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By David F. Smith

The American Society for Testing Materials4 has recommended that the melting temperature of potassium chromate be used-for indicating the temperature to which a coal sample should be heated in the standard method of analysis to determine its volatile matter content. The specified temperature is 950± 20° C., the melting point of potassium chromate being noted as 940° C. Le Chatelier5 originally found the melting point to be 975°; later6 he found 9400. According to Shemtschushny7 the melting point is 984°; he also found a transition at 679°. Groschuff8 found the melting point to be 971° and the transition temperature 679°. Amadori9 reports a melting point of 9.78° and a transition point of 666°. The International Critical Tables10 take the melting point as 975°, which is estimated to be correct to two significant figures. In view of the apparent uncertainty existing, it has been though worthwhile to make a careful redetermination of this datum. It is of interest not only to determine the melting point of the pure salt, but also of the commercial product, in order to test its suitability for use as a temperature indicator. The work was suggested by A. C. Fieldner, chief engineer, experiment stations division, U. S. Bureau of Mines.

Jan 1, 1929

By M. M. Tilman

The Bureau of Mines conducted research into the dispersion strengthening of lead by the coprecipitation method. Commercially available reagents in water solutions were reacted to form homogeneous precipitates of lead and aluminum compounds. The resulting precipitates were roasted to oxides and reduced in hydrogen to form mixtures of lead powder and alumina. The powders were isostatically pressed into billets which were extruded into rods. The rods were rolled into strip to provide material for testing. Alloys containing 0.5, 1, 2, and 3 nominal volume-percent A1203 were tested in short-time tensile tests and in tensile creep tests. An alloy of Pb-3 volume-percent A1203 exhibited an average tensile strength of 8,570 psi after rolling to 75-percent reduction at 125° C but had no measurable elongation. Alloys of lower A1203 content provided a better compromise between tensile strength and ductility. For example, an alloy of Pb-0.5 volume-percent A1203 had an average tensile strength of 6,590 psi with 9-percent elongation after rolling to 75-percent reduction at 125° C. Creep rates of dispersion-strengthened Pb-A1203 alloys were below 1 percent in 10,000 hours at stresses of 2,000 to 4,000 psi.

Jan 1, 1971

By Peter N. Gabby

A mineral survey of 8,300 acres of the 24,980-acre Burnt Creek Wilderness Study Area (ID 45-12), was conducted by the U.S. Bureau of Mines in 1985 at the request of the Bureau of Land Management. The study area is located in Custer County, ID, 90 miles northwest of Idaho Falls. No mines, claims, or prospects are in the study area. The northern half of the study area and adjacent lands to the north, northeast, and east are or were recently under oil and gas lease, Basalt and latite-andesite of the Challis Volcanics predominate in the study area. Several hundred feet east of the study area is a quarry in talus of Mississippian-age limestone that was used for sized 100-pound rock fill in the Old Dry Creek Reservoir dam. Two samples, one taken at the quarry and the other at a limestone outcrop on East Fork Burnt Creek, have CaC03 content in the range of 90 to 95 percent, and is suitable as the limestone component of Portland cement, However, limestone outside the study area could supply foreseeable demand. Lead- silver mineralization has been observed in Paleozoic carbonate rocks elsewhere in the Lost River Range, but these rocks do not occur in the study area.

Jan 1, 1986

By Richard G. Burdick

The Bureau of Mines conducted this research to determine the feasibility of using soil redox measurements, a relatively new method in mining geophysics, to locate or define a variety of conditions that are hazardous or otherwise of interest to the mining industry. The method was used in three widely separated areas in an attempt to de- fine subsurface concentrations of methane, the edges of coal-burn areas, and a hydrothermal vein set. Both a description of the method used and test cases are given in this report.

Jan 1, 1982

By I. AITKENS

Tourmalines are among the most beautiful of all the semiprecious stones, and are unsurpassed even by corundum in variety of hue. The stones most suited to jewelry purposes are those comparatively free from iron. One reason for the fact that the tourmaline has advanced rapidly in public favor in this country is that it is found in California in great profusion and of extraordinary quality. The superb green and especially the pink crystals found at Pala and Mesa Grande in San Diego County, Calif., are deemed superior to tourmalines from all other localities.

