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By Robert Maquil, Gilles Didier, Walter Steiner

"The 1580 m long dual-tube motorway tunnel Markusberg near Schengen, Luxembourg experiences strong swelling phenomena in each tube related to a 35 m wide diagonally crossing rock layer, some150 to 200m from the east portals. Overburden over the roadway is 26 to 30 meters. Tunnel construction started in 1998 and the tunnel was opened in 2003. The tunnel was driven downgrade from the West, the heave phenomenon started to occur as the tunnel approached completion. No indications of the presence of anhydrite and dissolved sulphates were known prior to tunnelling. Water samples had been taken from the beginning of construction and the concentration of anions and cat ions determined. Sulfate content was substantial, in one well it reached 22 mg/l, this high concentration requires the presence of other ions, in particular sodium and chlorine. Based on the knowledge at the time of construction heaving ground was removed from the tunnel invert and a free space was left below the roadway that is covered by a transversely spanned slab. In addition a series of posttensioned tiebacks were installed below the sidewalls. The void left in 2003 was 1.7m high and closed to less than 0.5 meters in 2007 then it became necessary to widen the free space. A central trench was dug with a height of about 2.5 meters and the benches were lowered.Level surveying had been carried out since 2002. In 2006 two extensometers were installed, one in the zone of strongest heave, the second at the edge of the swelling zone. The extensometer in the center of the swelling zone indicated heave with an essential constant rate with seasonal variations, the heave is concentrated in layer from 2 to 5 meters that heaved by nearly 300 millimeters within 5 years or 60 mm/year, which equals to approx. 1% extension per year. At the abutments heave rates of 20 mm/year where the support resistance is higher were observed. With data from other case histories a relation of heave rate with support resistance was established. Based on the numerous field observations hypotheses for the complex in-situ swelling processes, involving rock mechanics, mineralogical, soil mechanics and hydrogeological aspects were developed"

Jan 1, 2015

By D. Q. Li

"This paper briefly introduces problems that can occur in the design of rare earth separation processes and that require close attention during engineering design. Important factors must be considered include the following. 1) The separation process is primarily based on two points. One is the raw material composition and the other is the product purity requirements. 2) Optimization of the rare earth separation process requires optimization of the flowsheet configuration and each process parameter. 3) The separation of heavy rare earths is performed under non-equilibrium conditions. 4) The radioactive elements uranium and thorium must be removed from the feed to separation. 5) Process economy and environmental protection must be considered together in the evaluation of any separation technology options. INTRODUCTIONThe importance of rare earth (RE) is well recognized in high-tech applications and sophisticated national defense technologies. RE is the treasure house of the 21st Century new materials. The RE separation processes developed using HEHEHP (P507), P507-alcohol (ROH) and naphthenic acid (NA) have been widely applied in China. These processes have led to industrial production of all of the individual RE with up to 4N (99.99%) or higher purity (Li, Wan, Lin, Xie, Lin, & Wang, 1980; Li, Wang, & Xie, 1985; Li, 1995; Li, Wang, Meng, & Li, 2005). In order to achieve the best economic and environmental benefits, this paper discusses several problems to which attention must be paid in the design of rare earth separation process."

Jan 1, 2016

By N. L. Richards

In manufacturing for the 21st century, the first company to market often leads the pack in product development and sales. In this respect, manufacturing processes play an important role in transforming “raw materials” into a product(s) for sale to a customer. Thus it can be seen that upfront modelling of a design concept, or modelling of manufacturing processes in a plant, can play an important role in effectively ensuring the overall design and manufacturing route is carried out in an expeditious manner. In the paper various scenarios are considered with respect to modelling the microstructure and/or process, in various manufacturing processes. Also considered are the effects of service condition on the manufactured product in terms of creep and fatigue.

Jan 1, 2010

By Shiqiang (Rob) Hui, Jiaren (Jimmy) Jiang, Rees Llewellyn, Yongsong Xie

Wear has been estimated to cost the Canadian mining/mineral processing industry over $15 billion per year mainly for repair/replacement of worn parts in 2013. The associated production loss is difficult to quantify but add considerably to the problem. The Canadian oil sands sector which has to deal with extremely abrasive and erosive solids, has traditionally incurred extremely severe and often unique attack. Demonstrable progress in mitigating the wear problems has been achieved through materials development, more informed materials selections, and better component and operation condition designs. An integral contributor to these advances is a long-term collaborative research partnership between NRC and the mining/supply industry. In this paper, this continuing collaboration will be described. A main focus is to identify degradation mechanisms occurring in the most severe and important service applications and to correlate these findings with laboratory test data. Relevant abrasion and erosion (often combined with corrosion) properties have been established and correlated with composition and microstructures for all classes of resistant materials ranging from relatively soft elastomers to ultra-hard ceramics. A comprehensive wear properties database has been compiled. This capability has been instrumental in facilitating the development of improved materials, optimizing materials fitness/selection for service, wear failure analysis, and quality assurance.

