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By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004

By Hökmark. H., M. Lönnqvist

"The Swedish Nuclear Fuel and Waste Management Company are planning to construct a permanent storage facility for high-level nuclear waste at about 500 m depth in fractured crystalline rock. One potential concern for the long-term performance of the repository relates to large fracture shear displacements, since these may damage intersected waste containers. Although details in fracture surface geometries are known to influence slip magnitudes and distributions, fractures are commonly approximated as planar features with lab-scale properties due to lack of relevant field-scale data and to limitations in available modelling tools. The purpose of the work described in this paper is to explore the possibilities to use the distinct element code 3DEC to generate and analyze models with isolated, non-planar fractures and, based on the results of such models, get perspectives on the influence of basic disturbances such as ridges, steps and waves. Given the model set-up, fracture segments with orientations deviating from the critical one will contribute to stabilize the fracture. As a result, all analyzed non-planar fractures slip less than the critically oriented planar fracture. We demonstrate that the angle of deviation is the most influential parameter determining the slip magnitude for comparable surface geometries. Similarly inclined steps and ridges have almost equal slip reductions despite differences in surface area restricting the movement. Although it may be possible to translate the influence of such irregularities to an effective coefficient of friction that could be used as input to models with idealized planar fractures, additional analyses with randomly shaped and distributed asperities, different fracture sizes and with alternative stress loads, need to be carried out to devise a defensible strategy for this type of parameter variation. INTRODUCTIONThe Swedish Nuclear Fuel and Waste Management Company’s (SKB) concept for deep geological storage of high-level nuclear waste is the KBS-3 method according to which the waste will be encapsulated in copper canisters and deposited, surrounded by compacted bentonite clay, in vertical deposition holes at about 500 m depth in fractured crystalline rock (SKB 2011). A site has been selected in the Forsmark area, which is located some 120 km north of the Swedish capital Stockholm. One potential concern for the long-term performance of the repository that has been identified by SKB (SKB 2011) is related to large shear displacements along repository host rock fractures induced by a nearby earthquake, since these may cause mechanical damage to intersected waste containers. Due to lack of relevant data at the appropriate field scale and to limitations in available modelling tools, fractures are commonly approximated as planar features with lab-scale properties. The standard numerical tool, 3DEC (Itasca 2013), used in SKB’s rock mechanics analyses, for example, generates planar fractures by default. Results from dynamic 3DEC earthquake-models (Fälth et al. 2010) currently provide input to layout decisions, i.e., the diameter of the smallest planar fractures that must be avoided when deciding on waste container positions at different distances from potential earthquake faults. It is, however, well known that fracture surfaces are rough or undulating on a wide range of scales (e.g., Candela et al. 2012) and that such deviations from planarity influence the mechanical behaviour of the fractures (e.g., Dieterich and Smith 2009, Marshall and Morris 2012, Ritz and Pollard 2012). It will probably never be a realistic option to attempt to represent the geometrical complexity of a population of fractures of different size, shape and surface structure in any large-scale rock mechanical analysis relevant for the performance assessments of the nuclear waste repository. It may however be possible to find approximate ways to represent different styles and degrees of non-planarity by assigning mod"

Jan 1, 2015

By D. D. Campbell

"The Port Radium mine of Eldorado Mining and Refining Limited lies on the western tip of a large peninsula midway up the east shore of McTavish Arm, Great Bear Lake, about 30 miles south of the Arctic Circle. The mine is serviced by air, 950 miles from Edmonton, and by water, 1,380 miles from Waterways, Alberta.The veins were found, and the copper and cobalt minerals in them reported, by J. MacJntosh Bell of the Geological Survey of Canada in 1899. The veins were investigated by Gilbert Labine and E. C. St. Paul in 1930, and as a result of their work the Eldorado mine was brought into production in 1934. It produced silver and radium ores until 1940, at which time, as the silver orebodies had been mined out and the market for radium was negligible, it closed down. Early in World War II the need for uranium for the Manhattan Project was emphasized, and the mine was reopened in 1942. As a security measure Eldorado Mining and Refining was created a Crown company in 1944. The Port Radium mine has continued to be one of Canada's principal producers of pitchblende concentrates, and to date has about 25 miles of underground workings developed on fourteen levels.Regional GeologyThe general geology of the McTavish Arm area was mapped by D. F. Kidd in 1932 on a scale of one inch to four miles. A great deal of more detailed work has since been done by geologists of the Geological Survey and of Eldorado. The entire area at the end of McTavish Arm lies within the Precambrian Shield immediately east of its western margin. Most of the area is underlain by granitic masses which have intruded a sequence of late Precambrian sediments, volcanics, and hypabyssal intrusives. The pre-granite rocks now occur in extensive, irregular patches and pendants within the granite. Pitchblende deposits have been found in the district in all rock types, but the most favourable host rocks are the cherty sediments of the lower Echo Bay group."

