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By F. P. Haver

A method to recover copper and elemental sulfur from chalcopyrite concen¬trate, using a ferric chloride leach, CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S, was reported by the Federal Bureau of Mines in 1971 (Report of Investigations 7474). Since that time, additional work has been done to improve certain steps in the procedure; that is, the recovery of sulfur from the leach residue, the recovery of copper and iron from the leach solution, and the regeneration of the leach solution. It was determined that over 99 pct of the elemental sulfur in the leach residue could be extracted at ambient temperature with an ammonium sulfide solution. Heating the pregnant solution precipitated crystals of rhombic sulfur (99.5 pct purity) and liberated ammonia and hydrogen sulfide for recycle. Copper with a purity in excess of 99 pct was obtained from the leach solution by electrolysis, using a diaphragm cell, with an energy requirement of less than 0.7 kW-hr/lb. Metal was deposited as a weakly adherent powder that could be easily dislodged from the cathode and withdrawn continuously from the cell in the form of a slurry. During electrolysis, part of the Fe(II) was oxidized to Fe (III) at the anode so there was no chlorine evolution. The leach solution was regenerated by direct oxidation of the spent electrolyte with air or oxygen in a turboaerator at 80° C. This precipitated the iron dissolved during leaching in an easily filterable form, Fe203.xH20, and converted the remaining Fe(II) to Fe(III).

Jan 1, 1975

By J. J. Jakowsky

[The legislation in many States against the present method of producing carbon-black by the incomplete combustion of natural gas, and the continually increasing demand for gas for otter purposes, indicates that the supply of carbon-black may Gradually be decreased and that new methods for its production, utilizing a greater parentage of the carbon in the has should be developed. In the course of investigations of the effects on hydrocarbons of high voltage discharges, it was noted that under certain conditions natural gas could be decomposed and that carbon-black could be produced. The effects of several tyres of electrical discharges on natural gas have, accordingly, been studied' in order to find out the fundamental factors underlying the reactions and their possible influence in the recovery of a greater part of the carbon content of natural gas than is now possible. Present commercial plants using natural gas for the manufacture of carbon-black recover from 0.9 to 1.5 pounds of carbon-black per thousand cubic feet of gala consumed, or less than 5 per cent of the total Gabon in the gas: It should be noted, however, that the, present methods involve heating the gas to incandescense by burning it as a luminous flame, and a considerable part of the gas is thus consumed as a source of hest. If this heat can be supplied from some other source, or if a more efficient method of applying the energy con. tamed in part of the gas, to the decomposition of the rest of it, can be worked out, then a greater yield of carbon-black per thousand cubic feet of gas care be expected. The present abort paper contains a brief summary of tie investigations so far conducted upon natural gas.]

Jan 1, 1922

By Mark R. Pettitt

The results of an extensive research and development program to reduce the noise generated during coal cutting are presented. The characteristics and magnitude of continuous miner coal cutting noise sources are defined. This work consisted of development of a simulated coal ,cam to facilitate above-ground coal cutting tests, noise measurements in a reverberant acoustic chamber during simulated mining operations of a continuous miner (cutting the simulated coal scam), and noise measurements in an underground coal mine during continuous miner operation. In-mine and laboratory test results were in excellent agreement for both A-weighted overall levels as well as A-weighted one-third octave band spectra. Methods to reduce coal cutting noise are presented. These methods take full advantage of the dynamic characteristics of the forces generated during coal cutting. Dynamic cutting force isolation was shown to be a very effective technique. Finally, a continuous miner was equipped with a cutter head that incorporated (among other design factors) cutting force isolation. Successful, lung term, in-mine use of the cutter head demonstrated coal cutting noise at the operator's station of less than 90 dBA and 50% coal, 50% rock cutting of less than 93 dBA.

