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By T Nakamura, M. Itoh

Most of the used cathode ray tube (CRT) glass in Japan, which contains lead oxide, was exported and recycled in overseas factories of new CRTs. However, domestic treatment and recycling of waste CRT glass has become necessary because overseas CRT factories have shut down and exports of CRT glass have stopped. Some of the waste CRT glass recycled domestically is charged in lead blast furnaces instead of silica flux, because there is no local reproduction route for glass that contains lead. However, the mass of CRT glass that can be treated in this manner is limited because of its high silica content. Consequently, additional treatment methods for waste CRT glass are required so that more can be used as a lead smelting material. In this study, waste CRT glass was treated with hydrofluoric acid to dissolve the silica contained in the glass, and the dissolved lead was recovered by precipitation. Lead metal was recovered by electrodeposition from the prepared hexafluorosilicic acid solution.

Jan 1, 2011

By Vlad Ruzicka

"Uranium deposits in the Rabbit Lake-Collins Bay area are associated with the sub-Athabasca unconformity which separates crystalline Archean or Aphebian basement rocks from Helikian clastic sedimentary rocks of the Athabasca Group. The basement rocks are a part of Wollaston lithostructural domain.Most of the high grade deposits, such as Collins Bay ‘A’ and 'B' Zones and Eagle Point are associated with altered rocks of the basal unit of the Wollaston Group. Some deposits, such as Raven and Horseshoe are confined to the uppermost unit of this Group. The Rabbit Lake deposit occurs in the middle, meta-arkose unit of the sequence. Locations of some deposits (Rabbit Lake, Collins Bay ‘A’ and 'B' Zones) are also controlled by thrust faults, such as Rabbit Lake Fault and Collins Bay Fault.The deposits contain either monometallic (uranium) mineralization (Rabbit Lake, Raven, Horseshoe) or polymetallic (mainly uranium-nickel) assemblages (Collins Bay “A’ and 'B' Zones).IntroductionThe Athabasca Basin region, a part of the Churchill Geological Province of the Canadian Shield, is composed of Archean and Aphebian crystalline basement and younger, Helikian, unmetamorphosed supracrustal rocks. The Rabbit Lake-Collins Bay area is situated at the eastern margin of the Athabasca Basin region, which hosts a substantial proportion of Canadian uranium resources.The crystalline basement complex was subdivided by Lewry and Sibbald (1979) into lithostructural domains and these domains were grouped into major crustal units designated, from northwest to southeast, as Western Craton, Cree Lake Mobile Zone, consisting of Wollaston, Mudjatic and Virgin River domains, and Rottenstone Complex (Fig. 1)."

Jan 1, 1986

By M. Fafard, F. Chevarin, D. Ziegler, H. Alamdari, M Kavand

"Carbon anodes, used in the Hall-Heroult process, are consumed by the electrochemical reaction to produce metallic aluminum. It is also consumed by parasitic reactions with air and CO2. The carbon anode is made of petroleum coke with different particle sizes, butts (recycled anodes) and coal tar pitch. The mixture of fine particles (less than 150 µm) of coke together with the pitch material forms a matrix, binding the large coke particles together. It is generally thought that the binder matrix is more reactive than the other anode constituents. This conjecture was not clearly proved in the literature. The present study is focused on the CO2 reactivity of binder matrix and anode constituents at 960°C, both under chemical regime (100% of CO2) and under a concentration gradient (diffusion). The apparent reaction rates of these materials were measured. The role of the binder matrix in anode consumption and its disintegration (dusting phenomenon) was discussed.INTRODUCTIONThe metallic aluminum production is one of the most important industries in Canada. The Al metal is obtained by the Hall-Héroult process. The principle of this process is the electrochemical reduction of alumina in molten cryolite carried out by an electrical current between carbon anodes and cathode at 960°C (Equation 1). The carbon anode is typically composed of calcined petroleum coke (65 wt.%) and recycled anode (called also butt, 20 wt.%) with coal tar pitch (15 wt.%), playing the role of cement to ensure the cohesion of the anode block."

