Search Documents

By E. G. King

Strontium sulfide and barium sulfide occur as intermediates in commercial treatments of the impure natural sulfates to produce pure strontium and barium chemicals. Thermodynamic considerations involving these sulfides have been hampered by lack of basic data, such as the entropies at 298.15°K. This paper reports the results of heat capacity measurements of strontium sulfide and barium sulfide in the temperature range 50°-298°K. The entropies at 298.15°K. were derived from the heat capacity values. Free energies of formation at 298.15°k. were computed from the entropies and literature values of the heats of formation. Strontium sulfide and barium sulfide are thermo-dynamically less stable than calcium sulfide, but more stable than magnesium sulfide.

Jan 1, 1960

By J. M. Provost

1. Estimates have been made for eight coal beds in Marion County, but only the Pittsburgh is important from a production standpoint at this time. The Pittsburgh bed has the largest recoverable reserve, and the Sewickley is second in importance. 2. Known measured and indicated reserves thickness of 14 inches and on 1,800 short tons estimated at 3,141 million tons, as of January lion tons is in beds 28 inches and more thick in all beds, based on a minimum per acre-foot of coal in place, are 1, 1955. Of this total, 2,983 mil-Areas in each bed were omitted from the estimate because available data relative to the bed characteristics were too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1956

By Guy Ervin, Delwin D. Blue, John E. Conley

"INTRODUCTION Extraction of alumina from various materials, such as low-grade bauxite and clay, by means of a lime-soda sinter has been the subject of a number ofinvestigations (1, 2, 3, 4, 5, 7, 9, 10, 11, 12, 13, 16, 17). 5/ in recent years, Although many of the details of these investigations are lacking, it is believed that there is one difficultly that frequently develops under certain conditions, namely, that of thickening or gelation of the slurry formed during extraction of the sinter. If gelation occurs even to a slight extent* Serious mechanical difficulties result, very low liquor recoveries are obtained, and the extraction step becomes virlually inoperable. Under 'favorable conditions, a solid gel is formed which can only be removed from the equipment with great difficulty. At the Eastern Experiment. Station of the Bureau of Mines in College Park, Md., a study of lime-soda processes was begun in November 1941. This work has included studies on low-grade bauxites, kaolin clay, and nodular diasporic clay. Gelation was most serous with kaolin clay and least with diasporic clay. As a part of the Bureau's investigation, a study was made of the effect of the pertinent variables on gelation. The results permit the selection of various sets of conditions at which gelation will not occur. These data are essential to the final selection of optimum conditions for the over-all process."

Aug 1, 1946

By Eugene H. Skinner

The U.S. Bureau of Mines conducted experiments on the use of lightweight concrete in the density range of 100 Ib/ft3 for liners in underground mines. Three test sections were completed: a monolithic, portal-type structure with integral walls and arch constructed aboveground; an underground test section constructed in a mine drift using plywood forms; and a second section constructed in a drift using an air-supported formwork. The lightweight concrete in the two underground test sections was placed using piston pumps and a slickline. Fiber reinforcement was added to the concrete in the mine sections without any apparent problems with either pumping or placement of the concrete. In another experiment, the Bureau and Hecla Mining Co., Mullan, rD, used lightweight concrete in the density range of 25 Iblfe to replace timber blocking in a raise preparation structure. Other experiments are described in which low-density, lightweight concrete blocks were produced for mine ventilation doors, stoppings, and barricades. Other mine uses reviewed include pillars and collapsing beams. An advantage of low-density concrete is that it will display up to 50% deformation at a constant yield stress. These hlllovative concepts in deformable concrete lining systems will aid mine operators by decreasing capital and maintenance costs, increasing the available space in underground haulageways, and providing productivity gains and improved resource recovery in the soft, caving, squeezing, or bursting grollnu conditions often found in deep mines.