Jan 1, 1949

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By E. G. Joe

"Recent trends in Canadian mineral processing were reported in seven areas of interest covered by seventeen technical papers at the 1976 Annual Meeting of the Canadian Mineral Processors, held at Energy, Mines and Resources' Camsell Hall, Ottawa. New milling equipment included the Enviro-Clear thickener, large-volume Outokumpu flotation machines and abrasion-resistant polyurethane screens. Grinding experiences from a variety of milling operations were reported. Opportunities for increased sizing and grinding efficiency were presented. Flotation control by digital computer and by chemical additions were described in two mill operations. Slurry pumping and sampling techniques were described for various operations. Environmental control in milling was reported concerning dust suppression, arsenic removal and tailings disposal. Several aspects of gold milling were described by the most recently commissioned gold mine and by CANMET. Potash operations were reported showing the similarity of processing and process control to that of metallic minerals."

Jan 1, 1976

By C. Lapointe

"IntroductionTen years ago, when nuclear fission became practical, the element uranium, until then a not very desirable by-.product of the radium industry, became overnight the strategic material par excellence. One of the several important problems that had to be solved at that time was the rapid and precise determination of uranium in ores and concentrates.GeneralThe chemical analysis of uranium ores is a long and difficult business and is complicated by the presence in most ores of a large number of interfering elements. True, much progress has been made, during the past few years, toward simplification of the analytical methods, but the chemical determination still remains the job of a skilled operator. For this reason, the chemical method has been replaced, whenever possible, by a physical determination based on the measurement of the radiations emitted by the elements of the uranium family. There are several types of instruments suitable for these measurements, but of all the radiation detectors known to the physicist, such as ionization chambers, crystal detectors, scintillation, proportional counters, and the like, the Geiger-Mueller counters have proved to be the most satisfactory for routine determinations, because of their simplicity.The Geiger-Mueller counter is a very versatile instrument; it can be constructed to detect any type of radiation, corpuscular -0r electromagnetic. Here, however, we are interested in these counters because of their ability to detect the beta and the gamma radiations, both emitted by some members of the uranium family. The beta radiation is corpuscular, and is composed of fast electrons, while the gamma radiation is electromagnetic."

Jan 1, 1950

By Simon Weixiao Sun

Conventionally, carbon steel has been the primary material for salt mine headframe construction, protected by specialty paint layers to prevent corrosion. These layers require meticulous QA/QC during fabrication and erection, and the top UV protection layer typically loses effectiveness after an average of 10 years, necessitating ongoing maintenance. As headframes age, significant structural repairs are often required. Alternatively, stainless steel can eliminate corrosion concerns, though its high initial cost has limited its use in headframe design. However, when factoring in long-term maintenance costs, a 'maintenance-free' stainless steel headframe can be an attractive option for stakeholders. This paper compares the structural performance and economic considerations of painted carbon steel and stainless steel headframes, including initial capital and long-term maintenance costs. Additionally, it explores a hybrid approach, strategically using carbon steel in low-contamination areas to reduce initial costs and significantly minimize future maintenance efforts.

May 4, 2025

By Garston H. Blackwell

For ageing open pit mining operations where the economic viability of another pushback is questionable, mine life can be extended by increasing the wall slope. If the steepening is started where ore intersects the pit wall, the capital outlay for waste stripping is minimal. Such a venture must be conducted safely, and a basic requirement would include loading equipment capable of working remotely. In the application described, alternatives in the choice of loader included equipment available on site, or the purchase and assembly of used equipment. Only electric cable shovels were in use at the operation, and it was thought that these would be more capable of digging high muck piles at the productivity demanded by an increasingly efficient mill, and in a challenging environment less suited to a rubber tired loader or hydraulic front shovel. A decision was made to convert an older electric cable shovel to remote controlled operation and to include the application of semi-robotic control. The conversion was completed successfully and is described, along with methods developed for remote operation of a shovel, and the application of various sensors for semi-robotic operation. A plan of operations to mine out several completed double benches and make two quadruple benches with wide catchment berms is depicted. On completion of this task, the working benches developed would be wide enough to operate at near full production. Prior to moving the remote controlled shovel back into the pit, a large wall instability became active, eventually closing the operation. The instability could have been safely mined using the remote controlled shovel.

