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By David Thomas, Charles Harper, Brian Watters

The Star-Waddy Lakes area lies withjn the northeasterly-trending early- to mjd-Proterozoic volcanoseilimentary-pl utoruc belt referred to as the La Range Domllin. In the area investigated the domajn is composed of the Central Metavolcaruc Belt which is bordered by metasedimentary belts of the Crew Lake and MacLean Lake Belts to the northwest and southeast respectively. The boundaries between the Central Metavolcanic Belt and the flanking belts are generally marked by prominent zones of shearing. The volcanosed imentary succession is intruded by a variety of ultramafic to felsic plutons which, on the basis of lithology, field relations and geochronology, can be broadly subdivided into three groups or episodes. These are: a) an 'early' (ea. 1866 Ma), possibly subvolcanic, episode marked by composite intrusions ranging from gabbro-diorite to granite, b) an 'intermediate' (ea. 1854 Ma) plutonic event distinguished by more homogeneous felsic intru ions ; and c) a 'later' (ea. 1835 Ma) event characterized by leucocratic quartz-rich grani te intrusions. The La Range Domain has undergone polyphase deformation with a strongly developed northeast-trending structural grain. Large scale folding is manjfested by large regional sy nforms, arcuate and triangular patterns associated with many of the plutons and by tight to isoclinal folds within the adjacent metasedimentary belts. Inhomogeneous strain characterizes much of the Star-Waddy Lakes area. With strain gradients being typically very steep, zones of high strain consisting of zones of extreme extensional fabrics, discrete shearing, as well as broader zones of cataclasis and structural slicing, are often juxtaposed with areas of relatively minimal deformation . Dilation structures tend to favour these zones of highly contrasting strain. Late, brittle fractures, faults and shear zones are widespread and appear to be particularly important as loci for gold mineralization. Metan1orphic mineral assemblages indicate that upper greenschist to middle amphibolite facies conditions were attained. Geological and geochenucal evidence indicates that the Central Metavolcanic Belt evolved in an island arc environment. Metavolcanic rocks from both the Waddy and Star Lakes areas display similar characteristics on variation diagrams (e.g. AFM and the Jensen cation plot) in that the dominant trend is calc-alkaline with some basic to intermediate types having a mildly tholeiitic character. A few samples from the southern end of Lower Waddy lake display komatiitic to basaltic-komatiitic afl'injties. The relatively immobile minor and trace elements (e.g. Ti , Zr, Nb, Y, Cr) provide reliable characterization of the metavolcanics, particularly of the basalts, which have highly distinctive trace element properties. Geochemical patterns for the basalts are similar to those for modem volcanic arc basalts. Low initial 87Sr/86Sr ratios (0.7017 - 0.7019) are consistent with a subduction-related origin for the volcanics. The major plutons have chemical properties typical of volcanic arc granites and are largely calc-alkaline in character, showing little chemical variation from the volcanics.

Jan 1, 1986

By P. C. Santos-Munguía, F. Nava-Alonso, O. Alonso-González

"The gold recovery of a Mexican cyanidation plant, in Sonora, has been decreasing due to the increasing presence of gold tellurides. This work presents the results of different processes aimed to recover the remaining gold from the cyanidation tailings of the operation. The cyanidation in the mine is performed at 0.1 g/L NaCN and pH = 10.3, adjusted with lime. The treatments studied in the laboratory with these tailings were: cyanidation at higher cyanide concentration than that used in the plant, cyanidation with oxygen injection, cyanidation with oxygen and lead nitrate addition, and thiourea leaching. The results obtained with each of these treatments are presented and discussed with the final objective of proposing a method to recover the gold associated with tellurium.INTRODUCTION It has been demonstrated that gold telluride is refractory to the conventional cyanidation process and, for this reason, some alternative methods to recover precious metals from tellurides have been proposed. (Zhang et al., 2010). These include cyanidation with modified conditions or the use of non-cyanide leaching agents. This work presents the gold leaching results of tests performed with a sample of cyanidation tailings obtained from a Mexican deposit containing telluride species. The mine exploits a mesothermal deposit with a molar Te/Au ratio of 1, containing also lead, molybdenum, bismuth and tungsten. Gold is recovered from the ore by standard cyanidation, however, lately the gold recovery has decreased, likely due to the tellurium content of the ore. The sample used in this work was the cyanidation tailings of this deposit. It was treated in the plant by cyanide heap leaching (0.1 g/L NaCN, pH = 10.3 adjusted with lime). Some gold remained after the cyanidation and it was thought that this gold was associated with tellurium. The objective of this work was the recovery of the remaining gold from the tailings by an alternative process."

