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By Michel Ruel

"PID loops – also known as base layers or regulatory controls – form the foundation of any plant’s control layer and it is generally accepted that PID loop health has a direct impact on the plant’s bottom line. Keeping these thousands of control loops in good health has a direct impact on the plant’s bottom line: it reduces variability, improves quality and throughput, and decreases energy costs and raw material usage. This has been well proven and documented in many articles. In the last ten years, technology has evolved: control engineers can now keep track of control loop performance and link it to the root causes of variability. However, they lack industry-wide best practices and criteria for determining what can be considered as excellent, good, fair, or poor performance. To ensure that PID control loops continue to perform well and meet their objectives, control engineers need a combination of (a) an appropriate monitoring technology and (b) best practices for doing the maintenance of base layer controls.Most plants have limited resources and operate with an increasing number of constraints; therefore, using the right tools and including reports in daily workflow is key for success. This paper suggests roles and responsibilities of key players needed to work toward control performance best practices and discuss organisational changes to succeed.INTRODUCTIONAlthough PID controllers are reliable workhorses in the process industry, they are often underrated. Since the 1980’s, computer control has evolved and the control algorithms used by control engineers have become increasingly complex. However, PID controllers still handle over 90% of the control loops in operating plants. Table 1 shows the savings that can be realized by achieving best-practice in several different process control categories (Brisk, 2004). The savings are expressed as a percentage of production costs."

Jan 1, 2011

By B. St. Pierre

"The alchemists' symbol for antimony is a diamond with a dot in the centre. The latin name ''stibium'' gives this mineral its chemical symbol ""Sb"" and the name to the principal ore containing antimony. This is Stibnite, a sulphide of antimony, and the valuable mineral at the Consolidated Durham operations. Stibnite chemically pure contains 71.69% antimony metal.Antimony is used in many forms, as an alloy in the production of metal products and as chemical compounds of oxides and sulphides. In Biblical times, antimony was used as a medicine and as eyebrow makeup.Today, the largest single use of the metal is as a hardener and strengthener of lead, and corrosion inhibitor in storage batteries. New applications for antimony in its oxide form as fire retardants are broadening the overall demand especially in the chemical, plastic and fabric industries. Other users include the Military for such things as tracer bullets, shrapnel, smoke screens and flame throwers. An unusual property of the metal is that it contracts when heated which has made it a valuable alloying metal in the printing industry, for heat shields on re-entry vehicles used in the space programmes, and also for the manufacture of bearings."

Jan 1, 1977

By D. M. Doyle

"In this paper I will summarized the Falconbridge Nickel Mines1) energy costs and consumption data by fuel, process, cost centre and estimate our future costs and consumption patterns 2) detail the distribution of electrical energy 3) distribution of other forms of energy 4) describe present and planned energy conservation schemes; and 5) discuss economic justification and responsibility.There is sufficient material in this presentation to warrant several technical papers, however we felt that an overview of all our data and endeavors on the subject, would be most beneficial to those companies formulating energy conservation plans. The data briefly referred to in this slide presentation can be found in the technical paper.Over a five year period, total energy costs will vary between $63 and $94 MM depending on the future rate of energy cost escalation. An unrealistic 32% reduction in energy consumption is required to hold our own in the years ahead whereas an attainable 10°;, reduction in energy consumption would save $9 MM over this five year period.Total energy consumption, tonnage of ore delivered to plants and their ration BTU’s per ton of ore, are graphed for the years 1973 through 1976 and forecasted for the 1980’s. In 1974 we along with other member companies of the Mining Association, determined our purchased energy per ton consumption rate and set, as our goal, a 20% reduction by 1980. The dotted lines calculated from the energy audit, based on 1976 data shows there is a potential for a 10% increase in energy per ton. This could result from a lower than forecasted mining rate and operation of the new roasting, electric furnace and acid recovery facilities installed for environmental considerations at designed capacity."

