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Separation of Nickel and Cobalt from Manganese, Magnesium and Calcium by Synergistic Solvent Extraction - From Batch Tests to Pilot Plant Operation The synergistic solvent extraction system consisting of Versatic 10/LIX63/TBP was used for the separation and purification of nickel and cobalt from synthetic laterite leach solution after iron removal. Very encouraging results were obtained for separating nickel and cobalt from manganese, magnesium and calcium. In batch tests, the organic composition of the synergistic system was optimised and very large synergistic shifts for nickel and cobalt were observed. The ?pH50(Mn-Co) and ?pH50(Mn-Ni) values were as large as 1.65 and 2.40, respectively. The extraction and stripping kinetics of nickel and cobalt was fast. Semi continuous extraction tests were conducted with a pH profile of 5.5/6.1/6.5 in three stages at 40¦C. The nickel and cobalt extractions reached 99.9 per cent with only 5 mg/L Ni and <1 mg/L Co left in the raffinate. With two stages of scrubbing, only 2 mg/L Mn and less than 1 mg/L Mg and Ca were left in the scrubbed organic solution. With two stripping stages, the stripping efficiencies of Ni and Co reached over 95 per cent. A fully continuous pilot plant operation was conducted successfully for 280 hours. With an O/A ratio of about 2 and a pH profile of 5.5/5.8/6.0/6.3 for the four stages EX1/EX2/Ex3/EX4, both nickel and cobalt were almost completely extracted. Using a pH profile of 5.4/5.0 for SC1/SC2, the manganese scrubbing efficiency was over 96 per cent. Using three strip stages, over 98 per cent Ni and 99 per cent Co were stripped with only 64 mg/L Ni in the stripped organic solution. The nickel concentration in the loaded strip liquor reached 83 g/L, resulting in a ?Ni of over 28 g/L. The chemical stability of the system was also assessed over 12 weeks under proposed industrial operating conditions. Operation exclusively under strip conditions at 50¦C and 40¦C resulted in LIX63 oxime half lives of 1.1 and 2.1 years, respectively. Operation exclusively under extract conditions at 50¦C and 40¦C resulted in oxime half lives of 0.26 and 0.82 years, respectively. Losses of Versatic 10 were less than four per cent.

Sep 13, 2010

By D. F. O?Connor

The health & safety of all workers in an underground environment is paramount to the success of our operations. The diesel emission reduction projects are key to improving such an environment. However, care must be taken to reduce the risk to personnel during such tests and prevent exposure to other hazards. VALE Inco works in a close partnership with its unionized employees, manufactures, suppliers, researchers and government officials to ensure projects are done safely and efficiently to successful completion. The Creighton Mine Diesel Particulate Filter (DPF) project is an example of such a project that is currently under way to evaluate new and innovative technology that will further our search for improved environment for our workplace. This paper will discuss the issues and processes that are followed to ensure Diesel Particulate Filter (DPF) field tests are conducted safely and productively.

Jan 1, 2009

By Joseph Grumer

Theory pertaining to the exchangeability of fuel gases on appliances has been extended to exchanges of propane or butane with mixtures of these. In particular, new considerations were developed bearing on the hazard of an occasional emission of carbon monoxide and flashback and blowoff possibilities. The new considerations involve using current requirements for approval of liquefied petroleum gas appliances. These requirements were used to predict allowable tolerances in chemical composition of liquefied petroleum gases for existing appliances. In addition, changes in gasline pressure were computed which may be substituted in place of fuel exchanges during testing of appliances,

Jan 1, 1962

By M. O. Serbousek

To further investigate the potential of precast concrete sets as a support medium for underground mines, the Bureau of Mines designed an eight-piece precast reinforced concrete drift set for a small opening. Twenty-two sets of three different member sizes were tested to destruction under two loading conditions. A discussion of the test results and typical failure patterns is presented.

Jan 1, 1969

By P. Bousquet

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian mining industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (e.g., pyrite) contained in rock are exposed to air and water and subsequently oxidize to produce low pH water. This acid effluent has the potential to mobilize any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pyrite is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidizes a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

Jan 1, 2002

By Chang-Dong Li

Cadmium ingot and nickel powder were prepared by high-temperature distillation, solvent extraction and liquid phase reducing method with spent Cd-Ni batteries as raw material. The impacts of the temperature in the distilling stage, the concentration of H2SO4 in the leaching stage, the pH value in the extracting stage and the dosage of hydrazine in the reducing stage were discussed respectively. The as- prepared samples were characterized by the means of X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic absorption spectrometry (AAS) and inductively coupled plasma-atomic emission spectrometry (ICP-AES). The results showed that the recovering efficiencies of Cd and Ni reach 99.5% and 99.3%, and the purities of Cd ingot and nickel powder were higher than 99.90% and 99.80%, respectively.