Jan 1, 1985

By Laxman S. Sundae

A U.S. Bureau of Mines designed and fabricated in-seam tester (1ST), retrofitted with a dust shroud, was used to establish a respirable dust index (RDI) and to determine cutting forces from a variety of bit types in four coal mines and a salt mine. Results from cutting tests at four coal mines showed that radial bits required the lowest cutting force and the least specific energy. Generally, for each conical bit the RDI and cutting force increased when the included bit tip angles increased from 70° to 90°. During field tests it was not possible to measure the total quantity of respirable dust produced by each cut; therefore, attempts were made to determine the amount of dust that became airborne from each test cut. The test results show that the quantity of airborne respirable dust is very erratic and cannot be related to bit type. Two statistical methods were employed to analyze RDI, but no correlation was found between the RDI and bit type. Despite scatter in test results for RDI, significant difference was found in RDI generated in four coal seams. In general, RDI increased with the increased cutting force for each coal seam from mine 1 through mine 4.

Jan 1, 1989

By P. S. Haury

"INTRODUCTION Many ore deposits were discovered in the Wallapai Mining District, which covers the Cerbat Range in Mohave County, Ariz., during the early period of mining there from about 1865 to the 1890's. A considerable amount of production was obtained from shallow lead carbonate ores that carried considerable gold and silver.Mining was revived in 1906 and again during the First World War, and soma of the mines were deepened into the underlying sulfide zone. Substantial quantities of metal were recovered from two mines, the Golconda and the Tennessee-Schuylkill, that were, developed to depths of 1,600 and 1,400 feet, respectively. The Golconda is credited with $6,500,000 gross productions. 2/ This mine was not operated after 1917. The Tennessee-Schuylkill is still operating after a yield of about 300,000 tons of ore that averaged 4.33 percent lead and 7.74 percent zinc and contained an appreciable amount of gold and silver.Many of the old mines were reopened in 1942 or 1943 under the stimulus of premium prices for lead and zinc. A large proportion of this work was finished with loans from the Reconstruction Finance Corporation. It was believed that a good deal of lead and zinc could be recovered from the mines if a custom mill for concentration of the ores was available locally."

Aug 1, 1947

Approximately half of all the fuel energy used in the United states is now pro-vided by oil and natural gas. A persistent and rapid growth in energy demand during the last 3 decades has been absorbed largely by the liquid and gaseous rather than solid fuels. In 1948 the energy provided by coal was substantially the same as in 1920. Meanwhile, the use of oil and natural gas each had increased fivefold. On a per capita basis, the change is more significant. Coal consumption has dropped from about 6 tons per person to 4-1/2 tons, while oil has increased from 4-1/3 barrels to 14-1/3, and natural gas from 7,500 cubic feet to about 35,000. These facts would have only academic interest if the United States had unlimited supplies of all fuels. However, while the Nation's reserves of coal are adequate to meet our needs for centuries, those of oil and natural gas appear limited. It is obvious, therefore, that the security of our liquid-fuel position would be greatly enhanced if the supply could be based in an increasing degree on solid fuels, such as coal and oil shale, which make up more than 95 percent of our fuel reserves, instead of natural oil and gas. In addition, this would create new employment and help to stabilize the market for coal, which may be facing comparatively bleak prospects in the near future unless its position with respect to other fuels is improved.

Jan 1, 1950

By H. Polat, Q. Hu, S. Chander

"The collection efficiency of dust particles was determined in a laboratory dust chamber equipped with a water spray. Measurements were made in the presence of selected nonionic, cationic and anionic surfactants. For the nonionic and the anionic reagents, efficiency was maximum in a narrow range of concentration. The surfactant concentration corresponding to high collection efficiency was usually much below the commonly used concentration of l "", however. In comparison, much higher collection efficiency was observed for a cationic surfactant at extremely low concentrations. For delineating the mechanism of capture of dust particles, surface tension and contact angle results were used to obtain a correlation between the work of adhesion and the efficiency of collection. Such a correlation was reasonable for the nonionic surfactants but not for charged surfactants. In the latter case, electrostatic interactions between charged droplets and particles were more important, especially for the cationic reagent. INTRODUCTIONSeveral methods are used to control dust in mines. These include: ventilation, foam, scrubbers and sprays. This article is concerned with improving the effectiveness of water sprays, which are widely used to remove dust particles during continuous mining, by adding small quantities of surfactants. Water sprays produce small droplets which act as collectors of dust particles suspended in air. Sprays directed at the actual source of dust have the additional property of wetting the coal before the ·particles become airborne (Hamilton, 1974). Wetting agents, also called surfactants, arc known to play an important role in many applications where dust is a problem. However, conflicting reports exist in the literature with regard to the effectiveness of surfactants in water sprays (for a review, see Chander et al., 1988). In spite of the conflicting reports, the use of surfactants for dust control has increased over the years. In a recent study by the Bureau of Mines, a 27'6 reduction in respirable dust levels was observed in a mine test when surfactants were added to sprays (Foley, 1991)."