Jan 1, 1989

By Ronald B. Hollenbeck

The value of mineral production in Alabama continued to increase and reached a new high of $260 million, 3 percent above the previous high established in 1967. Record high values were reported for bentonite, crushed marble, lime, miscellaneous clay, portland cement, salt, sand and gravel, and scrap mica. The value of coal, total cement, petroleum, and stone accounted for 87 percent of the State's total value of mineral production. Alabama ranked second among the States in the production of bauxite and scrap mica and third in kaolin, masonry cement, and native asphalt.

Jan 1, 1970

By J. A. Ruppert, P. M. Sullivan

A process was developed on a laboratory scale in which iron contained in galvanizers ' zinc dross and aluminum contained in scrap zinc die - cast alloy were removed simultaneously . Melting both types of scrap together in the proper proportions resulted in formation of solid intermetallic Fe₂ Alg , which was readily removed from the melt by filtration and centrifugation . Recovery was 87 to 92 percent of the available zinc . Refined filtrate contained 0.02 percent iron and 0.20 percent aluminum. Aluminum content was further reduced to less than 0.01 percent by fluxing with zinc chloride . Low temperatures employed and inexpensive equipment requirements make the process commercially attractive .

Jan 1, 1964

By Dennis R. Dolinar, Christopher Mark, Gregory M. Molinda

Despite more than half a century of experience with roof bolting, no design method has received wide acceptance. To begin to improve this situation, National Institute for Occupational Safety and Health (NIOSH) conducted a statistical study of roof bolt performance at a number of mines throughout the U.S. Case histories were collected from 37 mines with a variety of roof bolt types and patterns in a wide range of geologic environments. Performance was measured in terms of the number of roof falls that occurred per10,000 ft of drivage. The study found that roof falls are rare when the roof is strong and the stress is low, even with light roof bolting patterns. The focus of this paper is on the more difficult conditions, where the roof is weaker and/or the stress is higher. Analysis of the results led to guidelines that can be used to make preliminary estimates of the required bolt length, capacity, and pattern. The guidelines are based on the depth of cover (which correlates with stress) and the roof quality (measured by the Coal Mine Roof Rating (CMRR), and the intersection span. Another contribution is a formula for estimating the horizontal stress level in the eastern U.S. coalfields as a function of the depth of cover. The design guidelines are currently being implemented into a computer program called Analysis of Roof Bolt Systems (ARBS).

By H. W. Wainwright

.1. The purification pilot plant and the equipment, solution, and gas cycle used for removing hydrogen sulfide and carbon dioxide are described. 2. As sulfur recovery is necessary in any large Fischer-Tropsch plant, pilot-plant runs were made at 300 p.s.i.g. to study the efficiency of tri-ethanolamine solutions in removing selectively hydrogen sulfide from gases containing varying amounts of carbon dioxide. 3. Aqueous solutions of TEA of 20, 30; 35, and 50 percent were investi¬gated. Data indicate that 30 to 35 percent is the optimum concentration if both selectivity and economy are considered. Slightly better selectivity is obtained with the.20 percent solution, but steam consumption is greater owing to the higher solution rates. Results from our pilot plant runs indicate that a 50 percent solution not only produces an acid gas of lower hydrogen sulfide content but also requires high solution rates to effect hydrogen sulfide purification. 4. Data from 37 runs using TEA are presented in tabular form. In addition, the data are correlated and presented in three sets of curves. By using these curves, it is possible to calculate the compositions of the purified and acid gases for various raw gas mixtures. 5. In cooperation with the Southern Natural Gas Co., investigations were carried out at 300 p.s.i.g. on the simultaneous removal of hydrogen sulfide and carbon dioxide, from gases using various concentrations of diethanolamine. 6. Data from 17 runs employing 20, 30, and 40 percent DEA are reported in both tabular and graphic form. 7. A comparison of the data from one DEA run made at 200 p.s.i.g. with those from the runs operating at 30O p.s.i.g. shows float the absorption capacity of the solution, and, hence, the steam requirements per gallon are about the sage for both pressures. .The only real advantage of the higher pressure is the additional volume of gas that can be treated. 8. The quantity of steam needed to reactivate fouled TEA and DEA solutions increased as the reactivator pressure was increased about 1,0 to 1.1 pounds of steam was required for each gallon of circulating solution when the reactivator was operated at 5 p.s.i.g. 9. A curve is included that shows the effect of the hydrogen sulfide con-centration in a lean 35 percent TEA solution on the hydrogen sulfide content of the purified gas and on steam consumption for reactivation. 10. Both TEA and DEA reduced the organic sulfur content of the raw synthesis gas considerably. Analyses of the lean amine solutions showed a gradual build up of sulfur compounds, indicating that the compounds formed by the amines and organic sulfur do not break down under the ordinary operating conditions of the reactivator. 11. Considerable operating difficulty was encountered in the pilot plant owing to foaming of the amine solutions. Laboratory experiments in which the effectiveness of certain antifoam agents was studied showed Alkaterge C to be most promising for the particular conditions studied.

