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By Jack Parker

"The original design of mine openings and pillars at White Pine was based upon traditional assumptions; i.e., that the principal load is due to the weight of overburden, and that horizontal stresses are equal to one-. third of the vertical.Beginning January, 1964, borehole deformation measurements confirmed suspicions that the principal stress is horizontal and several times greater than the vertical.Vertical stress appears to be directly related to depth, but lateral stresses vary considerably in direction and magnitude. The direction of major principal stress lies parallel to the bedding and is apparently parallel to tension joints. Lateral stresses appear to originate from an igneous intrusive.Mining induces stresses which add to the primitive stresses, in some areas precipitating failure. In this paper, rock failures are illustrated, methods of measurement and typical results are given, and measures to counter or utilize the lateral stresses are described."

Jan 1, 1966

By M. Somppi, Z. Yamak

"Gold producers invest significant effort in mining, processing, and creating an intermediate gold doré product. Nonetheless, equal effort should be extended to the final handling and processing of the doré bar, and managing the high-purity gold produced at the fine-gold toll refiner. This detailed attention to bullion handling and refining provides rigor and confidence that the mine site is achieving, through fair and controlled methodology, the most appropriate value for the final product. With the above in mind, the following study explores the importance of preparing a set of site best-practices for bullion handling and specifically, detailing the peculiarities of sampling methodologies and the impact on assays.INTRODUCTION Gold and silver handling practices are common place at mine sites and refineries. The practices include but are not limited to smelting, ingot casting, weighing practices, and secure transportation. Proper handling and processing of the bullion material ensures that the mine site is achieving the true value of the final product. Various handling aspects can critically impact the perceived value of the bullion. A few of these particulars include weight tracking, scale recertification and calibration, refining and melting practices, melt temperature measurement, sampling, pouring, bar cleaning, furnace technology and crucible selection, and assaying. Nevertheless, this report discusses and focuses on the importance of proper sampling and molten-metal temperature measurement and their potential impact on the final doré bar value. Refining or re-melting operations achieve a proper measure of the precious metal content of its bullion when the sample accurately represents the whole bar. At first this task appears seemly straightforward, however, taking a representative sample can be challenging and is also one of the most important tasks for valuing gold during the settlement stage at the precious metal refinery. Various bullion sampling methodologies exist; including: dip sampling, granulation, drilling, cutting, and vacuum pin sampling. The Royal Canadian Mint (2009) indicated in their technical review of refinery operations that pin sampling is one of the best methods for cases where representative sampling and accuracy are required, e.g. to determine the payable metal content. Pin sampling consists of inserting a sealed glass vacuum tube (Figure 1) into the molten metal; when the molten metal contacts a purposely-designed weak portion of the glass, the seal breaks and the metal is suctioned into the hollow centre (Figure 2)."

Jan 1, 2018

By J. Olaf Sund

"The New Brunswick gypsum and an-hydrite deposits make up part of the Windsor group in the Upper Mississippian. The present deposits were formed by surface hydration of the underlying anhydrite beds. The sub-hydrate, hydrate, and di-hydrate stages of gypsum are formed from the anhydrite by this hydration. The anhydrite was precipitated from sea water in embayments that were separated from the sea by a reef or bay-mouth bar. The anhydrite is the original form of the calcium sulphate precipitate.One gypsum deposit near Plaster Rock in northern New Brunswick was precipitated from sea water directly as gypsum, which is its present form."