Nov 1, 1931

By Guy A. Johnson

Despite the use of warning alarms to alert miners to the backward movement of large mining equipment, miners still are injured too frequently in backup accidents. Currently approved backup alarm technology consists of continuous sounding alarm systems. New technology has developed a warning system that initiates an alarm only if there is an object close behind the vehicle. This advancement eliminates constant exposure to the alarm because a warning is given only in case of a potential collision. Adoption of this development can improve safety and reduce damage, especially for front-end loaders (FEL's). It will also eliminate a source of nuisance noise in urban and residential areas. This Bureau of Mines report describes the general characteristics of infrared (IR) light, ultrasonic wave, and Doppler radar technology as used for backup alarms, and reviews the testing of the most promising detection devices.

Jan 1, 1986

By M. M. Fine

In an experimental study by the Bureau of Mines, in cooperation with National Lead Co., the roast-flotation process was found to be an effective means of upgrading certain cobalt-nickel stockpiles. The research was undertaken to determine whether the process could yield an enriched feed, with a minimum cobalt content of 6.0 percent, for the company refinery. The stockpiles (products of the company Fredericktown, Mo., milling operations) were essentially complex sulfides of cobalt, nickel, copper, lead, and iron, 1 sample of which contained 2.84 percent Co and 3.57 percent Ni. After a controlled oxidizing roast at 400° C., laboratory flotation with conventional sulfhydric reagents yielded an enriched concentrate analyzing 9.22 percent Co and 11.43 percent Ni, with recoveries of 84.9 and 85.8 percent, respectively. These are typical laboratory data; other data indicated higher grades were possible but at reduced recoveries. A brief, continuous campaign verified the applicability of the process to the raw material in question but was not continued long enough to establish optimum conditions. As a consequence, the results of the large-scale tests did not equal those obtained in the laboratory but definitely confirm the beneficiation possible from the roast-flotation process.

Jan 1, 1958

By J. H. Jansky, P. W. Jeran, G. L. Hassett, M. C. Irani

This Bureau of Mines report tabulates methane emissions from U.S. bituminous coal mines with daily emission rates of at least 100,000 cfd according to States, counties, and coalbeds. Most of the methane emitted is from mines in the Appalachian States. Total daily emissionin 1975 was 216.3 MMcfd, compared with 227.0 MMcfd in 1971 and 214.5 MMcfd in 1973. Thirty counties in nine States had daily methane emissions of 1 MMcfd or more, These emitted 93 percent of the total methane. The highest emissions were from Monongalia County, W. Va,, which accounted for 18.9 percent of the total. This was followed by Marion County, W. Va., 9.6 percent; Buchanan County, Va., 8.5 percent; Jefferson County, Ala., 6.1 percent; and Washington County, Pa., 5.9 percent. The Pittsburgh coalbed emitted 45.7 percent of the total methane, followed by the Pocahontas No. 3 coalbed with 12.9 percent. The report lists 196 mines, of which 60 had daily methane emissions of 1 MMcfd or more. Included in this compilation are the identification and thickness of the coalbed, methane emission, coal production and ventilation rates, number of drifts, shafts, and slopes used for ventilation purposes, shaft depth, age of mine, and gas-to-coal ratio.

Jan 1, 1975

Measure dangerously high concentrations (20 to 500 g/m3) of flammable, airborne dust. Approach Development of high concentration dust monitor (HCDM) which will measure mass concentrations of air borne dust by the principle of beta-ray attenuation. How It Works The HCDM is a battery powered, portable instrument that weighs 10.5 kg. It is capable of making continual (10 sec. time resolution) measurements of high concentrations of airborne dust and can record up to 8 hours of data in an internal memory. The data can be read out later on an analog or digital recorder. An internal pump pulls airborne dust into the sampling section, which contains a low-energy beta-ray source and a Geiger counter detector. No beta radiation escapes from the instrument, and no license is required for the operator. The mass concentration measurement is made while the dust is still airborne. Beta-ray attentuation is independent of particle size and composition of the dust, so the HCDM can he used with many types of dusts which may be airborne in flammable concentrations. A knowledge of the composition and minimum explosive concentration of the dust is necessary to understand the significance of the data from the HCDM. The HCDM was designed to measure air-

