Search Documents

By E. Kouame, M. D. Everell, D. Hodouin, T. Kasongo

"To properly operate a mineral beneficiation plant it is often necessary to have systematic evaluations of the performances of a piece of machinery, of one of the processes or of the plant as a whole. The state of a process can be described from a collection of data: flow-rate values, particle-size distributions and chemical compositions of the various streams of the circuit studied.However, the obtained raw data are generally redundant and inconsistent from a material balance viewpoint, due to natural disturbances, sampling errors, unreliable instrument readouts and laboratory analysis inaccuracies.BILMAT is a computer program which upgrades mineral processing data, adjusting them in a least-squares sense in order that they may verify material conservation constraints. As a consequence, the program is able to calculate the best values of unmeasured flow rates (such as. circulating load ratios). BILMAT is a very general program in the sense that it can accept various data from any type of mineral processing circuit, and its usefulness is demonstrated here for three processing circuits of a pyrochlore concentration plant: grinding, desliming and flotation.IntroductionComputation of the material balance around any metallurgical process, that is the determination of stream flow rates and composition. is a basic step in its evaluation. In spite of the simplicity of the physical laws of mass conservation. and of the very fundamental need to know the flow of components around a process. it appears, particularly in mineral processing. that material balancing is quite often a difficult task. The reasons for this involve the problems associated with collecting measurements in mineral dressing plants. They are generally poorly instrumented and invariably data must be collected through hand sampling. Due to the heterogeneous nature of the streams, segregation occurs and samples are often not adequately representative, a problem made worse by the lack of circuit sampling facilities, which are often completely ignored by plant designers. Furthermore, the nature of the measurements to be performed (for instance particle size distributions in the fine range) frequently gives inaccurate results."

Jan 1, 1981

By Claude Hubert, Alex C. Brown, Pascal Marquis, D. M. Rigg

"Numerous studies of the Bousquet mining district, Abitibi, Quebec, mainly following the successive discoveries of new gold deposits over the past two decades, have led to a broad range of genetic hypotheses for their gold deposition. A compilation of petrographic, structural, and geochemical data indicates that the gold deposits are composed chiefly of pyritic schists derived from felsic and mafic volcanic and volcaniclastic protoliths, and of auriferous massive pyrite hosted by pyritic schists of felsic affinity. The deposits are typically located within zones of local pyrite enrichment and advanced-argillic alteration which are in turn enclosed within much larger zones of disseminated pyrite included in regional-scale, commonly anastomosing, zones of sericitic alteration.Overprinting relationships between three sets of folds and foliations indicate that the host-rocks of the gold deposits have retained the imprint of three successive generations of ductile deformation resulting from regional dynamothermal metamorphism. Sericitic and advanced-argillic alteration, together with massive sulphide deposition, are interpreted to have taken place prior to the onset of the ductile deformation, based on observations 1) of altered fragments of wallrocks which are enclosed within massive sulphide bodies and were thus preserved through regional metamorphism, 2) of the syntectonic deformed pyrite, and3) of the syn-tectonic porphyroblasts of andalusite, garnet and plagioclase. The orebodies are oblate to prolate, and the pyrite-gold mineralization is typically vein-type, distributed in foliation-oblique and foliation-parallel veins. The gold-bearing structures postdate all foliations, and are associated with retrograde alteration assemblages that are pseudomorphic after pea~-metamorphic porphyroblasts in host-rocks, and with cataclasticfabrics that overprint syn-metamorphic pressure-solution features and annealing fabrics in pyrite.Retrograde gold-bearing assemblages indicate a chemical disequilibrium between the ore-forming fluids and their host rocks. This disequilibrium rules out the possibility that gold was remobilized from its own host, and suggests, instead, that the ore-forming fluids and their metal contents had an allochtonous source. Stable and radiogenic isotope analyses indicate that the fluids had a metamorphic origin, and that the associated alteration took place after the culmination of the Kenoran orogeny."

Jan 1, 1990

By G. McIsaac

"This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone’s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place.Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. “Whatif” scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan."

Jan 1, 2005

By G. McIsaac

This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone?s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place. Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. ?Whatif? scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan.

