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By B Chappell

Backfill in the form of mine waste tailings has inherent problems associated with attaining adequate strengths upon placement. Fines are usually removed to ensure adequate drainage, which lowers the cohesive strength of the fill, leaving the fines to be placed in a tailings dam. Electro-drainage and electro-chemical grouting is examined to investigate its effects on densification and shear strength within a silty clay tailing having low permeability and shear strength. Two separate grouting mechanisms are observed for the iron and silica grouts used. Electroosmosis is associated with iron grout that deposits within the tailing matrix under a converging pH gradient, and increases the permeability of the tailing. This process initiates cation exchange and causes cementing of the granular contact points between the clays. Electro-phoresis causes sodium silicate solution to deposit silica grout in the voids of the tailings. The resultant effect of these mechanisms results in an increase in cohesion, leaving the void ratio of the iron grouted tailings as it was but significantly reducing the void ratio of the silica grouted tailings.

Jan 1, 1998

By Ennis P. C

The Mt Keith ultramafic intrusive extends for about 200 kilometres from Agnew in the south to Wiluna in the north. It forms the host for a number of nickel sulphide orebodies including Mt Keith and Honeymoon Well. Long fibre minerals are associated with the orebodies. The presence of these minerals impacts on the issue of tailings disposal from several standpoints, particularly the slurry beaching properties and dust generation from dry beaches. Central thickened discharge (CTD) is an innovative method of tailings disposal that involves stacking tailings in a low conical hill instead of storing them in cells. In appropriate circumstances this leads to savings in capital costs and operating expenditure. The method was introduced to Australia in 1981, and is currently employed at four operating mines, Elura and Peak Gold, both at Cobar in NSW, McArthur River in the Northern Territory, and Union Reefs near Pine Creek, also in the Northern Territory. It is the proposed method for Century Zinc and Ernest Henry, both in Queensland. The paper describes laboratory test work and design parameters for the application of the method to tailings disposal at Honeymoon Well and compares them with comparable data for other CTD systems. Of particular relevance for design purposes are beach slope, density, and water recovery. Wind tunnel tests were conducted on the Honeymoon Well tailings samples to investigate dust generation from the dry beach surface and it was concluded that dust generation from an undisturbed beach would not occur because of crusting.

Jan 1, 1996

By White A. H, Vihena M. T M B

Presently, orebody modelling consists basically of fitting a mathematical model to represent spatially a certain geological variable, generally grade. An orebody model is constructed from a set of sample data obtained from various locations in the orebody, thus it is only one form of representation of the true phenomena. Checking the compatibility of the data with the modelling procedure is the most important factor when assessing confidence in the orebody model. The level of confidence in the model will depend on the adequacy of the data set and the validity of the basic assumption required by the modelling method. Fractal geometry is one way of modelling the spatial distribution of a geological variable in an orebody geometry. Fractals can be used to interpolate the Z(x) geological variable at unsampled sites. The concepts of self similarity and self affinity that form the basic assumption of fractal geometry theory which areinvestigated. The population distribution of the geological variable in question must be examined to determine the appropriateness of both fractal geometry and geostatistical modelling methods. The selection of the most appropriate method depends on the available data. A researcher or a practitioner needs to understand the strengths and limitations of the various modelling methods before choosing the most appropriate method. This study investigates the fractal properties of grade distribution using the variogram and some proposed variations as techniques to measure the fractalness. The aim is to assess applicability of fractal geometry theory to modelling ore grade distribution in a deposit. A comparison of the results demonstrates the methods which better capture the spatial behaviour of the variable under study.

Jan 1, 1995

The narrow quartz vein deposits at Konongo and Ghana Main Reef gold mines in Ghana were emplaced during the plastic flow cross folding of pre-existing sub-isoclinally folded volcanic and perivolcanic deposits of Proterozoic age. The older fold structures tightened differentially according to their position in relation to the axes of the cross fold pattern giving complex outlines to the reefs in both plan and cross section.Some 4500 measurements of bedding plane linears were used in the resolution of the Boabedroo footwall structure at Konongo. The methodology developed at the Boabedroo mine was then successfully applied to other complex bodies at the Konongo and Ghana Main Reef mines.All mine development, especially stope preparation, of the folded quartz reefs at Konongo and Ghana Main Reef was controlled by the geologist to ensure that the veins were removed with as few geologically enduced hiccoughs as possible.