Jan 1, 1982

By Tobias W. Goodman

The U.S. Bureau of Mines used a contact drilling strategy with short-collared assemblies in order to rotary drill long horizontal methane drainage holes in the Beckley Coalbed near Glen Daniel, WV. By decreasing the thrust, and increasing the rotation of the drill bit when in contact with the roof and floor rock, assemblies with 1-ft (0.3-m), 10-ft (3- m), and 144 (43-m) long collars were made in deflect and stay in the coalbed. Successful application of this procedure resulted in holes drilled full length in coal with the original assembly including bit. The test assemblies deflected away from the original bearings of the holes during drilling and arced. Four holes were drilled to depths ranging from 478 ft (145.7 m) before the strategy was developed, to 4,034 ft (1,230 m) when the strategy was applied. Total length of the holes in coal was 8,590 ft (2,618 m). After 577 days the total methane captured by the holes was 221,600,000 ft? (6,276,000 m3). The methane flow rate peaked at 805,000 ft3/d (22,798 m3/d), then decreased to stabilize at 670,000 ft?/d (18,974 m3/d) after 6 months.

Jan 1, 1989

By Kenneth H. Johnston

Information on oil and water production, volume of water injected, core analyses, and well completion data was collected on 28 Red Fork sand water-flood projects for comparison and evaluation of results. An average water injection efficiency of 35 percent, an average water-injected to oil-produced ratio of 16.8:1, and an average loss outside the flood pattern of approximately 45 percent of the injected fluid resulted in an oil recovery to January 1, 1969, of only 5.6 percent of the pore volume, or 9.1 percent of the initial stock-tank oil in place. The principal causes of poor oil recovery from these projects are the losses of large quantities of injection water from the flood patterns through oriented, natural fracture systems or zones of high permeability and excessive channeling of injection fluids from input wells to oil wells. For more efficient operation and a higher percentage of oil recovery from the Red Fork sand and other low-permeability-sand waterflood projects, directional orientation of both induced-and natural-fracture systems should be determined during early development. The success of a low-permeability-sand waterflood project depends to a large extent upon the orientation of the injection wells with the fracture system.

Jan 1, 1970

By B. W. Jong

The U.S. Bureau of Mines investigated anhydrous chlorination and caustic-acid leaching processes to recover Ni, Co, Mo, and W from waste hydroprocessing catalysts. In batch laboratory-scale equipment, the chlorination process extracted 61 to 99 pet of the metals. Final recovery was 65 to 99 pct. The caustic-acid leaching process extracted 81 to 98 pct of the metals. Final recovery was 36 to 99 pct. Chlorination processing included roasting, chlorination, hydrolysis of metal chlorides for recovering Mo or W, water leaching of Ni or Co from the spent charge, purification, and solvent extraction or precipitation of Ni or Co from the purified solutions. Caustic-acid leach processing included NaOH leaching, solvent extraction of Mo or W from the NaOH leach liquor, H2S04 leaching of the NaOH leach residue, purification, and solvent extraction or precipitation of Ni or Co from the purified solution. The estimated fixed capital cost for a commercial-scale plant processing 39,000 Ibid of waste Ni-Mo-AI catalyst was $8 million for the chlorination process and $9.6 million for the caustic-acid leaching process. The estimated operating cost was about $0.20 and $0.40 per pound of the waste catalyst, respectively, for the two processes.