Sep 1, 2005

By V. C. Pandolfelli, L. Paulino, C. E. Zangiacomi

The continuous improvement in aluminum industry over the last years has increased metal output at lower cost. The potlining plays an important role in this regard due to high cost involved and more recently in its environmental aspects. In order to increase potlife and thus minimize the aluminum cash cost, a systemic approach is needed, through investigating the main cathode failure mechanisms by using a pot autopsy as a powerful tool, and then making the necessary chances to achieve extended potlife. In addition, preheating and pot start-up may also damage the cathode if not performed with an appropriate technique or even if the lining materials are not specified correctly, among other factors. All these aspects will be presented and discussed in this paper. Increased potlife, especially now that the current is reaching values up to 300kA, will allow aluminum plants to match their goals more efficiently at lower costs.

Jan 1, 2006

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

By C. R. Whittemore

IT can be truly stated that no branch of the engineering industry has progressed more rapidly in the last few years than that of welding. In spite of depressed economic conditions, this industry has continued to advance along scientific lines, replacing the old hit-and-miss method of welding. The development work is intensive, and increased activity is recorded in every sphere of the industry, new applications of existing methods, together with new processes, being added to those already proved in practice. The general acceptance of the welding processes can be measured by their utilization as a manufacturing tool in the metal-working industries. Many manufacturers have partially or wholly adopted welding. These concerns have on their staffs welding specialists, design engineers, and metallurgists, who are qualified to design and supervise the manufacture of welded parts, at a considerable saving to the purchaser. The steady, consistent, and sound growth of welding is based upon investigation of the fundamentals of the various processes, together with their proper application. The classification of welding processes varies in different countries. In Europe, they are divided into two main classes, namely, heterogenous and autogenous. In the former, the parts are joined, as a ruler without melting the edges, and by using as filler a metal different from that of the object welded. Such welding differs from soldering and brazing in that higher temperatures are required to effect the union of the parts. In autogenous welding, the parts are joined by melting of the edges, with or without the addition of a material similar to the parts being joined.

Jan 1, 1936

By S. Castro, L. Gutiérrez, L. Uribe

"Use of lime in seawater as a pyrite depressant decreases Mo recovery in flotation of Cu- Mo sulfide ores. When technology that uses sodium metabisulfite (MBS) to depress pyrite is applied, the process is carried out at pH 6.5–7.5, the range where Mo recovery is higher than the usual pH 11.0–12.0 when lime is applied. Redox conditions and chemical reactions involved in depression mechanisms of pyrite by MBS, or sodium sulfite, in seawater are investigated and discussed based on the acidifying effect of MBS, oxidation of sulfite ions by dissolved oxygen, and the role of catalyst of some metal cations (e.g., copper ions) adsorbed on pyrite’s surface.RÉSUMÉ L’utilisation de chaux dans de l’eau de mer comme agent déprimant de la pyrite réduit la récupération de molybdène (Mo) dans la flottation de minerais sulfurés de Cu-Mo. Lorsque l’on applique la technologie utilisant du métabisulfite (MBS) de sodium comme agent déprimant de la pyrite, le procédé se fait à un pH de 6,5 à 7,5, gamme dans laquelle la récupération de Mo est supérieure au procédé habituel utilisant un pH de 11,0 à 12,0 lorsque l’on applique de la chaux. Les conditions de réduction-oxydation (redox) et les réactions chimiques impliquées dans les mécanismes de dépression de la pyrite par le MBS (ou sulfite de sodium) dans de l’eau de mer sont étudiées et débattues sur la base de l’effet acidifiant du MBS, de l’oxydation des ions sulfites par de l’oxygène dissous et du rôle de catalyseur de certains cations métalliques (par exemple les ions de cuivre) adsorbés à la surface de la pyrite. INTRODUCTIONThe copper industry is aware of the difficulties of floating Cu-Mo sulfide ores in seawater. Molybdenum recovery is partially depressed when lime is used to reject pyrite. In plant practice, sodium metabisulfite (MBS) has been demonstrated to be the most promising option for replacing lime in seawater."

