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By Wm. W. Odell

A study of certain gas making and fuel problems peculiar to the gas industry of California has been made by the Bureau of Mines. The work was done at the request of, and in cooperation with The California Gas Research Council 2, for the purpose of obtaining basic information on the gas-making fuels available to California, and their applicability to the present and future needs of the gas industry in that State. The data obtained have been applied in outlining a construction program, and indicate the possibilities in efficiently utilizing fuels in making gas by other than the oil-gas process. This paper presents an outline of the study and a summary of the principal results obtained, with some of the more important conclusions and recommendations based on this data. Gas is produced in California by processes which are both unique and different from those common to other parts of the United States. The bulk of the manufactured gas is made in and distributed from two main districts which are centers of population - namely, the Los Angeles district and the San Francisco Bay district. The gas manufactured in the Bay district is, almost exclusively oil-gas, whereas that produced in the southern part of the State, where natural gas is available, is mostly mixed natural gas and reformed-gas, but oil-gas is the chief product when the supply of natural gas is inadequate. Practically all of the gas companies are equipped with oil-gas generating apparatus, and anticipate using it in the future. As the continued use of the oil-gas process to the exclusion of all other processes, depends upon a continued supply of oil at a low cost, and the prospect of obtaining such low-priced oil in the future is somewhat uncertain, the questions have arisen: What will the future gas-making process or processes be? When will it be necessary to make plans for the installation of different gas generating equipment, and what will that equipment comprise?

Jan 1, 1926

By L. G. Austin

"This paper is based on the development of the Maza-Austin technique for characterizing thousands of coal particles by approximate analysis of the major inorganic constituents Ca, Al, Si, K, Na, Fe and S in each particle. The technique has sufficient sensitivity to work on small volumes, is fast enough to handle large number of particles within a reasonable period of time, and consists of scanning electron microscopy combined with energy dispersive x-ray spectrometry (SEK-EDS). A computerized SEK-EDS system that allows the automated analysis of hundreds of coal particles per hour' is described. The analysis is based on the location and tracing of coal particles embedded in a polished specimen, the selection of sampling points on the traced particles, the collection of an x-ray spectrum from each sampled point for a defined period of time, and the processing of the x-ray intensity to calculate point composition using ZAF corrections. Procedures for correcting for dead time, background, detector efficiency and spectrum overlap are described. These corrections are essential if reasonably accurate analyses are to be obtained from unknown complex mixtures of the elements in a coal or fly ash particle. Examples are given. INTRODUCTION Coal is a complex mixture of organic and inorganic materials. The inorganic fraction is referred to as mineral matter (Gluskoter, 1978) but can occur in three modes: (i) an observable mineral species; (ii) as cations held by ion exchange to carboxylic groups; and (iii) in chelate complexes. The mineral matter content normally represents a significant proportion of a coal, with an average value of about 15% for US coals (Gluskoter, 1975). The standard methods of analysis of the mineral matter in coals are performed on a sample selected to represent the whole coal as closely as possible, and give the overall inorganic composition in the coal. Such analyses are of limited use for solving problems originating from the behavior of individual coal particles, whose compositions vary widely from the average value. This is particularly true in pulverized coal combustion, where the current methods of predicting the slagging and ·fouling potential of a coal are based on the bulk ash composition, but the fly ash particles which create the deposits originate from coal particles with large differences in mineral compo1ition. Some examples can be found where, in a comparison between two coals, the one with the smaller slagging potential according to the mean ash composition was the one that behaved worst in the furnace (Moza et al., 1980; Koza and Austin, 1983). The u1e of gravity fractionation to assess the slagging potential of pulverized coals has shown that conventional ASTM analysis is not sensitive to differences in the distribution of mineral matter when comparing coals (Borio and Narciso, 1979). Bryer (1979) concluded that coals should be examined for fouling and slagging potential by analyzing gravimetric and size-fractionated coal, preferably pulverized· and ground to the size expected at the mill outlet."

