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By J. Groppo, W. Zhang, R. Honaker

"Rare earth elements (REEs) found in coal are in the form of minerals, ion-adsorbed onto clay surfaces or inner layers, or organically bound. Rare earth minerals such as monazite exist in coal and have grain sizes smaller than 5 µm. In this study, froth flotation was successful in concentrating rare earth minerals existing in a thickener underflow material derived from Fire Clay seam coal that contained around 431 ppm of total rare earth elements (TREE) on a dry ash basis. Conditioning with fatty acid followed by processing using multiple stages of conventional flotation produced a final concentrate containing 2,300 ppm TREE. Using a laboratory flotation column to limit hydraulic entrainment, the TREE content was further enriched to around 4,700 ppm, which equated to an enrichment ratio of 10:1.IntroductionRare earth elements (REEs) are becoming increasingly important and have been widely used as raw materials for the production of phosphor, metal catalysts, magnets and batteries (Binnemans et al., 2013; Zhang et al., 2015). REE recovery from alternative sources such as coal and coal byproducts has the potential to stabilize the economic viability of coal mining operations while providing a dependable supply of critical materials.The average REE content of the world’s coal resources is around 60 to 70 ppm (Zhang et al., 2015). There are many well-known coal beds with high contents of REEs such as those in the Far East coalfields in Russia with contents of 300 to 1,000 ppm, the Fire Clay coal seam in eastern Kentucky in the United States with contents around 500 ppm and the Sydney Basin in Nova Scotia, Canada, with contents of 72 to 483 ppm (Birk and White, 1991; Seredin, 1996; Hower, Ruppert and Eble, 1999; Blissett, Smalley and Rowson, 2014). The occurrence of REEs in coal and coal byproducts can be classified into three types: (1) rare earth minerals, such as monazite and xenotime, (2) ion-adsorbed REEs on clays and (3) REEs associated with organic matrices. The rare earth minerals in coal and coal byproducts are very small in particle size, generally on the micrometer and/or nanometer scales (Honaker et al., 2014). Froth flotation, which concentrates minerals based on surface chemistry differences, has been widely used to treat fine rare earth industrial minerals such as monazite, xenotime and bastnaesite (Abeidu, 1972; Cheng, Holtham and Tran, 1993; Pavez and Peres, 1994; Pavez, Brandao and Peres, 1996; Jordens et al., 2014). As such, flotation is a promising method for the concentration of rare earth minerals from coal and coal byproducts."

Jan 1, 2017

By L. G. Kirk

The Mississippi embayment ball clay region, including western Kentucky, western Tennessee, and northwestern Mississippi, accounted for more than 95% of the total U.S. ball clay production during 1985. Other producing states during the year were Texas and Maryland. The U.S. Bureau of Mines reported total domestic production for 1985 of 910,000 short tons. The United States exports approximately 20% of the annual ball clay production. Geologically, the ball clay deposits are sedimentary in origin and occupy the north- eastern flank of the Mississippi embayment. The commercial deposits have been confined to the Claiborne and Wilcox formations within mid to lower Eocene and upper Paleocene age strata. The deposits are lenticular in nature and highly variable in areal extent and thickness. They exhibit very abrupt lateral boundaries and are bounded laterally and vertically by unconsolidated sands, silts, and waste clays.

Jan 1, 1986

By J. G. Groppo

A beneficiation process has been developed to provide selective separation of unburned carbon from high LOI fly ash. Previous reports of utilizing froth flotation to achieve selective separations required long residence times and high reagent costs. A proprietary reagent system has been developed to address both of these limitations. Based on the results obtained from laboratory and pilot-scale investigations, a flowsheet design has been developed to produce two distinct usable products from class F fly ash; low LOI ash and a high carbon product suitable for reburning or further upgrading. A process flowsheet and description are presented.

Jan 1, 1996

By E. J. Rorem

Rockfall and unstable rock slopes can be effectively controlled by utilizing steel wire rope net systems, either as barriers or as slope draping. The chief advantage of such systems over rigid type barriers is the flexibility of wire rope netting, permitting kinetic energy dissipation, yet providing high strength and consequently low maintenance. A review of the design considerations involved with these systems, as well as a review of several mine and non-mine installations is presented with the hope that the information may contribute to the safety against the dangers of rockfall and other mine hazards in active and abandoned mines.

Jan 1, 1996

By T. W. Eddy

Research was conducted in which elemental mercury and its sulfide mineral (cinnabar) are removed from a copper sulfide concentrate by low temperature thermal applications. The goal of this research was to reduce, volatilize, and collect mercury vapor from concentrated smelter feed in a simulated drying environment while maintaining the chemical integrity of the residual. The study used synthesized concentrates composed of copper sulfide and mercury bearing minerals (such as cinnabar (HgS) or elemental mercury) to determine optimal residence times and temperature ranges.