Jan 1, 1952

By John R. Reigart

The Tri-State district, as its name indicates, is composed of portions of three States, the southeastern corner of Kansas, the northeastern corner of Oklahoma, and an adjacent strip of Missouri east of these portions of Kansas and Oklahoma. An area approximately 40 miles long in a northeasterly-southwesterly direction, and 30 miles wide at right angles thereto, containing minable occurrences of ore at widely scattered locations, comprises the district. However, what has been and is the main productive area, is a strip about 35 miles long and 10 miles wide, which begins at Miami, Okla., as its southern extremity and runs in a northeasterly direction through Commerce, Picher, and Hockerville, Okla., Baxter Springs and Galena, Kans., and Joplin, Webb City-Carterville and Carthage, Mo. Almost the entire present production comes from the area between Commerce and Baxter Springs.

Jan 1, 1932

By J. R. Thoenen

Occurrences of titanium, zircon, and other heavy minerals are widespread in Florida. Deposits concentrated as "heavy sands" by wave and wind action have been mined an or near Atlantic coastal beaches since 1916. An important inland concentration at Trail Ridge; .believed, to have formed along an ancient share line, was disclosed by preliminary investigations (1947) by the Bureau of Mines. This report describes investigations to determine the extent and grade of "heavy-sand" concentrations in other inland stabilized dune areas in the central and northeastern parts of the peninsular region of the State (fig. 1). Portions of the central highlands south of Trail Ridge and terraces and dunes in the coastal lowlands region, east and northeast of the ridge were investigated. Holes were drilled in 10 areas (see table 1 and fig. 2) along State and County roads and on private property. They were spaced 250 to 2,000 feet. apart to obtain a cross-sectional picture of "heavy-sand" content in the dune areas. These sections were generally placed in east-west directions normal to the general trend Of the peninsula to intercept one or more of the ancient shore lines in the various areas (figs. 3 to 13, incl.). A total of 433 drive piped and 333 jet holes were drilled, and 7,293 bulk and core samples were taken. Intermediate holes were placed at closer intervals when field analysis indicated 1 percent or more of heavy minerals present. All of the holes drilled and the analysis of samples that contain 1 percent or more of heavy minerals are listed in table 2. Profiles (figs. 14 to 20, inclusive) show the more favorable concentrations, which are irregular in outline and erratic in mineral content. The highest concentrations averaged 1.0 to more than 2.0 percent heavy-mineral content, but a few individual hole samples exceeded 3.0 percent in grade.

Jan 1, 1949

By John A. Kost

Previous work performed under Contract H0220003 suggested that the mean incombustible content could be obtained with fewer samples and smaller samples without greatly increasing the sampling error. Under Modification No. 4 additional surveys were made in twelve coal mines, representing six states. Same 2,500 samples were collected, analyzed for incombustible content, and statistically evaluated. The earlier findings were substantiated.