Jan 1, 1989

By R. C. Gabler

Laboratory tests on a combined nitrogen roast--two-stage leach--electro-winning approach show promise as a possible process for recovering copper, sulfur, iron oxide, and valuable minor metals (gold, silver, and molybdenum) with a minimum impact on the environment. During the nitrogen roast at 800° C, 15 to 20 percent of the sulfur together with a significant fraction of the volatile elements, such as arsenic, bismuth, lead, and zinc, are removed from the chalcopyrite concentrate. The resulting calcine, consisting of 8-chalcopyrite, troilite, and a bornitelike structure, is leached with hydro-chloric acid to remove 70 to 85 percent of the iron. The digenite in the leach residue is dissolved in an oxygen-saturated, spent sulfate electrolyte. Using a graphite 'anode plus sulfur dioxide to reduce interference from ferric iron, copper of 99.99+ purity is electrowon at current efficiencies of 88 to 92 percent and a cell voltage of 0.4 to 0.5 volt. Copper recovery for the overall process is 98 to 99 percent. Sulfur is obtained in the elemental form from the roasting and leaching steps. Iron can be recovered from the hydro-chloric acid leach solution. Gold, silver, and molybdenum are concentrated in the silica residue from the spent electrolyte leach.

Jan 1, 1975

By Richard J. Mainiero, Marcia L. Harris, James H. Rowland

In the past several years, there have been a number of blasting-related carbon monoxide migration incidents. In each case, there have been some common factors that appear to be related to carbon monoxide migration. Geology, heavy confinement of the blast, close proximity to the affected structure, and open pathways into the affected structure are just a few. Prince William County, VA is an area undergoing a boom in suburban development. In the year 2001, more than 4,050 new homes were constructed within the county.1 In the new housing development located in Bristow,VA, trench blasting was utilized to excavate proposed sewage and utility lines. On November 8, 2002, a trench blast was conducted for the installation of utility lines. Later that evening a carbon monoxide detector alarmed in a nearby house. The gas company and fire department sampled for carbon monoxide and measured 100 ppm and more than 200 ppm on the first floor and in the basement respectively. Subsequent efforts to prevent migration of CO into the nearby homes met with mixed results. The only reliable technique for protecting neighbors from CO appears to be the placement of CO monitors in the homes. The events are presented and discussed.

Permit quicker, safer clearance of hang-ups in the ore passes and chutes of underground mines. Approach Develop a device that can be operated from a safe distance to explosively propel a projectile into the hang-up. How It Works The Hang-Up Clearance Module, consisting of a stand, steel disk, explosive charge, and aiming device, is placed at a location convenient for line of sight aiming at the hang-up. This placement can be more than 100 feet from the target. Once aimed, the charge is remotely detonated, and the disk is converted by explosive force into a slug and propelled to the hang-up, bringing it down. The steel disk and an explosive charge are contained by a plastic casing. A small booster which is placed at the rear center of the explosive makes up the last component of the charge. Initiation is accomplished by standard means such as detonating cord or a number 8 blasting cap. When Initiated, a detonation wave travels through the explosive, inverting and consolidating the steel disk into a large slug. This slug is propelled at high velocity to the hang-up, delivering more than 5 million foot-pounds of energy on impact.

Jan 1, 1981

By Travis Q. Lyday

The Other South Pacific Island states extend from Palau, also called Belau, near the Philippines in the west, to French Polynesia in the east. However, a number of countries and territories have been omitted, from this chapter because their mineral production was insignificant to the local economy. These include the French over-seas territories of French Polynesia and Wallis and Futuna Islands; independent states, including Kiribati, Marshall Islands, Micronesia, Palau, Tonga, Tuvalu, and Vanuatu; the New Zealand freely associated state of the Cook Islands, and the New Zealand dependency of Niue. What mineral production existed in these islands was limited to construction materials such as coral reef limestone, crushed stone, and sand and gravel in minor quantities solely for domestic consumption. FIJI The mineral industry of Fiji continued to be dominated by gold, although this sector contributed less than 1 % to the gross domestic product (GDP) of the country. Gold and silver together ranked second in value among the country's exports. Fiji's economy contracted 11% during the 8-month period following the first, on May 14, of two military coups. Although the island nation had been a member of the British Commonwealth of Nations since its independence on October 10, 1970, Fiji's membership terminated with the emergence of the Republic or Fiji on October 15.

