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By B. McFadzean, N. Patterson, M. Becker, S. Geldenhuys

The retreatment of secondary tailings for platinum group metals recovery presents a range of potential challenges, which vary depending on the nature of the original ore and the type of pretreatment it was subjected to. These challenges include the prevalence of ultrafine particles, which promote slimes coatings on valuable minerals, hinder bubble-particle attachment, increase pulp viscosity, and lead to higher gangue entrainment; surface oxidation of minerals, which alters their floatability; and the presence of deleterious gangue minerals and residual platinum group metal species that are inherently difficult to recover by flotation. This study compares the batch flotation performance across a range of tailings samples from the eastern and western limbs of the Bushveld Complex. A complementary mineralogical analysis was conducted to gain deeper insights into mineral behaviour. The paper evaluates these findings to identify the key factors contributing to poor platinum group metal performance.

Mar 6, 2026

By J. Petersen, T. Moyo, J. Dinga

The leaching of chalcopyrite in ferric sulfate media is notorious for its slow and inhibited kinetics. Different methods have been proposed to improve the kinetics, including the use of organic compounds as additives to the leaching media. In this study, the enhancing effect of methanol, ethanol, 1-propanol, and 2-propanol on the leaching of chalcopyrite in aerated acid ferric sulfate solutions using different reactor systems was investigated. The results revealed a clear improvement of copper dissolution by methanol and 1-propanol relative to tests with no additives under similar conditions. Operating a continuous-flow mini-column reactor yields surprisingly good results, potentially related to the maintaining of a consistent leaching micro-environment on the mineral surface. Scanning electron microscopy studies showed that the alcohols result in the removal of surface deposits formed during the anodic dissolution, potentially thus facilitating improved cathodic reduction of the ferric ion to drive the anodic dissolution.

Jan 1, 2023

By J. Hadjigeorgiou, G. Knox

There is a considerable wealth of information on the behaviour of rockbolts under axial loading conditions both in situ and under controlled laboratory conditions. However, there is comparably less data on the behaviour of rockbolts in shear. Several authors have contributed to the understanding of the behaviour of conventional rockbolts’ performance under shear loading. Much of this data have been gathered through experimental programmes conducted on sections of the rockbolt. Considering the continuous coupling between the rockbolt and borehole interface, the approach is justified. Due to the design premise of energy-absorbing rockbolts with discrete couplings, full scale testing is required to quantify the behaviour of the rockbolts. This paper reviews published results obtained from two testing facilities, which are the SINTEF rockbolt pull test rig in Trondheim, Norway and the Epiroc Combinations Shear and Tensile test rig in Johannesburg, South Africa, both capable of conducting full scale testing of rockbolts. Based on this high-quality database it was possible to identify three distinct responses of rockbolts in shear. The behaviour under load is controlled by the presence or absence of an encapsulation medium (resin/cement grout), the reinforcement mechanism, and whether the rockbolt is continuously or discretely captured. As a reference the results are compared to the performance in shear of conventional grouted rockbolts.

Nov 24, 2025

By F. Shi , D. Lay, C. Antonio

High Voltage Pulse (HVP) technology has the potential to transform traditional mineral processing practice in the mining industry. HVP pre-treatment has been shown to enable ore preconcentration, achieve ore pre-weakening and improve mineral liberation. In order to improve the efficiencies of these novel HVP applications, it is essential to understand how HVP operational factors affect ore breakage in HVP pre-treatment. A two-level fractional factorial experiment using two rock samples, a gold-copper ore and a basalt sample, was performed to determine which factors have statistically significant influences on breakage probability, size reduction, and energy efficiency, and which factors have insignificant influences. Operational factors investigated include applied voltage, electrode gap, number of pulse discharges, the number of rocks being processed per batch, and rock size. In total, 1920 batch tests were conducted. For ore breakage characterised in terms of breakage probability and the degree of size reduction during HVP pre-treatment, the dominant factors were identified to be the number of pulse discharges, voltage, and the number of particles present in the processing zone. As all these three factors are related to the specific energy, it is concluded that the specific energy is the most important factor controlling ore breakage in HVP treatment. In terms of the efficiency by which spark energy is transferred from the generator energy, the factors found to have the most dominating influence were the particle size, the number of rock particles present in the processing zone and the voltage. Increasing the values of these factors reduced the loss of HVP energy during the energy transfer process. The factorial experiment using the two ore samples with vastly different mineralisation produced similar results. This proves that the dominant factors affecting HVP breakage are generally applicable to different ores types. Keywords: High voltage pulse, ore breakage, factorial experiment, specific energy