Jan 1, 1989

By D. Harrington

"While distribution of air currents to working faces is a necessity in coal mines, especially those having explosive gas, advancing faces in metal mines rarely have circulating air other than the ordinarily inadequate amount supplied through the compressed air system. Even where comparatively large quantities of air pass through main mine shafts and levels. whether the circulation is actuated by fans or by natural ventilation, only occasionally can a metal mine be found where any considerable percentage of the ""blind ends"" has circulating air of sufficient velocity to be measured by an anemometer or even be discerned by deflection of flame of candle, or of acetylene lamp; and unfortunately these ""blind ends"" include nearly all of the places from which rock is taken.During several years study of metal-mine ventilation in various mining districts of the United States, it has been found that in some mines many of the workers in ""blind ends"" practically continually breathe air with 0.02 to 0.04 per cent of CO gas from unremoved fumes from explosives; in other mines CO2 chiefly from timber decay and breathing of men, is so high that a candle will not burn though usually the acetylene lamp will, hence oxygen is below 17 per cent but above 12 per cent; in some regions CO2 from strata fills the entire mine forcing cessation of work; in other mines in dead ends, gases such as nitrogen, H2S, SO2, etc., are found under some conditions. In many regions with hot rock or water (especially in deep workings) men in blind ends must work with little or no circulation, in air above SO degrees F. and even above 90 degrees, relative humidity only too frequently being around 100 per cent; in other regions workers in blind ends in practically ""dead"" air must continually breathe enormous quantities of finely divided rock dusts. All of the above conditions are decidedly harmful to health and prevent the worker from delivering anything approaching an adequate quantity of work, and in addition, some of these conditions have direct or indirect effect in bringing about definite increase of accidents; all of the above mentioned bad conditions in ""blind ends"" in metal mines as well as their ill effects, are remediable by providing at those places adequate quantities of fresh circulating air."

Nov 1, 1923

To provide coal operators with an easy-to-use stress control design procedure to minimize coal mine bumps during room-and-pillar retreat mining conducted with available continuous mining machine technology. Approach The goal of this U.S. Bureau of Mines (USBM) re¬search was to facilitate safe and efficient room-and-pillar retreat mining of bump-prone coalbeds by limiting coalbed stress adjacent to expanding gob areas through variation of section layouts. The first step was design of total-extraction pillars and their associated pillar-extraction plans. The second step was development of a coalbed strength model. The third step was development of stress limit design criteria. The fourth and final step was development of a methodology to estimate the magnitude and distribution of development and abutment loads apllied to the pillar line. The linear geometry of unlimited-width sections allowed for the accomplishment of step four with the tributary-area and linear shear-angle concepts. Increasing overburden depths required limited-width sections separated by barrier pillars to control stress within total-extraction panels. The accomplishment of step four with limited-width section designs required prediction of abutment load distributions for rectangular gobs and apportionment of these loads over mixed pillar sizes. A parametric study of the complicated interaction of various combinations of overburden depths, total-extraction panel widths, and abutment pillar widths was conducted with the USBM-developed boundary-element program MULSIM/NL.

Jan 1, 1995

By John Ward Smith

An analytical method developed by the Bureau of Mines to determine dawsonite, nahcolite, and nondawsonite alumina (called excess alumina) extractable from Green River Formation oil shales is presented. The method requires water extraction of nahcolite followed by HCI-extraction of dawsonite and an unidentified mineral yielding excess alumina from the water-leached residue. Instrumental determination of sodium in the water extract and sodium and aluminum in the HCI extract measures the sample's content of the minerals. Detailed evaluation shows the method to be adequately specific, precise, and reproducible and free from uncorrectable interferences. The method's results define precisely the production of sodium carbonates and alumina possible from a sample of oil shale and the interval it represents. Shale-oil yields, nahcolite contents, and yields of extractable alumina determined on 83 samples representing an 821-foot section of dawsonite-nahcolite-bearing shale from .Colorado Corehole No.3, drilled in the north part of Colorado's Piceance Creek Basin, are presented. These samples resulted in nahcolite contents to 53.3 percent, oil yields to 48.3 gallons per ton, and alumina yields to 5.80 percent. Use of these data to evaluate the production potential of a section of the formation are suggested.