Jan 1, 2015

By C P. Gravenor

In 1953, a deposit of sedimentary oolitic iron ore was discovered in the Clear Hills area of northwestern Alberta. Since that time, detailed drilling has outlined reserves in excess of 200 million tons of ore grading 30 to 35 per cent iron. Attempts to physically beneficiate the ore to meet blast furnace or direct reduction feed specifications have been, in general, unsuccessful. In 1960, Premier Steel Mills Limited and the Research Council of Alberta jointly sponsored a pilot-plant test at the R-N Corporation at Birmingham, Alabama. About 5,000 tons of ore were treated, and briquettes containing 90 per cent Fe were produced, with 83 per cent recovery. At the same time that the R-N tests were being made, the Research Council initiated a program to produce high-purity powders by chemical methods. Several purification techniques were investigated; hydrochloric acid dissolution of reduced ore was finally adopted. Briefly, the steps involved in this acid process are as follow

Jan 1, 1964

By Stanley G. Butcher

"The methods generally applied to predict performance and financially evaluate beneficiation options are reviewed.Typical costs f or a western Canadian thermal coal operation are examined. Preparation-from truck dump to loadout-frequently amounts 10 over a quarter of total minesite costs. Failure to achieve projected yield-whether caused by mine or plant problems-s-substantially increases production costs because more coal has 10 he mined to meet a specific market demand. Problem identification by mass/ash balances is recommended.Thorough characterization of the coal and associated waste materials and more reliable prediction of beneficiation process performance are therefore essential to determine a project 's financial viability.IntroductionWestern Canadian coal prep a ration plant capacity is partway through a massive expansion program . In 198 1 potential product ion was 14 million tonnes, by 1985 it will be 26 million tonnes per year. Only two years ago the industry was concerned whether it could sustain this rate of growth to meet market demands : now with diminished market demand and lower coal prices being offered by our international competitors there are doubts whether t his potential will be fully employed , even by 1990.One direct consequence o f the occurrence of a variety of coals in a stunningly beautiful but complex geo logical setting such as the Rocky Mountains and their Foothills is that each project is unique. Coal is a low value per tonne product. To supply distant markets from geographically isolated deposit s necessitates expensive , dedicated , infrastructure . T o be profitable these operations must achieve eve ry advantage of the economy of scale.Each of the mi ne complexes commissioned in the 1970s experienced severe problems in the area o f co a l preparation . Most bought their way out , paying for major plant modifications by increasing the scale of their total operation . The current market recession may not allow new operations this route to profitability.The objective of this paper is to illustrate the economic impact of coal preparation problems on the profitability o f the total minesite operation and thus provide a sound basis for decision making process."

Jan 1, 1985

By V. S. Melamud, A. G. Bulaev

"Sulfide ore processing is characterized by significant losses of metals, for example, with flotation tailings. Therefore, flotation tailings can present an important source of metals. The treatment of flotation tailings is a technological issue due to low content of valuable metals (e.g. copper and zinc) and high iron content. The goal of the present work was to investigate extraction of base metals and gold from old flotation tailings containing 17% iron, 0.26% copper, 0.22% zinc, and 0.7 g/t gold. Chemical leaching in columns with 0.5 to 10% sulfuric acid solutions and bioleaching in air-lift percolators were used for the extraction of base metals. 1% H2SO4 provided high extraction of base metals and best selectivity. Recovery of copper and zinc reached 35% and 40%. Increasing H2SO4 concentration did not lead to significant increase in base metals extraction, but led to increased iron concentration in the pregnant solutions. The 1% H2SO4 leaching solid residues were used for further experiments. Acid leaching and bioleaching did not result in significant increase in base metals recovery. Leaching of the residue with 10% H2SO4 provided extraction of 4% copper and 20% zinc, and bioleaching for 100 days provided extraction of 16% copper and 12% zinc. The recovery of gold by cyanidation from the flotation tailings, the 1% H2SO4 leaching solid residue and residue of two-step acid leaching were 50, 49, and 65%, respectively. The results suggest that acid leaching can be effective approach for treatment of old flotation tailings.INTRODUCTIONAbout 80% of base metals (copper, nickel, zinc) are produced through pyrometallurgical treatment of sulfide ores. Mining and metallurgical treatments of sulfide ores are presently characterized by significant losses of non-ferrous and precious metals into the various wastes. For example, flotation of sulfidic ores yields formation sulfide flotation tailings. These wastes pose a problem not just because of their sheer volume, but some of them may affect local ecosystems. Nowadays, mining and metallurgical wastes can be considered as technogenical source of base metals."