Jan 1, 1996

By Robert L. Bates

In this paper I use the term "industrial minerals" in its broad general sense, and I distinguish two main groups. The first consists of the bulk materials, characterized by low unit price, nearness of deposits to markets, relatively simple methods of extraction and processing, and a tendency to be closely related to the construction industries. The second group includes those materials valued for exceptional purity, or for some special property such as hardness, immunity to acids, or dielectric strength. These materials are produced in smaller amounts, at high unit values, from deposits notably restricted in. distribution; and they require more or less sophisticated methods of production and beneficiation. The applications of this second group are not closely tied to any particular part of the economy. From the way in which the commodity committees of the Industrial Minerals Division are set up, I take it that the chief interest of most members is with the first group of materials mentioned above. Hence this paper will deal mainly, though not exclusively, with such bulk commodities as sand and gravel, clay, and stone. The first word in the title of the paper also requires brief explanation. It is here given a threefold interpretation. First is the role of the industrial minerals themselves in industry; this would probably be taken as the conventional meaning of the title* The second is the role of the industrial-mineral producers as citizens of the community. The third is what may be called the scientific role of these producers.

Jan 1, 1964

By Dapeng JIANG, Haixiao YANG, Shanxi WU, Jinwang Zhang, Guoliang XU, Yipeng ZHANG

The subsidence and deformation characteristics of strata with thick unconsolidated overlying strata is quite different from that with consolidated overlying strata. In this paper, based on the engineering background of large mining height mining in No.21 coal seam of Zhaogu No.2 Coal Mine in Henan Province, China, the PFC 2D numerical simulation and surface subsidence field observation was conducted to study the subsidence characteristics of strata with thick unconsolidated overlying strata (680m). Numerical model with dimensions of 2000m 750m was established and mining process with different working face lengths (150 m,200 m,250 m,300 m) and different working face advancing distances (40 m,80 m,120 m,160 m,200 m,240 m,280 m,320 m,360 m,400 m,440 m,480 m) were simulated. The surface subsidence characteristics and displacement field variation of rock strata under different working face advancing distances were observed and analyzed. The results show that with the advance of working face, the structure of subsidence-like basin will be formed in each rock stratum, and the influence range of mining on rock stratum is “bowl-shaped”, and the influence increases with the increase of advancing distance. The unconsolidated layer has a buffer effect on the mining-induced subsidence, and the buffer effect is realized by the expansion of the subsidence area. The movement law of strata under different working face lengths is similar to that under general mining, and the structure of subsidence-like basins will also be formed in each stratum. The influence range of strata after mining is ' bowl-shaped ', and the influence extent increases with the increasing of working face length; the internal subsidence of the unconsolidated layer is more intense and complex than that of the rock layer; the surface subsidence movement shows an obvious 'basin' phenomenon. The field observation data of surface subsidence also confirm the above results.

By E. A. Noble

In the Western Coal Region, successful reclamation of surface-mined areas includes the protection of groundwater sources. To accomplish this, a complete understanding of the geohydrology of the affected area is imperative. Successful mine design also calls for careful attention to geohydrology. Because the Western Coal Region is semi-arid land used mainly for farming and grazing, groundwater is a particularly sensitive topic. It is especially sensitive where the lignite scheduled for mining is itself the aquifer supplying the farms and ranches. Such is the case throughout much of the Western Coal Region, particularly where there are no near-surface sand and gravel aquifers that are commonly found in the glaciated portions of the Region. Just as mining can adversely affect groundwater supply, so can groundwater adversely affect mining. Mine flooding and highwall instability are examples of this. But, mine operators must realize that procedures they use to remedy geohydrologically-related mining problems can have a dramatic effect upon ground- water conditions in areas adjacent to the mine. A logical precaution is to require the acquisition of complete baseline data prior to making the first cut. We recommend that the mining plan not only incorporate the reclamation plan, but that they be developed as one plan.