Jan 1, 1975

By W. D. Mcmillan

Kaolin, or china clay, is the term applied to a group of hydrous aluminum silicates. Because of its purity, light color, and refractory properties, kaolin is used extensively in the manufacture of high-grade ceramic wares and as a filler by the rubber and paper industries. Although there are numerous pottery and enamelware plants in Texas, and large rubber and paper industries; all of the kaolin used in these plants is from other States, There are two known occurrences of kaolin in Texas, namely, the Leakey deposit in Real County and the several deposits of the Medley district in southern Jeff Davis County. An investigation of the Mueller kaolin deposit in the Medley district was undertaken by the Bureau of Mines. Following an examination of this deposit by W. D. McMillan, engineer in charge of the Texas field office of the Bureau of Mines, a proposal was made to investigate the deposit by diamond core drilling.

Jan 1, 1949

By L. B. Pankratz

Heat contents, measured above 298.15° K, and derived entropy increments are presented in tabular and equation form for the two crystalline forms of zinc sulfide (sphalerite and wurtzite) and for four solid solutions of iron and zinc sulfides having the compositions Zno.,,6Fe0.302S, Zno.750Fe0.250S, Zno.650Fe0.3505, and Zno.498Feo.502S.

Jan 1, 1965

By John J. Mulligan

Since 1941 the Federal Bureau of Mines has been conducting an intermit-tent program of placer and lode investigations to evaluate the potential tin resources of the western Seward Peninsula tin belt. Previous investigations were made in the Potato, Cape, Brooks (Lost River), and Ear Mountain areas. As part of this program the Bureau made a reconnaissance of reportedly tin-bearing stream gravels in areas adjacent to the previously worked tin deposits at Lost River and Potato Mountain. The objective of the reconnaissance was to determine if additional areas might be favorable for lode or placer exploration. The work was begun late in the fall of 1956 and completed during the following summer. The streams sampled were the Lost River and York Creek in the Brooks Mountain area and the Anikovik River and Kigezruk and Baituk Creeks in the York area. Samples were obtained by churn-drilling methods employing conventional placer-evaluation procedures. Holes were drilled at wide intervals at sites chosen as being representative of drainage areas rather than of individual gravel deposits. Minor to trace amounts of tin were found in the gravels of all these streams, but the highest grade was 0.35 pound of tin per cubic yard in the gravels of Lost River below the mouth of Tin Creek. Small amounts of gold were found on Baituk Creek and in one hole on the Anikovik River; the highest grade did not exceed 10 cents per cubic yard. Traces of scheelite and barite were found on York Creek, chromite was encountered in one hole on the Anikovik River, and minor amounts of titanium minerals (probably derived from basaltic intrusives) were found in the York area.

Jan 1, 1959

Comparative tests of four coals used industrially for coke production have been made by three laboratories of the Federal Bureau of Mines, each using its standard equipment and procedures for evaluating coal for coking. Two of the coals were blends used in the western and eastern sections of the United States, the third was a strongly coking coal widely used for producing coke in Alabama, and the fourth was a blend typical of those used for producing foundry coke in the Birmingham district. The coals used and the cokes produced from them covered a wide range of chemical and physical properties. The tests used at all three laboratories for determining the physical properties of the cokes were made according to ASTM (American Society for Testing Materials) methods. The excellent agreement found for the physical properties of the cokes indicated that, for the coals tested, the BM-AGA (Bureau of Mines-American Gas Association) 18-inch circular retort used at Pittsburgh, Pa" the 14-inch slot-type oven used at Denver, Colo., and the 17-inch slot-type oven used at Tuscaloosa, Ala., were substantially equivalent for evaluating coals for production of coke. Thus, added value is given to data obtained previously and independently at these three Bureau laboratories. INTRODUCTION Laboratory equipment to produce coke for evaluation has not been standardized by the industry. The results obtained with anyone design of equipment have been regarded as showing only the relative values of coal to produce coke of the requisite quality. Few systematic studies have been made to correlate results obtained in different types of equipment. Results of one, in which the Bureau of Mines participated, were published recently.2/ This

