Search Documents

By A. L. de Vegt

Hydrogen sulfide is an expensive chemical used in nickel, zinc and copper mining and metallurgical operations for selective recovery and concentration of metals from leach water streams, acid plant blow down streams, refinery electrolyte bleeds and precious metal plant bleeds. Hydrogen sulfide is either produced on site by catalytic reduction of elemental sulfur or transported to the site as liquefied hydrogen sulfide (H2S) or as a sodium sulfide solution (NaHS). Biologically produced hydrogen sulfide has economically very interesting application possibilities in the mining and metallurgical industry. Converting sulfates from waste streams into usable hydrogen sulfide by biological reduction results in operational cost savings in existing lime treatment systems. H2S can be produced biologically for less than $500/ton S. For the past ten years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove sulfate and heavy metals. The hydrogen sulfide produced is used for recovery of metals, mainly zinc, from the ground water stream. The system has been operating since May 1992 treating a flow of 5000 m3/d. At Kennecott's Bingham Canyon Utah copper mine a pilot plant started operation in November 1995 to develop the process for selective recovery of copper from leach water using biologically produced hydrogen sulfide from sulfate containing groundwater. Other pilot plants are operated at DOE's Pittsburgh Research Center and at Cominco Research focusing on selective recovery of metals.

Jan 1, 1998

By Crone Duncan

The search. for massive sulphide orebodies is steadily being extended to greater depths as well as expanding outward into the large portion of the earth's surface where the sulphide bodies are deeply weathered. Massive sulphide orebodies are generally not large in dimensions. They are not like disseminated type sulphide bodies that form large ground exploration targets that can be detected at greater and greater depths simply by increasing the geometrical spacing between the geophysical transmitter and receiver. In¬creasing the transmitter-receiver spacing with massive sulphide bodies eventually "waters down" the anomaly from the body until it disappears into noise. If high surface conductivity is present, as is common in areas of deep weathering, the problem is compounded by the increasing response of the surface layer, as the receiver-transmitter spacing is expanded. The search to greater depths has important implications other than just detection of the orebody. Drilling costs are increased and the probability of missing the target are increased. Missing an orebody is an expense that is difficult to evaluate in dollars per line mile of survey especially since one does not know the value of what was missed. A ground Pulse EM method has the capabilities of solving the problems of deeper exploration particularly in areas of surface weathering it can attain deep penetration without large coil spacings, it also provides information from a complete range of frequencies. The method has other operational advantages since it is free of geometrical restrictions as to coil alignments and can operate in areas of high power line noise.

Jan 1, 1975

By D. Brabec

One of the analytical problems in exploration geochemistry is the choice of a method of sample attack which would be rapid, simple and reliable in terms of precision and discrimination between different concentration levels of elements sought. The wet sample attacks currently used in analysis of silicate rocks vary from total decomposition to leaching by weak extractants. The total decomposition of such materials is usually achieved either by alkaline fusion or hydrofluoric acid attack. The first method requires the use of platinum vessels which is both expensive and slow for batch operation. The second type of attack is more widely applied in rock geochemistry1, but it is still relatively slow for exploration purposes and requires extra care (especially when hydrofluoric acid is used in mixture with perchloric acid). Considerable improvement in speed can be achieved by using the sample attacks which release only part of the metal present in a rock.2,4 One of such attacks is the leaching of pulverized rocks by hot aqua regia.3 Another technique widely used in geochemical prospecting involves fusion of the samples with potassium pyrosulfate (or bisulfate) followed by an acid leach of the malt .5 One of the advantages of these techniques is the use of glassware in decomposition stage which considerably increases the analytical productivity. It should be noted that partial chemical attacks tend to extract from a rock mainly the non-silicate metal which may give results more significant for exploration purposes than the analysis for total metal.

