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By Yuta Yamamoto

Seafloor massive sulfides (SMS) which contain Au, Ag, Cu, Zn, and Pb have been interested in as a target of commercial mining these 15 years. Japan has large potential of SMS and a national R&D project for the mining has been active these 5 years. However, the economy of SMS mining is very bad, because the waste tailing disposal cost is very expensive in Japan. A slurry flushing method is experimentally examined in this study for the improvement of the economy. During the flushing, because of density difference between the metal-rich ore and the waste rock, a kind of gravity separation is possible. The results suggest a possibility of the actual application.

Sep 14, 2011

By Ian J. Graham, Cornel E. J. de Ronde

New Zealand lies astride a convergent plate boundary that extends north-eastwards from the Taupo Volcanic Zone (TVZ) to Tonga. This boundary is marked by the Kermadec arc, c. 1200 km of which falls within New Zealand’s EEZ, and which is host to numerous volcanic edifices both on the arc and in a zone immediately behind the arc to the west. In 1999, thirteen volcanic centres in the southern 260 km of the arc were surveyed for their hydrothermal plumes with seven of them discharging vent fluids into the surrounding ocean. Three of the seven volcanic centres have had mineralised rocks recovered from them during dredging and submersible operations, namely Brothers, Rumble II West and Clark. Presentday plume data combined with mineralogical evidence indicate that the vent sites at Rumble II West and Clark are waning, although the presence of Cu-rich sulphides in samples recovered from Rumble II West suggest there may be a massive sulphide (Cu-Zn-Pb-Ba ± Au) deposit located within the caldera. Brothers volcanic centre is host to the largest polymetallic mineral deposit discovered along the Kermadec arc and has numerous, up to 7 m tall chimneys within a c. 600 x 200 m area located on its NW caldera wall. Geochemical data indicate that concentrations of base metals are variable and depend critically on sample type. When combined with mineralogical and plume data, this indicates addition of a magmatic fluid component to the vent fluids.

Aug 24, 2006

By G. Cherkashov

The geodiversity of seafloor massive sulfides (SMS) deposits at the slow- and ultra-slow spreading ridges is of great variety (Fouquet et al., 2010). Tectonics and magmatism are the two principal factors which control SMS formation and localization. The geological setting of SMS deposits is determined by their position relative to the rift valley and by the types of rocks hosted (Table 1). Depending on the first parameter, SMS deposits could be localized at [ ] the axial volcanic ridge or at the flank of the rift valley. Basalts, deep-seated gabbro, and serpentinized peridotites are distinguished among the hosted rocks. The outcrops of deep-seated rocks are exposed at the flanks of the rift valley. The tectonic mechanism of the lower crust and mantle rocks exhumation process is connected with very large offsets along the detachment faults, resulting in a forming oceanic core complex (OCC) (Smith et al., 2006; MacLeod et al., 2009). The SMS related to OCCs are represented by such ore clusters as Ashadze, Logatchev, Semyenov, and some others (Table 1) and are increasing steadily in number. This fact in combination with widespread OCC formation at the slow-spreading ridges (Escartin et al., 2008) and high grades of metals in SMS related to OCCs has provoked considerable scientific and economic interest in these types of deposits. It could be mentioned in this regard that the first two applications to the International Seabed Authority for prospecting and exploration of sulfides have been submitted for the areas in the spreading centres with wide distribution of the core complexes.

Jan 1, 2011

By S. W. Chang, James R. Hein, S-R. Lee, A. Zondervan, H. Choi

"Nine Fe-Mn nodules from the extensive nodule field in the east of Campbell Plateau of southwest Pacific Ocean beneath the Deep Western Boundary Current (DWBC) and Antarctic Circumpolar Current (ACC) were analyzed for the 10Be/9Be dating by AMS (Accelerator Mass Spectroscopy) at IGNS, New Zealand.Several types of nodule morphology were identified including distinctive discoidal forms with overgrowths resulting possibly from overcrowding and partial sediment burial. Five principal nodule facies were also recognized by location and occurrence (Fig. 1) (Wright et al., 2005). Fe-Mn nodules show various concentric internal growth textures, such as, cuspates, large parabolic cuspates, pseudo-columnar, columnar, globular, and laminated, which vary even in a nodule with hydrogenetic, early diagenetic, or mixed origin. Each texture shows micro-textural varieties and different mineralogy and/or chemistry. The genesis of each internal texture was indicated by the REE patterns, the mineralogy of Mnoxides, and the Mn/Fe ratios."