Mar 1, 1992

By Graham W. Marks

In broadening the utility of spectrochemical methods 9f analysis of ore samples 3,4/ a procedure employ in the total energy method, has been adapted to determination of silver in ores. Silver is the first element in group I of the periodic table to be studied in the Bureau of Mines program. Two silver lines in the spectrum, Ag X\ 3280.683 and 3382.89lR were used in the study, and the problems that had to be overcome were: (1) Influence of extraneous elements on line intensities, (2) preparation of standard curves, and (3) improvement in equipment and technique to increase accuracy. Sodium, potassium, sulfur, selenium, iron, cobalt, and nickel yielded low intensities and hence low results, particularly on the samples high in silver, but addition of 60 percent or more of lime counteracted these effects. One calibration curve must be used for samples low in silver and other for those high in silver. The chocks with fire assaying were close enough for preliminary or exploratory investigations, and the method is much more rapid.

Jan 1, 1948

By Robert L. de Beauchamp

The Bureau of Mines reviewed aluminum chloride technology to determine the problems associated with its preparation from minerals, and to ascertain the best areas for research to solve these problems. Commercial AlC13 production processes are described and the ?state of the art? for the preparation of AlC13 from aluminous materials is evaluated. Areas for further research are indicated.

Jan 1, 1969

By D. C. Crowell

This publication presents the results of a laboratory investigation of displacement of gas by injection or imbibition of water into sandstone models under essentially isobaric conditions. A brief discussion of scaling requirements is included. The influence on residual gas saturation of independently varying the parameters of dimensional ratios of the porous media, rates and methods of flooding, surface tension, initial water saturation, and permeability is shown. Of these variables, increased initial water saturation and decreased surface tension reduced residual gas saturation significantly, whereas variations in flooding rate and dimensional ratios had no apparent effect. No correlation was evident between absolute permeability and residual gas saturation.

Jan 1, 1966

By K. A. Johnson, H. F. Yancey

"INTRODUCTION Coals vary so widely in their burning characteristics that all coals prepared for domestic stoker use cannot be burned efficiently on every type of stoker. The overfeed stoker, a large number of which are in use in the Pacific Northwest, operates satisfactorily when burning low- to high-ash, noncaking bituminous or subbituminous coals, whereas on the clinkering-type, underfeed, bituminous stoker both caking and noncaking bituminous and subbituminous coals are burned, generally with ash contents below 12 percent and ash-softening temperatures between 1,800º and about 2,600º F. Because fly ash continues to be one of the most troublesome factors in domestic underfeed stokers, noncaking coals especially must be chosen carefully with respect to size composition, particularly as regards the exclusion of excessive fines. Their formation as a result of degradation in storage handling or because of crushing in .the stoker worm will increase the fly-ash nuisence.Bituminous and subbituminous coals with higher ash-softening temperatures and, often, higher ash contents have not been able to enter the domestic stoker-coal market in the Pacific northwest because clinkers are not formed readily during clinker-type underfeed-stoker burning, especially in mild weather, and because of the labor and attendant inconvenience required in handling larger volumes of ash. The work described in this report was undertaken to enable mines producing coals of the kind described to enter the stoker-coal markets. The anthracite stoker selected was one that conveys the refuse from the ash pit of the furnace and deposits it into one of two covered, dust-tight disposal cans."