Jan 1, 1978

By P. Fossi

This report describes a pilot-scale study of a hydrometallurgical process to treat high-grade nickel matte or a nickel-cobalt sulphide precipitate to produce high-purity electrolytic nickel. The first step of the process is the oxidative leaching of the nickel-bearing material by nitric acid; the nitrous gases generated during leaching are reconverted to nitric acid. The crude nickel sulphate nitrate solution is purified and is then subjected to a denitrification step. Nitrate separation is effected either by the crystallization of nickel sulphate or by precipitation of basic nickel carbonate. The electrolyte is prepared from the nitrate-free material and nickel is then recovered by electrolysis of the sulphate solution using insoluble anodes. Some technical and economic problems encountered with this processing route are discussed and the method is compared to the "all-chloride" process developed by Société Le Nickel.

Jan 1, 1977

By Joseph J. Mgumbwa

Pillars are any structures left between two or more underground openings. The stability of pillars is normally considered to depend on shape (defined by width to height ratio), rock mass strength, extraction ratio, in situ stresses and the gross structural features (i.e. joints, contacts, faults etc). Recent experience has shown that pillar stability is also controlled by the relative orientation of the orebody with respect to the in situ principal stress. In inclined orebodies, pillars are loaded in compression and shear, thus creating unsymmetrical stress distribution. Failure mechanisms of these pillars are little known. This paper investigates the failure mechanisms of pillars under shear loading. Two dimensional elastic numerical modeling was used to examine the behavior of pillars in different orebody inclinations relative to the major farfield stress orientation. First, the paper reviews pillar design approaches including the empirical pillar design chart and uses numerical modeling to investigate the effect of the major farfield stress orientation on pillar stability. It is concluded that the empirical pillar design chart be used with caution, and that for orebodies under shear loading mine planning and design should take this into consideration since such geometrical orebody/stress relations put mine structures at higher risk of instability.

Oct 1, 2010

By J. R. Goode

"The Las Cristinas deposit contains about 10.2 million ounces of gold at a grade of 1.3 g/t. The deposit comprises a layer of fully oxidized saprolite (SAPO), a layer of sulphide-enriched saprolite (SAPS), carbonate leached bedrock (CLB) and carbonate stable or un-leached bedrock (CSB). Gold occurs at about the same level in all lithological groups. The bedrock units contain minor amounts of copper (about 0.1%) as chalcopyrite, while SAPO contains virtually no copper it having been leached and deposited in the SAPS zone.A previous owner started investigation of the Las Cristinas deposit in Venezuela in 1991. Over the next seven years, 1174 holes with a total length of 159 km were drilled, extensive metallurgical testwork, including pilot plant operations, were conducted and feasibility studies were completed. Construction was started in 1997 and again in 1999 but was suspended.Crystallex has been producing gold in Venezuela since the early 1990’s. In 1997, Crystallex acquired Inversora Mael which had held two of the claims to the Las Cristinas concessions since 1986. In September 2002, Crystallex entered into a definitive agreement with the Corporación Venezolana de Guayana, (CVG), to develop the Las Cristinas deposit.An extensive program of studies and testwork was started in early 2003 to determine an optimum development plan for Las Cristinas. Mine Development Associates, SNC–Lavalin Engineers and Constructors, SGS Lakefield Research Limited, J.R. Goode and Associates, and Professor A. Laplante at McGill University acted as the main contractors.Because of the potential value of by-product copper, earlier flowsheets used carbon-in-leach for SAPO, but processed all other ore types by flotation to produce a gold-copper concentrate with cyanide leaching of cleaner tailings to maximize gold recovery. Cyanide recovery was necessitated by the high copper content of the leach feed. Initial studies of available data by Crystallex revealed that direct leaching of all ore types would provide about 11% more gold recovery than the previously selected flotation route with reduced capital and operating costs.Bench and pilot scale studies have confirmed that a SAG-ball mill-gravity-CIL route is very effective for all ore types and will give about 89% gold recovery. This paper describes the recent testwork, discusses the proposed plant design, and presents economic data."

