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By Robert B. Parsons

"It is generally acknowledged that Canadian and foreign-based mining companies are spending relatively fewer dollars in Canada and more dollars abroad than was the case not many years ago. It is common to see the Canadian tax system being fingered as one of the causes in this shift in direction. However, if one takes the time to peel away the surface of our tax system, and to probe a little deeper into its substance, it will be found that the Canadian taxation of mining is generally quite competitive. IntroductionCross-border shopping in the mining industry? - Absolutely! Economics 100 teaches that dollars are votes in the capitalist system, and mining companies are going to cast their limited number of votes where they can achieve the highest return at the least risk. The Canadian consumer knows that taxes are a major factor in cross-border shopping, and mining company executives know that the same tenet holds true in their industry. Unfortunately, mining operations are subject to such a bewildering array of tax rules that making an intelligent decision is not always an easy matter.Statutory Tax RatesConsider, for example, the ""statutory"" tax rates shown in Table 1. (Statutory tax rate in this table refers to the simple sum of federal and provincial tax rates on profits as specified in the tax legislation.) Looking only at the total statutory tax rates (such as 66070 for Manitoba) , one might quickly observe that the Canadian mining industry is subject to a truly onerous tax regime, especially as compared to the United States where statutory tax rates can be in the 34% range."

Jan 1, 1992

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016

By R. F. Dawson, A. S. Bagnall, K. Barron

"At Smoky River Coal Limited (SRCL), economic occurrences of structurally thickened coal deposits form attractive surface mining targets. These steeply dipping, structurally complex deposits require that special attention be given to pit wall design and operational practices.Where anchor support is feasible, there is potential for reducing footwall waste requirements and/or increasing coal recovery. SRCL has used rock anchors to support footwall slopes since 1985. This paper outlines design considerations and performance of rock anchor support systems at SRCL.Three case histories are included that illustrate the design process for supporting steeply dipping footwall slopes using rock anchors.IntroductionWestern Canada contains vast reserves of high grade coking coal largely located in two belts within the Rocky Mountain Foothills straddling the Alberta/British Columbia border. There are about one billion tonnes of ""clean"" coking coal reserves (Romaniuk and Naidu, 1986) situated near existing mining infrastructure. Within the reserve areas shown in Figure I, a total of six producers operate 10 large mines linked with ports situated on Canada's west coast. Al! of the producers operate conventional shovel/truck surface pits.Surface mineable reserves within some of the mountain coal mines are located on dip slopes or where the geologic structure has thickened the coal near the surface, creating low strip ratio targets. Footwall slopes in these mines are developed parallel to bedding, thus minimizing waste extraction and preventing undercutting of potentially unstable strata. The base of the mineable coal measures in both north and south regions is marked by massive quartz sandstone units (Torrens Member and Moose Mountain Member) which often form the footwall. Footwalls developed within this basal sandstone unit can attain very high unbenched heights often with little risk of instability. In cases where the footwall is developed on weaker strata above this basal unit, stability considerations control slope height when bedding dips exceed about 30°. In these situations it is desirable to assess the benefits of artificial support to increase the unbenched footwall slope height."

Jan 1, 1995

By David Meadows, Elmer Palmer, Steve Dixon

As part of the Goldcorp Inc growth plan Minera Peñasquito SA de CV has developed its polymetallic deposit with a large “state of the art” concentrator to process lead and zinc ores. The plant consists of two grinding lines including 38ft diameter SAG mills and 24ft diameter ball mills. During mid to late 2009 concentrator commissioning activities commenced. First concentrates were produced in October 2009 and now the plant is meeting its design basis of 65,000 mtpd per line. This paper describes the design and operational experience to date for its grinding circuit design, together with the recently commissioned HPGR crushing circuit.