Jan 1, 1970

By W. A. McKinney

In conventional dump leaching of porphyry mine strip wastes, many years are required to extract up to 20 percent of the copper from the contained sulfide minerals. Furthermore, none of the molybdenum, gold, or silver in the strip wastes is recovered by current leaching practices. Because mineralization occurs predominately along fracture planes, breaking of the rock during mining operations liberates and concentrates some of the metal values in the fines. Research shows that upgraded fines can be screened from mine wastes and froth floated for early recovery of copper, molybdenum, gold, and silver. For example, screening a dump sample assaying 0.35 percent copper as chalcopyrite removed about 20 percent of the copper as minus 1/4-inch material that analyzed 0.6 percent copper. About 35 percent of the molybdenum and 20 percent of the gold and silver also reported in the fines. Crushing the mine dump sample to minus 3 inch before screening increased the distribution of copper and molybdenum in the minus 1/4-inch screen fraction to 28 and 50 percent, respectively. Similar results were obtained by screening fines from two other large samples of mine waste dump materials. Flotation studies established that the enriched minus 1/4-inch fines from the three dump samples could be effectively concentrated. Comparative testing revealed that the combination of froth flotation of fines and acid-ferric sulfate leaching of the coarser fraction enabled doubling the recovery of copper over direct leaching of the samples. In addition, significant amounts of molybdenum, gold, arid silver were recovered by flotation.

Jan 1, 1970

By Lynda T. Holden, Philip L. LeHoux

Barneys Canyon Mine is a 1.8 million t.p.y. gold heap leach operation near Salt Lake City, Utah. The gold recovery plant has been operating since September of 1989. Carbon elution is done at atmospheric pressure with a high temperature caustic solution. No cyanide is used in the process. Operating experience is discussed.

Jan 1, 1990

By Rennie B. Kaunda, Robert J. Sterrett

Some people in the mining-engineering field mistakenly believe that mine-water management primarily revolves around the treatment of mine waters that fail to meet applicable water-quality standards. While water-quality control is undoubtedly important, it represents only a fraction of what constitutes comprehensive site-wide, minewater management. A more holistic perspective recognizes that it also involves mine dewatering to maintain safe and workable conditions, securing sufficient water supply for operations, strategically handling surface water within and surrounding the openpit to prevent issues like flooding, developing robust post-closure plans to mitigate long-term environmental effects, and proactively minimizing any adverse impacts on local communities and ecosystems. This article provides a brief overview of topics that fall within the concepts of mine-water management. The focus is on openpit mines, as they are generally larger than underground mines. The management of mine water is highly dependent on local and regional climate such as tropical, desert or temperate climate. Each climatic setting has its own unique challenges, but there are also commonalities.

Jun 1, 2025

By John E. Young

United States Steel Corporation's Winifrede Mine is operated by Lynch District in the mountainous region of Eastern Kentucky. This region is characterized by narrow mountain ridges and precipitous slows which present both an opportunity and challenge in the design and selection of coal handling facilities for the movement of coal from the section belts to the railroad cars. The narrow finger ridges precluded use of underground haulage and, thereby, presented the opportunity to use high capacity equipment on the outside bench. The precipitous mountain slopes, steepest at the Winifrede seam horizon, presented a challenge to select a solution for lowering the coal approximately 1000 feet from the seam level to the valley floor railroad load-out point. It was evident from the start of planning that these two factors predominated; namely, rail haulage and coal lowering, and solutions to these would determine the final design of the Winifrede Mine coal handling facilities.

Jan 1, 1970

By J. Paraszczak

Metal mining at great depths presents a number of serious challenges for mine operators. Among them is the high demand for fresh air required to cool down mine openings, evacuate noxious gases and contaminants and provide sufficient amounts of oxygen for miners. At the same time, modern mechanized mines extensively use diesel-powered load-haul-dump (LHD) machines, trucks and other mobile equipment. These vehicles not only emit exhaust gases and diesel particulate matter (DPM), but constitute an additional source of heat. As mine regulations get steadily more stringent with regard to air quality, the use of diesel engines has an additional adverse impact on ventilation costs. In this context, the present paper examines possible alternatives for diesel power trains, both those commercially available and those in development. They are reviewed with regard to their principles, required infrastructure, stage of technology development and progress. The questions of their flexibility, practicality and economic viability are also addressed. Finally, their possible benefits and potential for implementation in the conditions of deep metal mines are discussed. The paper concludes with short- to medium-term predictions concerning promising drive alternatives for vehicles destined to operate in deep metal mines.

Jan 1, 2009

By A. Juganda, H. PINHEIRO, J. Brune, N. SANDOVAL, G. Bogin, K. Gallagher, F Wilson

The present work discusses the nuances of scaling and flow similarity to develop a 1/40th scale version of a longwall coal mine. Details on the geometric, kinematic, and dynamic scaling of the physical model are presented and discussed. This works also discusses using a 30% CO2 – 70% He gas mixture as a surrogate for methane. It also presents the implications of various Reynolds numbers (ranging from 7,000 to 140,000) and rotation of the shearer drums in the dynamic representation of the airflow and gas mixtures in the physical scaled model.