Jan 1, 2020

By L. Ziyuan, S. Chunbao, K. Jue, H. Yang, S. Tichang

In this study, potassium ferrocyanide, a non-toxic cyanide precursor in dark and diffuse reflection environments, was applied as a reagent for the leaching of gold. The free cyanide ions were gradually released from the potassium ferrocyanide solution under the ultraviolet light. Orthogonal leaching experiments were performed in gold ore to analyse the effect of solution pH, potassium ferrocyanide dosage, and temperature in potassium ferrocyanide solution system under UV light. Response surface methodology (RSM) was applied to explore the role of potassium ferrocyanide in gold leaching, Optimised results showed that the gold recovery reached 67.74% in a high-alkaline environment at a 12.6 pH, 3.8 kg/t potassium ferrocyanide dosage, 62°C, and irradiance of 10mW/cm-2. The gold leaching kinetics was monitored by quartz crystal microbalance with dissipation (QCM-D) of potassium ferrocyanide solution. The results indicate that the gold extraction process consists of two processes: adsorption and leaching, and a rigid adsorption layer formed on the reaction surface. Furthermore, Xray photoelectron spectroscopy (XPS) analysis of the gold sensor surface after leaching reaction showed that -C≡N appears on the gold sensor surface, and the gold is oxidised to form AuCN complexes. Keywords: Gold leaching, potassium ferrocyanide, UV light, QCM-D, AuCN complexes

Jan 1, 2020

By A. N. Brown

Underground rock boring was the topic of the mining vacation school held at the University of the Witwatersrand in the week 4th to 8th February, 1980. The School, which dealt with the management and economics of the subject, attracted 75 delegates from all sectors of the South African mining industry, in addition to two delegates from Germany and one from Zambia.

Jan 1, 1980

By B. P. Watson, D. P. Roberts, R. A. Lamos

The Upper Group 2 (UG2) chromitite reef is a shallow-dipping stratiform tabular orebody in the South African Bushveld Complex, which strikes for hundreds of kilometres. Mining is extensive, with depths ranging from close-to-surface to 2 500 m. Pillars are widely used to support the open stopes and bords. Little work has been done in the past to determine the strength of pillars on the UG2 Reef and design was done using formulae developed for other hard-rock mines. This has led to oversized pillars with consequent sterilization of ore. In this paper we describe a back-analysis of stable and failed UG2 pillars on the Bushveld platinum mines, and provides a strength formula for UG2 pillars. The formula may be used cautiously on all Bushveld platinum mines with similar geotechnical, geometrical, and geomechanical conditions to the pillars in the database.

Aug 1, 2021

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By Ri McCrindle

"Analytical Chemistry is moving rapidly towards a concept where technicians have to do no more than press a button and print the result from an instrument that is a featureless ""black box"". In this environment we must ask how much traditional ''wet chemistry"" is still required for undergraduate students.Methods that can be fully automated will become increasingly important. An example of such a method is that of the slurry nebulisation and ICP-OES analysis of precious metal concentrate. Grinding the sample and adding Triton X100 as dispersant, complete analysis time is in the order of 90 min as apposed to the traditional Carius tube method which could take as long as 24 h. For most of the elements studied, the results using ""in-house"" reference material for calibration and as samples as well were within the 95% confidence level. Elements of low concentration in the sample (As, Bi and Se) were not within that level."

Jan 1, 2014

By W. Ferreira

Steel is produced in a basic oxygen furnace from hot metal obtained from a blast furnace. A sintered iron ore with good hightemperature properties (strength and permeability) should be used as feed to the blast furnace. The quality of this sintered ore depends on the reactivity of the iron ore used as feed to the sinter plant during the lime assimilation step in the sintering process. The penetration test is the standard method for evaluating the reactivity of iron ore with lime. It is, however, difficult to determine the exact depth of penetration from the standard test. A new test method is proposed that allows automatic evaluation of iron ores in terms of lime assimilation with increasing temperature. A comparison of the coefficients of variation for the new and standard methods for each ore type demonstrates that the results of the new test are more reproducible and more precise than those of the standard method. The test is also less time-consuming and easier to implement.