Jan 1, 1960

By T. G. Carter

"Damaging seismicity associated with deep faulting in both mining and civil excavations not infrequently occurs without warning, and often before proper mitigation measures have been put into place. Severe squeezing is also a common problem for excavating through deep major faults. While both problematic conditions are difficult to predict and characterize, there is often a need at pre-feasibility and feasibility level to more reliably estimate the possible level of risk posed by such geologic structures. This paper introduces some structural geologic techniques that have potential application for both mining and civil applications for aiding forewarning of the extent of these types of problem.INTRODUCTIONEncountering adverse faulting at depth in deep excavations, whether for mining or civil purposes can create serious economic and safety impacts. For deep mines or for deep tunnel projects, measures are available for aiding prediction of the extent of possible influence that large scale faults could create, but these techniques are rarely if ever applied as part of routine site investigation programs, or even as part of risk assessment evaluations. Several well established structural geologic methods of palao-history reconstruction have potential application for aiding forewarning of the extent of these types of potential problem by allowing estimates to be made of:• controlling stress orientations that might engender reactivation movement;• principal stress magnitudes that could lead to failure initiation, and• probable mechanisms of fault deformation - brittle (bursting) or plastic (squeezing).This paper explores several structural geological and rockmass characterization techniques that have application for unravelling fault structure of importance to deep engineering projects. Their application for mining or tunnelling purposes is advocated in conjunction with conventional rockmass characterization assessment approaches using GSI, RMR and/or Q to aid early recognition and definition of potential adverse ground condition behaviour associated with intersection of significant faulting at depth."

Jan 1, 2015

By N. Shi, T. G. Joseph

ABSTRACT Before any large plant is moved onto an oil sands dominated surface, particularly those surfaces encountered in-pit, it is imperative that the ground be evaluated for bearing capacity. A 2230 tonne mobile in-pit hopper/crusher facility designed for operation in the Canadian oil sands was modeled. This evaluation focused on track and outrigger pad versus ground interactions as the key performance indicators of appropriate ground performance below the unit in both operating and repositioning propel modes. A study of cyclic oil sand behaviour was also inferred from laboratory cyclic plate load data as an extension of the simulation model indications.

Jan 1, 2013

By G. W. Neumann

"In order to avoid pollution of water in Flemming Brook and Little River, which drain the area in which the Brunswick No. 12 Mine and Concentrator are located, the company has gone to considerable expense in preparing tailings storage and effluent setting ponds. The attached drawing gives a plan of the six settling ponds together with elevations of the dikes and the effluent weirs.All original dikes for the six ponds were constructed from humus-free clay and rock material, which was obtained, preferentially, by excavating from within the dike area. Run-off water, precipitated on the outside slopes of the dams will drain off without contacting the tailing material. A ditch was made north of the dam site to deflect surface run-off to the east into a branch of Flemming Brook.A secondary dike, made from tailings, has recently been erected on No. 1 and No. 2 tailings pond inside and above the earth-filled dike which serves as a roadway. Run-off from the tailings dikes will be retained inside the ponds by ditching between the roadway and tailings dike into ponds 4 and 6."

Jan 1, 1969

"Acid resistant brick lined autoclaves and related vessels are utilized in pressure oxidation for the recovery of gold, copper, and other metals. The combination of the corrosion resistant membrane, acid resistant brick, mortar and steel shell is a composite system that requires a sophisticated stress analysis. In order to obtain meaningful results both the model and physical properties of the materials must be carefully selected. Evaluation of the calculated results requires an understanding of both the failure mechanisms of ceramics and experience with the performance of existing lining systems.INTRODUCTIONAcid brick lining systems are used in pressure oxidation autoclaves and related vessels to provide thermal and mechanical protection for corrosion resistant membranes that are applied directly to the interior of the vessel shell. The acid brick and mortar must be resistant to the process conditions and must provide a mechanically reliable structure.The construction of lined vessels incorporates a wide range of materials that can include the carbon steel vessel, austenitic weld overlay, lead lining, organic membrane, ceramic brick, mortars and other alloy components. The physical properties of the materials can vary by orders of magnitude and when combined in the construction of the lined vessel create a complex composite structure. The materials may be bonded together or act independently of each other. Stresses are induced into the lined vessel include pressure, thermal expansion, chemical expansion and mechanical loads.The complexity of these systems makes it is very difficult to account for all of the variables in the structural analysis of lined vessels. Historically calculations were simplified and designers primarily relied on experience with previous applications.The greatly improved tools for Finite Element Analysis (FEA) available today allow for detailed calculation of the stresses imposed on the vessel shell and lining. Koning & Lauzon (2004) presented a paper on design fundamentals including a discussion on the application of FEA methods at Pressure Hydrometallurgy 2004 in Banff. When a designer carefully constructs a model and selects the correct materials properties for the calculations, meaningful and useful results can be achieved."