Jan 1, 2009

By Sean Gallagher

Bolting large sheets of wire mesh screen (WMS) to the roof of underground mines prevents injuries due to rock falls. However, WMS can be heavy and awkward to lift and transport, and may result in significant spinal loading. Accordingly, six male subjects (mean age =45.8 years + 7.5 SD) were recruited to lift WMS in a laboratory investigation of the biomechanical demands. Biomechanical modeling was used to estimate external moments about L5-S1 for sixteen lifting tasks, using two sizes of WMS. Full-size WMS involved a two-person lift, while half-size WMS involved a one-person lift. Lifts were performed under 168 cm and 213 cm vertical space. Restriction in vertical space increased the maximum L5-S1 extensor moment from 254 to 274 Nm and right lateral bending moment from 195 to 251 Nm. Lifting full sheets of screen (as opposed to half sheets) resulted in an average 33 Nm increase in L5-S1 extensor moment. The L5-S1 extensor moment was increased by an average of 44 Nm (18%) when lifting screens positioned flat on the floor compared to an upright position. Relevance to industry: Large flexible materials are commonly lifted in industrial work environments, and may involve the efforts of two or more workers. The current study examines the low back loading associated with lifting large flexible screens and presents recommendations to reduce spine loading.

Jan 1, 2009

By Murat Baydogan

Effect of retrogression and reaging treatment on hardness and stress corrosion cracking resistance of 7075 aluminum alloy was investigated. As received 7075 alloys in T6 temper condition were retrogressed at 170, 220, 240 and 380°C for different durations between 15 s and 60 min. Subsequent reaging was made at the T6 aging condition. Treated materials exhibited higher hardness and better stress corrosion cracking resistance than T6 temper in a wide range of retrogression temperature and time. The highest hardness was obtained after retrogression at 170°C for 210 s followed by reaging, corresponding to 20% hardness improvement. Improvement in stress corrosion cracking resistance of the alloy by as much as 85% was also observed. In this paper, improvements in hardness and stress corrosion cracking resistance are discussed on the basis of the microstructural changes during retrogression and reaging treatment.

Jan 1, 2006

By A H. Clemens, T A. Moore

This paper discusses a number of technical issues related to marketing coal. It outlines how the results of research undertaken in New Zealand and overseas can help producers address a range of technical factors that impact on production costs and marketability. The paper also discusses trends in coal utilisation for power generation and how new technologies may require coal with different characteristics. Research and development into options for CO2 sequestration are discussed including carbon storage in forests, and removal of CO2 from flue or fuel gas in power stations, and its disposal.

Jan 1, 1997

By P. Marinos, G. Tsiambaos, H. Saroglou

The anisotropic behaviour of “Athens Schist” has been brought out through the testing of specimens with varying orientation of schistosity with respect to the major principal stress under uniaxial, triaxial and dynamic conditions. A large number of results from tests on intact rock specimens of the “Athens Schist” were statistically analysed and evaluated. Le comportement anisotropique des roches du système “Schistes d’ Athènes” a été déterminé sur des épreuves avec une orientation différente de la schistosité par rapport à l’axe de chargement sous des conditions axiales, triaxiales et dynamiques. Un grand nombre des résultats a été statistiquement analysé et discuté. Zur Bestimmung der anisotropen Eigenschaften der Athen Schiefer wurden einaxialen, dreiaxialen und dynamischen Kompressionsversuchen an Gesteinskernen durchgeführt, bei denen die Belastungsachse verschiedenen Neigungen gegen die Schieferung hat. Die Messreihen an anisotropen unzerreissbaren Fels Samplen von Athen Schiefer wurden statistisch analysiert.

Jan 1, 2003

By Hon-Yim Ko

1972 constituted the second year of the projected five-year study on constitutive relations of coal. The schedule adhered closely to the five-year outline which is summarized in Table 1. This chapter is intended to serve as introduction and concise synopsis of the year's activities and results, which are presented in greater detail in the following chapters, which have been contributed by the individual researchers in charge of the various aspects of the project under study. Coal Sources, Material Procurement, and Sample Preparation Most of the studies performed during 1972 were done on coal from two sources: the Old Ben Mine #22 in Illinois, and the Bruceton Mine in the Pittsburgh seam of Pennsylvania, which may be considered typical of coal sources of economic importance in the Midwestern and Eastern part of the U.S. These two mines have proven to be reliable suppliers of coal material for our research. We have been able to establish good working relations with their personnel and feel that we can continue to count on their cooperation and help.