Jan 1, 2014

By Y. J. Cao

The purpose of this study was to investigate the flotation behaviour of unburned carbon in a cyclonic-static microbubble flotation column (FCSMC). The ash sample, collected from a power station in Guangdong province of China, was characterized by size analysis, X-ray diffraction, contact angle measurements, and X-ray fluorescence. The effect of the column flotation operating variables on the removal of unburned carbon from the fly ash was systematically studied. The feasibility of separating unburned carbon and ash was determined from the removal rate of unburned carbon (RUC) and loss on ignition (LOI). Within the range studied, the optimum diesel oil dosage was 1200 g/t, abies oil dosage was 600 g/t, pulp density was 20 per cent, superficial gas velocity was 1.4 cm/s, and circulating pressure was 0.20 MPa. The results indicate that the FCSMC technique is effective in removing the unburned carbon from the fly ash, which can be attributed to the generation of microbubbles and the continuous cyclonic circulation method. Under the optimized conditions, a cleaning ash with 2.13 per cent LOI and 94.21 per cent RUC was obtained.

Jan 1, 2012

By J. A. Batista-Rodríguez, F. J. López-Saucedo

A new methodology is proposed for the preliminary assessment of coal blend quality, which combines gamma-ray spectrometry and magnetic susceptibility measurements. This methodology does not replacethe conventional methods of assessing coal quality, but can help to control the quality of the coal blending process, as well as reduce the amount of proximate analysis required and the determinations of calorific value and total sulphur. The methodology includes five steps. First, both geophysical measurements aremade with handheld equipment. The samples with magnetic susceptibility ≤ 1 × 10-3 SI are then separated. From these samples, those with total gamma intensity ≤ 20 nGy/h are separated. These samples have a higher calorific value and lower ash and moisture content. To separate the samples of better quality and with lower total sulphur content, in step four the samples with total gamma intensity > 20 nGy/h are separated from those with magnetic susceptibility ≤ 1 × 10-3 SI. This last group includes samplesthat will cause less total sulphur-related environmental pollution. In the final step, the quality of both radioactive sample groups is corroborated from the calorific value measurement and ash, moisture, andtotal sulphur contents in at least 10% of all coal blend samples from both groups. In this study, more than1000 samples were analysed with this new methodology, and the results are remarkably similar to the ASTM classification of the Sabinas Basin coals.

Apr 2, 2022

By J. Mulenshi, J. Rosenkranz, P. Khavari, S. C. Chelgani

The geometallurgical concept has mainly been applied to primary ore deposits, starting from ore characterisation to the economic optimisation of the mining operation. However, as primary ore resources are becoming depleted and lower in grade, alternative sources need to be explored and a question of adaptability of the geometallurgical approach to the secondary resource repositories arises. The particle size distribution, chemical and mineralogical compositions of the Smaltjärnen historical tungsten tailings from physical separation in Yxsjöberg, Sweden were studied using drill core samples collected from different locations within the tailings repository in order to assess the amenability of the tailings to reprocessing. The tailings are dominated by the –600 to +149 μm particle size fraction. This fraction contains most of the elements of interest (W, Cu, S, Sn, Zn, Be, Bi and F) hosted by scheelite, chalcopyrite, pyrrhotite, cassiterite, danalite (both Zn and Be), bismuthinite and fluorite, respectively. The particle size distribution and mineralogical composition vary across the repository, suggesting a possible existence of geometallurgical domains, which require further assessment to evaluate metallurgical performance. Keywords: Historical tailings, tungsten, scheelite, geometallurgy, characterisation, mineralogy, reprocessing

Jan 1, 2020

By T. Szendrei, S. Tose

The generally accepted view in rock blasting is that the sources of energy for the fracture and movement of rock reside in the shock wave and gas action resulting from the explosion, and yet the mechanisms by which these sources interact with the rock have remained unclarified. It has also been noted that up to 50% of the work capacity of an explosive released in a blast cannot be accounted for by field measurements of energy partitioning. In this study, we describe a physical model that details the response of rock to both shock wave and gas action. An analytical model based on momentum conservation is derived to describe the dynamics of shock-driven expansion of the blasthole. Radial expansion of the hole is the key parameter that permits the derivation of the following characteristics of rock response to shock loads: hole expansion time; volume of displaced rock; energy consumed per unit volume; expansion energy efficiency; stress wave pulse length; gas pressure in enlarged hole. Soon after the completion of hole expansion, the shock wave degenerates to an elastic stress wave that runs through the burden. Blasthole expansions of between 50% and 300% of diameter are completed in under 1 ms and, depending on rock properties, consume 32% to 42% of the detonation energy or about 55% of the available mechanical (Gurney) energy. Gas pressure in the enlarged holes in five rock types is between 35 MPa and 650 MPa, and drives the mass movement of burden rock.