Jan 1, 2012

By Arthur M. Whiteside

Discussion of the laws bearing upon the economics of mining in this province at once resolves itself under three headings: (a) The rights and obligations of holders of mineral bearing lands; (b) Taxation of mines; (c) Regulation of methods adopted in financing mining operations. Titles: The law relating to titles is contained in the Mineral Act, Placer Mining Act and Coal Mines Prospecting Act. Origin: Mining laws in force in this province and elsewhere on the continent had their origin in the rule-of-thumb regulations adopted by prospectors themselves, when, far from the centres of civilization and the seats of the courts of justice, they found it necessary, for mutual protection, to fix the conditions of possession by right of location, and to prescribe the duties to be performed in order to enable the individual to maintain his ground against all comers. These regulations have been codified and added to by legislatures, until we find adequate protection and safeguard to property in the laws of this province.

Jan 1, 1924

By F. W. Gray

Ideal utilization of the heat energy in coal should theoretically be secured by supplying each atom of combustible material present with the exact quantity of oxygen necessary for complete combination. An intimate and equal admixture of the fuel particles with air is therefore to be sought. Coal, or the combustible substances of which coal is composed, may be used in solid or liquid or gaseous form. The use of coal in small particles intimately mixed with air is, in effect, a specification of coal in pulverized or dust form. There has been much important development of this manner of using coal, which may be instanced as the outstanding advance in the use of coal as a solid. The completeness and efficiency of combustion in a properly designed dust-fired furnace permits the use of locally available coals of inferior quality, and enables them to be used commercially instead of imported coals of better quality. That is to say, some grades of coal of low calorific value, that are not economically useable in lump form on grates, are useable in pulverised form, because of the more complete combustion thereby obtained, and the consequent more efficient results. In the case of coals that are unsuitable for steam-raising in grate-fired furnaces, because of clinker troubles, (arising usually from a combination of high sulphur content and low-temperature fusibility of the ash content) use in pulverised form has obvious advantages, and in addition gives the benefit of any heat units that are contributed by free sulphur in the coal.

Jan 1, 1924

By G M. Young

IT IS most appropriate that this first Memorial Lecture should be given in the Province of Quebec, near the site of the first metallurgical industry in Canada. At La Forge, about seven miles north of Three Rivers, iron was produced in 1783. We are told that the early settlers obtained most of their iron-ware -stoves, kettles, axes and ploughshares -from this smelter, with its foundry and forge. The Canadian copper industry also had its beginnings in Quebec when, nearly 100 years later, in the 1880's, several small copper smelters were erected in the Eastern Townships. Later, in 1899, Canada's first aluminum smelter was built at Shawinigan. From these small beginnings has grown a vast metals industry, the export value of its products being only exceeded by that of our forest products -newsprint, pulp-wood and lumber. As we are not a large country in terms of population, our domestic capacity to consume is often small in relation to our developed capacity to produce.

Jan 1, 1963

By Pim van Geffen, Dave Lawie, James Cleverley

A growing problem facing geoscientists, metallurgists and process engineers is the lack of knowledge transfer between the exploration and production teams. This siloing is generally unintentional, as a typical project may change ownership several times over several decades before it reaches the feasibility and operation stages. Many exploration projects generate vast amounts of high-quality, quantitative data with great spatial resolution, but unfortunately these data are often ignored in subsequent deposit modelling. Instead, deposit models tend to rely on subjective, non-standardized, qualitative classification of geological materials (e.g. rock type, mineral abundance) and processes (e.g. alteration style and intensity), obtained through visual logging of drill core. When projects advance to feasibility studies, the required quantitative data are obtained through expensive metallurgical test work and detailed quantitative mineralogical analysis, such as QEMScan or qXRD. These detailed tests are generally only performed on a small number of large composite samples and the results are extrapolated throughout the deposit, inherently underrepresenting their true variability. Geochemical data obtained during all stages of the project provide comprehensive data coverage at much greater detail and spatial resolution, which allows for the estimation of key metallurgical performance parameters that are required for accurate deposit modelling and domaining.