Jan 1, 2017

By In Kwon Um

The XRF Core-Scanner system performs non-destructive analysis of elements from Mg to U, in concentrations of ppm levels on split cores with digital images. Using the AVAATECH XRF Corescanner system, we conducted high resolution element analysis of deep sea sediment cores from Clarion-Clipperton fracture zone of the northeastern Pacific to reveal recent environmental changes. Comparison of data estimated by the XRF core scanner with ICP-AES showed relatively weak correlation coefficients except Mn contents. Down-core variations of most elements seem to be matched with each other and reflect changes of sediment colors. Especially Mn/Al ratio significantly change at distinct color boundaries. The variations of Mn/Al ratio with sediment colors are suggestive of changes in redox condition and further divided into two types probably affected by activities of benthic organisms. Be isotope age datings of select core (BC08-02-13) indicate that the color boundaries are approximately coincident with late Pliocene and Pleostocene also early Pliocene and late Pliocene boundary. Keywords: XRF core scanner, High resolution, C-C zone

Jan 1, 2011

By Robert Corcoran, Piotr Jasiobedzki, Roy Jakola, Michael Jenkin

Vast mineral resources of copper, zinc, cobalt and gold have been identified off the coast of Papua New Guinea at depths exceeding 2,000 meters. Accessing them in a cost effective manner and without destroying the marine habitat requires overcoming numerous technical and operational challenges. Although there are a number of deep-sea mining operations underway worldwide, the depths encountered are significantly less than will be required to mine these ore deposits. To date, only the oil industry has developed technologies for successfully accessing reserves at depths of 3,000m.

By I. V. Kubrakova, O. A. Tyutyunnik, M. L. Getsina, A. M. Asavin

An analysis of noble metals (NM) in natural samples is most problematic. Determination of their traces in geochemical samples, in part, for the purpose of deposit evaluation, is a difficult analytical task. A number of international standard reference materials of rocks and ores, in which NM content is certified, is estimated at a half dozen. For example, in the International proficiency test for analytical geochemistry laboratories (GeoPT), which is held by the Department of Earth Sciences (The Open University, United Kingdom), the data for gold and platinum are observed very rarely, and the results obtained in different laboratories differ on 1-3 orders of magnitude. It is caused by low contents of NM in nature, by a variety of their complex and mineral species, as well as by a complicated matrix composition of platinum-containing objects. Among these objects are ferromanganese ores, enriched strongly with Fe, Mn, Ni, REEs - the elements hampering a precise determination of NM due to a complexity of instrumental inter-element correction. The absence of the reliable methods of NM determination in these ores drastically limits the possibility of deposit evaluation.

By Daisuke Monoe, Kisaburo Nakata, Rika Takeuchi, Tetsuo Yamazaki, Tomoaki Oomi, Tomohiko Fukushima

There are generally two methane passes in conjunction with the seafloor natural cold seepages, as is schematically shown in Fig. 1. The first pass consists of the coupled anaerobic oxidation of methane and anaerobic sulfate reduction, as well as sulfur oxidation in the bacterial mats and immobilization thereafter in the sediment layer and on the seafloor. Through the first pass, calcium and organic carbonates are formed in biological and chemical processes from the methane (Luff and Wallmann, 2003; Luff et al., 2004). The detailed structure of the seafloor methane consumption process unit and its biological and chemical processes were introduced in Yamazaki et al. (2005). The other pass consists of direct bubbling into the water column. Through this pass, organic carbonate is formed with biological oxidation, and a small amount of the methane escapes into the atmosphere. Methane flux is supplied to these two passes through the sediment layer from the deeper structures. The structure of the methane supply process unit was introduced in Yamazaki et al. (2006).