Oct 9, 2024

By T. Nesane, S. S. Mnyakeni-Moleele, L. C. Murulana

The effectiveness of two synthesized ionic liquids, 1-(benzyloxy)-1-oxopropan-2-aminium 4-methylbenzenesulfonate (1-BOPAMS) and 4-(benzyloxy)-4-oxobutan-1-aminium 4-methylbenzenesulfonate (4-BOBAMS), were evaluated for mild steel corrosion inhibition in 1.0 M hydro-chloric acid solution, using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), and gravimetric techniques. Organic moieties responsible for the adsorption process on mild steel surface were investigated using Fourier transform infrared spectroscopy (FTIR). Gravimetric analysis revealed that the inhibition efficiency of 1-BOPAMS and 4-BOBAMS increased with concentration, with maximum inhibition values of 90.32% and 97.91%, respectively, at the highest concentration of the inhibitors. Gibbs free energy (ΔG°ads) values indicated a strong interaction between the mild steel surface and the molecules of the ionic liquids, and that the adsorption process was spontaneous. These values also show that the inhibitive nature of ionic liquids against mild steel corrosion is caused by a mixedtype of adsorption film formed on the steel surface. The Langmuir adsorption isotherm was used to describe the adsorption of ionic liquid molecules onto the mild steel surface. Polarization curves showed that 1-BOPAMS and 4-BOBAMS have a similar effect on both the anodic and cathodic half-reactions, indicating that they prevent the dissolution of mild steel through both physical and chemical process. Nyquist plots were defined by incomplete semicircle capacitive loops, showing that the charge transfer mechanism controls the corrosion of mild steel in acidic solution.

Apr 1, 2021

By A. Galibois, A. Dubé, H. Monette, J. L. Collins

"The start of mining operations often raises serious financial problems. In marginal cases promoters frequently demand financial aid from governments.In the past, the financial assistance has taken the form of gifts, procurement contracts, etc., but aid in such form has been severely criticized. A new formula has been developed to provide a more equitable distribution of the revenues accruing to the government and to private capital.The benefits to these two parties have been evaluated in an hypothetical case and compared in terms of internal rates of return on their investment, their shares of the undiscounted cash flows and their primary profits.The method based on the non-zero sum game theory provides a means for suggesting the lowest feasible annual production and the optimal sum contributed by the government in the form of outright gift, equity capital and convertible bonds. Other financial hypotheses can also be optimized by the computerized analysis."

Jan 1, 2014

By I. Silin, H. Wotruba, A. Liono, I. Volobayev, Y. Rubinstein, D. Gürsel

Old, abandoned or in situ processed and storaged tailings can be a potential source of remained valuable metals and minerals. By reprocessing of tailings, it is possible not only to achieve economical profit from recovery of valuable metals, but also to reduce environmental damage caused by tailings such as generation of acid mine drainage from sulfide minerals, mobilization of heavy metals, soils and groundwater contamination. In addition, storage facilities can be successfully redesigned with modern geotechnical requirements and monitoring to avoid a dam collapse of abandoned tailings. In this case study, the processing of low grade abandoned tailings was investigated. Copper (0.15%), cobalt (0.032%) and gold (0.35 ppm) were determined as main valuable and recoverable metals. Cobalt occurs as cobaltite and cobaltiferrous pyrite, while chalcopyrite represents copper. The fine fraction of tailings below 32 μm is enriched with cobalt and copper. Preliminary test-works with initial tailings sample were aimed to recover copper, cobalt and gold. The previously tested magnetic and gravity separation could not recover the metals in a pre-concentration step. Flotation tests of the tailings sample had shown a suitability for flotation without previous regrinding of the tailings. The valuable minerals are first proposed to be recovered by collective flotation, followed by a selective circuit with production of a low grade copper concentrate and a cobalt bearing pyrite concentrate. Based on various tested collectors, amounts of sulfidisation agents and activators, a suitable reagents regime was determined and used for up-scaling by locked cycled test. Keywords: reprocessing, tailings, copper, cobalt, gold, flotation, cobaltite, cobaltiferrous pyrite

Jan 1, 2020

Exxaro installed their first ultra fines treatment plant at Leeuwpan Coal mine. The plant is now fully operational and results already show that the plant has great potential. The plant was designed and installed by DRA. Several challenges were faced during the installation due to the space constraints in the Leeuwpan plant. Efficiency tests were conducted on both modules after commissioning and showed very promising results. A lower ash product with a higher yield can be produced with the fine coal dense medium cyclones compared to the spirals previously employed.