Aug 1, 2013

By J. C. Hampton, L. A. Matzar, C. R. Gamwell

In geomechanics, conducting uniaxial or triaxial compression tests require samples to be prepared to a certain length-to-diameter ratio. This ratio is typically defined as 2:1 (length to diameter) and is accepted as a common standard for all materials on which mechanical properties testing is performed. Variations in sample length can cause changes in measured strength properties across multiple material types, such as cement, rock, or soil. Within the oil and gas industry, it is not uncommon to receive samples for technical services work that are slightly under or exactly the length requirement before surface grinding and sample preparation. Many of these samples are discarded from uniaxial and triaxial compression tests and used in another manner; therefore, it is necessary to study the length-to-diameter ratio in efforts to understand the limits and validity of testing samples that are slightly out of the 2:1 ratio. This paper discusses uniaxial compression tests performed using Berea sandstone and a standard cement mixture of 2.54-cm diameter to study changes in rock strength and properties. Compressive strength for each lengthto- diameter ratio over a range of 0.5:1 to 2.2:1 was measured. The investigation was extended to study near-end effects, where the sample length is near, but not exactly twice the diameter. It was discovered that the cement samples conformed reasonably well to the suggested ASTM correction factors. The sandstone did not conform to the correction factors and further analysis is required to develop a correction factor unique to the material. Near end effects, in both the cement and Berea, were found to increase compressive strengths, especially when the L/D of the samples was increased slightly over a 2:1 L/D.

Jan 1, 2015

By H. O. Olsen

"GeneralTHE IRON ORE at Marmora is a replacement deposit of Precambrian limestone and is overlain with Palaeozoic limestone. It is a low-grade magnetite deposit and the ore will require concentration be-fore it can be used economically for the production of iron and steel.Present plans estimate an annual production of 500,000 tons of concentrate in the form of pellets. This will require mining approximately two million tons of ore and\ waste annually. Shipment of pellets from Marmora to a ship-loading dock at Picton will be made by rail on a year-'round basis. Shipments from Picton to the Lackawanna plant of the Bethlehem Steel Company at Buffalo, N.Y., will be carried on during the Lake shipping season.LocationThe mine, located a mile southeast of Marmora village in Hastings county, Ontario, is 31 miles north of Belleville and 3•7 miles east of Peterborough. Marmora is 130 miles from Toronto and 150 miles from Ottawa. Highway No. 7 passes half a mile north of the mine and Highway No. 14 half a mile west of the mine. The Canadian National railways' branch line between Trenton and Bancroft passes through the property just east of the open pit.HistoryThe Ontario Department of Mines conducted an airborne magnetic survey of the district during 1948 and 1949. Maps of this survey were released to the public early in 1950. Bethlehem representatives carried out ground surveys in the Marmora area shortly thereafter and in June, 1950, commenced diamond drilling."

Jan 1, 1955

By Allan R. Punkkinen

Safe extraction of the valued ore resource in the deep levels of VALE Creighton Mine has progressed in a pillar-less fashion using vertical retreat, slot-slash and uppers retreat methods since the cessation of ?cut and fill? mining in the late 1980?s. Sequencing of the panel extraction and filling has been the key to successful exploitation of high stress orebodies at depth. In late 2010, discussions between the Operating Department and Creighton Ground Control revealed an opportunity to evaluate a trial primarysecondary sequence in the west end of the 400 Orebody at the 2340m horizon. To manage the trial primarysecondary project, a high level risk analysis and management of change was carried out to mitigate potential danger. As part of the requirements, an instrumentation project was conducted in the hanging wall and footwall bottomsills of the secondary panel and within the secondary panel itself. The extraction sequence was modeled with Map3D® software, confirming high stress levels with the advance of the primary panel. Enhanced ground support was installed based on modelling results. A key objective of the instrumentation project was to verify support system response to mining and to obtain knowledge in regards to the behavior of the stope. This paper describes the first time that this type of new innovative instrumented rockbolt technology had been used in a hard rock mining environment. Understanding of the physical deformation mechanisms of ground support in response to high stress conditions is the basis for an effective ground control strategy. The data played an important role in subsequent enhanced ground support system design at the mine and importantly, established the fact that the secondary pillar had not totally failed. Subsequent cavity monitor results helped establish that fact.