Jan 1, 2004

By Beaumier. M., J. -P. Lalonde

"Les réultats obtenus dans les sols sur quatorze aires d'essai et six cheminements régionaux dans I'A bitibi-Témiscamingue indiquent clairement qu'il existe des variations régionales importantes dans les teneurs en éléments traces de l'horizon A1 formé sur l’épais recouvrement glacio-lacustre de cette région. Les anomalies obtenues correspondent à celles qui ont été décelées lors de précédents levés des eaux souterraines et du till de base.Selon les critères d'évaluation utilisés, treize des quatorze aires d'essai ressortent comme anomales dans Ie contexte abitibien; dix de celles-ci sont tres anomales. Ceci suggère fortement qu'un levé régional de sols, fondé sur une approche multi-éléments, identifierait entre 70 et 90 % des cibles géochimiques reconnues par des échantillonnages en profondeur. Les résultats d'un échantillonnage systématique effectué sur une région de 1000km2 viennent aussi appuyer cette hypothèse. Conséquemment, les sols formes sur les sédiments glacio-lacustres sont un médium très utile pour inventorier de grandes regions recouvertes par ce typ e de sédiments.L 'horizon A1 est Ie plus utile pour ce type de levé parce qu'i1 est facil e d échantillonner, qu 'it assure une plus grande constance du typ e de matériel échantillonne et qu'il contient des teneurs accrues.De multiples mécanismes de dispersion géochimique ont joué des rôles d 'importance variable pendant et après la mise en place des sédiments glacio-Iacustres. Les plus importants sont la pression hydrostatique, la diffusion chimique et électrochimique ainsi que la bio-accumulation. Si on veut progresser dans la connaissance de ce milieu complexe, on devra adopter une approche plus systemique tenant compte de I'interaction des mécanismes agissant dans l'environnement global avant, durant et apres Ie depôt du mort-terrain."

Jan 1, 1984

By Hongfei Li, JianLong Wang

This paper introduces the technical characteristics, transformation scheme and production practice of the project in which Copper P-S Converter was replaced by Bottom Blowing Continuous converting for the first time, and introduces the technical achievements obtained by the project. The application practice proves that bottom blowing copper continuous converting technology can completely solve the problems of fugitive off-gas pollution in the ladle transportation, large amount of flue gas and fluctuation of flue gas caused by P-S converting. Comprehensive energy consumption and operating costs of producing blister copper, safety and environmental risks are greatly reduced, and economic, environmental and social benefits are significant. It is one of the preferred technologies for upgrade and to replace P-S converting technology. INTRODUCTION At present, more than 80% of copper production capacity is still using the P-S converting technology with a history of more than 100 years. During P-S converting process, melted copper matte needs to be transported by ladle, and it needs to rotate the furnace body several times, causing a lot of serious environmental and safety risks such as SO2 flue gas emission and low-altitude SO2 pollution. In addition, the high operating cost caused by low rate of air blowing, the short life of the refractory materials and high energy consumption during P-S converting become big problems. Other problems such as large amount of flue gas, low SO2 concentration, large fluctuation of flue gas volume and SO2 concentration, and discontinuous flue gas cause high cost of subsequent flue gas treatment are also needing to be solved. In order to solve these problems during the P-S converting, metallurgical engineer in various countries has spared a lot of efforts to develop continuous blowing process for decades. The continuous converting that have been industrially applied are flash continuous converting, Mitsubishi continuous converting, Noranda continuous converting, Bottom Blowing Continuous converting and multi-lance top blowing continuous converting

Jan 1, 2019

By David R. Skuse, Jacek A. Kostuch, Steven M. Fortier

"Particulate ground calcium carbonate (GCC) is used as a filler and coating pigment in a wide range of applications including papers, paints, plastics and films. In this paper we will overview the requirements for GCC used in both filling and coating applications in the paper industry and highlight the processes used in the production of these materials.INTRODUCTIONCalcium carbonate is both abundant and very widely distributed occurring most commonly as limestone, marble and chalk (Harben 2002). Given, the high purity, whiteness and relative inertness of these materials it is not surprising that they are heavily utilised in a range of industrial applications. Worldwide ground calcium carbonate (GCC) capacity is estimated at 50.5 million tonnes per year (Roskill, 2002). This usage is divided between relatively coarse materials that are used in applications such as landscaping, cultured marble and carpet backing and finer grades that find application in plastics, rubbers, inks, paints and paper. Given the usage of calcium carbonate products across a very wide range of consumer products, the outlook for GCC is very promising with growth expected in many markets. Growth is anticipated across many applications in the emerging nations and more specifically in paper applications on a global basis.Over the last several decades the GCC processing industry has evolved to be well adapted to both the cost effective production and delivery of standard products and the production of high performance speciality products. Many of the standard unit operations found in the metaliferous raw material processing industry are also used, albeit in some cases in modified form, in the processing of GCC. Coarse products (diameter > 3 - 10 µm) are typically produced by dry processing routes. Whereas, the finer products are typically produced by a combination of wet and dry processing."