Jan 1, 1976

By Robert D. Thomson

Land use is the single most important element affecting the quality of our physical environment. .The minerals industry is a user of land and by its very nature, directly affects the landscape. Mining is a very visible activity. Producers of sand and gravel, crushed stone, clay, cement and lime operate right at the interface of the public. These production sites must be located near population centers. People are more travel oriented than years ago and through use of the expanded interstate highway system visit remote and little-visited areas. They visit communities on their vacations, places they enjoy on weekends and places they drive past on business trips. Although not residents of these localities, they have a strong interest in changes that occur in the landscape. As a result, the public has a greater concern today about mining and its use of land. From 1930 through 1971, the minerals industry used 3.65 million acres, or 0.16 percent of the land mass in the United States (4)2/. Of the total 3.65 million acres utilized, about 59 percent was accounted for by the area of excavation, 20 percent by disposal of overburden and other mine wastes from surface mining, 13 percent by disposal of mill or processing wastes, and 5 percent by disposal of underground mine wastes; the remaining 3 percent was subsided or disturbed as a result of underground workings. Nonmetallic minerals and fossil fuels each accounted for 43 percent of surface land used during 1930-71; the metal mining industry utilized the remaining 14 percent.

Jan 1, 1976

By A. A. Sobek

Controlled release systems delivering the required concentration of an effective bactericide over an extended time period have been developed by The BFGoodrich Company's ProMac® Systems group. The ProMac system is site-specific and includes a four-step approach to controlling acid mine drainage (AMD): (1) Diagnosing the problem, (2) Prescribing the treatment, (3) Supervising the application of controlled release bactericides, and (4) Honitoring the success of applied treatment. The success of the ProMac system is evidenced by improved water quality, healthy vegetation, a reduction in levels of acidophilic thiobacillus, and a corresponding increase in population of beneficial microorganisms.

Jan 1, 1986

By E. Watkins, V. Gangrade, P. Zhang, J. Addis, D. W. H. Su, T. Minoski, C. Hollerich, M. Van Dyke, S. Schatzel, H. Dougherty

"This paper presents the results of a comprehensive study conducted by the Centers for Disease Control (CDC), National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Mining Research Division (PMRD) to evaluate the effects of longwall-induced subsurface deformations and permeability changes on shale gas well integrity and safety under shallow cover. NIOSH researchers selected a study site over a southwestern Pennsylvania coal mine, which extracts 1,500-ft-wide longwall faces under 482 feet of cover. One in-place inclinometer well and three permeability monitoring wells were drilled and installed over a 125-ft by 275-ft centers abutment pillar. In addition to the inclinometer well and monitoring wells, surface subsidence measurements and underground coal pillar pressure measurements were conducted as the first 1,500-ft-wide longwall panel on the south side of the abutment pillar mined by the site.A number of FLAC3D finite difference simulations (Itasca Consulting, 2017) were conducted to estimate surface subsidence, coal pillar pressure increases, and horizontal displacements in the in-place inclinometer (IPI) monitoring well. Comparisons of the FLAC3D finite difference simulation results and the surface, subsurface, and underground instrumentation results show that the measured IPI casing deformations are in reasonable agreement with those predicted by the FLAC3D models, and that the measured surface subsidence and underground pillar pressure are in excellent agreement with those predicted by the 3D models. Measured permeability changes were incorporated into a preliminary calculation to evaluate the effect of a hypothetical shale gas well leak on longwall ventilation. Results from this 2018 research clearly indicate that under shallow cover, the measured horizontal displacements within the abutment pillar are at least one order of magnitude higher than those measured in a 2017 study under deep cover and slightly higher than those measured in a 2014 study under medium cover. This research represents a very important step and initiative in utilizing the knowledge and science obtained from mining research to improve miner and public safety as well as the safety and health of the workers in the oil and gas industries"

Jan 1, 2019

By W. M. Schafer

The risk that water quality will be degraded by mining activity can be evaluated using risk analysis techniques. Water quality impacts can occur where water-rock interactions with tailings, waste rock, or leached ore lead to increased loading of constituents into surface or groundwater. Constituent loads contributed by mining facilities are determined by the migration route and chemical evolution of mine water. Mass load contributions from mines can be determined by estimating the prototype pore water in contact with mining waste, predicting the rate and timing of flow, assessing the degree of geochemical attenuation, and modeling chemical mixing with natural surface or groundwater. Mining facility siting and design measures can alter the chemical evolution of mine water by varying the quantity or quality of flow. Stochastic risk management techniques provide a powerful tool for quantitatively identifying the environmental consequences of various siting and design alternatives.

Jan 1, 1998

By M. J. Beus

Technology to enhance safety during mine hoisting has been developed by researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health. Assessment of current hoisting technology suggests that monitoring conveyance position and load directly from the skip or cage top offers several significant safety advantages. Wireless data transmission schemes and a package consisting of sensors, batteries, and a charger mounted on the wire rope and skip have been developed. A state-of-the-art automated hoisting test facility was constructed to test the concept in a controlled laboratory setting. Field tests in a full-size shaft are underway.