Mar 19, 2022

By Raymond Sandiford, Kenneth Xu, Taehyun Moon

Tunnel approach structures situated in slow moving earth flows are subjected to significant earth pressures. The authors have developed a system, utilizing collapsible concrete columns, that limits such loading. The system uses an array of collapsible concrete columns in front of the structure to absorb downslope movement and limit-imposed loads. This concept has been modelled using 3D FEM analyses and a rudimental lab test. For implementation, the collapsible columns would be prefabricated in strengths to mimic the soil strength profile. This concept has merit, and analytical results demonstrate that collapsible columns are a viable means to limit loading.

Jun 23, 2024

By Keith G. Wallace

In 1982 the U.S. Congress passed the Nuclear Waste Policy Act (NWPA) to provide for the development of an underground repository for spent nuclear fuel. This development will be managed by the United States Department of Energy. In 1986, the President selected three areas for site characterization to determine their suitability for the development of an underground repository; those sites were: 1) A site in volcanic tuff located at Yucca Mountain in Nevada, 2) a site in bedded salt located in Deaf Smith County in Texas, and 3) a site in basalt located in Hanford, Washington. At present conceptual repository designs are being developed for each site. A key element of a repository design is the underground ventilation system required to support construction, nuclear waste emplacement, and potential waste retrieval. This paper describes the preliminary ventilation system designed for the repository in tuff. The concept provides separate ventilation systems for the construction and waste emplacement activities. The paper further describes the means by which acceptable environmental conditions will be re-established to allow re-entry into previously closed rooms for the purpose of inspection, maintenance or retrieval.

Jan 1, 1987

By Timothy C. Richmond

The Stillwater District is located in south central Montana approximately 75 miles southwest of Billings, the state's largest city. It lies along the northeast front of the Beartooth Mountains and is within the boundaries of the Custer and Gelatin National Forests. The district contains some of the nation's most spectacular mountain scenery. Montana's highest peaks, including 12,799 foot Granite Peak, rise a few miles south of the area. Much of the district is located on a gently undulating plateau which averages 8500 ft. above sea level, broken by hills up to 10,000 feet and slashed by glacially carved canyons, some of which are more than 3,000 feet deep.(Fig. 1) Immediately to the north and east, the land falls away to the Great Plains, stretching unbroken to the Mississippi River. Two major tributaries of the Yellowstone River, the Stillwater and Boulder Rivers, traverse the area and several large streams originate in the district itself. Access to the high mountain country and the adjoining Beartooth Primitive Area is restricted to a few horse and jeep trails continuing from the terminus of improved roads in the bottom of the Stillwater and Boulder Valleys. Hunters, fishermen and cabin owners make intensive use of the area along its improved transportation routes, but hikers seldom venture more than three miles beyond the end of the roads. People from the Billings area are the most frequent visitors.

Jan 1, 1974

By Louis Schaarschmidt, Helmut Mischo, Ibrahim Alsalamin

In order to store high-level radioactive waste underground, the German repository concept considers clay, crystalline and salt formations as suitable host rock materials (National Citizens’ Oversight Committee, 2024). The current research projects of the Chair Underground Mining Methods at TUBAF (Technical University Bergakademie Freiberg) in nuclear waste repositories mainly focus on storage within salt formations. In this scenario, the high-level radioactive waste is supposed to be packed into specifically designed containers and then transported underground and emplaced in horizontal storage drifts. The residual temperature of the radioactive waste leads to the question if there are optimization possibilities for waste handling, the storage and the long-term emplacement of such high temperature level waste. A deeper understanding of the heat transmission from the container into the host rock might lead both towards possibly shorter surface interim storage times as well as size optimization possibilities of the repository itself. TUBAF has conducted research that successfully proved that an optimized container positioning yields more favorable thermal patterns and can be achieved with conventional mining equipment.