Dec 1, 1945

By Ernest L. Corp

Seepage forces computed by a finite-element flow program are combined with gravity forces in an elastic-plastic stress-analysis program to determine the stability of mine-waste slopes. Computer output provides a cross-sectional plot of the dam or embankment showing the safety factors for each element. The combined finite-element program called SEEP-SLOPE was used to analyze several trial embankments and the 1972 Buffalo Creek Dam failure Safety factors computed by the finite-element method (FEM) were compared with those computed by Bishop limiting-equilibrium method. For individual slip circles, there was little correlation between the factors of safety computed by the two methods. Both predict failure, but FEM shows a different mode of failure plus development of potential failure zones not indicated by conventional methods. Besides having a better theoretical basis than the Bishop method, FEM requires no assumptions regarding the location or geometry of the failure surface. As a result, the program will show progressive development of a failure zone, and areas can be pinpointed where remedial measures should be taken. In addition, nonhomogeneous cross sections can be analyzed, and zones of potential piping can be defined.

Jan 1, 1975

By R. H. Grau, A. Sainato, S. J. Schatzel, T. M. Kohler, A. T. Iannacchione

This Bureau of Mines research study found gas emission rates from an advancing face, and flows and pressure of gas from an exploration drill hole were dependent upon the geology of salt encountered in a domal salt mine. Normal production-grade "pure" salt adjacent to an anomalous' zone was found to have a methane emission rate of less than 5 ft3/ ton (0.1 m3/t) of mined salt from a room advanced by a continuous miner. Extremely low gas flows [less the 4 ft3/h (0.1 m3/h)] and lack of pressure buildup were also observed from this normal salt in a 154-ft (47-m) exploration drill hole. These data indicate that methane emissions should not be a problem when mining in this type of salt. In the adjacent anomalous zone, methane emission rates ranged from 15 to 70 ft3/ton (0.4 to 1.8 m3/t) of mined salt from an advancing face. Gas flows of approximately 42 ft3/h (1.2 m3/h), and pressures in excess of 900 psig (6,200 kPa) were observed in an exploration drill hole when the anomalous zone was encountered. This information suggests a greater methane emission hazard from the anomalous zone than from the associated normal salt. If this trend of increasing emissions problems associated with anomalous zones of salt is common with similar anomalous zones encountered or observed in other domal salt mines, then special control strategies should be employed to minimize this potential mining hazard.

Jan 1, 1984

By E. D. Gardner

The mine of the Eureka Standard Consolidated dining Co. is at Dividend, Utah, in the Tintic mining district. It is operated under the same management and controlled by the Antic Standard Mining Co.; the two properties adjoin each other. The Eureka Standard is worked through a vertical shaft; the ore is mined by a stringer-set-and-fill method. One hundred and thirty men were employed in April 1933. The normal daily tonnage is 100 tons; the ore is shipped to the smelter at Garfield, Utah.

Jan 1, 1935

By W. A. Selvig

"The purpose of the investigation described herein was to determine how closely different laboratories can check one another in making determinations of fusibility of coal ash with the De Graaf electric coal-ash fusion furnace: how well duplicate determinations by the same laboratory will check, and how the results with the De Graaf furnace compare with those of the standard gas-furnace method of the American Society for Testing Materials.4Thanks are due the following laboratories who cooperated in this study by making fusibility tests with the Do Graaf electric coal-ash fusion apparatus: J. J. Brennan, testing engineer, Northern States Power Co.; R. E. Gilmore, superintendent, Fuel Research Laboratories, Canadian Department of Mines A. T. Leavitt, president, and W. Mueller, chief chemist, Hamilton By-product Coke Ovens. Ltd.; Edgar Stansfield, chief chemical engineer, Scientific and Industrial Research Council of Alberta. Canada; and H. S. Vassar, laboratory engineer, Public Service Electric and Gas Co.The ash-fusibility determinations by the standard gas-furnace method were made in the Coal Analysis Laboratory of the Bureau of Mines at Pittsburgh under the direction of H. M. Cooper, associate chemist. The investigation was made at the suggestion of A. C. Fieldner, chief engineer, Experiment Stations Division of the Bureau of Mines.Routine determinations of the fusibility of coal ash are made in the laboratories of the United States Bureau of Mines by the gas-furnace method. This method was standardized after considerable experimentation5 on the nature of the fusion of coal ash and the various factors which affect its determination. The method was subsequently adopted by the American Society for Testing Materials as one of its standard tests."