Jan 1, 1993

By Wilson AC

Permian coal from Western Australia's only producing coalfield at Collie is the dominant fuel used in generating electricity for the State's interconnected grid. Collie coal is sub-bituminous, non-coking and has a low ash, medium volatiles and high moisture content. The seams were laid down in a fluvial basin which extended beyond the Collie Basin and included the Wilga and Boyup Brook Basins at least. Adjacent parts of the southwest Yilgarn Block are prospective for Collie-type basins. In the past few years significant deposits have been delineated within the Perth Basin, specifically on the Vasse Shelf and in the Hill River area. In the former area high quality steaming coals are correlated with the lowest coal bearing member at Collie. The seams are amenable to underground mining and because of their high quality, the coal may have export potential. Sub-bituminous coal deposits of Jurassic age are present in the Hill River area. Exploration has down-graded the prospectivity of the Carnarvon and Canning Basins for sub-bituminous near-surface coal deposits. Tertiary lignite deposits are present in palaeo-drainage systems in the southern part of the State and their potential for development is being evaluated.

Jan 1, 1986

By Quan P. M

The great advances made in the application of solvent extraction to the recovery of copper from low grade ore sources over the past 15 to 20 years are well known. Solvent extraction is an essential step in the recovery and purification of copper from dilute sulphate leach solutions by which some one million tonnes of copper are now electrowon annually. A reagent is also available for the selective recovery of copper from chloride leach solutions and this may hold the key to the processing of complex sulphide ore concentrates. By comparison, the use of solvent extraction in the recovery and processing of zinc has as yet found little favour and is confined to only a few specific and comparatively small applications. This is despite the ready availability of a large number of low grade zinc sources and zinc-bearing wastes and residues. It is suggested that this difference is due in large part to the absence of suitable reagents having the particular features required to enable them to fit into a solvent extraction - electrowinning based process for zinc. Ideally, for the recovery of zinc from dilute sulphate solution, an extractant should operate on a proton exchange principle and be strong for zinc in the same way that o-hydroxyaryloxime reagents are strong towards copper. It should load efficiently with zinc at the pH of typical sulphate feed streams without the need for neutralisation and yet be stripped efficiently by spent zinc electrolyte. Another factor of major importance for many applications, however, is that it should be highly selective for zinc over ferric iron. These features have now been realised in a development extractant DS5846, which is a formulation of a novel class of reagent currently under investigation by Zeneca Specialties. The properties of this reagent are described with respect to selectivity, isotherms and how they compare with phosphoric and thiophosphoric acids that have been previously proposed for the extraction of zinc. For the recovery of zinc from concentrated chloride solutions a solvating or neutral donor type of extractant is required which again should ideally have high selectivity for zinc over a number of other metals, particularly iron. The new reagent Acorga ZNX50 is based on a formulation of a novel class of compound developed specifically for this purpose. It gives efficient extraction of zinc from feed solutions that are four to six molar in chloride ion but is readily stripped at 60 - 65¦C using either water, dilute brine, or spent zinc chloride electrolyte. The reagent is highly selective for zinc over iron and a range of other metals including cadmium, arsenic, lead and magnesium.

Jan 1, 1993

By Willis I. L, Stevens B. P J, Stroud W. J

The Early Proterozoic metamorphic rocks of the Broken Hill (BH) Block have been recently subdivided into sixteen formations and four groups (Willis et al., 1983b, Stevens et al., 1983). This stratigraphic subdivision has relied upon recognition of distinctive mapped rock units and "associations" of mapped rock units, which characterize particular lithostratigraphic units. The rock units and rock unit associations define local ordered sequences which can be compared and correlated, thereby establishing the stratigraphic succession. In the Clevedale homestead, Thackaringa, BH City, Bores Mine-Freyers mine, Silver King mine, and Brewery Well areas, coherent stratigraphic successions have been interpreted. These areas illustrate the regional variability of the stratigraphic succession and facies changes within individual stratigraphic units. Stratigraphic type sections are located in the Thackaringa, Bores Mine-Freyers mine, Silver King mine, and Brewery Well areas. The principles of stratigraphic interpretation applied in the BH Block can be used in other areas of Willyama Supergroup outcrop such as the Euriowie, Olary and Mount Painter Blocks. The general technique may also have applicability to other highly deformed and metamorphosed terrains.