Jan 1, 2004

By D. M. Doyle

"A study of the various components contributing to energy costs and their relationships to generally trended operating data, such as tonnage, operating costs, etc. over progressively shorter time periods provides information for an energy audit. A study of annual data gives some insight into the importance of various energy components. As the time frame of the study 11rogresses through monthly, daily and finally, into quarter hourly data, the variations become more evident and most important, strategies develop to minimize energy costs. The results of an audit conducted during the summer of 1978 at Wesfrob Mines are reported to illustrate this important phase, prerequisite to a meaningful energy cost avoidance program.The balance of the paper deals with the energy conservation program at Falconbridge Nickel Mines Sudbury Operations, the material and control equipment, the commitment, the new energy accounting practices and lastly, the policies. Examples of successful energy conservation endeavors include automatic peal electrical load control, waste heat recovery from mine air and compressor cooling water, energy reductions resulting from lower building temperatures and curtailmen: of idling loads. The use of pulse meters to measure the flow of gas, steam, compressed air and electrical energy, with their signals interfaced to process computers, allows monthly, daily and if necessary, immediate reporting of energy and energy per unit of production information. The program so reported at Falconbridge’s Sudbury Operations is credited with an annual cost avoidance of .9 million dollars in a 14.0 million dollar annual energy account."

Jan 1, 1979

By Kim Le Roux

Cemented paste backfill (CPB) is a relatively new material that is increasingly being used in open stope mining across the world. The advantages offered by this high density tailings backfill include: a lower total cost associated with backfill placement, reduction of excess water underground; and the elimination of the need to process the tailings prior to placement. However, almost all backfill design is based on the performance of laboratory prepared samples since it is difficult to obtain undisturbed samples and conduct in situ testing due to the lack of access to backfilled stopes and the safety concerns in accessible areas. The logistical problems associated with conducting in situ testing and obtaining undisturbed samples of cemented paste backfill (CPB) has lead to the reliance in the mining industry on performance data obtained from laboratory prepared CPB samples. The degree to which these laboratory prepared samples represent the actual in situ condition is not well defined, partly because the influence of the mixing, transport and placement process on the material properties it is not well understood. Therefore, there is a need in the industry to understand how the material properties and hence the performance of the laboratory prepared CPB compares with in situ material. This paper reports the findings of an investigation into the in situ properties of CPB at a gold mine in Northern Ontario. A combination of in situ and laboratory testing, conducted on undisturbed samples, was used to quantify the in situ properties and performance of the CPB. These results were then compared to those of a laboratory based investigation of the same CPB. It is evident from this investigation that the bulk properties of the in situ CPB are different from those of the laboratory prepared CPB. The most significant observed differences are that the in situ CPB has a higher void ratio and a lower degree of saturation than the laboratory prepared material. The implication of these differences on the stability and performance of the CPB will also be explored in this paper. 1

May 1, 2002

By I. Jackman

"Gold is present in different forms and associations in different ores. Flotation is used to recover gold and minerals associated with gold, but the applicability and type of flotation vary. The purpose of flotation in a gold recovery plant is largely dependent on the mineralogical association of the gold, and environmental and economic considerations. In this paper, the role of flotation in the recovery of gold is reviewed. The paper will describe examples of gold recovery by flotation including flotation of native gold, gold associated with sulphides including specifically copper sulphides, gold associated with tellurides, gold ores containing carbonaceous material and gold contained in tailings.INTRODUCTIONFlotation is widely used in the recovery of gold. However, the objectives and the mode of application are quite variable dependent on the type of ore, the gold association(s), other metal values, marketing considerations and environmental requirements. In this paper, a range of different applications of flotation incorporated in the recovery of gold are discussed. The reasons for each particular application are outlined and metallurgical results are presented.The mineralogy of the ore and the gold associations are fundamental influences on gold recovery. The use of flotation to concentrate gold is dictated by the mineralogy of the ore and gold. The fundamental factors are mineral/gold size, liberation size, association of the gold and type of gangue minerals or other valuable minerals. Gold can exhibit a range of sizes in a host from relatively large size (+50 µ) to refractory size (1 µ and sub-micron size). Similarly, the gold can occur in a number of phases in the same host. For example, the gold was present as petzite (AgAu telluride), calaverite (AuTe2) and native gold in a gold telluride ore and each of these minerals was associated with the pyrite host.Understanding the gold mineralogy and association is important in establishing the correct process route. The gold mineralogy is established by good mineralogy, use of diagnostic tools such as diagnostic leaching and assay by size fraction analyses and basic metallurgical testwork."