Sep 24, 2006

By Andrea Koschinsky

Recent technological breakthroughs in the fields of ceramics, medicine, aerospace engineering and electronics (semi- and superconductors) are constantly creating new uses and an ongoing increasing demand for a variety of rare valuable trace metals. These so-called high-tech elements such as hafnium (Hf), titanium (Ti,) niobium (Nb), tantalum (Ta), zirconium (Zr), molybdenum (Mo), vanadium (V) and the rare earth elements (REE), many of them of strategic importance, occur inter alia at elevated and potentially economic concentrations in marine ferromanganese nodules and ferromanganese crusts, making those deep sea deposits potential future resources of these metals. As these metals are mostly present in the lattice of the manganese and iron phases, which are strongly intergrown, rather than in separate mineral phases within the nodules and crusts (Koschinsky and Hein, 2003), reductive dissolution of the host phases is a prerequisite to release and dissolve the valuable metals. To evaluate the association of these rare valuable metals with their mineral carrier phases, sequential leaching experiments were carried out on selected samples in a first step in our project.

Jan 1, 2011

By U. Schwarz-Schampera, C. Rühlemann, H. -R. Kudrass

Within 2006 BGR will conclude a contract with the UN International Seabed Authority (ISA) for the exploration of polymetallic nodules. The contract covers an area in the Pacific nodule belt between the Clarion and Clipperton fracture zones, that which is about 75.000 km2 in size at water depths between 4200 and 5000 m (see Fig. 1). Up to now, 7 consortia or state parties have acquired similar exploration “licenses” for polymetallic nodules in the central Pacific Ocean and the Indian Ocean. These licenses of the UN authority are required according to the UN convention on the law of the sea (UNCLOS) as the areas of interest are located outside of national EEZs. The “licenses” then reserve exclusive rights to the applicant for a time span of about 15 years.

Aug 24, 2006

By Tetsuo Yamazaki

Manganese nodules, seafloor massive sulfides, and cobalt-rich manganese crusts in deep-sea areas have been considered as future metal sources (Mero, 1965; Halbach, 1982; Lenoble, 2000). Manganese nodules were the first recognized deep-sea mineral resource and many efforts concentrated on the R&D of mining systems (Welling, 1981; Herrouin et al., 1989; Yamada and Yamazaki, 1998) and assessment of environmental impacts (Burns et al., 1980; Foell et al., 1990; Yamazaki and Kajitani, 1999). No mining venture, however, has been active for this potential resource. The reason is that the rate of world economic growth has been slower than anticipated in 1960s. During the 10 year period of 1994-2003 (Fig. 1), on the other hand, there was about a 33% increase in the world copper demand. Of that increase, about 60% was consumed by China. Most of China?s increased copper demand took place over the final 4-5 years of that period. The growth is expected to continue for several years, and in 10 years or sooner the same situation is expected for India. Copper is the third metal in global demand, but its small abundance in the Earth?s crust is not well recognized (Table 1). From the production rate and the abundance, a copper shortage, or crisis, has a high probability than the other metals. Japan has no domestic copper resources and needs a counter measure for this potential coming copper shortage. Fortunately, Japan has a manganese nodule mining claim in the Clarion-Clipperton nodule field, Kuroko-type massive seafloor sulfide deposits in the Okinawa Trough and Izu-Ogasawara areas, and cobalt-rich manganese crusts around Okinotori-Shima and Marcus Islands. We need to re-evaluate their potential as copper resources and to realize their development.