Jan 1, 2015

By I. Le May

"The assessment of integrity in plants is discussed, together with the codes that are being developed for in service evaluation of engineering fitness for service. The use of Risk Based Inspection is described and some examples are provided of the evaluation of in service components in which flaws have been detected. An example of the assessment of the structure of a mine processing facility is described, and application of Risk Based Inspection and plant assessment procedures to mines is discussed. Periodic assessment of large plants and components to determine their integrity for continued safe operation is becoming a more accepted approach than formerly when regular shutdowns were the normal practice. This is on the way to becoming the preferred procedure for petrochemical plants and power generating plants, and the same philosophy is appropriate for many mining operations. Both the American Petroleum Institute (API) and the American Society of Mechanical Engineers (ASME) have committees developing codes for the continued operation of equipment as distinct from the existing design codes. The philosophy is one of risk-based inspection, which can be on a purely qualitative basis or more quantitatively based.The purpose is to reduce the inspection of unnecessary and non-critical items and to concentrate on the most critical components, reducing costs and downtime and increasing safety. The approach differs from that considered by many maintenance engineers, in that defects that are identified during an integrity evaluation do not automatically cause a component or structure to be condemned or require that repairs are made right away. The seriousness of the defect must be considered and the safe operating life can be estimated before it becomes necessary to replace or repair the unit or component. This is no different from what is done today with passenger aircraft and, to an increasing extent, with pressure vessels, reactor vessels and similar components in the petrochemical and power generating industries."

Jan 1, 1998

By S. J. Prout, J. M. Lang, D. Lascelles, K. Sarinas

"There is a growing demand for ore characterization methods to support metallurgical development programs from a true geometallurgical perspective. Today, there are multiple automated mineral analysis systems on the market, many of which are based on conventional mineral liberation data. However, liberation data can be limited when assessing the floatability of a mineral to predict its recovery as it doesn’t consider the surface area available for collector absorption and bubble attachment; whereas mineral exposure measurements can. Using the First-Order Rate equation to predict the recovery versus time of variously exposed particles, a model has been developed to predict the recovery of copper sulphides at a particular grind size. This model provides the opportunity for the prediction of copper recovery and grade from multiple, small-scale samples. These predicted values can be imported into resource modeling software, and guide the domaining of geometallurgical units within the ore body. Data has been analyzed from various global copper porphyry systems and compared with actual flotation testwork.IntroductionAs part of the development of a mining project, resource estimation primarily focuses on the definition of the quantity and grade of the ore in the deposit; as the project evolves from preliminary economic assessment through to feasibility, the geological model is usually further populated with hardness and recovery data.The CIM Definition Standards (2011) identifies measured mineral resource as the part of a mineral resource for which quantity, grade or quality, densities, shape, and physical characteristics are estimated with confidence sufficient to allow the application of “modifying factors” to support detailed mine planning and final evaluation of the economic viability of the deposit as an asset. The modifying factors include, but are not restricted to, mining, processing, metallurgical, infrastructure, economic, marketing, legal, environmental, social and governmental factors.With market fluctuations, many investors in the mining industry have become more and more risk averse which has increased the demand for more reliable data to support these modifying factors. This has led to the widespread use of geometallurgy and statistical analysis to better inform the resource estimation. Geometallurgy is used to characterize ore variability and is especially useful for highly variable or strongly zoned deposits, several close deposits that will be milled together, projects requiring complex or new metallurgical approaches, brownfields or sight-of-mine exploration, expansion projects that exploit new, deeper or adjacent reserves, and projects with significant legacy drill core that are being re-evaluated due to new economic circumstances."