Jan 1, 1969

By J. K. Richmond

Early research on coal dust explosions by the Federal Bureau of Mines and in other countries is reviewed to examine the effect of a single inhibitor, rock dust, on the explosion limits of coal dust. The parameters studied in this research included coal dust fineness, volatile content, and type of initiation. This research resulted in appropriate safety regulations in the respective countries. Also reported are the results of recent research in the Experimental Mine of the Bureau of Mines to investigate in detail the limits of coal dust explosions; the research used three types of coal with rock dust added as the independent variable. New experimental techniques and new criteria for defining propagation/nonpropagation were applied to the experiments. Also, a limit explosion propagation model is proposed based on the assumption of rapid devolatilization of the coal particles, with the subsequent combustion of the evolved volatile products contributing primarily to the propagation of the explosions. The model assumes also that the resultant char acts mainly as an inert diluent similar to the rock dust. The model also suggests that the function of stronger initiation is mostly to lift more dust from the mine surfaces.

Jan 1, 1975

By S. J. Broderick

"INTRODUCTION Dark soils are commonly believed to be better for agricultural purposes than light-color soils. Much of this feeling may be purely psychological, as many persons have unconsciously acquired the habit of associating richness of soil with color light soils, however, may be just as rich in humus and plant foods as the best of the dark soils. A dis-cussion of the manifold attributes that play an important role in soil technology is beyond the scope of this paper, but the color factor will be considered, as it has a particular bearing on some field experiments using coal-mine waste as a darkening medium.It has been established that dark soils absorb more of the sun's radiation, consequently are maintained at a higher temperature than light soils. This physical principle is applied in our daily lives in the choice of clothing. White clotnes in summer are cooler than dark ones. Conversely, dark clothes in winter are warmer than light-color clothing. A decided advantage of dark soils over light soils is the higher average temperature of the former, resulting in an earlier maturing crop. This advance of the maturing season may range from a few days to a month, depending on such factors as climate, crop, and degree of color of the soil. It has been reported that in parts of Russia where the growing season is short, perhaps comparable to that in Pennsylvania and. New York, cotton has been grown successfully on soils originally of light color, but darkened with coal, dusts. The growth of cotton is, accordingly, speeded up a full month. 3/"

May 1, 1940

In this Part, we have included copies of the flip charts and overhead projector viewgraphs used in the two briefings we conducted as part of this seismic detection and location task. The first one was an overview and problem definition briefing given to the seismic consultants on September 7, 1972. The second was a formal oral presentation of study results to technical staff members of the Pittsburgh Mining and Safety Research Center on November 21, 1972.

Jan 1, 1974

By L. J. Froisland

The U.S. Bureau of Mines conducted laboratory studies on sulfuric acid (H2S04) digestion of alunite [KA13(S04)2(OH)6] as a means for treating domestic deposits of this mineral. Digesting alunite ore in boiling H2S04 at concentrations of 88-wt-pct acid or higher breaks down the alunite and permits a convenient separation of potassium and aluminum. The digestion reaction is a complex sulfation reaction occurring in two stages. In this reaction, the potassium component extracts into the H2S04 for eventual recovery as potassium sulfate k2s04 in a separate unit operation. Aluminum is left as acid-insoluble aluminum sulfate [A12(S04)a], which can be extracted by a 95° C water leach. Additional purification of AI2(S04)a produced in this study is needed to meet cell-grade alumina (Al202) purity specifications. Extraction and separation of potassium and aluminum from the alunite ore were consistently above 90 pct.

Jan 1, 1989

By D. A. Doughty

The Bureau of Mines developed two methods for determining iron II and iron III in 2- to 5-mg samples of coal using electron paramagnetic resonance (EPR) spectrometry. One method used solid coal samples; the other method used aqueous solutions. The method using solid samples was more simple, technically, but required the use of X-ray fluorescent analysis, or another independent method, for determining total iron in the samples, and the results were subject to some uncertainty. The method using aqueous solutions appeared capable of greater certainty and did not require additional methods of total iron analysis but was more involved procedurally. The coals analyzed were found to contain much more iron II than iron III.