Jan 1, 2005

By Masaru Nakamizu, Tetsuya Fujii, Tatsuo Saeki, Ken-ichi Yokoi

Methane hydrate, a solid compound formed from methane and water, occurs naturally in permafrost regions on-land and in deep continental slopes offshore and has been examined as future energy resources. The existence of methane hydrate in the eastern Nankai Trough region, offshore Japan, was confirmed by drilling the MITI well “Nankai Trough” in 1999. Aiming commercialization of methane hydrate production, the Research Consortium for Methane Hydrate Resources in Japan (MH21, core associations: JOGMEC[*1], AIST[*2] and ENNA[*3]) under METI [*4] has been executing geological and geophysical surveys around the eastern Nankai Trough since 2001 as a nation project.

By M. E. Williamson

A seafloor based robotic drilling system is being developed for the National Institute of Ocean Technology in Chennai, India to support a National initiative for marine methane hydrate research. The system will be capable of core sampling to 150m below the seafloor in 3000m of water under telemetric control of an operator onboard a research vessel at the surface. Unlike previous robotic drilling systems, this unit (designated the ACS) will use wireline methodology to reduce the number of tool handling operations required to complete the borehole (conventional rod drilling requires 2025 tool handling operations to complete a 100m hole, while wireline requires only 48 operations to reach the same depth).

By Pierre-Yves Morvan

One of the numerous challenge for underwater mining is the positioning. This paper describes an architecture for the integration of an Ultra Short BaseLine (USBL), an Acoustic Synthetic BaseLine (ASBL) operating in Sparse Array mode and a Doppler Velocity Log (DVL) closely coupled with an Inertial Navigation System (INS) for precise subsea positioning in severe environments. By using such architectures, the INS can help to reduce the noise on the measurements coming from acoustic sensors. Another advantage is the capability to reduce the number of required transponders on the seabed, and as a consequence, reduce the time for the deployment and calibration of each transponder. The paper further describes sea-trials performed to assess the ability of a complete positioning system to provide decimetric positioning precision even with a single beacon deployed in the navigation area.

Jan 1, 2017

By Naoki Hiroyoshi, Kunihiro Hori, Kengo Sekimura, Mayumi Ito, Kouki Kashiwaya, Eiji Yamaguchi, Masami Tsunekawa

Cobalt-rich ferromanganese crusts and nodules ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei. During the mining operation, these rocks should be separated as unfavorable waste rocks with the manganese minerals. The ferromanganese crust and nodule ores require mineral processing to remove the substrate rock before the smelting. Deep-sea manganese nodule ores in contrast contain vanishingly small rocks, and can be directly treated with a smelting process without mineral processing treatment. This paper shows phisical and chemical description of the ores for the purpose of mineral processing, and reports liberation degree measurements of crushed ores and gravity separation tests. A mineral processing treatment flow is proposed from the obtained results. There is the first report of applying gravity separation in the treatment of coarse sized crushed products of cobalt-rich ferromanganese crust and nodules ore.

By Robert G. Ditchburn

Dating seafloor mineralization at hydrothermal centres of submarine arc volcanoes is important for understanding deep-seated volcanic events that can produce deposits rich in base and precious metals. The activity ratios, 228Th/228Ra, 228Ra/226Ra (Bq.Bq-1) and 226Ra/Ba values (Bq.g-1) are used for dating barite- rich seafloor massive sulphide (SMS) in the age ranges 0.3 ? 12 years, 3 ? 35 years and 500 ? 15,000 years, respectively. Thus, the time elapsed to amass an economic deposit and, ultimately, its capacity for sustainable extraction, can be estimated. 226Ra/Ba and 228Ra/226Ra values have been measured in relatively young chimneys that were collected, 1998 to 2006, from hydrothermal sites at Brothers and Clark volcanoes (Kermadec arc) and East Diamante volcano (Mariana arc) to check these initial ratios, essential for calculating ages for older mineralization at the same sites, were not varying significantly. We found that the 226Ra/Ba value for fresh SMS mineralization at the Brothers NW caldera and East Diamante hydrothermal sites have been reasonably stable for 6 years and 2 years, respectively. At both sites, the 228Ra/226Ra value for fresh SMS has been stable for 5 years. This was established from young chimneys where the measured 228Ra/226Ra value could be corrected for radioactive decay using the age derived via the 228Th/228Ra method. However, long-term stability of the initial 226Ra/Ba and 228Ra/226Ra values has yet to be proven. These isotopes of Ra are used as a proxy for better understanding of the transfer of Ba from deep magmas to the seafloor, via the circulating fluids of the hydrothermal system.