Jan 1, 2017

By H. O. Seigel

Induced Polarization includes many types of dipolar charge distributions set up by the passage of current through consolidated or unconsolidated rocks. Among its causes are concentration polarization and electrokinetic effects in all rocks and the phenomenon of Overvoltage in rocks containing electronic conductors such as metallic sulphides and graphite. In normal rocks the polarization effects may be usually con-fined within relatively narrow limits and any large departures may be at-tributable to the presence of electronic conductors. In practice, Induced Polarization is measured in one of two ways. In the first a steady current of some seconds duration is passed and abruptly interrupted and the slowly decaying transient voltages existing in the ~round are measured after interruption. This is known as the "pulse", "transient", or Direct Cur-rent Induced Polarization (D.C.I.P.).The second method entails a comparison of apparent resistivities using sinusoidal alternating current of two or more frequencies, generally within the range of 1/10 to 10 c.p.s. Induced Polarization extends the

Jan 1, 1962

By A. H. Harvey, M. Delangen, A. D. Fernie

"A large-scale expansion to Pacific Coast Bulk Terminals Ltd. has now been completed and placed in operation. The original plant, built approximately eight years ago, consists of the direct rail-car to ship transfer of bulk commodities. The extension includes additional rail-car unloading, a transfer house system for directing commodities to storage or ship, major storage and reclaim facilities, a second shiploader and a second deep-sea berth. In addition to the facilities for overseas shipments, a wood-chip loader and a barge berth have been installed for domestic shipments of wood chips and, occasionally, for other local commodities. The design considerations imposed by the nature of the products to be handled are covered in this paper."

Jan 1, 1969

By Graham Walker

A new Code of Practice for the brake performance of off -highway vehicles was established in Alberta in 1976. Vehicles loaded to gross vehicle weight must be capable of stopping with mechanical brakes five times in quick succession on a grade of 10 per cent from a speed of 28 miles per hour. Comparative trials of various brake systems have been carried out and some combinations capable of meeting the Code are identified. Some problem areas in truck braking are reviewed and potential developments indicated.

Jan 1, 1977

By J. Lammers, D. Adams

Most pressure oxidation operations introduce oxygen through a large multi-use nozzle in the vapour space of the autoclave. Sparge pipes extend inside the vessel to the point of discharge below the compartment agitator. However, two zinc pressure leach operations have successfully used a bottom entry oxygen sparge system for a number of years. Recently, the concept has been used in a whole ore gold pressure oxidation operation as well as a copper pressure leach plant. Both of the latter operations also introduce cooling water for temperature control through the same sparge pipe. This paper addresses the benefits of the bottom entry system with regards to autoclave performance and the positive effects on agitator performance.

Jan 1, 2004

By R. D. Browns

In his Budget Speech on March 31, 1 977, the Honourable Donald S. Macdonald expressed concern about the financing of investments through new equity issues. He mentioned the need to render more attractive participation in the equity market by investors in all in come brackets. One of the measures introduced in the budget to accomplish this goal is the proposal to increase the dividend gross-up and tax credit in respect of most dividends received by an individual from Canadian companies. The following comments and tables serve to illustrate the impact of this particular proposal.

Jan 1, 1977

By W. Keith Buck

Introduction During World War II years, the magnetometer was used by various field parties of the Geological Survey of Canada, specifically in the search for chromite, a strategic war mineral. Throughout the summer of 1944, Professor J. W. Ambrose used the instrument experimentally on eight separate projects (1). Since then, several members of the Survey have come to consider its use to be of valuable assistance in the season's mapping. Dr. C. H. Stockwell, in particular, regards use of the magnetometer as a necessary part of detailed geological survey work. Throughout the field season of 1949, the magnetometer was used by Dr. Stockwell?s party as an aid to mapping in detail, to the scale one thousand feet to the inch, the south-west quarter of Dasserat township, Temiskaming county, Quebec. The principal geophysical project that was undertaken was the location of the Horne Creek fault and the Diabase fault in the area approximately midway between Arntfield and Kearns, on the Quebec side of the Interprovincial border. The location of these faults on either side of this central area was known. The Horne Creek fault is a subsidiary fault to the Cadillac 'break' which extends ?westward from Val d'Or through Cadillac to beyond Larder Lake. It lies to the north of that major fault zone and has a general southwesterly trend.