Jan 1, 2012

By R. F. Dawson, A. S. Bagnall, K. Barron

"At Smoky River Coal Limited (SRCL), economic occurrences of structurally thickened coal deposits form attractive surface mining targets. These steeply dipping, structurally complex deposits require that special attention be given to pit wall design and operational practices.Where anchor support is feasible, there is potential for reducing footwall waste requirements and/or increasing coal recovery. SRCL has used rock anchors to support footwall slopes since 1985. This paper outlines design considerations and performance of rock anchor support systems at SRCL.Three case histories are included that illustrate the design process for supporting steeply dipping footwall slopes using rock anchors.IntroductionWestern Canada contains vast reserves of high grade coking coal largely located in two belts within the Rocky Mountain Foothills straddling the Alberta/British Columbia border. There are about one billion tonnes of ""clean"" coking coal reserves (Romaniuk and Naidu, 1986) situated near existing mining infrastructure. Within the reserve areas shown in Figure I, a total of six producers operate 10 large mines linked with ports situated on Canada's west coast. Al! of the producers operate conventional shovel truck surface pits.Surface mineable reserves within some of the mountain coal mines are located on dip slopes or where the geologic structure has thickened the coal near the surface, creating low strip ratio targets. Footwall slopes in these mines are developed parallel to bedding, thus minimizing waste extraction and preventing undercutting of potentially unstable strata. The base of the mineable coal measures in both north and south regions is marked by massive quartz sandstone units (Torrens Member and Moose Mountain Member) which often form the footwall. Footwalls developed within this basal sandstone unit can attain very high unbenched heights often with little risk of instability. In cases where the footwall is developed on weaker strata above this basal unit, stability considerations control slope height when bedding dips exceed about 30°. In these situations it is desirable to assess the benefits of artificial support to increase the unbenched footwall slope height."

Jan 1, 1995

By A. de Ville d’Avray, G. Guezennec, P. Wavrer, E. Braak

The aim of the European CEReS project was to develop an innovative copper recycling route based on the coprocessing of coal production waste by bioleaching and printed circuit boards (PCBs) from Wastes of Electrical and Electronic Equipment (WEEE). Coal waste is processed by bioleaching in stirred tank reactors, and the resulting bio-lixiviant solution is used to extract copper from PCBs pre-treated by catalytic cracking. Copper is then extracted using solvent extraction, stripping and electrowinning. The whole process flowsheet combines thermal, biotechnological, physical and hydrometallurgical operations. Once the process concept has been validated at laboratory scale, a simulator of the whole process has been built in the USIM PAC software platform. The tool enables to improve the analysis of the results of the lab-scale experiments and to design industrial-scale scenarios by simulation. The results of such simulations allow to estimate the economical interest and to perform environmental impact assessment. After presentation of the CEReS project objectives and main results, the paper describes the methodology used to build the simulator and define the scenarios corresponding to feasible process routes. The main results of the simulations are then presented with technical, economic and environmental point of views. INTRODUCTION Because of rapid technological innovations in the electronics industry, electronic waste represents the fastest growing waste stream in the world, especially in developing countries (Işildar et al., 2018). Meanwhile, the global copper demand is expected to go on rising in the future. As significant amounts of copper are present in end-of-life printed circuit boards (PCBs), it becomes a necessity to develop efficient copper recycling routes. Metal refining from e-waste is traditionally performed by pyrometallurgical processes. However, the hydrometallurgical processing of PCBs, which has been shown to be technically feasible at laboratory scale with a wide range of leaching reagents, could be a less energy intensive and more flexible alternative (Tuncuk et al., 2012). However, a large amount of leaching reagent is required to leach the metals from PCBs.

Jan 1, 2019

By Robert B. Parsons

"The junior mining company's bank account is depleted, but there are high hopes for the company's property. Where to get the necessary development funds is a common problem facing many juniors.This month, Tax Notes discusses briefly the principal income tax implications of several alternative development plans that are typically available to the junior mining company and its shareholders.IntroductionAt some point in time, many junior exploration companies face a common dilemma-a promising prospect has been proven up and is read y for further development, but alas, the company is flat broke! In this situation, a number of alternatives is available to the company, including the possibility of ""going it alone"" by raising capital through a public offering, or by striking a deal with a ""major"" or some other substantial investor.This article focuses on the latter possibility, and discusses in broad term s the main income tax implications of various arrangements between a typical junior exploration company and a larger public company for the development of a particular property. It will be appreciated that a discussion of other important considerations, such as those pertaining to securities exchange regulation s and company law requirements, is beyond the scope of this article.Jointly Owned CorporationPerhaps the simplest way of dealing with the problem of financing the development of a property is to sell the property outright, pocket the proceeds, and run! Clearly, though, this alternative is unacceptable to most prospectors and developers, who are predictably reluctant to completely relinquish their equity interest in a promising property. An additional strike against such an outright sale is that the sale could trigger an income tax liability. Generally speaking, in the case of a simple sale of a mineral property, for income tax purposes the proceeds are applied to reduce the taxpayer' s unclaimed balance of Canadian development expense (""CDE""), with any unapplied excess being brought into income and taxed at ordinary corporate tax rates."