Jan 1, 2017

By E. O. Reinbold, J. H. Johnson, D. E. Keski-Hynnila

A field laboratory for use in monitoring underground mine air quality has been developed and proven in underground service. The laboratory includes two separate monitoring systems and data analysis computer programs. One is the Mine Air Monitoring Laboratory (MAML). This is an enclosed trailer-mounted laboratory capable of monitoring CO2, CO, NO, NO2 particulate matter, S02, NH3, temperature and air velocity in the mine drift. The MAML can be up to 1000 feet away from the area being monitored. The second system is the vehicle data system, mounted on the load-haul-dump (LHD) vehicle, which monitors engine speed, engine fuel rack position, exhaust gas temperature, ambient temperature, vehicle speed, CO2 concentration near the operators' breathing zone and the mode of operation of the vehicle. The two computer data analysis programs and the two field instrument systems comprise a complete Mine Air Quality Laboratory (MAQL) for underground pollutant studies. Data from the systems have been used for studying vehicle duty cycles, ventilation systems, exhaust after-treatment devices, vehicle exhaust system design and portable instrumentation. Descriptions of the laboratory are presented along with a summary of some of the experiments performed. The capabilities of the lab are discussed, along with future potential uses.

Jan 1, 1981

Up to thirty years ago, coal preparation in western Canada, except at four plants, had not included actual coal washing. The exceptions were at Nanaimo and Royston, B.C., where tub washers and wet tables were in use; at Hosmer, B.C., using. Robinson cones; and at Leitch Collieries, Passburg, Alta., using a feldspar jig. The two last named collieries had a short life and were not operating in 1920. The industry was divided, as at the present day, into two sections, steam (bituminous) coal and domestic (largely sub-bituminous) coal, the first generally supplying industrial needs and the second householcl and other heating requirements. The two sections overlap to some small degree today as prepared sizes, chiefly stoker, and briquettes, from steam coal are shipped for house-hold use, and domestic slacks are used in certain industrial plants. The .domestic operator, for reasons shown later, was not primarily concerned with actual coal washing as a phase of coal preparation, and bent his efforts to improvement of screening and loading plants, with hand-picking of coarse sizes. The bituminous operator, on the other hand, felt it necessary by 1920 to consider coal washing. When the mines were comparatively young, coal quality could be controlled to a considerable degree by selective mining, by leaving behind some of the seam or by-passing districts in a mine where the coal was of inferior quality to that in other districts. This obviously had its limitations, and so the next step was coal washing.

Jan 1, 1952

By C. T. Dzgoev, S. S. Gudkov, IRGIREDMET JSC, S. G. Schtoick, A. V. Yepiforov, S. V. Balikov, I. I. Yevtuschevich

The pressure oxidation (POX) and pyrometallurgical process comprises POX of gold containing sulfide and polymetallic lead-zinc concentrates prior to reduction smelting of POX products to generate a lead-silver-gold alloy. Refined lead and gold-silver alloys are then obtained using conventional processes. Zinc and other base metals are recovered from the POX solution. In the course of POX, zinc dissolves in the solution and lead concentrates in a solid residue in the form of sulfate compounds. Sulfur forms the major iron sulfates and jarosites. In order to dissolve sulfur and arsenic from solid residues to the solution, the slurry hot curing was carried out at the temperature of 95°C within 2 hours. After filtration of the slurry, zinc was recovered from the solution. The resulting cake was washed with water and subjected to hot alkaline treatment. After alkaline treatment, the cakes were blended with fluxes and subjected to reduction smelting to generate lead concentrate containing precious metals. This concentrate was refined to obtain refined lead and gold-silver alloy. After iron and arsenic were removed from POX solutions using sodium carbonate, zinc was precipitated as carbonate. After thickening and filtration, zinc precipitate was roasted to generate saleable zinc oxide. Using this process, the recoveries of values to saleable products were 97% Au and 95% Ag to the alloy, respectively, 91% Pb to refined lead and 5% Pb to lead and antimony alloy and 94% Zn to zinc concentrate. The features of the technology is that it has high recovery indices of precious and base metals to saleable products and can be used to process various polymetallic ore and technogenic raw materials.