Jan 1, 1951

By J. C. Farge, G. G. Jacox

"The effect of composition and process variables on the properties of Marmet and modified Ni-Hard slugs will be discussed. The effect of shape on the over-all performance of grinding media and its relationship to the end product has been investigated and these results will be reviewed. The cost effectiveness of slugs versus balls has been well documented under various operating conditions and this will be presented in detail. IntroductionThe selection of grinding media is based on the cost-to-wear ratio combined with the consideration that it must stand repeated impacts without breaking. The specific consumption of grinding balls and slugs depend s primarily on their microstructure, which, in turn, is controlled by chemical composition and by the processing condition s to which they are subjected during manufacture.The first part of the paper deals with the optimization of alloy content to produce cast iron slugs with microstructures consisting essentially of marten site and carbide and with hardnesses of 650 B.H.N. and higher. The second part deals with the use of cast iron slugs to replace forged steel balls in milling operations. Tests indicate that the shape of the media has little if any effect on results and that the hardness and microstructure of grinding media will determine its relative performance. Where price is equal under similar milling conditions, the cost effectiveness of cast iron slugs is superior to that of forged steel balls.In order to understand the role of alloying elements in cast irons, it is judicious to consider the microstructural changes which occur during solidification and subsequent cooling, particularly from above the eutectoid temperature. Solidification starts with the formation and growth of dendrites of austenite. As temperature decreases, an eutectic nucleates and grows between the primary austenite dendrites. Immediately after solidification, the structure consists of proeutectic austenite and of the eutectic of primary carbides and austenite. On cooling to room temperature, austenite can be retained or transformed to pearlite, bainite, martensite or mixtures thereof. It is necessary to prevent decomposition of austenite into pearlite by adjusting the alloy content. For best abrasion resistance, the microstructure at room temperature should consist essentially of martensite and carbide. These types of irons are known as ""martensitic irons "". Depending on the carbon content of the austenite and cooling rate, "" as-cast"" martensitic irons will contain different proportions of martensite and retained austenite. The more carbon in solution in the austenite, the lower is the temperature at which the martensitic transfoemation takes place. By the time room temperature is reached ., the transformation is seldom complete, and the end product is generally a mixture of martensite and retained austenite."

Jan 1, 1980

By H. Tetu, F. Pells

"The copper-molybdenum property of Brenda Mines Limited is located in the Okanagan district of British Columbia, approximately 25 miles west of Kelowna. The Okanagan Valley is a resort and fruit-growing area, and therefore pollution control measures are more stringent than in some remote areas.The Brenda plant began production in April 1970 and is operated at a rate of 24,000 tons per day. The plant site is located at an elevation of 4,800 feet, which is approximately 3,600 feet above the level of Okanagan Lake. The site is in the Okanagan drainage basin.The major consideration in the design of the system was the prohibition of any downstream discharge. It was therefore necessary to redaim as much water as possible and to minimize the addition of fresh water to the system. The maintenance of a water balance is of critical importance.This paper will outline the major design criteria for the systems and the site investigations which were carried out. The design and construction of the facilities will be de-scribed and current operating experience will be outlined."