Jan 1, 2018

By Ken McIntyre, Trodel Wolf-Dieter

"Sirius Minerals is a UK based fertilizer development company focused on advancing into operation its polyhalite project in North Yorkshire, England. The operation is known as the Woodsmith Mine which has an estimated 2.7 Billion Tonnes of reserves and is currently in the construction phase. DMC Mining Services was selected to carry out the construction of four shafts for the project, a production shaft of 6.75m diameter to a depth of 1594 m, a ventilation shaft of 6.75 m diameter to a depth of 1565 m, and two additional shafts to support the construction of the material transport system (the MTS and Lockwood Beck intermediate) to 360m in depth for servicing the underground conveyor network for transport of product from the mine site to the costal port facilities located at Teasside. This paper will review the status of the project to date and the innovative approaches that DMC is utilizing to ensure a safe and successful shaft sinking project. INTRODUCTION The Woodsmith Mine in North Yorkshire is a Sirius Minerals-owned deep potash and polyhalite mine located near to the hamlet of Sneatonthorpe, Whitby in North Yorkshire, England, approximately 75 km east of York. The area of interest is more than 700 km2. The £3.2 billion project is to develop the Woodsmith Mine to extract polyhalite, and a tunnel system to transport it to a materials handling facility and harbour at Teesside. The site is the world's largest and highest-grade deposit of polyhalite and is expected to produce 20 million tonnes of polyhalite, potash and POLY4 per annum, as well as create over 1,000 direct jobs and many more indirectly. It has the potential to generate over £2 billion of annual exports for the UK. As the project will require mining to be undertaken in the North York Moors National Park, many objections were raised about the mine. Sirius Minerals has gone to great lengths to ensure that the project is sensitive to the local landscape, including: mineshaft head frames that will be positioned below ground to reduce their visual impact; surface buildings will be kept to a minimum; and the entire site will be landscaped and screened by existing woodland to blend in with the surrounding area. The project will also abide by strict environmental limits which govern our activity during the construction phase."

Jan 1, 2019

By A. C. Hitchins, C. N. Orssich

The Eagle zone is a gold-bearing, sheeted, quartz vein porphyry deposit hosted by the Cretaceous Dublin Gulch biotite granodiorite stock, located in central Yukon, 50 km north of Mayo. The deposit occurs at the western end of the stock and has been drill tested over a 1000 m by 500 m area, to a depth of 150m. Mineralization consists of 1 cm to 2 Cm wide, parallel, grey and white quartz veins with accessory gold, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, native bismuth, bismuthinite, and scheelite. Vein densities range from two to fifteen veins per metre and average approximately five per metre. The majority of the veins have potassic and or phyllic alteration envelopes. Alteration of the granodiorite becomes pervasive as vein densities increase. Mineralization outside of the Eagle zone, but spatially related to the Dublin Gulch stock, includes: (i) scheelite bearing sheeted quartz vein zones within the east-central portion of the stock; (ii) a swarm of gold-bearing quartz-sulphide veins up to a metre wide in a zone along the northern contact of the stock and extending 7 km further west; (iii) the Mar scheelite skarn located on the south side of the stock; and (iv) cassiterite-bearing breccias located 2 km north of the stock. A geological potential resource of 64.5 Mt tonnes at a grade of 1.03 g/t Au has been estimated for the Eagle zone from widely spaced core and reverse circulation drill holes. Mineralization is open at depth, on strike to the west and beneath the hornfels to the north.

Jan 1, 1995

By A. Ouellette, E. Nilsson

"Preventative maintenance is a burden for equipment users but a demand from the machine suppliers to ensure performance. Machine availability depends on preventative maintenance being followed.Mining equipment is becoming more and more sophisticated and productive, yet less and less time is available for preventative maintenance. Manufacturers invest in reducing costs, simplifying operating requirements, and lowering maintenance requirements, but it is the users who must invest more heavily in the advanced maintenance systems to keep the units operating.IntroductionPreventative maintenance has been, and still is a key factor in avoiding disturbances in production due to equipment downtime. Manufacturers ask for it in extensive maintenance schedules, check lists, programs, etc. often with a ""threat"" that, if not performed, the machine guarantee will not be valid. Modern mining and construction machinery has become sophisticated, like all other machinery, with elaborate hydraulic, electric and electronic systems and computerized controllers. Maintenance organizations within the mining industry have grown to heavy cost centres just to keep up the availability of the equipment.It is difficult for machine manufacturers to have maintenance programs that suit every user. International suppliers have to deal with different cultures, education levels, environments, organizations, etc. Maintenance programs recommended by manufacturers often do not meet some user's needs while they are ""overkilling"" to others. Preventative maintenance schemes recommendations of what to do, in what frequency, etc.) usually fit mechanical components in the equipment, e.g. wear measurements, crack indications, lubrication, oil changes, etc. But how does one perform preventative maintenance on huge hydraulic systems, electrical and electronic systems and computers? Failures in these systems usually occur without any warning and are more or less impossible to predict. Another difficulty in creating effective preventative maintenance programs for these kinds of systems is the relatively low volume of mining and construction equipment that is produced per year. For example, although Atlas Copco is one of the largest manufacturers in the world of underground blast hole drilling machines, the company still does not produce more than a few hundred drilling jumbos per year. These are made in more than 10 different models, with different systems and components, and very often are custom adapted to the end user's requirements."

