The purpose of this work is to present the trends and treatment processes for arsenic handling in the copper mining industry with a focus on the scorodite process. INTRODUCTION Between 2000 and 2015 the global copper concentrates production has grown from approximately eleven to fifteen million metric tons per year. Chile produced 26.5% of the total copper from concentrates and in the future copper production in Chile is expected to increase, mainly as a result of the production of concentrates (Figure 1)

Jan 1, 2019

By Jayne Somers

Methane (CH4) is a potent greenhouse gas, accounting for 15 percent of all global greenhouse gas emissions in 2005. Since methane has a much shorter atmospheric lifetime than carbon dioxide (CO2), reducing methane emissions can achieve considerable climate benefits over the next 25 years. Coal seams often contain significant quantities of methane and CH4 released to the atmosphere from gassy mines during coal extraction is a major source of greenhouse gas emissions. Methane (CH4) emissions from coal mining activities constitute approximately 6% of total global human-related methane emissions. Coal mines around the world have recognized that methane is a clean energy resource that can be captured and used productively. Coal mine methane (CMM) is currently utilized for power generation, natural gas pipeline injection, vehicle fuel, industrial process feed stocks, on-site mine boilers, mine heating, and home heating distribution systems. Upgrading mine degasification systems can often improve gas quality and create favorable project economics. The United States has been a leader in coal mine methane (CMM) recovery and use since the 1990?s. There are now 15 projects at active underground mines in the U.S., as well as 26 abandoned mine methane projects. Recovery and use projects at active underground U.S. mines reduced methane emissions by approximately 49 Billion cubic feet in 2010. In an exciting new development, a ventilation air methane (VAM) mitigation project at the CONSOL McElroy mine in West Virginia was installed by Verdeo. Operational since September 2012, this is the first commercial-scale VAM project in the U.S. and the project will reduce methane emissions by an estimated 920 MMCF/yr. As part of the U.S. Greenhouse Gas Reporting Program, actual data on methane emissions from underground coal mines was collected for the first time in 2011 and reported to U.S. EPA in September 2012. The data collected will help inform stakeholders, particularly the underground coal mining industry, of CMM emission sources on public and private lands. The detailed data will also shed light on the specific sources of methane from active underground coal mines and highlight project opportunities for the U.S. coal industry. The paper will cover U.S. coal mine methane emissions, U.S. CMM utilization and destruction projects, Federal policies and State incentives for CMM capture and utilization. 2011 CMM data from the U.S. Greenhouse Gas Reporting Program Subpart FF will be analyzed and compared with previous U.S. Greenhouse Gas Inventory estimates. Other developments, including the voluntary carbon market, will be discussed.

Aug 1, 2013

By A. H. Lang

"The great interest taken in uranium in Canada during the past few years has resulted in the discovery of a very large number of occurrences, and in much research that has added to the knowledge of the mineralogy and geology of uranium deposits. The object of this paper is to present that information in condensed form. Some of it has been published before, but the writer has been asked to bring it together and to add more recent, unpublished data. The paper therefore contains short accounts of the mineralogy of uranium and of the types and distribution of occurrences; brief regional descriptions, including information on some of the characteristic deposits; and conclusions regarding prospecting and development possibilities.The writer has access to much confidential information supplied in compliance with regulations of the Atomic Energy Control Board. He has used this only for making broad generalizations that could not affect individual interests, and only where the owners of properties have agreed to its use.Much of the information on mineralogy and geology is derived from the work of others. The writer is particularly indebted to M. H. Haycock and S. Kaiman of the Mines Branch; H. V. Ellsworth, S. C. Robinson, E. J. Brooker, H. R. Steacy, W. E. Hale, and A. M. Christie of the Geological Survey; and E.W. Nuffield, J. S. Stevenson, and other officers of provincial Departments of Mines. For information and many courtesies he is greatly indebted to so many officers of Eldorado. Mining and Refining (1944), Limited, and owners and staffs of private properties, that it is impossible to mention them individually."

Jan 1, 1950

By Jaeheon Lee, Junmo Ahn, Doyun Shin

"Many alternative leaching systems including bacterial leaching have been introduced to avoid passivation on the surface of chalcopyrite and to increase the leaching efficiency of copper from chalcopyrite. Recently, glycine, one of the simplest amino acids, has been emerging as an efficient and environmental-friendly lixiviant to recover copper. In the present study, an alkaline glycine–peroxide lixiviant system was used to leach copper from chalcopyrite concentrate and the leaching mechanisms were also investigated by a suite of kinetic studies under different conditions. The chalcopyrite concentrate contains 28.8% copper with 30.8% sulfide sulfur. The effect of concentration of glycine and hydrogen peroxide of the leaching solution was investigated. Glycine concentration was varied from 0.5 to 1.0 M and the hydrogen peroxide concentration was changed between 3 to 5%. Leaching time and pulp density were also varied. Hydrogen peroxide is an oxidant of the system and the leaching efficiency with periodic additions of the peroxide was also studied. A mineralogical study was performed using XRD and SEM. To investigate the surface of the residue materials, XPS was used to see if any passivating layer was formed during the leaching. Detailed results from mineralogical, chemical, and metallurgical studies will be presented and discussed.INTRODUCTION The greatest global resource of copper is low-grade chalcopyrite and heap bioleaching may be the only economic option for its processing. However, formation of a passivating layer on the surface of chalcopyrite slows down the oxidation reaction and reduces the efficiency of the process."

Jan 1, 2017

By C. R. Edwards

"Since the first commercial extraction of uranium in the early 1940s, the range of feasible process alternatives has greatly increased. This paper reviews process options to reduce extraction costs, improve efficiencies, effect safer operations, and lessen environmental impacts. Equipment and processes used in the past, in use now, and that could be considered for future use are described.BackgroundTwo billion years ago life on earth consisted solely of single celled creatures of the simplest design (Gould 1989). Incredible as it may seem, uranium fission reactors were operating then also. In what is now western Africa, a series of natural reactors were fueled by rich uranium deposits in contact with underground rivers. Water from the rivers provided the moderator necessary to sustain the nuclear fission chain reaction. These primordial reactors ran down after about 600 000 years (Ontario Hydro 1989).Because it is ubiquitous in the earth's crust, humans have always been in contact with uranium. Mining of uranium, albeit not intentional, is ancient ; uranium minerals were embedded in ore veins mined for metals such as silver and copper.Uranium was discovered in 1789 in Berlin by an apothecary, Martin Heinrich Klaproth, who named the element after the recently discovered planet Uranus. The metallic element uranium, as opposed to its compounds, was extracted in 1841 by the French chemist Eugene-Melchior Peligot. The atomic mass of uranium was calculated to be 120, but the Russian genius Dmitri Ivanovich Mendeleev (famous and welcome everywhere except in Russia, where his liberal politics were detested by the Tsar), found this did not fit into his periodic table, and submitted a value of 240. Mendeleev was close; the exact atomic mass is 238.029.Henri Becquerel's detection of the radioactivity of uranium in 1896excited scientific study of the metal, but virtually no practical use was found for uranium outside of a minimal consumption as a colouring agent for glass and ceramics. Scientific interest intensified in the 19305. In 1933 Leo Szilard patented the concept of the nuclear chain reaction. While walking to work on a fine fall London morning and mulling over the problem of how to release atomic energy, he was stopped by a red light. He stood in thought and conceived the notion of the neutron-activated chain reaction before the light turned green. The patent was filed in 1934, and Szilard assigned it to the British Admiralty in order to keep it secret, in an honourable but ultimately futile effort to prevent the misuse of science (Bronowski 1973)."

Jan 1, 1992