Jan 1, 2010

By J. E. Xu, J. Y. Zhang, M. Q. Sheng, K. Wan

"SynopsisThe densities of selected CaO-Al2O3-MgO slag systems were measured at 1823K by the Archimedean method. Thirteen different slag compositions were chosen based on different levels of the MgO content and the mass ratio of CaO/Al2O3. The results indicated that the density of the slag decreases with increasing MgO content (from 0–3.78 mass%), but increases with further increases in MgO content up to 11.33 mass%. At a fixed MgO content of 5.5%, the trend of density change with CaO/Al2O3 in the slag is similar to that for changes in MgO content. On the basis of the regular solution approximation rules of excess molar quantities, an attempt was made to estimate the molar volume of the slags investigated. The application of the molar volume model confirmed that the present expanded approximation rules are applicable to predict the molar volumes of the melts discussed.IntroductionDensity is one of the most important fundamental properties of slags, which influences metallurgicaly phenomena in many ways. Density is sensitive to the nature of the chemical bonds and the species in the melt, and is of great importance not only for theoretical research on the structural properties of molten slags, but also for industrial applications. Density is also required to estimate other key properties used to assess the behaviour of high-temperature molten oxides, e.g. viscosity, surface tension, and thermal conductivity.Liquid calcium aluminate slags that contain magnesia are the basis of most ladle slags for secondary refining processes. The CaO-Al2O3 binary phase diagram (Hallstedt , 1990) shows the eutectic composition (50 wt% CaO and wt% Al2O3) has the lowest melting temperature. The main emphasis of this study is on the 12CaO·7Al2O3 refining slag with MgO additions. The CaO-Al2O3-MgO ternary system is of considerable importance in industrial metallurgical processes, and is fundamental to the understanding of metallurgical slags, ceramic materials, and geological phenomena."

Jan 1, 2015

By F. P. Janse van Rensburg, P. J. Le Roux

"There are numerous factors that affect open stope stability and often result in falls of ground. These falls of ground can be attributed to factors such as beam failure due to a larger than normal roof area (hydraulic radius too large), adverse ground conditions, seismicity, the stress-strain environment, absence of support, and poor drill-and-blast practices. The effect of time on the stability of open stopes is sometimes underestimated and is relatively unknown, especially on Target Mine. Actual data was collected from open stopes at Target and analysed to show the effect of time on open stope stability. The benefits of this analysis will include improved understanding of time-dependent failure, which can assist in reducing dilution and the risk of sterilization of future mining blocks. IntroductionTarget Mine is situated adjacent to the town of Allanridge, some 20 km from Welkom in South Africa’s Free State Province, and is the most northerly mine in the Welkom Goldfields area (Figure 1). The mine consists of a single surface shaft system with a sub-shaft (Target 1C shaft) and a decline. Ownership was attained by Harmony Gold Mining Company Limited in May 2004 (Harmony Gold Mining Company Limited, 2010). Before discussing the selection of open stopes for the back-analyses, a brief explanation of open stoping as practiced at Target Mine will be given. The orebody is some 180 m in thickness and 270 m wide and comprises multiple reefs overlying one another. The 180 m thick reef package is termed the Eldorado Reefs, as shown in Figure 2. The Eldorado Reefs suboutcrop against the Dreyerskuil Reefs, as shown in Figure 3. The dip of the reef varies from as low as 10° in the west to 75° in the east.Compared with most Australian and Canadian open stoping mining operations, Target Mine is unique. In most Australian and Canadian mining operations the hangingwall and footwall of the open stopes comprise waste rock, and the orebody dips relatively steeply. Due to the depth of Target Mine, some 2300 m to 2500 m below surface, a destress slot (Figure 4) is mined to create an artificial, shallow mining environment whereby the field stress is managed and kept at values of around 60 MPa. The destress slot comprises a narrow tabular stope with an average width of 1.5 m, and is mined on the Dreyerskuil Reefs.At Target Mine the hangingwall, sidewalls, and footwall of the open stopes all comprise reef of different grades, except for the EA1, where the EB footwall is waste rock. If a stope, for example, is mined alongside an existing old stope, the western sidewall of this stope will consist of backfill. The general mining direction of open stopes is from the lowest position of the reef on the west, progressing up towards the east as shown in Figure 5."

Apr 1, 2019