Jan 1, 1983

By Robert B. Parsons

"New Brunswick Finance Minister John Baxter pulled something out of a hat for the mining industry in April, but there is a general concensus in the industry that he should put II back where it came from.The industry has never been in the mood f or progressive rate structures, but that is exactly what New Brunswick 's 1984 budget offers to this depressed sector of the economy.IntroductionThe Province of New Brunswick stunned the Canadian mining community in April with the announcement that the province' s 16% mining tax rate would be replaced with a progressive rate structure effective January 1, 1984 (Table I). The proposed change, contained in the bud get papers tabled by Finance Minister John Baxter on April 17, caught the industry totally by surprise. The move to a progressive rate structure was completely unexpected for a variety of reasons:• Generally speaking, relations between the province and the industry have been relatively good, yet the industry was apparently not consulted with respect to the proposed measure and had no indication that a change of th is nature was coming. This is in stark contrast to the mood which prevailed during the major revamping of the province' s mining tax regime in 1977: at that time, the industry was invited to contribute in advance to the province's plan for a new tax structure.• The new structure would appear to make th e province less competitive in terms of mining tax rates with Ontario , Quebec, and other provinces, despite indications in the past that New Brunswick is very cognizant of this competitive factor in formulating mineral policy.• A joint report in November 1978 by federal and provincial officials to federal and provincial finance and resource ministers, which was careful not to directly criticize Ontario and Quebec's progressive mining tax rate structures, recommended that provincial "" tax regimes be examined to ensure the inclusion of appropriate mechanisms to avoid the excessive taxation of cyclical type profit "" , and that ""the federal and provincial governments consider the concern over progressive tax regimes expressed by the industry and examine mining and royalty tax regimes and the income tax regime with a view to alleviating the effect of such regime on the aggregate marginal tax rate"". In this context, any move to a progressive rate structure would be viewed by many observers as retrograde."

Jan 1, 1984

By C. Cortés

Flotation is a highly interactive process where a change or disturbance in any part of the circuit results in different final grades and recoveries. This high variability of the circuit metallurgical performance complicates the diagnosis of the scavenger stage at the end of the line, as copper losses in the final tailings are erratic and not totally a consequence of problems in the scavenger section. The assessment of the scavenger performance requires a more elaborated procedure than that used for others stages of the circuit. This communication describes the application of an approach that combines results of laboratory flotation tests with those of surveys performed at the plant. The approach is based on running surveys in one of the circuit lines to collect samples for determining grade vs. recovery curves for total mass and size-by-size fractions. Full mineralogical and liberation analyses are also considered on some samples of the feed and tailings streams selected to have a range of feed grades. A separate sample of the feed is used to run laboratory flotation tests to determine optimum flotation time. Two additional pieces of information are the effect of operating variables on recovery, determined through a test program based on design of experiment techniques, and operational data on every cell in the line gathered by visual observation. The application of this approach to one of the scavenger lines at Los Colorados concentrator (Minera Escondida, BHP Billiton) is demonstrated.

Jan 1, 2007

By D. A. Garland, A. D. Jackson

"Alanx ceramic/metal composites are proprietary products developed by Lanxide Corporation who joined with Alcan to form Alanx Products L.P. in 1988. Alanx ceramic/metal composites are composed of silicon carbide in a combined alumina and metallic aluminum matrix. In laboratory slurry wear tests conducted by Alanx ceramic/metal composites have shown to perform well against other wear resistant materials. At the Kidd Creek Concentrator Alanx CG896 ceramic/metal composite was tested in two pumping applications, the primary cyclone feed pumps and the filter feed pumps. In both instances the wear rates of the parts made of Alanx CG896 were far less than the gum rubber parts traditionally used. As of year to date September 1992 the unit cost to repair primary cyclone pump parts has dropped 58% from 1991 figures. For the filter feed pumps the unit cost to maintain the pumps has dropped by 33% as compared to 1990 figures. The total savings represented by implementation of Alanx wear parts, based on projected year end unit costs for 1992, as compared to 1991 costs for primary cyclone feed pumps and 1990 figures for filter feed pumps, is $166,753. INTRODUCTIONAt the Kidd Creek Concentrator the cost to maintain the primary cyclone feed pumps and the filter feed pumps was a constant concern. Rubber wear part consumption was quite high and the manpower required was considerable. For 1991 the total cost to maintain five primary cyclone pumps was $244,062. The cost to maintain the filter feed pumps in 1990 was $72,076. A wear material was needed that would increase the time between repairs and that would increase the reliability of these pumps between scheduled shut downs."