Jan 1, 1995

By Leonard Kellogg

Introduction The Mine Manager or Superintendent is a man faced with a difficult problem. He must direct the activities of his mine in such a manner that, over a period of time, the greatest possible profit will be realized. In this respect, a mine is no different from any other business organized for profit. What makes the mine manager's task so difficult then? The profit of a mine is determined by -among other things -the grade of ore, the market price of the metal or metals produced, and the cost to operate the mine. The mine manager cannot do much about the first two of these, but he has considerable control over the operating cost. This cost will depend in large measure on the nature of the programme on which he plans to operate his mine. This operating plan may be broad or specific, on a long-range basis or on a month to month basis. The development of the plan, however, is made very difficult by the existence of so many factors which must be considered. These may be (1) factors requiring decisions based on the best judgment and interpretation of engineering and geological information available, or (2) items which must be considered but which are largely non-controllable. To be more specific, examples of such items would be: (1).-(a) The amount and type of development work to be done in relation to amount of ore to be mined. (b) Mining methods to be followed and type of equipment to be used. © Amount of exploration diamond drilling to be done if the orebody is not clearly defined. (2).-(a) Rock type and degree of hardness. (b) Width, depth, and pitch of veins. © Amount of work requiring timbering. (d) Faults encountered. (e) Water and gas conditions met with.

Jan 1, 1952

By K. H. B. Wenzl

"Since the autumn of 1973, the world's attention was captured by the startling revelation that conventional energy supplies were not inexhaustible but were in fact quickly dwindling with future shortages imminent until lagging exploration and technology yielded additional energy sources to catch up with the spiralling increase in demand. This situation was precipitated by the Arab Oil Embargo and the resulting soaring cost of world crude oil.During the past few years there has been tremendous activity in the energy field which has had a direct impact on the Inca Metals Company Ontario Division operations. The company's reaction has been to establish an energy management program which will be described later in the paper. First, a brief description of the Inca Metals Company and the primary energy resources which are utilized will assist in putting the program into perspective.The Inca Metals Company, a unit of Inca Limited, is responsible for the production and sale of primary metals products worldwide. The company's operations in the Sudbury District include mines, ore concentrating plants, a Smelter, Nickel and Copper Refineries and an Iron Ore Recovery Plant. The Ontario Division also has a mine and concentrating plant in Shebandowan near Thunder Bay, and a metals refinery at Port Colborne. Inca is the largest producer of nickel in the non-communist world and is also a major producer of copper and platnium group metals."

Jan 1, 1978

By L. K. Walker, G. A. Kosick, P. D. Young

"MillEX is an information management system designed by mineral processors for mineral processors. The system utilizes ""cutting edge"" software technology to gather and store all automatically and manually recorded data from the plant operation and laboratories. This data is delivered to the desk of superintendents, metallurgists, technicians and managers, and permits the user to query, correlate, graph, report and present this data in minutes. In the past this task would have taken days and even weeks of tedious work to complete.MillEX allows the engineer/analyst to quickly develop a very thorough understanding of the complex relationships of process variables and equipment that exist in the plant, and their effect on product quality and quantity. The time and resources that are currently wasted on duplicating data entry will be an effort of the past.This paper describes the structure of MillEX and how it conforms to the needs of mineral processing personnel.INTRODUCTIONPicture a personal computer on your desk which will carry out the following commands:1. Plot a graph over the last six months, using weekly averages, of percent minus 200 mesh material in the primary cyclone overflow.2. Overlay this graph with a graph of concentrate grade versus recovery over the same time period.3. Retrieve a prior month end report, update all operating supplies tables and metallurgical performance with this months data, and embed the graphs created above.4. Edit text and print the current month end report. This is only one example of the type of power MillEX isbringing to the mineral processing industry."