Jan 1, 1992

This paper comprises a description of on-stream analysis instrumentation, including sample handling, X-ray optics and data processing. It also includes a discussion of some typical applications of an on-stream analyzer as related to the mineral processing industry. Introduction T WO automatic X-ray spectrometers have been developed for the simultaneous analysis of as many as six elements in a given sample. These instruments, namely the On-Stream Analyzer and the new Vacuum Simultaneous Spectrometer, have been designed specifically for process control in industry where large numbers of static samples or a number of flowing sample streams must be analyzed continuously with both speed and accuracy. This paper is concerned particularly with the application of these instruments for the continuous analysis of dynamic samples. The Instruments The On-Stream Analyzer and the Vacuum Simultaneous Spectrometer are intended to serve industry by offering two basic approaches to the problem of continuous sampling of flowing sample streams. The On-stream Analyzer (Figure 1) is designed for the completely automatic and unattended analysis of flowing sample streams in a programmed cycle of operation.

Jan 1, 1965

By J. Weyer

"Threshold limit values (TLVs) for NO and NO2 have been reduced drastically in 2016. Emissions of diesel engines have been reduced in the last decades. In many cases this is not enough to stay under required TLVs. Remaining gas in the blasted rock is set free during loading and transport. At the end, only a combination of measures with a further reduction of diesel motor emission, replacement of diesel driven vehicles by electric equipment, new explosives with reduced NO and NO2 production, changes in the organization and effective ventilation measures can ensure that the TLVs are not exceeded. KEYWORDS Blasting fumes, Gas measurement, Gases, Threshold Limit Value (TLV) SHORT HISTORY OF EXTRACTION OF RAW MATERIALS The extraction of raw materials—besides haulage and transport—is one of the main processes in mining and tunneling. The principal objective is the creation of a material which can be transported from the place of extraction (face) to another place for further processing or direct use. Furthermore, recently a desired grain size distribution has become more important. A revolutionary development took place in the course of centuries. With the use of primitive tools like shovels, chisel and iron in the 12th/13th century in Freiberg, ore mines performances of 12 16 cm per man and week could be reached in cross section of 1 m2. Recalculated with an assumed average density, this is a performance of 0.006 t/h. With the introduction of black powder into the subsurface in 1627 by Caspar Weindl in the city of Schemnitz (nowadays Banska Stiavniza), performances increased. A part of the hard extraction work was now done by the explosives. But first in 1767, it was recognized in a mine in Freiberg that more than 1 hole could be drilled (hand-drilling) and blasted. This discovery was so important that a plate with an inscription describes this event. The performance was increased more than 10 times compared to the extraction with chisel and iron. Since this time, drilling and blasting has been the most important innovation force for the increase of the performance. Problems with noxious blasting fumes led to the construction of the first tunneling machine by Henry Joseph Mouse in 1846 (beside shield machines from 1825) (Stack, 1982)). The triumph of mining machines started only interrupted by the two world wars. The development of hard rock boring machines (including roadheaders) was enforced after 1945. An almost complete extraction by hard rock boring machines was predicted for the turn of the millennium. And, indeed, one could find powerful machines in Canadian potash mines which were able to mine 1000 t of potash in 1 hour. That was an increase in the performance by several powers of ten. But already in the 1980s, it was recognized that the ambiguous goal could not be reached. Problems with wear of the tools, radius of curves, minimal length of openings, size and costs of the machines led to a more or less parity between drilling and blasting on one side and machines on the other side, of course depending on the field of use. For this reason, drilling and blasting is still the dominant extraction technology for raw materials. In the development of drilling and blasting technologies, the focus was mainly on the improvement of the safety but also on the increase of the blasting power and performance. Examples are tests for the increase of the power of ANFO explosives which were carried out in the 1970s and 1980s, in the former teaching mine “Reiche Zeche”. In the 1980s vehicles for loading and mixing of ANFO explosives have been developed, the blasting cab sensitivity of ANFO has been increased, emulsion explosives have been developed and up to now further developments like PMMA LOX EX explosives are on the way. At the turn of the millennium, 6 million t/a explosives have been used worldwide. Annual rates of increase of 2% have been predicted (Weyer, 1999). Meanwhile the focus changed from an increase of the performance"