Jan 1, 1973

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the laws of El Salvador has been prepared from the best available information in Washington , but is released subject to correction and amplification , if necessary , by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State . Under the terms of the Code of Commerce ( arts . 12ff . ) , foreigners living in El Salvador can engage in business on the same terms as nationals . This involves ( = $434.00 ) - except for those with a working capital , of less than a thousand pesos inscription in the merchants ' register , which can be refused only in case of manifest disability of a permanent nature .

Sep 1, 1930

By Fred C. Turin, William J. Wiehagen

This study examined musculoskeletal injury risk at four mining sites: underground coal, underground limestone, surface copper, and surface phosphate. Each site offered opportunities to investigate musculoskeletal disorder (MSD) injury risks and how those risks might be identified and categorized. The National Institute for Occupational Safety and Health (NIOSH) worked with these sites to (1) identify work activities that showed evidence of MSD injury risk, (2) examine physical risk factors that can lead to MSDs for a handful of work tasks at each site, and (3) develop a set of ideas for problem-solving to help reduce risk factors for examined work tasks. For each site, NIOSH implemented a plan that was refined over the time period of this study. The plan consisted of four steps. The first step was to use mine injury records, a musculoskeletal discomfort questionnaire, front-line supervisor interviews, and a list of management concerns to identify work groups and work activities that have significant evidence of MSD risk factors. The second step was to select work tasks for evaluation. The third step was to interview those who do the work and make observations to characterize the MSD risk factors and musculoskeletal symptoms that exist for target tasks. The final step was to conduct brainstorming sessions with workers who perform the work or have a stake in the production task. The brainstorming sessions served to identify general strategies (ideas) for reducing MSD risk factor exposures. A final report of findings was presented to mine management and workforce representatives at each site. The risk factors and ideas for improvement identified for each site were specific to the target tasks examined. These target tasks were diverse, but there were some key similarities. For instance, jobs were found at each site that required a significant amount of manual work involving the upper extremities and low back. Handling heavy and awkward objects, forceful arm and shoulder exertions, and working in awkward postures were common for a variety of jobs across the four sites.

Jan 8, 2004

By John E. Pahlman

The Bureau of Mines investigated the feasibility of removing heavy metals from mineral-process waste streams by precipitation with lignochemicals and humic acids. Lignochemicals are by products from the paper industry, while humic acids are obtained by caustic treatment of peat, subbituminous coal, and lignite. These high-molecular-weight organic materials have many functional groups, which can coordinate and form innercomplex salts with heavy metals that are crystalline precipitates. Filtering of a humic-acid-or lignochemical-treated solution or waste stream containing these precipitates removes the heavy metal sequstrates. Tests were conducted with two lignochemical samples, three humic acid samples, lime (CaO), and sodium hydroxide (NaOH) in which increasing amounts of these additives were reacted with 50 mL of solution containing Fe3+ , Al3+, Cr3+, Pb2+, Cu2+, Cd2+, Zn2+, Co2+, Ni2+, Mn2+, and Hg1+. At the appropriate pH, greater than 90-and 99-pct removal was achieved for these 11 heavy metal ions from the 10-and lOO-ppm solutions, respectively, using lignochemicals and humic acids. Removal efficienC)' with these organic materials is better than that with CaO, especially for the more toxic ions, Hg1+, Cd2+, and Pb2+. Unlike the precipitates formed with NaOH or CaO, those with lignochemicals and humic acids are compact and noncolloidal. The volume of their sludge is sharply lower than that of the finely dispersed lime or soda precipitates; thus, their removal in settling tanks or by simple filtration is enhanced.

Jan 1, 1988

By D. J. Parker

Ability to signal the hoisting engineer in shaft mines is of utmost importance from the standpoint of safety and economy. The problem of signalling from the cages and especially from the moving cages has received too little attention from mine operators; however, this problem has been given considerable thought and attention by at least one large metal-mining company in Utah which has devised successful, economical, and safe systems of signalling from the cage whether it is moving or at rest. A Report of Investigations on "Methods used in Utah for signalling mine hoists from moving cages," by C. A. Allen, then a metal-mining engineer in the Bureau of Mines, was issued in June, 1920. As this report contains interesting history of systems of signalling from moving mine hoists, and describes several systems then in use, it is here quoted in full.