Jan 1, 2016

By I. I. Bethcherman

Introduction 1.-lmportance of Physical Nature of Condensates The metals of commercial interest which have reasonably high vapour pressures below 1,200° C. are mercury, cadmium, sodium, zinc, magnesium, lithium, and calcium. With the exception of mercury, these metals occupy high positions on the electrochemical series and form compounds with very high negative free-energies of formation. It is highly desirable that such metals should not be produced in a form which is finely divided, on account of their reactivity with atmospheric gases. Powders of magnesium, calcium, and even zinc (blue powder) are dangerous to handle and cannot be coalesced by simple melting techniques. Vaporization in vacuo forms a convenient method of handling and purifying the alkaline earth metals in particular and a previous paper by the authors dealt with some of the factors controlling the separation of metals by this technique (12). An essential part of the operation is the condensation of the vapour to produce a massive deposit which may be conveniently melted and handled by established metallurgical techniques. This investigation sought to determine the conditions affecting the nature of solid condensates.

Jan 1, 1951

By Sergio Romo, Gerardo Fuentes, Adriana Garcés

Refractory ores with gold entrapped in a sulfide matrix, must be processed in a first stage with chemical or physical treatment in order to liberate the gold for a subsequent step with cyanide. The goal of this research was to compare the refractory behavior of a gold concentrate treated using two pretreatment methods: pressure oxidation and fine grinding. Gold concentrate from Viacha Mining in Bolivia, assaying 50.11 gpt, with a P80 of 131 ?m was used. The concentrate contains arsenopyrite and pyrite as main sulphides in the matrix. A preliminary test with cyanide resulted only 13.5% of gold extraction with 4 hours of stirred leaching. Using an autoclave oxidation with sulphuric acid and 12 bar oxygen pressure at 220°C pretreatment, the cyanide gold extraction increased to 69.0% in 4 hours. When material was ground in a pulverizer, producing a P80 of 20 ?m and the product directly cyanided, stirred leaching gave a gold extraction of 65% in 4 hours. For both techniques, the effect of temperature, sulfur produced in autoclave oxidation, optimization of the cyanide and the nature of residues were also studied.

Jan 1, 2014

By L. I. Kiss, S. Perron, S. Poncsák, A. Perron

Aluminium industry has an increasing interest in the diminution of the energy consumption of the Hall-Heroult process by the reduction of the anode bottom covering with gas. Electrically isolating carbon-dioxide bubbles, produced at the anode, increase the ohmic resistance of the cell. As the gas production rate is determined by the applied current density, anode covering can be decreased only by a faster evacuation of the gas from the inter-electrode space. Among others, the inclination and curvature of the anode bottom promotes the release of the bubbles and thus decreases the mean value of the covering. Indeed, anode, insert in the molten cryolite bath has a square shape with horizontal bottom. However, inhomogeneous anode consumption, electro-erosion, bath circulation and the inclination of the bath-metal interface modify this shape gradually during electrolysis. Anode bottoms become inclined with rounded comers. This concentrates the gas generation to the center zone of the anode. As the bubble layer cannot be observed directly because of the hostile environment and the opacity of the bath, real scale air-water systems are used to study the impact of the anode geometry on the anode covering and the bubble induced flow. However, the physical properties of such a system are different than that we can found in the real cells. A simulator using the Lagrangian description of the bubble layer has been built and presented in earlier papers. This tool was used to investigate the effect of the anode inclination on gas covering and bath velocity, for both C02-cryolite and air-water system. Results obtained for the second system were compared to experimental data .

Jan 1, 2006

By R. Bruce Graham

"For the purpose of this paper, the Chibougamau area is taken as lying between lats. 49°20’ and 50°10’ N;-longs. 73°45’ and 75°30’ W. It comprises an area of some 4,000 square miles and is centred 300 miles north of Montreal.The first recorded report of metal deposits in Chibougamau was that of James Richardson in 1870-71 (I). In 1903 discoveries of asbestos, copper, iron, and gold made by Peter McKenzie stimulated considerable activity in the district. By 1909 interest had become so marked that considerable pressure was brought to bear on the Quebec Government to build a rail-way into the region. It was finally decided to have an authoritative opinion on its economic possibilities, and the Chibougamau Commission was appointed for this purpose (2). They examined the district in 1910 and concluded that at that time a railway was not warranted. Nevertheless, the district continued to be prospected and from time to· time gold and copper discoveries were made. Thus the Merrill Island deposit was discovered in 1920, the Campbell Chibougamau Cedar Bay deposit in 1922, Obalski in 1928, Opemiska Copper in 1929, and Norbeau in 1930.Difficulty of transportation was a severe detriment to the development of the region. Consequently the Quebec Department of Mines completed a road into Chibougamau in 1949. Further activity was encouraged. The Chibougamau Explorers, Quebec Chibougamau Goldfields, and Kayrand deposits were found in 1950. ** The copper-siderite zones on Copper Cliff ground were found in 1952 and 1953. Opemiska Copper, Campbell Chibougamau Mines, and Chibougamau Explorers were encouraged to prepare for production following favourable exploration results."