Jan 1, 1971

By Tong Gao, Jingyu Qin, Xiangfa Liu, Zengqiang Li, Yaoxian Zhang

"The recycling of aluminum materials is a green industry while Al–Si–Fe is a typical scrap aluminum alloy. The key point of recycling Al–Si–Fe alloys is to separate Al and Fe. A method by introducing Al–Si–Fe alloy into Mg melt has been investigated in this work. A separation layer with gathered Fe–rich and Al–poor Fe3Al0.7Si0.3particleswereobtained at the bottom of the cooled ingot, indicating that ß–Al5FeSi phase evolves to Fe3Al0.7Si0.3,and quantities of Al are released to the upper Mg matrix simultaneously. However, the evolution of Al3Fe by adding binary Al–Fe alloy into Mg melt is different. It is supposed that element Si plays an important role in the phase evolution procedure, thus affects the performance of this method.INTRODUCTIONThe rapid development of aeronautic, automotive and aerospace technologies strongly depends on the consumption of materials while sustainable development is the future direction. Aluminum is a recyclable material and Fe is one of the most common impurities. Fe can be introduced into Al alloys by adding low–purity alloying materials and by using unprotected ferrous crucible, tools, or equipment (Belov, Eskin, & Avxentieva, 2005; Lu& Dahle, 2005).For instance, wear–resistant rings are usually inserted into piston head when producing Al–Si pistons and an infiltration procedure by putting the cast iron rings into Al melt before casting is always essential. As a result, both the re–melting of pistons and the reuse of Al melt for infiltrating rings lead to the enrichment of Fe element, which can be even high to5 wt.%(Viala, Peronnet, Barbeau, Bosselet, & Bouix, 2002).It is widely known that coarse ß–Al5FeSi particles will form in high Fe–contained Al–Si–Fe alloys which is harmful for the mechanical properties. In the past decades, several methods to eliminate the harmful effect of ß–Al5FeSi have been investigated which can be widely referred (Munson, 1967; Lee, Kawamura, Inoue, Cho, & Masumoto, 1997; Suárez–Peña& Asensio–Lozano, 2006; Eidhed, 2008).These methods can be divided into two kinds. One is to aggregate and remove the Fe–rich phase through the methods of centrifugation, gravity filtration or magnetic separation. The other way is modifing the morphology of flake–like ß–Al5FeSi by overheating the melt or adding neutralized elements. However, these traditional methods are rarely used due to respective disadvantages, while the commonly used method in industries is using primary aluminum for dilution. However, only less than 30wt.% of scrap Al can be added into primary Al melt for each melting work while it also results in the decrease of product quality simultaneously(Zhang, Liu, & Liu, 2016)."

Jan 1, 2018

By J. E. Nesset, E. R. Bobicki, K. L. Bilaniuk

The introduction of froth flotation technology in Canada, and in particular, in British Columbia, began not long after it was successfully applied in the Broken Hill mining area of Australia which began around 1905. It proved to be a revolutionary and transformative technology that resulted in marginal operations in copper, lead and zinc becoming profitable in spectacular fashion. The paper presents the technology of both oil flotation and froth flotation in the context of the challenges of the time and its early application in British Columbia at the Le Roi No.2 mine (1903), the Britannia Copper mine (1912), and at the Allenby concentrator of the Copper Mountain mine (1918-19). New-found archival documents indicate the Britannia application to be the first production application of froth flotation for copper ore outside Australia, a claim that is currently made by the Braden mine (now El Teniente) in Chile. Flotation was initially an add-on process following gravity methods but was rapidly shown to be far superior method for the bulk and selective recovery of metal sulphides. Flotation proved particularly successful for the recovery of zinc sulphide (the so-called ‘zinc problem’) which was considered a contaminant at the time. The ‘copper problem’ related to the poor recovery of fine copper sulphide particles that were not amenable to gravity methods. The success of flotation led to changes in both the scale and methods of mining, concentration and smelting in a manner that allowed integrated mining companies to flourish. Many are still with us today. INTRODUCTION The advent of froth flotation in the early 20th century was truly a revolutionary technological development, not only for the mining and metallurgical industries, but arguably more so for business and society overall. The Canadian technology historian Jeremy Mouat stated (1996) “The development of flotation was the greatest single metallurgical improvement of the modern era...it is not overstating the case to claim that flotation was of central importance to the smooth functioning of the global economy”. It should, therefore, be a story of interest to us all. The aim of this paper is not to retell the full story, that has been well covered by others (Hoover, 1912; Rickard, 1916a; Hines & Vincent, 1961; Lynch et al., 2010) but rather to add some Canadian perspective and the key role played by companies and individuals in those early days, focusing on events in British Columbia’s copper industry. EARLY DEVELOPMENTS During the later half of the 19th century, a number of flotation-related patents were issued. These include the 1860 patent (Britain) granted to William Haynes for a process to separate sulphides from ground ore by mixing it with oil (1-10% wt) followed by a separation process in a water-filled vessel; the 1877 patent granted to Georg and Adolph Bessel (Germany) for a process involving the mixing of oil and graphite ore followed by boiling in water to produce a high grade graphite froth (>90% carbon); and the 1885 patent granted to Rebecca ‘Carrie’ Everson for the separation of sulphides by mixing sulphide ore with small quantities of oil, and adding water followed by sulphuric acid. These processes are more properly referred to as bulk oil flotation due to the relatively large quantity of hydrocarbon used.