Feb 1, 2025

By S. F. Diehl

Suites of monomineralic sulfide and carbonate minerals, as well as mine-waste composite samples, were analyzed using chemical and microanalytical techniques to understand behavior and bioavailability of mine waste elements such as Cu, Fe, Pb, or Zn. Petrographic, scanning electron microscopy (SEM), and laser-ablation inductively-coupled mass spectrometry (LA-ICP-MS) studies of mineralogical residence sites of trace elements are important because trace elements affect the chemical and physical behavior of minerals. Leachate solutions show that chalcopyrite, bornite, azurite, malachite, and galena are host to the trace elements Ag, Al, As, Cd, Co, Cr, Mn, Ni, Pb, and Zn. SEM studies reveal whether these trace elements occur within mineral inclusions or are substituted within lattice structures. SEM analysis reveals mineral phases not identified by X-ray diffraction (XRD), such as inclusions of sphalerite and cobaltite(?) within chalcopyrite.

Jan 1, 2010

By W. Nazarewicz

The introduction of continuous papermaking in the early 1800's was the beginning of the industry as we know it today. Since that time, the majority of the paper produced has employed an acid process. However, in the mid 1960?s, European producers began a transition to an alkaline papermaking process. Early European mill conversions to alkaline papermaking begun in the 601s, accelerated during the 1970's influenced by the dramatically higher cost for OPEC energy as well as the high cost of fiber and imported filler clay.

Jan 1, 1986

By John C. Draper

[Duquesne Light Company's three power plants in western Pennsylvania are now receiving high BTU clean coal from a new coal preparation plant. When burning coal from this plant, particulate emissions are greatly reduced and the sulfur content of stack ace descend. The cleaner coal also leads to more effecting overall operating of the power plants because of less bulk handling of fuel and ash. Environmental improvement is an important benefit of the cleaner, more complete combustion.]

Jan 1, 1976

By Richard B. Stein

This paper will present an overview of several hydrometallurgical processes which can be used for sea-nodule metal recovery and some simplified economics. Before going any further, here are some of the basic figures from which the economics were developed. The first is to establish a representative composition for a typical nodule feed (Slide 1). This set of chemical analysis figures can be taken as typical for a deep Pacific nodule feed and shows manganese at 30%, copper at 1.1%, cobalt at 0.2%, nickel at 13% and iron at 10% for the metals of economic interest1.

Jan 1, 1982

By William F. Abercrombie

The role of the laboratory is described in relation to the prospecting and exploration of kaolin clays. Test methods used to evaluate crude ore samples of kaolin clay for commercial consideration are reviewed. A background of the kaolin mineral and known means of prospecting this mineral are presented. Common analytical methods are discussed with special emphasis on those in use today.

Jan 1, 1982

By B. Mishra, Q. Shi, Y. Zhao, G. Zhao

Shale is anisotropic due to the presence of bedding planes. The anisotropic strength of shale has been extensively studied. However, little attention has been paid to the size effect on shale strength considering the anisotropy. This research uses the discrete element method to study the size effect on the strength of shale under the uniaxial stress state. It is assumed that the anisotropy is caused by bedding planes, while the size effect is caused by randomly distributed flaws. The numerical model of shale comprises three components: shale matrix modeled by bonded particles (2) bedding planes modeled by smooth joints (3) flaws modeled by discrete fractures. The developed model is scaled to different sizes and tested in the uniaxial compression and the direct tension tests. The test result show that the uniaxial compressive strength decreases as the specimen size increases when the loading direction is perpendicular or parallel to bedding planes. The uniaxial compressive strength is determined by the flaws while the bedding planes only play a limited role. However, the size effect on the direct tensile strength depends on the direction of bedding planes. When the loading is perpendicular to bedding planes, the size effect is not prominent. The direct tensile strength is determined by the bedding planes while the flaws have little effect. When the loading direction is parallel to bedding planes, the direct tensile strength decreases when the specimen size increases. The direct tensile strength is determined by the flaws while the bedding planes have little effect.

Mar 2, 2022

By M. W. Osterberg

The Cyprus Pinos Altos mine exploits small high grade Cu-Zn skarns using trackless equipment and a modified room and pillar mining method. The skarns occur around early Laramide diorite and quartz monzonite stocks. Stage I calc-silicates and sphalerite developed in the Pennsylvanian Magdalena Group between diorite and the marble front and were partially incorporated into a diffuse breccia body. Stage II calc-silicates and Cu sulfides formed in the contact zone with quartz monzonite and along NE-SW faults, overprinting stage I rocks and breccia. The result is a geologically complex deposit formed in two distinct pulses.

Jan 1, 1992