Jan 1, 1993

By Irving Wigden

The world is fast becoming information based. Mine companies migrate business infrastructures to be handled electronically. Suppliers move onto the worldwide web. In this ?e-world? successful suppliers will recognize they no longer trade in just equipment, but in knowledge. Companies can no longer just provide products and services, but instead must find ways to harness their knowledge to provide new value for customers. Mine customers will be attracted to suppliers that can help them streamline the process and use Information Technology to optimize operations, increase profit, reduce cost and enhance shareholder value. With the continued move to industry standard communications and software platforms, technology that formerly stood alone can now be integrated with other technologies. This creates more powerful systems that mine operators can use quickly, easily and cost effectively. These unified architectures improve productivity, provide higher asset optimization and allow more informed decision-making. As a leading supplier of process automation solutions for the industry, ABB provides a dynamic range of such control systems. These systems are designed for instrumentation controls, variable speed drives, electrical distribution, electrical equipment and related services for Mine Automation. Enhanced by ABB´s new family of integrated software solutions ? collectively known as Industrial IT ? ABB´s control and Scada systems place you in the best position to optimize your plant, process and enterprise operations. The paper discuss system integration and installation of High-Tec system in an underground mine. ABB has the ambition to be a System Integrator and co-operate with partners in different areas of technology. To day it is a problem to find one Supplier that can be responsible for the complete Automation System. The design of the system is also much depending of the design of the mine and also which caving procedure that is used in the current mine. Much of the work must be done in a feasibility study and during the design phase. If there is careful planning and consideration during these phases is vital in order to avoid costly changes during the commissioning phase The paper will also include a presentation of the benefit of using Automation in an Underground Mine, and how important the integration of the Human Being is to the Automation System. The most profit gained in mining industries are received when the mines can reduce internal and external disturbances in the production flow and speed. Must of the experience and discussed in this paper is from advanced technology, that has been developed in Scandinavian and adopted of LKAB in Kiruna. The author of this paper has been responsible för the Automation projects in the Kiruna Mine during 1994 - 1999. These projects include: Broadband communication of data, audio, compressed video in one data stream. Control System for Haulage -1045m Automation of Load Haulage and Dumping machines (LHD) Control of Production Drilling Riggs from a Central Control Room.

May 1, 2002

"Sink-float analysis is often used to obtain yield-ash and density partition curves in the coal industry. These provide a valuable tool for evaluating the performance of a separation process. However, for dense minerals, obtaining complete grade-recovery and density partition curves is more difficult due to the lack of heavy liquids available with the required densities. This paper examines a potential solution to this problem which is to perform batch fractionation of mineral samples in a laboratory-scale REFLUX™ Classifier using high viscosity fluidising liquids. The REFLUX™ Classifier is a gravity separation unit consisting of a system of parallel inclined channels positioned above a vertical fluidised bed. Operated in semi-batch mode, a charge of particles is fluidised from below and particles up to a certain density are elutriated from the top of the system. The fluidisation rate is then increased incrementally to fractionate the sample at progressively increasing densities. Previous work by Hunter et al. (2014) and Iveson et al. (2015) has shown that this method provides excellent agreement with yield-ash and partition curves for coal, especially when glycerol solutions are used as the fluidising liquid. This approach has now been extended to obtain the grade-recovery and density partition curves of high density mineral samples. This method has the potential to provide the minerals industry with an effective tool to evaluate the performance of unit operations separating at cut points higher than the available heavy liquids.INTRODUCTIONMeasuring efficiency and effectiveness is of key importance in the continuous improvement of mineral processing plants. For density based separation, one way the performance of a process can be evaluated is the measurement of density-based partition curves. Currently, this is done in the coal industry using the sink-float method, where heavy liquids are used to fractionate particles into discrete density intervals. However, with high density minerals such as iron ore, liquids of sufficient density are rare, and in most cases also pose serious health and safety concerns to laboratory operators. Most commercial laboratories do not perform sink-float separations above a density of about 4400 kg/m3, the maximum density of Clerici solution without operating at excessive temperatures (Koroznikova, Klutke, McKnight & Hall, 2007; Rosenblum, 1974)."