Jun 1, 2012

By Paul A. Glapa

Quality is much more than providing a product that functions properly. True quality is a way of thinking, a way of doing business, and, ultimately, a way of satisfying a customer?s long-term needs. A true commitment to quality requires a top-down management commitment, with a willingness to change what needs to be changed and to expand upon ?best practices? that are already done well. Is there a cost to creating and maintaining a quality program? Of course there is, but the cost of not having a focused program is much greater. We have come to regard quality as an investment that pays dividends to both the supplier and customer. The lack of quality costs everyone and the customer pays the ultimate penalty. With modern, highly engineered surface mining equipment the end user calculates cost in terms of lost production (revenue), not simply the cost of the part. Bucyrus International, Inc. is a company that has listened to its customers and has dedicated itself to implementing an advanced quality program. The ultimate goal being the creation of a high quality product with extended reliability for the customer. The result is reflected in Bucyrus? current product offerings and highlighted by the new 495HF electric rope shovels at Albian Sands mine.

May 1, 2003

By Y. M. Shneerson, E. E. Zhmarin, E. M. Vigdorchik

One of the Gipronickel Institute activities is research and development of customized leaching technologies. The work is performed in several steps. Leaching kinetics are studied on a lab-scale according to a special procedure. Experimental data are processed using mathematical models of batch and continuous processes. Reliability of kinetic data and preliminary calculations is verified experimentally in laboratory reactors of various capacities. If necessary, certain parameters of the mathematical model are adjusted after pilot plant tests in continuous mode ( 4-reactor train, each with 25 L capacity). The specified kinetic characteristics along with the mathematical model are used for further development of industrial leaching technology.

Jan 1, 2005

By R. Kamguem

The surface of a mechanical part plays an important role in determining performance in service. The presence of scratches left by the cutting or tearing of the material on the surface of the workpiece supports the concentration of stress and strain. This article presents the experimental study for high speed milling of the aluminum alloy 7075-T6, using cutting tools different by the nose radius and coatings (TiCN, TiAIN, TiCN + A12O3 + TiN). A multi levels factorial design of experiment (DOE) and statistical analysis was used. The roughness parameters investigated are Ra, Ra, Rv, Rc, Rsm, and Rk. The results show that the feed rate, the types of coatings and the geometry of the cutting tools have the most significant impact on the surface roughness profil. Surface finish charts according to feeds and cutting speeds were established for each tool tested.

Jan 1, 2011

The original JKMRC AG/SAG mill model was developed over 30 years ago and has been upgraded a number of times since then, with the current published version being the Variable Rates model that is now over 15 years old. Since this model was developed further enhancements have been derived, some of which are applied in-house and some which have yet to be incorporated. The published and the commercially available model in JKSimMet is currently undergoing a comprehensive overhaul with a vastly extended data base for model evolution and validation. Improvements developed within the AMIRA P9 project, in-house development and a number of collaborative projects, are being incorporated into the upgraded model structure. Enhanced capabilities will include: power-based breakage rates scaling; a far wider mill filling range (from 10% to 40%) that exhibits peak in throughput as mill filling increases; higher ball loads; improved pebble discharge function; improved slurry discharge function incorporating important mill design and operational influences; and the new size dependent breakage function. The model will also be able to accommodate some influence of liner design and multi-component ores (blends of hard and soft components). This upgrade is still a work in progress but substantial changes have been made to date. This paper presents some of the new improvements and their influence on the predictive capability of the model.

Jan 1, 2012

By K. E. Prince, S. Burling, R. J. Ring, M. K. Maley, W. R. Taylor

Vanadium occurs as a component of carnotite, which commonly occurs in calcrete type ores, and in association with uranium in some sandstone-hosted deposits. Increasing demand for vanadium, which is used in high-strength steel and Vanadium Redox Flow Batteries (VRFBs), is offering some uranium producers a potential option for by-product vanadium recovery to improve project economics at a time when uranium prices are low. This paper presents the results of recent optimisation studies on the Bigrlyi deposit for the recovery of both uranium and vanadium. The impact of carbonate leaching conditions on uranium and vanadium extraction from a range of carnotite-in-calcrete ores is also examined, with vanadium extraction limited by the proportion of non-carnotite vanadium present in the ores. The findings are particularly relevant to developing projects as results show that elevated vanadium content in ore does not necessarily equate to a high vanadium extraction in leach.