Jan 1, 1972

By J. A. Kosek

Work has been conducted under Bureau of Mines Contract Number HO 357078 to develop instruments for detecting CO, NO and NO2 in a mine atmosphere, using fuel cell technology. The approach has been to optimize the fuel cell sensor configuration for the specific detection of CO, NO and NO2 in the presence of other mine gases utilizing recent advances in catalyst, electrode and solid polymer electrolyte membrane technology. Para-metric testing has been conducted on three electrode sensor cells to define performance and life characteristics as a function of temperature, feed flow and applied sensor voltage. Extended life testing has been performed on sensor cell configurations exhibiting favorable characteristics. Reliable, efficient gas sampling and electronic control circuitry has been fabricated for use with the sensor cells, and integrated into devices to meet the performance and design specifications for portable, battery-powered, hand held direct indicating gas detectors for use underground. Twenty of the production-type, direct indicating CO detectors have been tested and delivered to the Bureau of Mines under the present contract. Three prototype diffusion head CO monitors have also been delivered for evaluation under the pre-sent contract. The gas sampling pump and related parts have been replaced by a diffusion tube assembly in which CO reaches the sensing electrode surface by diffusion alone. In addition, delivery will be made of ten direct-indicating nitric oxide detectors and ten direct-indicating nitrogen dioxide detectors. These instruments are very similar in design to the direct indicating CO detector.

Jan 1, 1979

By P. J. G. du Toit

Coal has been mined by hydraulic means in various countries, i.e., the hydraulic excavation as well as the hydraulic transportation of coal has been practiced. The hydraulic breaking (excavating) of the coal dealt with in this report is done with a monitor directing a continuous jet of water against the coal, pressures of the water fed to the monitor range from 1500 to 2500 psi at 1000 to 2100 gallons per minute Transportation of the coal from the face is by fluming if a gradient exists in excess of 2 or, when a favorable gradient does not exist, the coal is pumped from the face by various types of pumps which can also provide a means of hoisting the coal to a higher elevation as required. This report presents: 1.) preliminary design and systems specifications of a demonstration miner (referred to in this report as a hydrominer), 2.) mining configurations showing good promise for typical U.S. thick coal seams in three seam pitch categories, (0° - 7° = Flat, 8° - 250 = Moderately pitching, 26° - 90° = Steeply pitching), along with cost and performance analyses for each system, 3.) a definition of a test program that will provide sufficient engineering data for the design of a water jet cutting head adequate to cut coal in those typical U.S. thick coal seams The cost analysis data showed hydraulic methods to be economically competitive with present thick seam raining methods. It was also obvious from studies of thick seam methods that the hydromonitor coal breaking techniques are more effective in removing most of the coal with its long reach of 60 ft. (or more), is a safer mining system, and produces very low coal-dust content in the air (usually less than 0.25 to 0.5 mg/cubic meter). It is recommended that the USBM sponsor a full fledged continuation of the hydraulic mining program: (a) lab, test, (b) preliminary field test, (c) full scale mine section demonstration.

Jan 1, 1977

By G. J. de Korte

Dense-medium beneficiation of fine (minus 0.5 mm) coal is not a new concept and has been used in South Africa previously. The dense-medium fine coal plant at Greenside Colliery operated for almost 18 years and, despite proving a difficult plant to operate, did succeed in producing a fine coal product with a low ash content of 7%. No other beneficiation process available could achieve this. Dense-medium beneficiation of fine coal was also used in other countries, of which the plants at Homer City in the USA and Curragh in Australia were the best known. The first application of dense-medium cleaning of fine coal was, however, at the Tertre plant in Belgium1. This plant was built in 1957. About nine years later, a second fine coal dense-medium plant was built at the Winterslag Mine, also in Belgium. According to reports, this plant operated satisfactorily for a period of some 17 years.

Jan 1, 2002

By Adam K. Smith

Occupational hearing loss is a permanent illness with no recovery currently possible. For underground coal mine workers, Noise Induced Hearing Loss (NIHL) continues to be a serious health issue. One of the principal and fundamental machines used in underground mining operations is also one of the loudest. Noise generated on the continuous mining machine is the result of 3 operational components: the cutting system, the dust collection system, and the onboard conveying system. During underground acoustic evaluations, the conveyor system noise was observed to be dominant. In order to more closely examine sound generated by the continuous mining machine, sound power levels were measured in a reverberation chamber at the Pittsburgh Research Laboratory (PRL). Different chain types and configurations were installed on the conveyor system, and the resulting sound power level ranged from 118 dB(A) to 108 dB(A). Noise generated by the dust collection system was also examined and found to be 107 dB(A).