Jan 1, 1929

By Joseph W. Martin

The Bureau of Mines investigated the backscattering of low-energy gamma rays as a method for rapidly determining the incombustible content of coal mine dust. In this method, 60-kev gamma rays from americium-24l penetrate the dust and are reflected by elements in the dust to a thin crystal scintillation detector. The number of backscattered gamma rays is proportional to the incombustible content. Tests of 40 dry, mine-dust samples containing 50 to 100 percent inert material show an average error of 2 percent. Calibration of the apparatus is necessary for each rock dust to account for variable composition. Results for samples containing more than 6 percent moisture are subject to error, but the values are lower than values obtained by chemical analysis, and thus fall on the safe side. Development of a small portable meter based on the backscatter principle appears feasible. Such a meter would find application within coal mines to check the effectiveness of rock dusting procedures.

Jan 1, 1968

By Donald R. Corson

The Bureau of Mines is conducting research on the effects of various established and potential soil-stabilization additives to hydraulic backfill. This initial phase is an evaluation of the effect of inclusion of varying amounts of Portland cement and combinations of cement and a dispersant on the bearing strength of backfill. Results of unconfined compression tests are given for over 200 sample cylinders incorporating a fill material with cement or cement and dispersant. Inclusion of a minor amount of dispersant (0.2 percent by weight) is found to yield a significant increase in strength for 20-to-1 and leaner sand-cement mixes. An apparent optimum concentration of dispersant exists beyond which no further increase in strength is achieved. A dispersant-cement ratio of l.8- to-1 yielded a strength increase of 515 percent over the strength of untreated 40-to-l sand-cement mixes.

Jan 1, 1966

By d&apos, Kathleen J. Amico

This summary appears in Minerals Yearbook volumes I and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonwealth of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The several commodity and area chapters contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operations at or near mines.

Jan 1, 1967

By D. S. Kingery

Investigations over several years have disclosed that the principal manners of occurrence of shuttle-car injuries are in order: 1. Victims in contact with roof or crossbars. 2. Victims in contact with ribs or timber legs. 3. Victims falling from, or jerked from, shuttle cars. 4. Victims in contact with overhanging brows or protruding pine for pin timbers, or water lines. 5. Contact with persons or collisions with parked equipment. 6. Victims injured by roof falls or falling timbers caused by knocking out roof supports with shuttle cars. 7. Victims injured by runaway shuttle cars. 8. Victims injured while loading or unloading timbers or other materials from shuttle cars. These recurring types of shuttle-car accidents reflect the physical conditions of the working sections, certain safety deficiencies in shuttle-car maintenance and design, and unsafe practices by operators.

Jan 1, 1952

By D. Montagna

The Kroll-Betterton process for debismuthizing lead is based on adding calcium and magnesium to impure molten bullion to form solid Ca-Mg-Bi inter-metallic compounds that float on the surface as drosses. Present practice in industry is to hand-skim off these drosses, often followed by hydraulic pressing to squeeze out some of the entrapped liquid lead. In an effort to develop an improved technique, the use of an argon-shrouded dipping centrifuge to perform the required phase separation was investigated. Centrifugation experiments demonstrated that the bismuth content of an impure bullion could be lowered from an initial 0.5 percent down to 0.03 percent with a lead recovery of 90 percent, which is comparable to lead recovery after hand skimming of drosses in commercial lead-debismuthizing operations. Centrifugation provides better control in removing drosses, faster operation with less oxidation and relatively little fuming, and recovery of a lead bullion that approaches commercial specifications.

Jan 1, 1972

By J. P. Coughlin

The U.S. Bureau of Mines has developed a monitoring system that acquires and analyzes data for use in determining the conditions that may precede mountain bumps in coal mines. Based on a UNIX workstation linked to an array of geophones in a working longwall operation, the system captures complete waveforms of microseismic events and simultaneously obtains continuous samples of the voltage levels of each geophone. Event rates and locations are calculated and displayed in real time on the UNIX workstation, which is situated in an underground instrumentation room. These results also are transmitted from the workstation to a display computer near the longwall face. The system runs continuously and has the capability to acquire, analyze, display, and archive microseismic (transient) data and single point data, such as closure and pressure changes, simultaneously.

Jan 1, 1993