Jan 1, 2016

By G. Wilson

"Satisfactory hydraulic performance of a centrifugal slurry pump is not the only design criterion. If abrasive wear exists the severity of any damage can be reduced and the life of the wearing parts prolonged by selecting the correct pump to suit the conditions of service. This paper is concerned with the design and construction of centrifugal pumps for handling abrasive solids. The wear phenomena due to the slurry being pumped and the materials used to combat abrasive, wear are outlined. The hydraulic design of the impeller and casing and their relationship to wear and the hydraulic radial and axial unbalance are discussed. The prediction of abrasive wear in pumps can not be precise, as many factors are involved - and this is the object of current research."

Jan 1, 1973

By J. K. Szymanski

"RÉSUMÉPour maintenir de bonnes performances technique et économique dans l’exploitation par chambres vides (open stope) il est primordial d’assurer un contrôle efficace des limites réelles des chantiers d’abattage. C’est pour cette raison que, de plus en plus souvent, les opérateurs miniers utilisent un dispositif de laser (Cavity Monitoring System: CMS) qui permet de mesurer les dimensions réelles de chantiers en vue de calculer principalement la dilution et les pertes du minerai ainsi que d’autres paramètres. Malheureusement, il n’existe présentement aucune méthodologie commune, qui permettrait d’interpréter ces résultats selon les mêmes critères pour faciliter d’évaluations juste et précise de la réalisation par rapport à la planification en vue d’en apporter de corrections, dans les différentes opérations minières, si nécessaire. Dans la première partie du présent article on discute les principales séquences d’exploitation utilisées dans l’extraction par chambres vides. Par la suite, à l’aide des sections transversales et longitudinales on illustre toutes les phases des travaux miniers. Ceci en vue de permettre au lecteur de comprendre mieux c’est qui peut se passer effectivement dans les chantiers d’abattage. Par après on donne les définitions générales de principaux facteurs de performance technique. Finalement, l’exemple numérique, élaboré à partir des résultats de l’arpentage au laser effectué par la mine Bousquet 2 dans un chantier d’abattage, donne les détails concernant les définitions ainsi que les valeurs de nombreux facteurs de performance technique, qui pourraient être utilisés, par après, par les opérateurs miniers dans le suivi de leurs exploitations souterraines."

Jan 1, 1997

By B. A. Zaharov, J. M. Shneerson, L. V. Chugaev, M. T. Zhunusov, A. M. Markelov, S. V. Drozdov

The main direction of research was the application of autoclave technology for the flotation concentrates or biooxidation feedstocks. The industry modernization also expects the possibility of increasing the yield of the flotation concentrate, to allow an increase in gold extraction in flotation circuit. This paper provides brief description of results obtained for concentrates with the yield of 4 and 8%, as well as corresponding biooxidation feedstocks. Technological efficiency of autoclave oxidation is shown for both concentrates and biooxidation feedstocks. The process has been evaluated on a laboratory and a continuous pilot plant scale. Gold extractions from POX discharge are ranging from 94-97% for each product, with only 5-7 kg/t cyanide consumed.

Jan 1, 2014

By Tapio Leskinen, Jouko Koskinen, Timo Nlltti, Lappalainen Seppo, Pentti Vanninen

"The Courier 300 on-stream analysis system manufactured by Outokumpu has now been in operation at five of the company's concentration plants long enough to give a reliable basis for closer examination of the benefits achieved in control of these processes. The first system was installed at the Pyhiisalmi mine at the end of 1967. Since November 1970, two analyzers have been in operation at Pyhiisalmi feeding the assay data to a process computer which controls the whole plant and does the optimization of the process. In October 1970 the Courier 300 analysis system was installed at S. T. O. LESKINEN J. KOSKINEN the Keretti concentrator of the Outokumpu mine, followed soon by installations at the Vihanti Mine in May 1971, at the new Vuonos mine in November J 971 and at t he Kotalahti mine in December 1971. Since installation of the Courier analysis systems, considerable improvements have been achieved in the control and the economy of the plants. Immediate knowledge of the changes in the process and the possibility for rapid action has resulted in evener production and higher capacity and recovery. The recovery has been increased most significantly at the Vihanti concentrator, which operates on a complex ore. Consumption of chemicals has been reduced at all concentrators. Due to the fact that process control and partly also bilance analysis are not achieved by conventional methods any more, it has been possible to reduce the personnel of the laboratories drastically. Two of the plants, viz. the Pyhiisalmi and the Vuonos concentrators, are computercontrolled. The Vuonos concentrator started operation in January 1972 under computer control from the very beginning. The Pyhiisalmi concentrator has been computer-controlled since 1970. The Courier 300 analysis system was described in detail at the AIME Centennial Annual Meeting (1971). In this paper, less attention is paid to the analysis system. Only the sampling system of the Courier 300 is described in more detail. In the development of sampling equipment, effective use has been made of the company's wide knowledge of the problems involved and the test field offered by its concentrators. The sampling equipment includes secondary samplers and six basically different types of primary samplers, with which most sampling situations can be managed."