Jan 1, 2008

By J. E. Shigley

The gemological properties that allow natural emeralds and blue sapphires to be distinguished from other gemstones are summarized in this paper. A variety of synthetic and laboratory-treated emeralds and blue sapphires are also encountered in the jewelry industry today. Gemologists distinguish these latter materials from their natural counterparts based primarily upon features seen with magnification, such as inclusions and/or growth zoning. In some cases, however, these observations and standard gem-testing methods are insufficient, and the use of non-destructive analytical methods, such as optical spectroscopy and chemical analysis, are required for positive identification. The commercial value of synthetic and treated gems are much less, and can be insignificant in comparison to that of an important untreated natural gemstone. Identification of synthetic and treated gem material is essential to maintaining integrity in the jewelry industry. Loss of consumer confidence in the gemstones sold at the jewelry counter could have a negative impact on the exploration and mining of natural emerald and blue sapphire.

Jan 1, 1998

By Zdzislaw Specht

THIS paper discusses elementary laws pertaining to seismic reflection methods and presents a general and simple criterion for determining the direction of dipping of a reflection horizon from observational data of distance and time. The important development of practical geophysics and the successful results obtained in America, Germany, and other countries, caused introduction of geophysical methods of prospecting in Poland. Of all methods, seismic prospecting has proved most successful in the area of the Carpathian foreland, where new oil reserves are to be expected. Because of the great depth of the sedimentary column in that area, rang-ing sometimes over 2000 meters, it was obvious that only the seismic reflection method could give reliable information regarding the structural features of these strata at such a depth. During the experimental surveys it appeared that the complicated geological conditions of that area do not always allow prediction of the depth and the angle of dipping of reflecting horizons, and for that reason information about the inclination of a given horizon has great importance in the determination of subsurface structure. Therefore the problem arises of obtaining from seismic reflection data reliable information as to the direction of dipping of reflecting strata, without any previous knowledge of the average velocity and depth of geologic horizons under consideration.

Jan 1, 1940

By James R. Boyle

The Bureau of Mines initiated a program to address short-and long-term objectives of wetlands restoration as a option for reclamation of lands mined for phosphate. The short-term objectives were to identify a suitable wetland test site, initiate an extensive premining monitoring plan, develop an acceptable mining plan, and recontour and revegetate the test site. These goals were accomplished using a unique combination of expertise provided by Federal and State agencies and private industry. A 6.5-ha forested wetland with an associated streambed was offered by private industry as the test site. A premining monitoring program was established and carried out from May 1982 to October 1983. A control site was established to determine ecological changes unrelated to mining. Clearing and mining began in October 1983 and was completed in April 1984. Grading and streambed restoration was completed in February 1986. Revegetation of the site was completed in February 1987. The program to meet the long-term objective of postmining monitoring is described.

Jan 1, 1988

The Southwest Pacific is a region of active volcanism and geothermal systems. Only in New Zealand have the geothermal systems been exploited for electricity generation and industrial processing. At present, approximately 280 MWe of geothermal electricity is generated in New Zealand. A considerable amount of further exploration work is required before the total geothermal potential of the region can be assessed and before the significance of these resources can be judged against other local energy sources.

Jan 1, 1990

At a regional scale, the Otago Schist has been divided into textural zones, metamorphic zones, structural transposition zones, and terranes and lithologic associations. Each of these subdivisions reveals aspects of the internal structure of the lithologically monotonous Otago Schist but, to date, a map of the schist derived directly from structural data has not been made. In the present study, digitised structural data from the QMAP GIS were used to make a form line map of Schist foliation which, in turn (and using certain non-unique guiding assumptions), was used to construct a provisional foliation thickness map of the Otago Schist. Contours of dominant foliation (Sp) thickness have been drawn from 4 kIn above to 16 km below the reference level of the Caples-Torlesse terrane boundary in the schist structural pile. A recent revision of the Otago Schist textural zone classification has shown that the grain size of metamorphic white micas increases progressively with textural grade. There also appears to be a correlation between schist mica grain size and foliation thickness. Using mica grain size, it may eventually be feasible to establish the vertical structural position of samples in greenschist facies parts of the schist pile to a precision of ¦ 1 km or better, even if they are in inliers or fault-bounded blocks. Foliation thickness and mica grain size are thus potentially useful tools for research and exploration in the Otago Schist in that they assist with structural interpolation and extrapolation. Even at this early stage of application they can be used to provide hitherto unobtainable, semi-quantitative estimates of displacement on Mesozoic and Cenozoic faults and folds.  

Jan 1, 2001