Jan 1, 1949

By B. B. Adhikari, S. Alam, Ohto Kawakita, Abe Pangeni

Effective recovery of gold was investigated by using adsorption gels prepared from pure cellulose, cotton and paper by treating with concentrated sulfuric acid. Only gold was adsorbed with extraordinary high loading capacity from varying concentrations of hydrochloric acid separated from other precious metals and base metals. The formation of fine powders of metallic gold was visually observed, which is attributable to the selective reduction of gold (III) ion to metallic gold clue to its high oxidation-reduction potential. Recovery of gold from the leach liquor of hydrochloric acid of circuit boards from spent mobile phones was attempted using pure cellulose gel.

Jan 1, 2011

By L. Jiang

The evolution of twinning in an AM30 Mg alloy was examined by uniaxial tension and compression testing at temperatures from ambient to 250°C and a strain rate of 0.1/s. The samples were cut along the extrusion direction from extruded AM30 Mg alloy tubes. Specimens deformed to various strain levels were examined by optical microscopy and electron backscattered diffraction (EBSD) techniques. The results indicate that the initial extrusion texture plays an important role in the formation of different types of twins and that the twinning behavior also depends on the strain path. Contraction and double twinning are the dominant twinning mechanisms in uniaxial tension, while extension twinning prevails in uniaxial compression. The different twinning behaviors are shown to be responsible for the sharply contrasting strain hardening characteristics of the experimental flow curves.

Jan 1, 2006

By D. Larouche, M. Mardan

Hot tearing is a complex defect in aluminium castings which is produced during solidification when a certain amount of liquid phase remains and weakens tensile resistance of the alloy. In direct chill casting of aluminium alloys, hot tears initiate at the surface of sheet ingots just after the primary cooling zone, where the microstructure is particularly vulnerable. In order to study the hot tearing susceptibility of these alloys, and the effect of grain refiners on their thermo-mechanical behavior , tensile tests were carried out in the semi-solid state ( ~95% solid) and at low strain rates using an apparatus called DCSS, for Direct Chill Surface Simulator. This apparatus, originally developed at Alcan Arvida R&D Centre (ARDC), is an instrumented rig test reproducing the conditions prevailing during the primary cooling stage of the DC casting process. The mechanical behavior of solidifying shells and the hot tear formation under applied tensile loads were measured and the occurrence of hot tearing was observed. Temperature in different locations of the casting, applied load and surface strain were monitored during the tensile tests conducted on aluminum alloys AA5182, AA6111 and AA3104. The microstructure of the tested samples was examined using the optical microscope to evaluate their columnar or equiaxed aspect and their effect on the mechanical response of the alloy. A special emphasis has been given to the evaluation of fractions solid existing in the castings at the start of the tensile tests, taking into account the local temperature, thermal gradient and cooling rates experienced. It was found that excessive grain refiner additions decreased the strength of solidifying shells because of the increased level of porosity induced by easier nucleation of new phases (gas included). It was also observed that cooling rates increased with the level of grain refiner, a phenomenon that was associated to the higher number of contact points obtained with small equiaxed grains. Finally, the concept of a stress based criterion for hot tearing was reinforced by the strengths obtained on not grain refined AA5182 and AA6111 showing similar fraction solid near the surface, but significantly different grain sizes.

Jan 1, 2006

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By T. R. Chari

The safe-level dilution of low-level radioactive wastes in large volumes of selected granular material is proposed as an alternative method of permanent waste disposal to current Canadian practice of concentration and encapsulation. Accepting the fact that a "background level" of radioactivity exists throughout the world, the authors feel that the concept of controlled dilution of radioactive wastes to a level in keeping with "background" is a plausible alternative to current thinking on the subject and is worthy of equal consideration.