Jan 1, 1973

By Janos de Warga

"After a short introduction to the history of the semi-conductor theory, the paper describes the principles of electron and hole flow in the semiconducting materials, the operation of the PN junction, and the rectification process in multi-layer devices (diodes and SCR's). The various methods of purification and zone-refining of the silicon are illustrated prior to the discussion on the most commonly used junction-forming processes (alloying, diffusing, etc.). Modern device fabrication and packaging operations are illustrated. Factory testing, evaluation, electrical parameters and guaranteed rating characteristics are listed. It is explained in this paper how the various device parameters affect the electrical performance of the finished unit and how the finished unit characteristics (turn-on, turn-off time, etc.) will influence the equipment rating. In concluding, some typical items of equipment are highlighted, and the applications of these semiconductor rectifiers in the chemical, mining, pulp and paper, and steel industries, etc., are dealt with."

Jan 1, 1967

By A. S. Dawson

Introduction The purpose of this paper is to discuss, in a general way, the application of geological principles in the exploration for, and development of, deposits of industrial minerals. Mention of geological factors pertaining co specific minerals will be by way of illustration only. Since many prospectors are little acquainted with the geological setting and mode of occurrence of deposits of these minerals, some prospecting possibilities in the field will be pointed out. Geology is a tried and proven tool in the search for and exploitation of metalliferous deposits and of oil and gas fields, but, so far at least as Canada is concerned, only very rarely has a directed, intensive search been made for deposits of industrial minerals. Examples might be cited, however, where, in other countries, such investigations have yielded rich rewards. Thus, development of the vitally important potash deposits of New Mexico was the result of a deliberately planned programme of geological investigation, first by United States Government agencies, and later by private interests. War or the threat of war, or peace-time industrial expansion, can render concentrated exploration for specific minerals desirable or even essential. Such exploration is, primarily, a geological problem. Admittedly, there is in general less scope for the application of geology in the search for, and development of, deposits of industrial minerals than of metalliferous minerals, oil, etc. Where the latter are concerned; the objective of exploration is to find a material that is valuable, within broad limits, no matter where it is located or how it occurs. The unit value of the material is limited only by the amount of the valuable constituent in the formation- its possible upper limit is tremendously high. On the other hand, many industrial minerals constitute in themselves 90 per cent or more of the formation- their amount cannot increase and their unit value is commonly low. Moreover, for commercial exploitation, the deposit must, in general, be reasonably close to markets or to plant or other facilities for processing the raw material, since, owing to its low value, this cannot be transported any great distance. As a consequence, intensive geological search for and investigation of such deposits has been restricted to industrialized areas. Obviously, however, it is good insurance for any operator to understand the geological background of his deposit, particularly in the case of new developments.

Jan 1, 1949

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By Rejean Gagnon, Fernand Rochefort

"Haulage costs, in most operations, represent a large portion of total cost. Quebec Cartier Mining Company came to the conclusion t hat an electric trolley assist providing more horsepower than available from dieselgenerator sets presented the best oppor tunity for improvement. Accordingly, a testing and development program was carried out which resulted in the design, installat ion and application of a practical system. This paper describes the development of the system, the equipment used as well as the actual operation. A projection is also made to indicate further improvement in productivity. A comparison is made of truck operating data before and after activation of the trolley assist system in order to determine its economic impact."

Jan 1, 1972

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a' very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948