Jan 1, 1961

By Ott F. Heizer

This paper describing the practice at the tungsten concentrator of the Nevada-Massachusetts Co., Inc., at Mill City, Nev., is one of a series being prepared by the Bureau of Mines on milling practices, methods, and costs in the United States. The ore, which contains about 1.10 per cent of scheelite (CaW04), is concentrated on tables and by means of a magnetic separator and roasters. A product containing 70.43 tungsten trioxide is shipped. The plant was designed for a capacity of 100 tons per 24 hours, but at present 142 tons of ore are milled per day. The author acknowledges the assistance of William O. Vanderburg, associate mining engineer, U. S. Bureau of Mines, in preparing this paper.

Jan 1, 1930

The following is a Maintainability Design Checklist for coal mining equipment. The purpose of the checklist is to provide a summary of design review points for the maintainability assessment of new or existing underground equipment. It specifically focuses on the identification of equipment design features, tasks, or procedures that impact equipment downtime, repair costs, labor hours and maintainer skill level requirements. Some checklist points are general in nature. The checklist was designed to be used across all categories of underground equipment. The intent is to draw attention to design features and maintenance procedures that will increase maintainability requirements. You are encouraged to adapt this checklist to site specific or machine specific requirements by: Inserting specific performance criteria for various categories of maintenance tasks. For example; all hydraulic lines on a shuttle car should be replaceable in 15 minutes or 25 minutes, etc. Adding or deleting checklist items for different categories of equipment. You would include environmental control equipment, for example, on face equipment and not on shuttle cars or man trips. Adding additional checklist items based on site or equipment specific maintenance histories or experience, company maintenance standards, or other factors.

Jan 1, 2000

By Hisataka Sakakibara

Although the pathophysiology of vibration-induced white finger (VWF) is still under discussion, evidence has been accumulated to understand the underlying mechanism. VWF is pathophysiologically characterized by an enhanced vasospastic response to cold, which can result from an imbalance between vasoconstriction and vasodilation in the digital arteries in response to cold (i.e., vasoconstriction-dominant). The imbalance is supposed to be due to faults in vascular vessels and sympathetically mediated vascular tone. Enhanced vasospastic response to cold Narrowing of arterial lumen with medial smooth muscle hypertrophy. Possible functional factors for enhanced vasoconstriction • Increased sympathetic nervous activity to cold (e.g., norepinephrine) • Increased release of endothelin-1 (ET-1; an endothelial-dependent vasoconstrictor) from the endothelium • Increased reactivity of alpha2-adrenoreceptors to cold Possible functional factors for decreased vasodilation • Decreased release of nitric oxide (NO; an endothelial-dependent vasodilator) from the endothelium • Decreased release of calcitonin gene-related peptide (CGRP; a vasodilatory neuropeptide) from sensory afferents The question is how their interrelations or imbalances among them are Vibration and arterial damage The next question is, how does hand-arm vibration exposure induce such pathophysiological changes in VWF patients? Recent morphological evidence from animal experiments shows that vibration acceleration stress (including shear stress) and smooth muscle contraction contribute to arterial damage of smooth muscle and endothelial cells. The vibration-induced arterial damage is frequency-amplitude-dependent.

Jan 6, 2006

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future. To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951

By C. F. Winquist

The Bureau of Mines is engaged in research to evaluate the effects of cutter bit wear at coal mine faces. This paper addresses one element of conical bit wear, bit rotation. A discussion on mounting configura-tion and bit forces and their effects on rotation is presented. The effects on rotation and bit forces of bit attack angle, cutting depth, and skew are determined for two types of conical bits during linear cutting of sandstone-inclusive rock. The results indicate that a 10° negative skew angle and 35° attack angle produce the maximum rotation of 17.5° for each foot of cutting. Data on bit rotation and bit forces are presented in an appendix.

Jan 1, 1985