Jan 1, 1979

By Allan J. Guse

The primary limiting factor for hoisting capacity from great depths is the self-weight of the typical steel wire ropes used for mine hoisting. Steel wire ropes possess properties making them very suitable for mine hoisting including high strength and durability, but have the negative characteristic of being relatively heavy in comparison with their strength. Also, as hoisting depths increase, the service life of steel wire ropes decreases due to the higher stresses and physical effects on the ropes. The significantly higher strength-to-weight ratio of synthetic ropes compared with steel ropes offers the primary advantage of hoisting a larger payload with a similar size rope and hoisting plant. The beneficial properties of synthetic ropes could be used to improve the overall economics of deep underground mining both for new deep shaft projects and for existing mining operations expanding to deeper orebodies. A research and development program has been initiated to evaluate the suitability of a fully synthetic rope for the mine hoisting application, including rope discard methodology and NDT testing. The three phases/projects are: 1) proof of concept with focus on coilability under load (successfully completed in 2012); 2) high speed and load durability optimization & NDT Development; and 3) in-situ mine trial.

May 1, 2013

By R. Lepsoe

THE basic products of the Company are lead and zinc. Around 950 tons of these metals are produced each day. In the last decade, the production of by-products has increased to such an extent that they are now nearly as large an operation as that of the base-metals. Of the many by-products, the most objectionable, and up to a few years ago the most useless, was the sulphur. The sulphur comes in the ore from the Sullivan mine. It is in the ore chiefly as lead, zinc, and iron sulphide. By selective flotation, these three sulphides are separated into the lead concentrates, the zinc concentrates, and the mill tailings. These mill tailings contain the bulk of the iron and the sulphur. Of the 6,5CO tons of ore treated per day, about 5,000 tons are wasted to the mill tailings dump, and, while now valueless, will in future years undoubtedly be used as a source of iron and sulphur. There are about 1,500 tons of sulphur and 2,200 tons of iron per day in the tailings, and about 400 tons of sulphur left in the total concentrates. In the recovery of lead and zinc in the pure form, the first step is the roasting operation. Here, most of the sulphur is driven off as sulphur dioxide in the gases. It has always been apparent that this sulphur should be. recovered and utilized if possible. At the same time, this would cure the smoke nuisance. Because, in spite of the low concentration of sulphur dioxide and the fact that it was discharged from stacks at an elevation of 400 feet above the plant, some damage to vegetation close to the plant had been experienced.

Jan 1, 1937

By S. A. Vazhnov, A. G. Kalimov, A. A. Potienko

In this paper we describe a mathematical model of the magnetic field and magnetohydrodynamic processes simulation in aluminum reduction cells developed in St. Petersburg State Polytechnic University, Russia. The model includes: (a) calculation of the currents in the busbar system and inside the aluminum cell construction elements including cathode and anode structures, aluminum and electrolyte layers; (b) magnetic field simulation using the integral equation method; ( c) investigation of the magnetohydrodynamic characteristics on the basis of a shallow-water approach. The developed model was used to investigate operational characteristics of the different industrial aluminum cells. Calculated magnetic field distributions and MHD stability parameters were compared with the available experimental information; the comparison demonstrated a reasonably good agreement.

Jan 1, 2006

By W. P. Corking

"The purpose of this paper is to describe the relationship of the goldbearing ore to structure at the Pickle Crow mfoe. Information beyond this scope may be found in the reports and papers of Hurst( l), Bothwell(2), Thomson(3) , and Monette( 4).The property lies on Crow river, in Patricia district, 80 miles northeast of Allanwater, and about 125 miles northeast of Sioux Lookout on the Canadian National railway. From April of 1935, when the mill began operation, to the end of 1944, a total of 564,890 oz. gold and 49,275 oz. silver were recovered from 958,416 tons of ore.Mining on the property is at present carried on in two separate orebodies, the Howell and the No. 2 vein. Stoping has been carried on from every level on the Howell vein to a depth ot 2,450 feet below the surface and from several levels on the No. 2 vein through a mile long cross-cut on the 750-foot level to the Howell vein workings. A steadily increasing volume of ore is being obtained from the No. 2 vein.Each of the two orebodies consists of vein quartz with small amounts of other gangue minerals either in a single vein or a stockwork of veins. Both lie within sheared walls and carry gold in the free state. Fig. 1 shows the position of the veins with respect to the surrounding rocks. It will be noted that the delineation of the beds of iron formation shows that the lava flows and minor, interbedded sediments that make up most of the country rocks are areally folded and contorted.STRUCTURENearly all gold found to date in sufficient quantity and concentration to make ore in the Pickle Crow area is confined to these major quartz veins . Both strike a little north of east and dip north, and in both cases the attitude of the enclosing rocks is somewhat more north of east in strike and more steeply north in dip than that of the veins. As a result of this disposition both veins migrate across their enclosing rocks at a moderate angle in both dip and strike. (In this connection it should be noted that No. 2 vein dips at a considerably flatter angle than its host rock, but has a very pronounced rake to the northeast, effecting the same result as in the Howell vein.)"