Jan 1, 2016

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By Taisuke Sakakibara, Shinya Suzuki, Tatsuya Kato, Chiharu Tokoro, Kenichi Muto

Surface complexation using a diffuse layer model were constructed for arsenic (As(V)), zinc (Zn(II)) and silicate (Si(IV)) for aluminum hydroxide in the co-precipitation process. From experimental investigations using isotherms, zeta potential measurement and XRD analysis, it was confirmed that co-precipitation involved not only surface complexation but also surface precipitation. However, surface complexation was major mechanism for As(V), Zn(II) and Si(IV) removal under the target removal level of the Japanese effluent standard. In surface complexation modeling, exchange capacity of aluminum hydroxide was determined from specific surface area obtained from experimental measurement and site density obtained from reference. Surface complexation coefficients were determined by fitting the removal property and sorption isotherm obtained from co-precipitation experiments. These parameters were in agreement with the numerical parameters found by Karamalidis and Dzombak (2010) who reported a database of adsorption equilibrium constants for gibbsite. The surface complexation models constructed in this study were applied to neutralization process of an actual AMD treatment. Our model could successfully represent the pH edges for As(V), Zn(II) and Si(IV) in the neutralization of AMD.

Jan 1, 2015

By L. Li

ABSTRACT Stope backfilling is a common operation in many underground mines, which requires a barricade at the base of the stope near the drift entrance to retain the backfill in place. In this paper, the distribution of pore-water pressure in barricades made of waste rock is analyzed. An analytical solution is introduced and applied to estimate the pore-water pressure along the base and full height of the barricade. Results show that the analytical solution generally accurately predicts the distribution of pore-water pressure obtained from the numerical calculations, especially in the upstream part of the barricade, where it is most critical.

Jan 1, 2013

By S. Shimaya, T. Maejima, M. Shimo

"The authors conducted the in-situ gas-tightness tests in a fractured rock at the Namikata underground LPG storage site in Ehime prefecture, Japan. The test consisted of two independent setups, a gas-tightness test that used boreholes, and a chamber-scale test that used a horizontal drift sealed with a concrete plug. In each test, the gas pressure was increased up to the onset of the measurable gas flow to obtain the maximum containment pressure. This paper discusses the hydraulic conditions for gas leakage initiation and the importance of the pore pressure measurement for monitoring the gas-tightness of the LPG storage cavern based on the test results.INTRODUCTIONJapanese first underground LPG storage plant was constructed by JOGMEC, the Japan Oil, Gas and Metals National Corporation, at Namikata in Ehime prefecture in granitic rocks (Kato et al., 2007). The “hydraulic sealing principle” (Åberg, 1977) that utilizes groundwater flow into an unlined cavern to prevent the leakage of gas through fractures in the surrounding rock mass was employed for storage of LPG. This paper describes the results of the in-situ tests performed at the Namikata Site to obtain information on fundamental gas-tightness characteristics of fractured rock. Two types of in-situ tests, a borehole gas-tightness test and a chamber gas-tightness test, were carried out near the storage caverns. Figure 1 shows the cavern layout of the Namikata underground storage plant and the test locations. The storage facilities consist of three caverns (W26m×H30m×L485m). The cavern crown lies at a depth of 150m below the sea level in Cretaceous granitic rock (Figure 1). Water curtain boreholes excavated from the water gallery tunnel at EL-125m level are located above and side of the caverns to prevent water drainage from fractures during the construction stage as well as during operation. The borehole tests were performed from a drilling adit excavated from the eastern end water gallery tunnel, while the chamber test was conducted at the southern edge of an exploratory drift extending from the central water gallery tunnel."