Jun 1, 1930

By William J. Wuest

This U.S. Bureau of Mines report presents an overview of ground control considerations associated with floor heave. Factors affecting heave, such as in situ stress, floor characteristics, and mine geometry, are described. Floor-displacement monitoring and data analysis methods are outlined. Finally, floor heave remediation is discussed. The remedial techniques are divided into four categories: mine maintenance, supplemental support, mine structure, and techniques for multiple-seam operations. Other subjects covered in the report include laboratory and in-place testing of floor rocks, U.S. and international case studies, effects of mine layout, determination of excess horizontal pressure, and types of heave failure. The emphasis of this report is on practical considerations; theoretical discussions are kept to a minimum.

Jan 1, 1992

By P. M. Daling

The objectives of this study were to examine a representative cross section of formal safety analysis techniques developed for the nuclear and aerospace industries, to recommend those methods that would be suitable for application to the mining industry, and to include those methods in a user's manual. Volume II of this report, the user's manual, describes several methods that were determined to be immediately transferrable to the mining industry. The handbook gives detailed instructions on appropriate application and utilization of the methods. Other techniques will require further development before they can be effectively transferred to the mining industry.

Jan 1, 2006

By Tom Retka

This three volume final report summarizes the activities and conclusions of this contract. The objective of the contract was to develop noise control modifications on a retrofit basis, for auger miner coal-cutting systems. Manuals were prepared to assist mine shop personnel in retrofitting the auger miner with these noise controls. Final Report Volume I - Details all vibration and acoustical tests conducted in develop¬ment of the noise controls. Final Report Volume II - Noise Control Modification Manual for the Jeffrey 100-L Auger Miner describes the various noise control modifications to the auger miner, along with fabrication procedures, cost and vendor information. Final Report Volume III - Noise Control Modification Manual for the Jeffrey 94-L Bridge Conveyor describes the various noise control modifications to the bridge conveyor, along with fabrication procedures, cost and vendor information.

Jan 1, 1978

By Robert C. Dyni

This U.S. Bureau of Mines (USBM) report summarizes a field demonstration of pneumatic backfilling technologies conducted at the abandoned Hillside Coal and Iron Slope in Vandling, P A. Researchers demonstrated two pneumatic backfilling technologies recently developed under the USBM's Abandoned Mine Reclamation Research Program, the Pneumatic Pipefeeder and the High-Efficiency Ejector. Both systems had previously been evaluated at the USBM's subsidence abatement investigation laboratory near Fairchance, P A. The objective of the demonstration was to fill 100% of the abandoned tunnel with backfill stone to prevent further subsidence. The Pneumatic Pipefeeder was used for 21 days, at a rate of 63 to 124 t/ d (69 to 136 st/d), to fill 88% of the tunnel. The High-Efficiency Ejector was used for 2 days, at a rate of 125 to 132 t/d (138 to 146 st/d) to fill the remaining 12% of the tunnel. The backfill placed by both systems was tightly compacted. The major problem encountered was wear on the polyethylene pipeline from the abrasion of the high-velocity backfill. The use of heavier steel pipe minimized the problem. A cost analysis for the entire project is given.

Jan 1, 2010

By Jun Yi

In this paper, single-component gas sorption and transient diffusion processes are described within coal matrix exhibiting bimodal pore structure. The coal matrix is treated as a poroelastic medium manifesting swelling and shrinkage effects due to the sorption of gas under effective overburden stress. Gas transport is considered Fickian with molecular (bulk) and surface diffusion processes simultaneously taking place in the macro-and micropores of coal, respectively. The numerical formulation is intended to be explicit in nature to investigate the influences of sorption phenomena on the macropore volumes and on the overall gas transport for the cases of gas uptake by and release from coal. Results of the study show the presence of hysteresis during a sorption?desorption cycle of the gas. It is also found that the overall gas transport takes place at a rate significantly less than that in the macropores only. Thus the existence of a retardation effect in the overall gas transport is concluded. This retardation effect is primarily due to the micropore resistances, in particular gas adsorption, and is independent of the changes in the macropore volumes. It is shown that macroporosity of the coal matrix may change during gas transport due to combined effects of pressure and sorption-induced swelling or shrinkage of the coal. It is estimated that the macroporosity variation is non-uniform in space and time, as it is expected in reality, and typically taking values less than ±10 percent of the initial porosity.

Jan 1, 2009