Jan 1, 2016

By Pierre Beaudoin, Michel Bourassa, Robert Lanthier, Samir Chéfaï

"Mine Doyon, in collaboration with CRM's Process Control Division, improved the control strategy at the SAG mill I Ball mill grinding circuit. The project aimed at increasing operation stability and throughput. First, a needs analysis was achieved in order to define the control philosophy and to upgrade the process control equipments and instrumentation. The stabilizing control strategy has been developed and implemented successfully using single loop PID controllers. The monitoring feature as well as the rule based supervisory control strategy were implemented on 486PCs running Process Vision and COMDALE/C softwares. Main features of the control strategy are described in this paper while results are presented and discussed.RésuméLa Mine Doyon, en collaboration avec le service de contrôle des procédés du CRM, a optimisé la stratégie de contrôle au circuit de broyage. Les objectifs du projet étaient !'amélioration de la stabilité de !'ensemble de !'opération et la maximisation du tonnage usiné. Une analyse de besoins a été réalisée pour concevoir la philosophie de contrôle et déterminer les ajouts a apporter a I 'instrumentation et au systeme de contrôle. Une stratégie de contrôle à deux niveaux, integrant stabilisation et supervision, a été developpee et mise en opération. La regulation est réalisee par une combinaison de contrôleurs Moore de type PID. Le monitoring et la stratégie de contrôle a base de règles soot implantés sur des micro-ordinateurs de type PC/486 avec les logiciels ProcessVision et Comdale/C. Les principaux aspects de Ia stratégie de contrôle sont décrits dans cet article et les résultats obtenus soot présentés et discutés."

Jan 1, 1995

"Batch flotation testwork demonstrated that a low-grade chromite ore from Bird River, Manitoba, was best floated at pH 2 using Armac C (coco amine acetate) collector and sulphuric acid as pH modifier. A grind of 100% minus 150 um was necessary for liberation, and flotation selectivity was greatly enhanced by prior desliming. A concentrate analyzing 24.2% Cr203 with a recovery of 90.2% was obtained, after three cleaning stages, from ore grading 6.05% Cr203. Total rougher collector concentration was 500 g/t and cleaner collector concentration 380 g/t. Similar grade and recovery were obtained during the pitot-plant evalualion, when a concentrate analy zing 22.3% Cr203 with a recovery of 93% (based on deslimed feed) was obtained for a total collector addition of 630 g/t.Selective flotation in a region of positive surf ace charge implies anionic activation, and a possible flotation mechanism is suggested.IntroductionIn an earlier study(1) of the beneficiation of chromite ore from Bird River, Manitoba, several methods of beneficiation were explored. These included ore sorting, heavy-media separation, and gravity concentration with flotation using Armac C (coco amine acetate) collector at pH 2, and sulphuric acid as pH modifier. Because flotation was not fully evaluated, a laboratory study was undertaken to determine the optimum parameters of chromite flotation. Optimization of parameters was established first on a laboratory scale followed by confirmation a t the pilot -plant level. Flotation of chromite using Armac C and sulphuric acid as a pH modifier has been reported as being selective for low-grade chromite ores(2)."

Jan 1, 1990

By R. R. Potter

"IntroductionAlthough iron formations were recognized in western New Brunswick about 1820, commercial production was not achieved until 1848. The Jacksonville deposits near Wood stock were developed first, and ore was treated at a blast furnace constructed 5 km to the southeast on the Saint John River. Several charcoal burners were also constructed. Pig iron was produced sporadically until 1884, when operations were finally suspended. There was little further interest in the area until 1953, when Stratmat Ltd. initiated an ambitious exploration program. At the same time, the company carried out research on an electric-reduction process to produce metallic iron and ferromanganese. The technical feasibility of this process (Udy process) was confirmed, however the high energy costs were prohibitive and work ceased in 1957. Some metallurgical research was carried out by Mandate Refining Ltd. about 1970 and more recently by the New Brunswick Research and Productivity Council.The Years Prior to 1848New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Man y of these people sett led along the Saint John River, including the area of excellent farmland near the present town of Woodstock.There were indication s that some of these earl y settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 836 when Dr. C.T. Jackson, a geologist commissioned by the Stat e of Maine, investigated the mineral potential of the area. Jackson (1836) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron deposits were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry."