Jan 1, 2015

By Philippe Caudal

This paper presents a case study in which a slope failure was observed on the west wall of the LAB Chrysotile mine in the vicinity of the main ramp in January 2010. Airborne LiDAR results were used to evaluate slope geometry before and after the failure occurred. Back analysis of the failure was performed to assess rock mass properties at the slope scale using various numerical techniques: limit equilibrium, finite elements and fracture networks. The various approaches correlated well with field observations.

Aug 1, 2013

By Tassos Grammatikopoulos, Vladimiros Papangelakis, Douglass Duffy, Cheryl Washer, Srinath Garg

Flotation operations in Sudbury, Ontario, seeking to separate pentlandite and chalcopyrite from mixed sulphide deposits, produce pyrrhotite tailings that have been disposed of in tailings ponds for over 50 years. These reactive tailings are viewed as waste, despite containing ~0.8 wt% Ni, and represent an environmental liability because of their acid mine drainage (AMD) potential. Given the large quantities of pyrrhotite currently stored in Sudbury, and declining ore grades elsewhere, these tailings have shifted from being viewed as a waste to a potential resource. Recent advances in the bioleaching of low-grade sulphide ores have raised the prospect of bioleaching as a potential low-cost processing option. However optimization of this proposed process requires a thorough understanding of the mineralogy of the pyrrhotite tailings that would be leached. The work presented here addresses the characterization of two distinct Sudbury pyrrhotite tailings, namely from the Vale and Glencore operations, using electron microprobe, XRD and QEMSCAN analysis. Particular focus is given to how the mineralogy may affect bioleaching as a processing option, through the deportment of nickel and the various phases present

Jan 1, 2015

By K. Janghorban

Multilayered ceramic-metal composites were produced by solid state diffusion bonding of polycrystalline alumina and three Al alloys containing 1 to 2%Sr, 2% Mg and Mg + Si (5057 Al alloy), The multilayered structures were fabricated at 610°C under a compressive stress of 3 MPa for 2 hours in He-5%H atmosphere, The ceramic-metal interfaces were studied by SEM and TEM equipped with energy dispersive spectrometer (EDS). Addition of 1 wt % Sr to Al promoted good adhesion, without producing any interfacial products, while the Al-2%Sr was poor in this regard due to the presence of dispersed A14Sr which is an intrinsic phase in the Al-Sr phase system, The Al-2%Mg alloy produced a continuous film at the interface, which was characterized to be MgAl2O4. Al alloys containing Mg and Si (5057 commercial alloy) produced not only the spinel structure (MgAl2O4), but another phase rich in Mg and Si (close to Mg2Si), These latter interfacial reaction products were not the intrinsic phases in Al-Mg alloys, and were reaction products at the Al2O3 ?Al alloy interfaces.

Jan 1, 2005

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By R. L. Bruening, N. E. Izatt, S. R. Izatt

"Rare earth elements (REE) are essential and unique components of many high-technology products without which functioning of modern society would be greatly impaired. Commercial deposits of REE are limited to a few geographical locations. Largely untapped sources of REE are available in endof- life (EOL) magnets, rechargeable batteries, and electronics. Presently, < 1% of REE in EOL wastes is recycled. Conversion of EOL wastes to liquid streams allows use of IBC’s Molecular Recognition Technology (MRT) process to selectively recover, separate, and purify target REE and associated metals at g/L to mg/L or lower concentration levels. The MRT process together with its applications to separations of REE and associated metals in recycling as well as in mining are described. Economic and environmental advantages of MRT are presented. INTRODUCTIONRare earth elements (REE) include the lanthanide series (La-Lu), Y, and Sc. These elements are not rare, but concentrated minable deposits are scarce (Cordier 2012; Haxel, Hedrick, & Orris, 2002). Over 95 % of the world’s supply of REE is controlled by China (Hanson, 2011a) where they are mined, processed, and the pure elements incorporated into a growing number of consumer and military products. The consumer products are marketed worldwide. Since REE are vitally important in consumer and military products, this situation has caused other nations to scramble to develop the capability to produce their own supply (Cordier, 2012).In the U. S., Molycorp has reopened the Mountain Pass REE mine in California and production has begun (Goldenberg, 2010). Development of a reliable internal source of REE is of high national priority in the U.S. (Hanson, 2011b; Hess, 2012: “Obama Announces”, 2012). These elements have in recent decades been incorporated into new consumer and military products that are essential to our economy and defense. These products range from wind turbines, high performance magnets, hybrid car rechargeable batteries, energy efficient lighting electronics, flat screen televisions, and smart phones to advanced weapons systems (Haxel et al., 2002; Levkowitz & Beauchamp-Mustafaga, 2010)."