Jan 1, 1983

THE exceptional rainfall characteristic of the West Coast of Tasmania, in conjunction with the rugged topography of the district, has always suggested the utilization of water-power, and from the earliest days of the Mount Lyell Company theeventual installation of a hydro-electric power scheme, making use of some near-lying lake, has constantly been kept in view. At the period of the inception of the company, however, the time was not ripe for such an undertaking, and it is only oflate that the various important considerations involved have sanctioned incun;ing the heavy expenditure necessary, with the positive assurance of permanently reaping the benefits expected. The West Coast of Tasmania contains many lakes of varioussites; situated at high levels, and, although the catchments of these lakes are not very extensive, still, the excessive rainfall is so constant over long periods that its regularity may be relied on as offsetting the limited catchments. The explanation of the abnormal rainfall is simply the circumstance that the West Coast Range forms the first high land barrier which is met by the moisture-laden westerly and north-westerly winds blowing off the Southern Ocean. By the time the clouds strike the mountains they ride very low, consequently the elevation of the range, the peaks of which do not exceed 3000 to 4000 ft. above the sea, is sufficient to cause a copious precipitation. Lake Margaret, which is situated five miles north of the reduction works, was first recognized as a possible source of waterpower by Mr. Hugh Ohrisp, a surveyor, who visited it about 1893-4. Earlyl in 1895, while the preliminary work on the erection of the first furnaces of the Mount Lyell Co.'s reduction...

Jan 1, 1915

By Boland J

Prediction of rock cuttability by various excavation machines such as tunnel boring machines, road headers, rippers, picks, roller disc cutters, excavators, etc is of major concern to both civil and mining engineers and rock mechanics. In principle, the design of a rock cutting tool is based on achieving maximum excavation with minimum input energy, minimum applied force, minimum equipment weight and volume and, more importantly, minimum tool wear. When a rock material is indented by the force of a cutting tool and then unloaded several material zones form underneath and around the tool. As the tool moves into the rock the volume of its associated rock cavity (ie volume of displaced rock) expands and depending on the indenter's shape various phenomena may occur. Immediately beneath the tool a small zone in which the stress state is more or less hydrostatic, is formed which is underlain by an inelastic, or damaged, material zone. Both size and shape of this damaged zone control the magnitude of the indentation force and the chip formation mechanism during unloading. The rock is unable to store the whole strain energy induced by the tool and consequently the extra energy is expended either in forming new fracture surfaces and/or in plastic deformation in the damaged zone. Therefore, it is not surprising to see that both perfect-elastic and rigid-plastic constitutive models are not generally suitable for modelling indentation of rocks. In contrast elastoplastic constitutive models are more appropriate as they can include both elastic and plastic deformations (Kral et al, 1993). Elastic solutions for several half-space indentation problems can be found in most text books on elasticity and in particular in Timoshenko and Goodier (1951), Sneddon, (1951), Poulos and Davis (1974) and Johnson (1985a). If a failure criterion, eg the Mohr-Coulomb failure criterion, is applied to delimit elastic solutions for indentation problems, a lower bound limit of the applied indentation force (for a given indentation depth) can be estimated. It may be noted that elastic analyses, without any delimiting failure criteria, normally overestimate the indentation force. Plastic solutions for a few indentation problems may be found in Hill (1950), Johnson, (1985a) and Alehossein et al (1992). When analysing the behaviour of indented rocks the choice of an appropriate constitutive model describing effectively the behaviour of the rock at various stages and phases during indentation is a challenging issue. Several questions need to be answered before starting an effective analysis. The first question is of course: Which one of these is more appropriate for modelling zones underneath and around a cutter, elasticity or plasticity theory, continuum damage mechanics or fracture mechanics, and what is the bridging link between these various theories? Which mode is more dominant in fracturing rock, tensile or shear mode? What governs the mechanism of chip formation? What is the function, shape and the behaviour of the pulverised zone that forms just underneath a cutter? Is the hydrostatic stress state assumption reasonable for this zone? How does the rock change during the absorption and dissipation of the input energy and how does the indentation energy vary with rock type and depth of penetration? How can we model the damaged zone under the indenter? Furthermore does a plastic material form beneath the pulverised zone? When and how do radial and ring cracks form around and under an indenter?