Jan 1, 1954

By W. D. Fogwill, P. J. Clarke

"The Dawn Lake uranium deposits are located 340 km north of La Ronge, Saskatchewan, in the Athabasca Basin between the Midwest Lake and Rabbit Lake deposits. Four zones of uranium mineralization, called the ""11, 14, 11A and 11B Zones,"" lie within the Athabasca Sandstone, at the sub-Athabasca unconformity and in the basement.At Dawn Lake, approximately 100 metres of Helikian Athabasca Group clastic sediments overlie Aphebian Wollaston Group pelitic and calcareous metasediments and pegmatites. Uranium with some nickel, cobalt and copper, occurs near the sheared stratigraphic contact between calc-silicate gneiss and graphitic, pyritic pelite. The mineralization lies in an area of low magnetic susceptibility which is thought to represent a rock sequence lying stratigraphically high within the Wollaston Group. There is no obvious vertical displacement of the unconformity by faulting, despite considerable brecciation, shearing and slickensides seen in the basement rocks. This suggests horizontal displacement on steeply dipping wrench faults as the main tectonic control along the 11, 11A and 11B trend.Below the Athabasca unconformity, the Wollaston Group rocks are altered to fine-grained mixtures of clays, chlorite and silica commonly called regolith. Along the mineralized trend post-Athabasca fracturing and (or) compaction have occurred through this clay-rich alteration zone, causing the steeply-dipping primary foliation to become contorted. This ""crenulated"" horizon can reach depths of 35 metres below the unconformity and is thickest along fault zones in the calc-silicate rocks. The ""crenulite"" is a distinctive unit which at Dawn Lake is commonly found above pods of ore located deep below the unconformity.Much of the mineralization in the 11A and 11B Zones occurs above, beside and below the thickest part of the crenulated zone, although the crenulated rock itself contains negligible amounts of carbonate, pyrite and uranium. Intense vuggy alteration and collapse breccias are found in calc-silicate rocks deeper and to the west of the 11A and 11B mineralization. There are at least two ages of uranium deposition in the basement zones, shown by small bright cubes of ""pitchblende /"" overgrown and replaced by duller botryoidal ""pitchblende II. ""Sooty pitchblende and yellow secondary minerals are the result of still younger reworking.The geological setting of mineralization, along the contact between carbonate-rich calc-silicate rock and pyritic pelite, suggests that the uranium was concentrated at a pH/Eh boundary located between deeply weathered, carbonate-rich and sulphide-rich basement rocks."

Jan 1, 1986

By Euler De Souza, Kyle Penner

"Booster fans play an important role in assisting main fans by boosting the air pressure of the ventilation air passing through it. The correct placement of underground booster fans in a mine is a critical decision since it not only influences the mine’s operational capacity in terms of costs and efficiency, but also affects safety and environmental conditions. There are many booster fan installations around mines that are inappropriate, in some cases resulting in system failure (fan stall) or in a major negative impact on mine production. Inadequate booster fan placement has resulted, in some cases, in extensive air leakage which has compromised the economics of the operation and, in other cases, in recirculation of contaminants which has seriously compromised safety. This paper provides guidelines for proper design and siting of booster fans underground, to not only achieve an economic ventilation system but to create safe work conditions and efficient atmospheric conditions. Procedures for the planning, installation, operation and maintenance of booster fans are also presented. A case study illustrating the design and siting of a major booster fan installation in a potash mine, supported by computational fluid dynamics analysis, is presented.INTRODUCTIONIn large underground operations with complex ventilation networks offering high resistances, the never ending increased required quantities of air can almost only be supplied through use of high pressure main fan systems. These fans may, in effect, induce significant leakage losses in the system, having a negative impact on safety performance. In such cases, booster fans can be designed to decrease the main fan pressures and reduce the leakage flows, improve system efficiency and reduce costs. In well designed systems, booster fans can thus be used to redistribute the airflow and assist the main surface fans.When the pressure supplied by the main fans is insufficient to meet the ventilation circuit pressure requirements, booster fans are placed in strategic locations where pressure boosting is essential. Booster fans are typically sited in sections of the circuit offering high ventilation resistance and requiring this form of ventilating air motivation. Booster fans are thus required when the mine expands, and so the resistance of the ventilation network, and the primary fans no longer can supply the required pressure and flow."