Jan 1, 2012

Mirador - Overview ? Located in Andean foothills of SE Ecuador ? Copper-gold porphyry hosted by calc-alkaline Late Jurassic granitic and porphyritic rocks ? 438 MT of 0.61% Cu and 0.19 g/t Au measured and indicated resources (at 0.4% Cu cut-off) ? Additional inferred resources of 235 MT of 0.52% Cu and 0.17 g/t Au ? Initial 25,000 tonnes/day production, expanding to 50,000 in year 6 320 MT of 0.62% Cu, 0.2 g/t Au ore mined at an average 1.4:1 strip ratio over a 21 year mine-life

May 1, 2006

By Robert Dickson

Princess colliery is operated by Old Sydney Collieries, Limited, a direct descendant of the General Mining Association of London, England, which, in the first quarter of the nineteenth century, pioneered in coal mining in Nova Scotia. The coal worked is a 5 ft. 6 in. seam known generally through the Sydney coalfield as the Harbour seam but referred to locally as the Sydney Main. Entry is made by shafts, 680 feet deep, sunk in 1871 on a headland forming the northern entrance to Sydney harbour. From them extend the main roadways of the colliery, a distance of 700 feet to the shore line and a further distance of 14,700 feet in submarine areas to a total length of 15,400 feet. It was the first colliery in Nova Scotia designed to work submarine areas. Lateral development extends across a frontage of 16,000 feet and the submarine area from which the coal has been extracted is slightly over 6 square miles. There yet remains sufficient territory ahead of the workings to assure a future life to this colliery estimated at over 80 years at the current rate of production. In this area the seam dips at 6 to 7 per cent and face workings have reached a depth of 1,690 feet below the sea level. Until 1923 extraction of the coal was by room-and-pillar, followed by the drawing of the pillars. At that date the superincumbent strata had reached a thickness of 1,400 feet, resulting in heavy weighting on the roof and severe side pressure on the coal ribs. In combination with a soft, heaving pavement this created a set of conditions involving great difficulties and expense in keeping open places driven in the solid sufficiently long to permit recovery of the coal in the pillars by methods and equipment then available. The operator was forced to resort to extraction by longwall as the only economical method of winning the coal.

Jan 1, 1948

By Veerendra Singh, Y. Rama Murthy, Sunil Kumar Tripathy, Nikkam Suresh

"High intensity dry magnetic separation is commonly employed to separate different para-magnetic minerals including mineral sand. Separation in these separators is majorly influenced by the combined effect of gravity, centrifugal and magnetic forces on a particle. These separators are included in the process flow-sheets either for pre-concentration purposes or for the beneficiation of paramagnetic minerals. Separation in these separators is majorly influenced by the difference in the magnetic susceptibility of the associated minerals, particle size and shape along with the process variables of the machine. Particle size is one of the major parameter that plays an important role and decides its probability of selectivity under the magnetic field. However, effect of particle size on the performance of these separators are not well understood which is evident from the literature.In the present investigation, an effort is made to bring out the effect of particle size on particle separation in an induced roll magnetic separator while treating ilmenite fines. Effects of operating parameters, such as; magnetic field intensity, roll speed, feed rate and splitter position have been studied and their influence on particle size has been analysed in terms of yield (wt.%) to magnetic product, particle size distribution characteristics in terms of D50 and D80 size, skewness, kurtosis. Also, the particle size distribution of each test was fitted in Rosin-Rammler equation. The test results were analysed statistically to understand and quantify the influence of each variable on particle separation. It is found that, rotor speed of the separator had maximum influence on yield to the magnetic product whereas splitter position had major influence on D50 and D80 (µm) size of the product."

Jan 1, 2016

By Dwayne D. Tannant

The Adra tunnel near Naramata BC experienced a fire in 2010 that burned timber sets within the tunnel and caused severe spalling of rock from the roof and tunnel walls. The nature of the damage is documented and efforts completed to rehabilitate and open a portion of this tunnel to the public are described. The use of shortcrete and rock bolts is a technically and economically superior support system to timber sets as well as being far more fire resistant.

Jun 1, 2012