Jan 1, 1999

By L. Bloom

"Man-Made Parameters" refers to the importance of selecting appropriate analytical procedures to acquire useful chemical data. The correct procedures are particularly critical at the sample preparation stage where decisions concerning pulverizing equipment, sample size, contamination and dissolution will impact on the final results independent of the instrumental method of analysis. Several experiments were designed to quantify the impact of these approaches.

Jan 1, 1993

By J. W. Rold

In 1973 housing and construction conflicts threatened Front Range gravel resources. The legislature addressed the problem by passing HB 1529, which required the Colorado Geological Survey to map the deposits and forbid local governments to change lands over commercial mineral deposits from zones allowing mineral development to zoning which conflicted with development. It charged counties to develop Master Plans for Extraction. Plans must consider resource quality, multiple-sequential-use potential, surrounding area compatibility, neighbors, quality of Life, extraction maximization and reclamation potential. Imprecisely worded statutes, budgetary constraints, lack of enforcement and political pressures have limited benefits from the law.

Jan 1, 1987

By G. R. Coonan

A number of famous studies have shown that house damage relates better to peak particle velocity than to acceleration or displacement. The relationship is true but doesn't go far enough. Why, for example, can construction shots go well above 1.0 or 2.0 inches per second without reportable damage? Recent studies have shown that vie must look at frequency and duration of an event in addition to amplitude. The complexity of measuring frequency, duration, and amplitude makes the average blaster in the field shudder. An even more excruciating problem is the need to obtain such data inside the building or residence in order to accurately predict the damage potential or human response to nearby blasting. The author reviews current research programs and suggests new areas of research necessary to help maintain a balance between complicated research requirements and simple field measurements.

Jan 1, 1980

By A. F. Stewart

Slope design in an open pit mine includes the determination of a number of parameters, including bench height, bench face angle and berm width. By way of a case history of two highwall slopes (160m and 220m high) excavated in dipping strata in an operating coal mine, this paper illustrates the influence that bench face angle can have on the stability of an entire slope. The two highwall slopes, the lower of which experienced significant instability, were excavated in essentially the same lithologic and structural environment, with the main differences between the slopes being the angle at which the bench faces were excavated and the excavating methods that were employed. In addition to describing the instability that occurred on one of the pit walls, relevant aspects of the engineering geology, slope design and excavation procedures are described.

Jan 1, 1998

By David B. Crouch

Wastes in various forms have always been a part of mining, and management of mine waste has evolved from the early days of "push it over the side and down the creek" to today's highly engineered waste facilities. Changes have been brought about not only by technological advances in the ?3M?s? - mining, milling, and metallurgy - but also by environmental awareness and changing social values that have been manifested in an ever-growing maze of regulations. This is a dynamic era, and the debate goes on. So it is that planners have to anticipate permit and regulatory requirements in the site-selection process along with the traditional criteria. The McLaughlin gold project is an example of how one company, Homestake, has met this planning challenge. In August of 1980, Homestake Mining Company announced a major gold discovery in northern California known as the McLaughlin Project. The property is approximately 80 air miles northeast of San Francisco near the junction of Lake, Napa, and Yolo Counties. This is an area where mercury has been mined off and on for over 100 years; gold has never been mined in the area. The gold is microscopic and finely dispersed in a complex geologic setting. Reserves are estimated at approximately 20 million tons at a grade of approximately 0.16 ounces per ton.

Jan 1, 1983

By H. EI-shall

In this paper, the results of a fundamental study involving zeta potential and turbidity determinations of solid suspensions are discussed. Illustrations of how these results are utilized to design field applications of solid grade polymers to clarify mine drainage water are presented. Other applications in different industries are also reported. The operational and economical advantages are examined.

Jan 1, 1994

By Donald L. Gaughenbaugh

Under the terms of the 1970 amendments to the Clean Air Act, the EPA established national ambient air quality standards for a number of pollutants. Sulfur dioxide (SO2) was one of these pollutants. These ambient air quality standards have had perhaps their biggest impact on the power utilities. In an effort to meet the air quality standards set forth by the EPA, utilities using high sulfur fuels have been forced to install flue gas desulfurization (FGD) systems. The majority of FGD systems in operation today are nonregenerable systems, that is the by-product of the system is disposed of, usually into settling ponds. Limestone slurry is the most common reagent used to remove SO from the flue gases. The calcium carbonate (limestone) slurry interacts with the flue gas, absorbing the SO2 and forming a by-product of calcium sulfate/sulfite which is disposed of.

Jan 1, 1986