Jan 1, 1992

By A. Himsley

"There is an ever-increasing demand these days for efficient methods of removing metals from solutions especially for selectively recovering a particular metal from a mixture of metals in solution.Up until the mid l 930's the only methods widely practiced for such separations involved precipitation techniques or electrolysis. Both these methods have limitations and indeed can only be used for certain metals.It is only within the last 40 years or so when synthetic ion exchange materials became available that chemists in industry and universities have been able to apply ion exchange techniques to a wide variety of separations that not only would be impossible by precipitation methods but which are now achieved with much greater efficiency.Ion Exchange TechniquesIon exchange is a unit process that can be applied using either liquid ion exchangers or solid resin particles. Liquid ion exchange - or solvent extraction as it is often referred to - is used in a number of special areas dictated mainly by the nature of the separation.On the other hand, ion exchange resins are much more widely used and consequently a great deal more is known about their application to a variety of metal separations.In both systems there is a loss of the ion exchange material which in the case of solvent extraction results in hydrocarbons going to waste. The ion exchange resin systems lose resin in the form of small particles, referred to as ""resin fines"", and these are insoluble.The loss of liquid ion exchanger is due to the fact that it is slightly soluble in water and consequently the loss is a function of the volume of liquid with which it comes into contact and is not related to the amount of metal processed."

Jan 1, 1975

By James F. Archibald

In historic mining practice, typical thin liner support systems have been considered to comprise non-reinforced or mesh-reinforced shocrete linings. In the early 1990?s, development of alternate forms of liner systems was initiated in Canada which is now undergoing significant international growth in countries which sustain major mining activity. Now internationally designated as thin, spray-on liner systems, a wide spectrum of liner materials, ranging from liquid/liquid to liquid/solid component combinations, has become commercially available. This innovative family of products is characteristically identified as being rapidly deployable, capable of creating ultra-fast setting coverage over rock surfaces, and able to develop tenacious adhesion and pull strength capacities for resisting rock falls and movements. This paper presents a summary of current liner developments and use in principal mining districts world wide. Additionally, a database of material properties for principal product types used in mining and a review of common quality control testing procedures under development are provided. Such information is based upon recent Canadian and international efforts being taken to assess and develop user standards for the implementation of thin, spray-on liners as rock support in mines. This work is intended to continue for a period of years, with the eventual goal being to establish support and installation guidelines for mines based on quantifiable laboratory and field research.

May 1, 2002

By Jr. Blanchette, Claude Bazin, Paul Blatter

"Reporting of the gold production during a month implies to estimate the mass of gold that is processed by a mill, recovered as dorés, lost to the tailings and the change of gold inventory within the plant equipments. Carbon in pulp and/or carbon in leach tanks may contain gold inventory as large as 72 000 g (2 200 troy oz) of gold which needs to be estimated from measurements obtained from sampling the material contained in a tank. Sampling and analysis introduce measurement errors that could be systematic and/or random. This paper examines the effect of measurement errors on the estimation of the gold inventory and on the variation of the inventory in the carbon in leach tanks of the Agnico-Eagle Mines Limited Lapa concentrator. Results of the analysis demonstrate that the inventory is measured with ±10% reproducibility, while the variation of inventory used for mass balance is known with ±300% reproducibility.INTRODUCTIONThe preparation of a production report implies to reconcile measured data with the constraint of material balance over the considered period of production. The sampling and data reconciliation problems were recently reviewed by Morrison (2008) and Jansen (2009a; 2009b). Typically a production report is prepared to cover a period over which the mass conservation hypothesis can be considered valid. In gold processing plants, the change of inventory can seldom be neglected and plays a significant role in material balance calculations. This is particularly true for circuits using carbon adsorption, where the complete cycle of carbon is measured in days.In a 2000 t/d gold ore processing plant, the inventory can be as large as 140 000 g of gold in gravity concentrator bins, carbon in pulp tanks and in the electrolysis circuit. This is equivalent to the mass of gold that fed the circuit during 10 days of operation with 7 g/t feed assays. The change of inventory may therefore strongly impact the production figures and especially the plant recovery at the end of a week or a month. Despite the financial impact associated with gold inventory, few publications are devoted to the subject. Bruington (1991) and Morrison (2008) discussed the problem and stressed the need for the development of reliable methods to estimate the gold inventory in carbon in pulp or carbon in leach circuits."