Jan 1, 2019

By K. Huang

"Solvent extraction (SX) is one of the most effective techniques for the multi-metal separation. However, repetitive pre-treatment of feed-in solutions and/or multi-steps two phase equilibrating in conventional SX processes were always unavoidable due to the poor separation selectivity between those metals with similar physicochemical properties. In this paper, our recent efforts, aimed to develop a “Three Liquid Phase Extraction” (TLPE) strategy for one-step separation and selective enrichment of different metals respectively into three coexisted liquid phases, are reviewed. Various feasible “Three Liquid Phase Systems” (TLPS) are evaluated. The TLPE technique provides a potential possibility for multiphase extraction to separate multi-metals.INTRODUCTIONLiquid-liquid Solvent Extraction (SX) is one of the most effective techniques for metal separation and purification. Traditionally, extraction and separation of multiple valuable metals from the leaching solutions of complex ores, industrial wastes and byproducts have to face such difficulties that multiple target metals with similar physicochemical properties co-exist in the solutions, and therefore their mutual separation selectivities are very poor. In conventional organic-water two phase SX processes, repetitive pre-treatment of feed-in solutions including the adjustment of the solution acidity, removal of impurities and/or multi-step liquid-liquid two phase equilibration were always unavoidable (Wang and Chen, 2001). Only one of the target metals is obtained in each extraction step, therefore the whole separation processes for multi-metal separation are typically very long and costly.Liquid-liquid-liquid three phase extraction is a developing technique for separation of complex systems containing multiple target components (Tan, 2003; Shen, 2006; Yu, 2009). The technique is in fact a three-liquid-phase selectively partitioning of different target components through the control of phase-forming behaviors of extraction system to create a unique separation medium with three co-existed liquid phases. The separation selectivity of “Three-Liquid-Phase System” (TLPS) may derive from its three-layered liquid phases from up to down with different hydrophobic or hydrophilic environment, and therefore each phase has its own specific selectivity for dissolving of an individual component. In a well designed “Three-Liquid-Phase System” (TLPS), multiphase extraction and selective separation of different components respectively into three different liquid phases can be achieved by only one-step of extraction. Owing to its distinct advantages, “Three-Liquid-Phase Extraction” (TLPE) technique has found many potential applications in purification of various organic chemicals (Shen, 2007) and biological activities (Chen, 2002; Tan, 2006; Jiang, 2008), treatment of environmental wastewaters (Shen, 2006; Yu, 2009; Yu, 2010; He, 2012), extraction of valuable components in natural products (Liu, 2010) and separation of multi-metals in complex leaching solutions (Jin, 2009)."

Jan 1, 2012

By A. Hynes, T. Skulski, D. Francis

The Archean volcano-sedimentary succession in the LG-3 area has undergone two phases of deformation and has been metamorphosed to upper greenschist and amphibolite facies. Marine, fine-grained sediments and mafic pyroclastics comprise the lowest observed stratigraphic unit. These sediments are overlain by a thick sequence of submarine basalts and minor basaltic andesite. The lavas are characterized by high Al/Al+Si, Ti values, low Mg numbers and flat REE profiles (lOx chondrite). A sedimentary prism of coarse elastics which was deposited close to an exposed plutonic highland, overlie the volcanics. Massive lavas of basaltic andesi te and associated volcano-sediments comprise the uppermost stratigraphic unit. These lavas are characterized by high Mg numbers, Ni, Cr, LREE (lOOx chondrite) but low Ti, Al/Al+Si and HRee. The supracrustal rocks were intruded by tonalites and tonalitic gneisses.

Jan 1, 1984