Jan 1, 1983

By Xiaoqi Sun

"Rare earth elements (REEs) have a series of specific properties making them invaluable in products including lighting, electronics and magnetism. The elements have been used in many commercial products, for example, turbines, electric vehicles, batteries, lighting, computers, cell phones and lasers. Heavy REEs are attracting the interests of scientists from many countries, and these elements have become critical to develop high-tech materials. Ion-adsorbed rare earth deposits were first discovered in China. The minerals are also called weathered crust elution-deposited rare earths. The particular types of deposits are distributed throughout southern China. The ion-adsorbed deposits are rich in medium and heavy REEs, accounting for more than 80% of the world’s total medium and heavy REEs production. However, the separation of heavy REEs from ion-adsorbed deposit is difficult owing to their similar chemical properties. The conventional separating technologies have caused serious pollution. A novel extraction strategy has been developed in this laboratory and is presented herein.INTRODUCTIONThe unique properties of rare earth elements (REEs) render them important in high-strength magnets, lighting phosphors, polishing compounds, and ceramics. Especially for applications that take advantage of the f-orbital electrons, substitutions outside the REE family are often difficult to impossible (Nassar, Du, & Graedel, 2015). Extracting and separating individual elements from mined ore is not easy, requiring lengthy operations to separate them, and this results in high costs and adverse effects on the environment. The low concentration of REE in the earth’s crust makes economic exploitation difficult (de Boer & Lammertsma, 2013) and the sustainability of the REEs separation industry has aroused considerable attention (McLellan, Corder, Golev, & Ali, 2014). To eliminate protons and break the dimmers in organic phosphonic acids or carboxylic acids, the saponification of acidic extractants by acid-base neutralization reactions are widely used in industrial REEs separation (Sun, Luo, & Dai, 2012a). The saponification procedure contributes to increased extractability and selectivity of acidic extractants to a considerable extent. The common industrial saponification mechanisms and technological processes are shown in Figure 1 and include ammonium saponification (saponified by NH3·H2O), sodium saponification (saponified by NaOH), calcium saponification (saponified by Ca(OH)2), and magnesium saponification (saponified by MgO). These inevitably result in wastewaters containing NH4 +, Na+, Ca2+ or Mg2+ because of the cation-exchange extraction mechanisms (Xiao, Long, Huang, Feng, Cui, & Wang, 2013; Song, Fu, Wang, Liu, Zhou, & Li, 2014; Sun & Waters, 2014)."

Jan 1, 2016

By Leiting Yue, Peng Ren, Yu Shen, Zhihong Liu, Haibao Shao, Longgong Xia, Feng Yu

The Kennecott-Outotec Flash Converting technology has been proven as an advanced and mature process in 5 individual plants during the past 2 decades. High grade copper matte (65–72%) produced in the flash smelting, or other smelting technologies is granulated to 3-5mm granules in a water torrent, and further crushed to fine powder (≈50µm) and dried to contain less than 0.3% H2O. Oxygen enriched air, together with fine copper matte powder and lime flux are injected into the reaction shaft by a matte burner. The copper making and slag making reactions will happen in very short time and distance during the particle falling and settling. However, industrial practice has found negative effects caused by sodium contamination. Na is introduced in the copper matte granulating process, and appears as Na2SO4 on particle surface. When Na content was high, scaling problems in the boiler will be worse, and the processing air will be blocked by the growing accretion around the matte burner, and as-produced blister copper is always high in S and O. In this present study, an industrial matte sample was used in the experimental work. Na was introduced into the matte powder by Na2SO4 solution soaking. The burning behaviour of the doped copper matte powder has been investigated as a function of the impurity concentration and processing temperature. Morphology and composition of these samples explained how Na2SO4 converts and reacts in the oxidizing atmosphere, and how they or their converting species influence the burning behaviour of matte particles. Cross-sections of as-prepared samples were analyzed with SEM-EDS, and the reaction mechanism has been carefully interpreted. Results from the present study can benefit both academic and industrial people. INTRODUCTION "Flash Converting" technology was developed jointly by Kennecott Utah Copper Smelter and Outotec (Finland) OY in 1992. The first industrialization of the technology was in Utah Smelter in 1995. Since 2006, it has been successfully applied in Xiangguang Copper, Tongling Jinguan Copper Branch, Fangchengang Jinchuan Copper, and Ningde Southeast Copper. The technology has also been further developed in those smelters. At present, roughly 2 million tons blister copper is produced annually through the Kennecott-Outotec Flash Converting technology, accounting for more than 10% of global primary copper production. The technology has advantages of high efficiency, high sulfur capture rate, good in environmental issues, mature equipment supporting, high automatic control level, low comprehensive energy consumption and flexible connection with the smelting unit, which make the technology to be one of the best choices in investing a new large-scale copper smelter or updating an old copper project in the world.