Jan 1, 1995

Over the last 100 years in the Polish mining industry considerable work has been done to assess optimum slurry, develop flexible delivery systems and adjust the fill technology to a wide variety of mining and geological conditions. Sand or industrial mineral waste materials for the backfilling of underground voids are used to control ground movement and surface deformation. This paper discusses various criteria to be considered in the preparation of a fill, including slurry properties, mine infrastructure, mining geometry, placement methods and the purpose of the backfill. This paper presents laboratory and in situ test data on the influence of materials parameters on the slurry flow in a pipeline system, stiffness, permeability, binding time and strength of a backfill, on the distribution of mixture in underground voids or the penetration between roof fall materials.

Jan 1, 1998

By H Aoki, A Nakayama, K Morita, S Yamada

The thermal conductivity of mold flux is crucial for optimising the productivity and quality of steels. This study investigates the thermal conductivity of molten oxides, including CaO-BO1.5-AlO1.5 (CBA), CaO-BO1.5-AlO1.5-SiO2 (CBAS), and CaO-MgO-BO1.5-AlO1.5 (CMBA) melts, using a hot wire method. Additionally, their structure is examined using Raman spectrometry and magic angle spinning nuclear magnetic resonance (MAS-NMR) to explore their relationship. Furthermore, first-principles calculations are employed to assess the covalency of each bond in the melts for a more quantitative analysis of their relationship. The study confirms that an increase in the CaO concentration of the CaO-BO1.5-AlO1.5 melts reduces the amount of bridging oxygen and consequently decreases thermal conductivity. The covalency of the B[4]-O bond is highest, especially when the second-nearestneighbour Al atoms transition from Al[6] to Al[4], forming the AlB3O7 structure with B[4]. The relationship between thermal conductivity and the structure of CaO-BO1.5-AlO1.5-SiO2 melts can be quantitatively assessed using the degree of polymerisation of the network structure and the variation of covalency as indicators. Furthermore, replacing CaO with MgO in the CaO-MgO-BO1.5-AlO1.5 melts reveals a mixed alkaline earth effect on thermal conductivity.

Aug 21, 2024

By C Wels

Current best management practice requires the placement of a cover onto most types of mine waste including tailings, waste rock and/or spent heap leach rock at closure of the mine. The objectives of a cover system may vary from site to site but generally include dust and erosion control; chemical stabilisation of acid-forming mine waste (through control of oxygen ingress) contaminant release control (through control of infiltration); and/or provision of a growth medium for establishment of sustainable vegetation. In our experience, there has been a general tendency by stakeholders to develop performance criteria for cover systems, which are tied directly to these specific design objectives. In many cases, this practice has led to the development of single, often very conservative, numerical values of cover performance criteria such as ænet percolationÆ, ærate of oxygen ingressÆ and/or æplant density/mixtureÆ. In our opinion, there is a need to develop cover performance criteria on a case-by-case basis and with due consideration of the short-term and long-term impacts on the receiving environment at a particular site. This paper puts forward a methodology for developing site-specific performance criteria for a cover system designed to isolate acid-forming mine waste and to control acid rock drainage. The proposed methodology links the predicted performance of a cover system to groundwater and surface water impacts. This way, the appropriate level of control (of oxygen ingress and/or net percolation) required by the cover system can be determined. A case study is presented that illustrates the application of the methodology proposed in this paper.

Jan 1, 2003

By S Raval

The estimation of greenhouse gas emissions from coalmines is increasingly becoming a priority for both operators and regulators. At the same time, involved scientific challenges in the methane measurements is generating significant interest from global research community. Various technology providers are also actively engaged in improving their sensors and platforms to address the measurement challenges and capitalise the market opportunities. This presentation highlights rapidly evolving multifaceted landscape of coalmine greenhouse gas emissions. It covers the advances in sensors for the detections, including ground-based, airborne, and satellite-based systems as well as models for the emission estimations, including attempts to reduce the involved uncertainties.