Jan 1, 2020

By J. A. Brusset

THE Greenhill mine of West Canadian Collieries, Limited, is situated at Blairmore, Alberta, and produces 2,500 tons per day of bituminous coal. On Monday, October 25th, 1943, smoke was discovered by a party of firebosses on their regular weekly inspection of air-ways. Probably the fire had been smouldering for several days but, as it had started on the outcrop at the top of an old raise filled with dirt, only a small quantity of smoke could filter through, and the plume of mist that crowns the fan at that season had prevented the fan-man from noticing it. This raise is only about 200 feet from the fan, and is 70 feet long between the fan-drift and the outcrop. It was impossible to prove the origin of the fire, as it had probably started several days before it was discovered, but it is possible that a careless smoker may have thrown a match into the opening at the outcrop, and that the old, dry timber had caught fire. The airways are in No. 2 seam, a bituminous seam 18 to 25 feet thick surmounted by shales and sandstones. Only 45 feet vertically above it is No. 1 seam, 12 feet thick, overlain by a strong conglomerate. In that vicinity, No. 1 seam had been worked out about ten years ago and the strata between the two seams are undoubtedly fissured. The pitch of both seams is 43 degrees.

Jan 1, 1945

By W. M. Williams

"Although manganese is a metal virtually unknown to the layman, it is hardly necessary to point out to the engineer the importance of manganese in modern metallurgy, an importance intimately linked with iron (and steel), the basic materials of engineering construction for hundreds of years and certain to remain so for long into the future. World steel production will approach and perhaps reach 1 billion tons/year in the 1980s; with a manganese content between 0.5% and 1 % in ordinary steels, and more in specialty steels, manganese use worldwide will soon approach 15 million tons annually. Manganese was discovered and isolated in Sweden in 1774 by Karl Wilhelm Scheele (who also discovered molybdenum), but the element was only of scientific interest for several decades. By the early part of the nineteenth century, however, manganese oxide had become commercially available and was in use for colouring glass and for the production of chlorine. Commercial application in metallurgy appears to have been limited to the manufacture of crucible (or ""cast"") steel, a highquality product made by carburizing wrought iron, and melting it in small batches to make ingots which could be rolled and used for special applications, e.g. for the manufacture of fine tools or for ""steeling"" the cutting edges of implements such as wrought iron axes and chisels.* However, it was not until Bessemer&apos;s epoch-making invention of cheap steel in 1856, and the dramatic expansion of the steel industry thereafter, that manganese assumed the importance that it holds in modern steelmaking."

Jan 1, 1999

By Robert P. Harrison, Marie-Christine Patoinel, Kristian E. Waters

This paper describes a collaboration between McGill University and Hatch Ltd. to expose undergraduate students to real-world industrial projects. As part of the final-year design course, the students receive a detailed lecture on Scale-Up of New Technologies&apos;, including seven case studies drawn from over fifty years of full-scale industrial projects. The students are taught the basic concepts of scale-up, including the limits of pure theory and the need for empiricism. Insights from real scale-up failures and successes are fictionalized as Projects A, B, C, etc. The students are then asked to identify the guiding principles that can be distilled from these case studies.

Jan 1, 2011

By Adam Jordens

Along with gravity separation and froth flotation, magnetic separation is one of the most common techniques for separating minerals. Minerals are separated by a magnetic force that is dependent on a combination of the applied magnetic field, the magnetic field gradient and the magnetic properties of the minerals themselves. Minerals may be classified as diamagnetic, paramagnetic or ferromagnetic based on the way they interact in a magnetic field. The magnetic susceptibility of a material may be determined by using a vibrating sample magnetometer to determine the magnetic moment of the material in an applied magnetic field and then converting this measured moment into the material?s magnetic susceptibility. In the case of rare earth minerals, magnetic separation is commonly used to remove ferromagnetic iron-bearing gangue minerals and to concentrate paramagnetic valuable minerals such as monazite and xenotime. These magnetic separation steps are frequently preceded by a gravity separation step as many iron oxides and rare earth minerals have specific gravities that are much larger than those of typical gangue minerals. By varying the magnetic field intensity it may be possible to use magnetic separation to selectively separate the paramagnetic and ferromagnetic minerals that report to the concentrate after gravity separation. Test work on a Canadian rare earth ore has shown that a gravity concentration step using a Knelson concentrator was able to selectively concentrate heavy magnetic minerals as evidenced by increased recoveries, relative to the Knelson tailings and fresh feed, after processing through a wet variable intensity magnetic separator. Mass pull to the Knelson concentrate was 4.5 % and the magnetic recovery of this concentrate, at 0.94 T, was approximately 40 % higher than the magnetic recovery from the Knelson tailings (70 % versus 30 %). The products of the wet high intensity magnetic separation were also analysed using a vibrating sample magnetometer to determine the magnetic susceptibilities of the various concentrate and tailings products.

Aug 1, 2013