Jan 1, 2019

By J. -P. Tshibangu, M. Ramos da Silva, F. Descamps, C. Schroeder, J. -C. Verbrugge

"The mechanical behaviour of rock materials is largely influenced by the stress state and pore pressure; this needs to be considered in many applications, such as petroleum engineering, tunnelling or stability of underground excavations.Conventional triaxial tests (d2 = d 3) are generally used to assess the influence of confining and pore pressure. In this work, those tests are performed on a porous rock named Sorcy limestone, along with more advanced stress paths like triaxial extension (d 2 = d 1) and purely deviatoric tests with independent pore pressure control. Those tests are combined to a true triaxial study on the dry rock in order to investigate the effect of true triaxial stresses and, hence, build three-dimensional limiting envelopes accounting for the influence of pore pressure.Three-dimensional limiting envelopes of dry Sorcy limestone are built in meridian and octahedral planes. The shape of the octahedral sections changes with the mean stress from triangular to hexagonal and then quasi circular. At even higher mean stresses, the evolution continues towards a triangle with apexes oriented in the direction of triaxial extension stress states. In meridian sections, the deviatoric stress first increases with the mean stress. The transition between this deviatoric mechanism and the cap surface occurs at different mean pressures depending on the Lode angle.Terzaghi’s effective stress is found to govern the yield and plastic behaviour of saturated Sorcy limestone. Triaxial tests show that the limiting envelope does not depend on the loading path (conventional compression and purely deviatoric stress paths). In triaxial extension, the brittle-ductile transition is observed for a higher mean pressure than in triaxial compression, as previously found for true triaxial tests on the dry rock.Finally, it is shown that upon appropriate normalisation, the dry and saturated yield envelopes come very close one to each other. This suggests that only the size of the yield envelope changes between dry and saturated state (pore pressure = 5 MPa); its shape does not seem to evolve."

Jan 1, 2015

By L. Bichler, C. J. Verdon

In this work, the effect of doping yttria stabilized zirconia (YSZ) with 5, 10 and 15 mol% erbium oxide (Er2O3, erbia) was investigated using spark plasma sintering (SPS) technique. Sintering was carried out at 1300°C with 30 and 60MPa uniaxial pressures and a 5min hold time. Densification kinetics were studied using displacement response from the SPS machine. As-sintered microstructure characterization was carried out via scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, while chemical composition was characterized by energy dispersive X-ray spectroscopy (EDS). The results suggest that sintering carried out at 60MPa produced high density composites even though erbia dopants were found to inhibit material densification and grain growth during sintering. 5, 10 and 15mol% erbia- YSZ had cubic crystal structures, as verified by XRD analysis.

Jan 1, 2014

By Yves Pépin, Sylvain Lefebvre, Dimitrios Filippou, Guillaume Hudon

"Titanium dioxide pigment plants using the so-called “chloride process” produce considerable amounts of chloride waste, which contains predominantly iron chloride. In most cases, this waste is dissolved in a weak hydrochloric acid solution and then neutralised. The metal content of the waste is dumped as hydroxide sludge, while its chloride content is lost in an effluent.Rio Tinto Iron & Titanium has developed a new proprietary process whereby pure metallic iron and chlorine gas are recovered from chloride waste by electrolysis. This process uses a two compartment cell separated by an anion exchange membrane to prevent iron cycling between its trivalent and divalent valence. The cathode is made of titanium Grade 7, while the anode is a dimensionally stable one of the type “metal–mixed metal oxide” (MMO) for the evolution of chlorine gas. The catholyte is concentrated and pH-adjusted iron-rich chloride solution originating from chloride waste. The anolyte is recirculating solution containing alkali or alkali earth chlorides such as MgCl2, NaCl, etc. Current efficiencies above 90% can be achieved at temperatures about 80°C using catholyte solutions almost saturated in iron chloride and other chlorides.In this paper, we discuss the details of this process, and how this could be integrated within a chloride pigment plant for the treatment of chloride wastes."

Jan 1, 2016