Sep 1, 2024

By A Datar, D Mulligan

The extractive phase of broad-scale mining can have major impacts on landscapes and associated ecosystems. Post-mining ecological rehabilitation typically starts with reconstructing topography. A fairly common industry practice has been to use landform elements such as plateaus, terraces, and gentle slopes for stabilisation purposes. However, this approach can lead to the generation of fairly uniform landforms that do not necessarily reflect natural ecosystems. Previous research in undisturbed and agricultural landscapes shows that ecological attributes and diversity in microclimates is positively correlated with landform heterogeneity. An objective of this study was to investigate if those findings are still valid in post-mining rehabilitating landscapes on North Stradbroke Island, Queensland, Australia. We investigated the relationship between landform heterogeneity and status of ecological recovery. The landform heterogeneity is measured through variance in three landform characteristics (relief, slope, aspect) using remote-sensing data and the status of ecological recovery is represented by ecological indicators measured through field surveys. The results indicate strong correlations between landform heterogeneity indices and native vegetation species richness with sensitivity to the spatial scale of investigation. It is recognised that climate, substrate and rehabilitation practices act as primary drivers of rehabilitation success. However, the results indicate that, in some examples, landform heterogeneity (heterogeneity in relief and slope angles) contributes up to 30 to 50?per?cent of the variance in native vegetation species richness. While the primary drivers of ecological recovery are difficult to control over extensive areas and extended time periods, landform heterogeneity provides a tool to indirectly control the micro-environmental parameters to improve ecological recovery. Reducing the uncertainties in the choice of ecological and landform indices and the degree of landform heterogeneity suitable for particular rehabilitating landscapes would be site specific. The introduction of desired landform heterogeneity may provide a very effective tool for significant improvement in ecological rehabilitation across broad-scale post-mine landscapes, an outcome of benefit to industry, government and local communities.CITATION:Datar, A and Mulligan,?D,?2014. Do we need to change the way we set up the stage?, in Proceedings Life-of-Mine 2014 , pp 29–46 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By S Arnold

Properties of the soil profile fundamentally control water-limited ecosystems. Soil water availability affects vegetation dynamics of plant communities, but is also affected by these communities in return. Understanding this eco-hydrological interplay and the role of physical soil restoration is crucial for successful rehabilitation and management of post-mining landscapes in semi-arid areas. However, uncertainties exist in both the mathematical description of plant communities within ecological submodels and the predictability of future rainfall events. This study uses information gap decision theory combined with an ecohydrological system model to investigate how both uncertainties impact decision-making in the context of ecosystem rehabilitation. A range of management strategies are investigated to identify the optimal soil thickness for successful rehabilitation of native plant communities in Central Queensland. The results emphasise that thicker soils can counterbalance uncertainty in mathematical description of plant communities by increasing the simulated survival probability of plant communities. However, the influence of thicker soils on the robustness of plant communities against a change in future rainfall amount is rather marginal. By allocating an economic value for restoring a particular thickness of soil layer, these results can be used to evaluate the costs of ecosystem re-establishment with regard to two target measures - the survival probability of the plant community and their robustness against climate change.CITATION:Arnold, S, 2012. Finding optimal soil restoration strategies in the face of uncertain future rainfall amount, in Proceedings Life-of-Mine 2012 , pp 91-96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By M Zhu, G Tranell, J You, K Tang, X Ma

The thermal conductivity of slag is critical for the efficiency of high temperature metallurgical processes such as the smelting reduction of ferroalloys, the ladle refining and the continuous casting mold flux in steelmaking. Experimental determination of slag’s thermal conductivity is fraught with challenges, as seen in yielding data for the SiO2-Al2O3-CaO system that are often inconsistent and widely dispersed. In molten slags of this system, thermal transport occurs via phonons within the network structure. To quantitatively describe thermal conductivity based on the microstructure, hightemperature Raman spectroscopy was employed to measure the silicate tetrahedra Qi (i = 0, 1, 2, 3), with Q4 species inferred from mass balance. This study also integrated molecular dynamics simulations to provide a fundamental understanding of the microstructure units distributions. Machine learning algorithms, especially deep neural networks, were applied to establish the relationship between slag composition and the configuration of tetrahedra. The thermal conductivities were then connected with silicate tetrahedra Qi using an Arrhenius-type formalism. This study sets the stage for extending our findings to more complex, multicomponent slags, enhancing their practical application in industrial processes.