Jan 1, 2019

By Richard E. J. Putman

THE MINERALS INDUSTRY has always been a heavy user of energy in most of its unit operations: power in the mining, comminution, flotation and electro-winning processes; fuel in its smelting and other metallurgical processes; and, of course, fuel in the on-site generation of power and steam. Many of the techniques for using computers to perform energy management and conservation tasks have been known for some time, but they have not been widely implemented because the return on investment has hitherto been insufficient. Recent trends, however, have not only caused the dollar return to rise due to higher purchased energy costs, but the cost of the investment to fall. One trend has been the generally lower cost of computer control systems themselves, due to vendors having adopted the newer, lower-cost and more reliable electronic component technologies now becoming universally available. The second trend is the development of low-cost, but high-speed, remote multiplexing devices, which have reduced considerably the expense of bringing data from points scattered over a wide area, which is typically the case when applying energy management systems to a minerals processing plant. By taking advantage of these and related developments, computer control systems can now have a rewarding impact on plant energy management and conservation practices, and recent advances in application technology have opened up new and additional opportunities for energy cost reduction and control.

Jan 1, 1978

By Gerardo Fuentes

Arsenic extraction from Chilean copper concentrates up to nearly 99% was achieved, using hydrothermal reactions. Arsenic appears in nature in more than 200 mineral species, being arsenopyrite (FeAsS), enargite (Cu3AsS4), and tennantite (Cu12As4S13) the most common species. In addition, arsenic is present in a large amount of copper concentrates, produced in northern Chile. Medical statistics show that in northern Chile, the amount of cancer to the lung, skin and bladder are the highest in the country. The latter situation, demonstrates the importance of studying metallurgical processes that do not generate atmospheric pollution. The hydrometallurgical processes such as hydrothermal treatment in autoclave reactors, do not produce gaseous emissions. On the other hand, the arsenic remains in solution from where it can be transformed in scorodite by widely known methods. Previous works about hydrothermal treatment of enargite have shown the feasibility of transforming the enargite of the copper concentrates into chalcocite or mineral species of the chalcocite family such as djurleite, digenite and for this reason enrich the concentrate in copper and pass the arsenic to solution. For this research, two Chilean copper concentrates were used, concentrate 1 with 5.5% arsenic and concentrate 3 with 1.8% arsenic. These concentrates were subjected to a complete chemical and mineralogical characterization. Later these concentrates were carry out to batch tests of hydrothermal treatment. Also, these concentrates were subjected to grinding to have different particle sizes. For the hydrothermal tests, a liter capacity Autoclave Engineer reactor was used. Characteristic of this reactor was the maximum temperature 350°C, 5000 PSI pressure, and 900 rpm agitation speed. Kinetic tests were carried out with the two concentrates maintaining the same solid: liquid relationship, the same agitation velocity and the variables studied were treatment temperature, time of reaction, concentration of copper in the solution and grain size of the concentrates. The conclusions of the study indicated arsenic extraction of the order of 93.98% from the concentrate 1 and arsenic extraction of the order of 98.74% from concentrate 3. After the hydrothermal treatment, the solids and solutions were characterized chemically, by electron microscopy and X ray diffraction. Also the solids were characterized by grainsize through a particle size analyzer (MICROTRAC). Results of batch treatment shows that arsenic can be release almost completely from real copper concentrates using this hydrothermal process and the next stage will be a scale up process in order obtain results for pilot plant design. INTRODUCTION Arsenic is an impurity that appears associated with copper minerals forming enargite, tennantite, tetrahedrite, and that due to the pyrometallurgical treatment either in conversion or roasting furnaces, it goes into the atmosphere together with the sulfur dioxide. A great quantity of literature can be found to eliminate arsenic or try to separate arsenic from copper. The methods used are mainly leaching processes with or without pressure (Padilla, Jerez & Ruiz, 2015) with different reagents like chloride media (Herreros, Fuentes, Quiroz & Viñals, 2003) or chloride media with sulphuric acid (Riveros & Dutrizac, 2008) or sodium hypochlorite (Mihajlovic, Strbac, Zivkovic, Kovacevic & Stehernik, 2007). It is known too that Chile is the first copper producer in the world and a great quantity of its minerals are in the north of the country, in Antofagasta.

Jan 1, 2019