Jan 1, 2011

By Stephen L. Chryssoulis

"""Preg-robbing"" of gold by carbonaceous matter during the cyanidation of certain types of carbonaceous gold ores is well documented. Recent studies established that ""preg-robbing"" of gold is not limited to carbonaceous matter. Gold sorbed on the surface of pyrite grains was detected and quantified by TOF-LIMS (Time of Flight Laser Ionization Mass Spectrometry). Crystallites of pyrite from a number of ores from different geological environments have been shown to have gold on their surface apparently sorbed from the ore forming solutions. Surface gold accounts for significant fractions of the gold head assay. Preg-robbing of gold by pyrite from pregnant cyanide solutions was also documented, and accounts for significant losses to tailings. Preventative measures are discussed.1.0 IntroductionThe detection and subsequent quantification of gold sorbed on the surface of pyrite particulates came about during routine determinations of the deportment of gold employing the comprehensive mineralogical approach (Chryssoulis and Cabri, 1990). In some pyritic gold ores it was discovered that the sum of the various forms in which gold ""conventionally"" occurs, was short of the gold assay. The mineralogical procedure used involves the independent determination of each fraction of gold, in other words there is no form of gold which is calculated ""by difference"". The systematic shortfall after having added the forms of gold listed in Table 1 led to the inquiry for the 'missing' gold and its discovery on the surface of pyrite grains, such as crystal facets and fractured surfaces.Preg-robbing of gold by pyrite from pregnant solutions was first described by Lloyd. In his studies, preg-robbing was measured by changes in the solutions/solids gold assays. This paper describes the first application of a direct measurement method for surface gold on pyrite particles from untreated and processed samples, its impact on gold deportment and processing. The advantage of the direct measurement lies in the absence of interference from other forms of gold, leading to more accurate and precise determinations of this unconventional form of gold."

Jan 1, 1997

By Jessica Egan, Daniel Hodouin, Mohammed Reza Khalezi, Steve Bellec, Claude Bazin, Carl Duchesne

"A model for gold leaching was developed and implemented into a simulator. The simulator uses a description of the ore that is based on the mineral composition and precious metal content. The model accounts for the distribution of minerals and precious metals through the size intervals. An ore texture model based on precious metals and minerals grain sizes within the ore is used to predict the exposed surface of the species in the various size intervals. A model is proposed to predict the rate of dissolution of any species dissolution using the exposed surface, particle size, cyanide and oxygen concentrations, temperature, pH and agitation. The flow of slurry through a leaching tank is modelled using a parallel arrangement of perfect mixers to simulate a bypass and a Cholette-Cloutier mixer model. The simulator can be used for circuit optimization but was developed to provide an environment for learning the basic concepts of process analysis methods. Examples are given to illustrate the application of the simulator for planning tracer tests and sampling campaigns.INTRODUCTIONThe constant pressure to improve the operation of processes that are already close to optimum imposes to plant engineers to be aware of the available process analysis tools and to be able to use them to assess process operation and make a diagnosis to possible problems. Some of these tools are:•,Sampling the streams of a process;•,Data reconciliation;•,Analysis of mixing in reactors;•,Estimation of rate parameters;•,Optimal tuning and flow sheet modification;•,Automatic control and real time optimization.Although some of these tools are part of the curriculum of many university engineering programs, the students are not exposed to actual process analysis problems. In addition the complexity of the ore dressing processes compounded with unavoidable measurement errors and plant disturbances can discourage many motivated engineers. These factors often lead to an incomplete valorization of the collected data and a poor return on the investment associated with the sampling, testing and analysis of the samples.Simulators are readily available for process optimization (Yalcin and Shang, 2006) by allowing:•,The simulation of various flow sheet configurations;•,The simulation of a change of operating conditions;•,The simulation of various control strategies;•,The training of plant operators.However few simulators have been developed with the objective of providing an environment for training plant engineers and technicians to the use of tools for process analysis and optimisation."

Jan 1, 2008