Jan 1, 2011

By Irina A. Pulyaeva

Hydrogenetic Fe-Mn crusts are ubiquitous in the ocean basins and play an important role in marine mineral-deposit research because of their widespread occurrence and high concentrations of valuable and rare metals. Directed research, which started in the last quarter of the 20th century, has provided significant results, with substantial amounts of data produced on Fe-Mn crusts structure, composition, and distribution in the global ocean. Detailed study of several seamounts has given confidence about the scale of Fe-Mn crust development and their characteristics. Now, commercial interests gain more and more attention. However, at the same time some theoretical questions related to Fe-Mn crust history including controls on metal sources and concentrations have not yet been answered. Here, we present the overview of age, composition, distribution, and geological setting of hydrogenetic Fe-Mn crusts from Pacific and Atlantic seamounts and discuss the geological evolution and conditions that led to the formation of potentially economic concentrations of metals. The age, composition, and distribution of Fe-Mn crusts in the Atlantic and Pacific oceans were determined by using a Fe-Mn deposits database compiled from our original data, published papers, published databases, and other international sources. Comparative analysis of Fe-Mn deposits from the Atlantic and Pacific oceans shows that there are similarities in basic characteristics of crust formation in both oceans. Simultaneously, there are significant differences in the scale of Fe-Mn crust distribution and composition that can be explained by differences in geological settings and characteristics of the deposition environment.

Jan 1, 2011

By Guillaume Blanc

The development of marine mining in the offshore areas adjacent to most of the insular and continental European States is limited by the complex and evolving nature of its legal regime on the basis of the relevant applicable international, European and domestic rules. As the development of marine mining requires investments in capital-intensive technologies, the bankable feasibility of marine mining projects is very much dependent on the legal security of mining rights, assets and operations in offshore areas. This is quite difficult to assess due to the constant accumulation of applicable and potentially conflicting international and domestic laws in these areas, in particular the coastal zone, the territorial sea, and the Exclusive Economic Zone (EEZ). The often conflicting interaction of international treaties, laws and regulations in offshore areas raises specific and major issues in terms of permitting processes, access rights, ownership rights over the mineral resources explored and mined, flag vs. coastal State jurisdiction over mining vessels and marine mining equipment, international environmental liabilities, and unitisation and multi-forum disputes. In addition, the determination of jurisdiction and the legal regime under which marine mining could take place is becoming even more complex with the development of EU Law and the recent revision of the International Law of the Sea, particularly the new extension regime of the EEZ and jurisdiction over the continental shelf.

Jan 1, 2004

By C. W. Devey, K. S. Lackschewitz

The mineralogy and geochemistry of hydrothermally altered wall rocks from different modern basaltic- and felsic-hosted hydrothermal fields at seafloor spreading centers and convergent margins have been studied to determine the characteristics of different types of alteration and to calculate the magnitudes of elemental exchanges between seawater and wall rock.

Aug 24, 2006

By Simon McDonald

The Neptune Group was established in 1999 to apply for exploration permits within New Zealand’s 200nm EEZ. These applications were to investigate and commercialise hydrothermal Seafloor Massive Sulphide (SMS) deposits identified by international researchers and to locate others. SMS are volcanically related seafloor accumulations of copper, lead and zinc with high levels of gold and silver. Neptune has three granted exploration licenses within the New Zealand EEZ and has application in other jurisdictions. Neptune undertook the world’s first commercial drilling exploration work of SMS in December of 2005.

Aug 24, 2006