Aug 21, 2024

By Kam KM, Tran B

Statistical techniques of Box and Jenkins (1976) have been used to assess the existing control schemes and determine the dynamics of flash smelting furnace at the Kalgoorlie Nickel Smelter. Pertinent process variables, such as, oxygen flow, flux flow, matte grade and iron to silica ratio in slag, were considered in the analysis using routine operating data collected over two periods of operation. Results indicate inadequate control of some of the important variables. Dynamic characteristic parameters (dead time and response time) between a set of input and output variables were identified to improve optimisation of the existing thermodynamic model used for flash furnace control.

Jan 1, 1996

By J Zhao, Q B. Zhang

The shock behaviour of a material represents its response to very high strain rate loading at pressures associated with those generated by explosive and blasting loadings. Three sets of shock wave experiments have been conducted to determine shock Hugoniot behaviour, spall tensile strength and shear strength using a plate impact facility. Embedded manganin stress gauges (ie longitudinal and lateral gauges) and high-speed velocimetry using heterodyne techniques were used for the measurements of stresses, shock velocity and free surface velocity. The gabbro exhibited classic linear Hugoniot equations of state in the US-up (ie shock velocity-particle velocity) plane; while for marble a polymer-like non-linear response was observed. The detailed experimental procedures used to make these measurements are to a great extent standard methods when determining mechanical properties and deformation fields at high strain rate.CITATION:Zhang, Q B and Zhao, J, 2015. The response of rock materials to one-dimensional shock loading, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 665–672 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

Remote sensing techniques can be used to map joint sets in a rock mass for the estimation of in situ block size distribution and improved optimisation of blasting. This paper reviews remote sensing using photogrammetry and laser mapping for mapping rock masses and presents elements of the analyses applied to data acquired with these mapping technologies. These techniques enable a user to map areas of hundreds of square metres rapidly with high precision. Using this data computer programs such as Sirojoint can provide estimates of joint position and orientation with orientation measurement accuracies better than one degree. The paper describes the use of remote mapping and provides potential users with a description of some of the advantages and limitations of the mapping techniques and the data they produce. Mapping of lithology and structure of rock masses is an important task required in many areas of mining and construction. It is a complex task routinely performed using established techniques developed to provide consistent results under a wide range of conditions. The techniques for data acquisition and analysis described in this paper enable more accurate mapping to be performed rapidly and enable mapping of inaccessible sections of a rock mass. These techniques will provide geologists and geotechnical engineers with more detailed, accurate data than previously available.

Jan 1, 2001

By S Jeon, K Aikawa, M Ito, A Kusano, I Park, N Hiroyoshi

In mineral processing of complex sulfide ores containing copper (Cu), lead (Pb), and zinc (Zn), flotation has been commonly used. Typical Pb mineral in the ores is galena (PbS), while some types of the ores contain anglesite (PbSO4). This article reviews our recent studies on the effects of coexisting PbSO4 on the flotation of complex sulfide ores, and a method to suppress the floatability of sphalerite (ZnS) in the presence of PbSO4 was proposed. Comparison of flotation experiments for different types of model samples showed that PbSO4 makes the separation of Zn from Cu difficult; that is, for the model sample containing PbS without PbSO4, Zn could be separated from Cu, while when the model sample containing PbSO4, Zn was recovered together with Cu as froth. Solution analysis and thermodynamic calculation suggested that Pb2+ was released from PbSO4 and reacted with ZnS to form PbS, acting as an adsorption site for the flotation collector, xanthate. This would be the main reason for high floatability of ZnS in the presence of PbSO4. As a method to suppress ZnS floatability for the ores containing PbSO4, a pre-treatment of the ores to remove PbSO4 prior to flotation was proposed. The results of model experiments using mixture of ZnS and PbSO4 showed that ~97 per cent of PbSO4 was dissolved within 30 minutes of pretreatment using ethylenediaminetetraacetic acid (EDTA) as extractant, and thus ZnS floatability was markedly suppressed. Moreover, Pb2+ extracted from PbSO4 during the pre-treatment could be recovered as zero-valent Pb by the cementation using zero-valent Fe as a reductant. The details of ZnS flotation in the presence of PbSO4 and the effects of the pre-treatment are discussed based on the results of surface analysis like XPS.

Aug 24, 2022