Jan 1, 1989

By D. W. Frommer

Processing of nonmagnetic taconites by selective flocculation-des liming and anionic flotation of calcium-activated silica has been investigated using innovative procedures as a means of improving operating costs. Areas chosen for cost-cutting evaluation were grinding, fine screening, and water conservation and reclamation. The investigation was performed on Marquette range nonmagnetic taconites in the Bureau of Mines Twin Cities Metallurgy Research Center flotation pilot plant, at feed rates ranging between 900 and 1,100 lb/hr. With fully integrated water reclamation, flotation concentrates containing 65.8 percent Fe and 3.4 percent Si02 were made in the best operating period, with accompanying weight and iron recoveries of 40 and 74 percent, respectively. During this same period, the estimated cost of both flotation and water reclamation reagents was only $0.80 per ton of concentrate (1968 pricing basis). This cost is about 15 percent lower than obtained previously at this Center for flotation reagents only. The investigation demonstrated additional potential savings in operating costs of approximately $0.96 per ton of concentrate through autogenous grinding as a substitute for ballmilling. Fine screening of intermediate concentrates was employed advantageously, but the frequency of blinding may be a factor militating against use of the screen in this flotation system.

Jan 1, 1973

By C. B. Manula, R. L. Sanford, R. A. Rivell

The large amount of computer code required for this simulation model dictates that reasonable limitations be placed on some of the input variables. The program permits the following maximum sizes: 1. Ten mine car stations 2. Twenty track intersections 3. Three hundred mine cars 4. Eight motors 5. One hundred profiles 6. Twelve intersections between stations 7. Forty-five profile changes between stations 8. Thirty station pairs (routes) These may be changed by the user providing the particular computer in use has available core storage. Major Array Descriptions This section is a detailed description of four of the major arrays used in the rail haulage simulator for data storage and logical control. Other arrays are used; however, they may be considered sub¬servative to the major ones. These major variables are explained on the following pages. Motor Control Array (XXXDEF). The first 99 locations in this array are arranged according to and are developed by data input. Unit conversions are made at input time which include: 1. Tons to pounds. 2. Rolling resistance in pounds/ton to percent/100. 3. Miles per hour per second (mphps) to feet per min. per minute. 4. Miles per hour to feet per minute. The following information is stored for each motor at the array

Jan 1, 1974

By David F. Smith, F. A. Hartgen

"Incidental to a cooperative investigation with the Carnegie Institute of Technology and the International Combustion Engineering Corporation on the burning characteristics of a powdered coal and the powdered semi-coke therefrom, the U. S. Bureau of :alas has determined the relative temperatures at which rapid self-heating occurs in these two fuels. Determinations were made on various screen sizes of the two fuels. Chemical analyses on different sizes were made in the bureau's Coal Analysis Laboratory, of which H. M. Cooper is in charge. The true densities were determined b the method given in Bureau of Mines Technical Paper 8.4The apparatus used in the determination of the temperatures for rapid self-heating was similar to that used by Wheeler A 10-gram sample of the fuel was placed upon a screen in a glass tube enclosed in a vertical electric furnace. The tube was surrounded with sand. One thermocouple -as imbedded in the sand and another in the fuel. Measurements of the temperatures were obtained at regular intervals with a recording potentiometer, as the furnace temperature was uniformly raised. Dry air was passed down through the fuel samples at a uniform rate of 123 c. c. per minute; the temperature of the air was substantially that of the furnace."

Oct 1, 1929

By Clark R. Neuharth

To assess the supply status of ultra-high-purity silicon for national defense needs, the U.S. Bureau of Mines conducted a general study of the availability of materials and processing technology for silicon used in the manufacture of infrared (IR) detectors from raw materials to the highly advanced device state. The United States possesses all of the raw materials and processing technology for IR detector-grade silicon production, but does not produce at all of the processing stages on a regular basis. Consequently, the United States continues to rely on foreign sources for some of these critical materials.

Jan 1, 1989