Jan 1, 2019

By Edgar A. Manker

"Today's market for columbium has only developed in the last two decades, and in this sense it is ""newer"" than molybdenum, vanadium and most other steel alloying elements. In this short period, it has assumed a very important role in steel alloying and in superalloys. From a few hundred thousand pounds of columbium in 1960, consumption has grown to nearly 30 million pounds per year, with a market value approaching two hundred million dollars.To assess the outlook for columbium, we will first consider the historical development of consumption and supply, particularly noting that all of today's major mines were developed during the last two decades. From current production, we will attempt to reasonably project the future. This future may well include new producers, particularly some producing columbium as a co-product with tantalum.The growth of current applications, and emerging new applications, will be considered with regard to future consumption and in relation to future trends in pricing.IntroductionThe nineteenth century was a busy time for the discovery and naming of new elements. Among those discovered were columbium in 1801 and niobium in 1844. Although it was later shown that columbium and niobium are the same element, the two names are still used today. Niobium has been pronounced the ""official"" name by the International Union of Pure and Applied Chemistry, but columbium is still widely used in commercial practice, and we have chosen to use columbium in this paper."

Jan 1, 1981

By J. G. Trowell, D. T. Magee

"IntroductionMANITOBA'S first recoverable oil was from the California Standard Daly 15-18 well in Lsd. 15, Sec. 18, Twp. 10, Range 27, W.P.M., completed early in 1951. This well also gave the first indications of commercial production in the Williston basin, which is centred in North Dakota and extends into southeastern Saskatchewan and southwestern Manitoba. Subsequent drilling in the Manitoba portion of the basin has revealed the presence of oil in more or less commercial quantities at various points in an area approximately four townships in width and eleven townships in length.Although completions are becoming fairlly widespread in the area,, the greatest activity is in the Virden district, with the focal point in the Daly field, approximately eight miles west •of Virden. This paper will deal with the various techniques used in the Daly field, where •completion problems have •been unusually troublesome. Techniques evolved there have already been used with success at other points in southwestern Manitoba.Daly FieldGeneralTo date, all production has been from the Mississippian limestone, which is encountered •at depths ranging from 2,300 to 2,500 feet. Pay thickness is •of the order of 100 feet. Core analyses indicate average porosity .of about 9 per cent but permeabilities, for the most part, are extremely low."

Jan 1, 1953

By A. G. Eccles

Western Mines' milling circuit produces three concentrates (copper, lead and zinc), with the tailings being disposed of at the bottom of Buttle Lake. In view of the mine's location and the method of tailing disposal, a comprehensive pollution control program has been in effect since start-up. Changes -in the ore over the past few years have required the use of increasing quantities of sodium cyanide in order to effect a good copper-lead separation. This led to the use of alkaline chlorination for destruction of ?residual cyanide and precipitation of dissolved copper contained in the tailing effluent. The development of Western Mines' alkaline chlorination plant is discussed in detail, including initial test work and the evolution of procedures leading to the present operation. The current monitoring program is also reviewed.

Jan 1, 1977

By G. D. Just

"Extensive mechanization of underground mining operations, improvements in blasting technology and the development of simulation models for systems evaluation has now made it feasible to optimize rock fragmentation and materials handling operations. Methods of achieving these objectives are described in this paper, with particular emphasis on the need to obtain precise field data measurements. Techniques are illustrated with reference to the sub-level open stoping system of mine production. IntroductionThe primary objective to be achieved in any mining system is to deliver a specified grade of ore to the mineral processing plant at a planned delivery rate and at the minimum total mining cost. Design and management of such a system is complicated by the large number of unit operations and the often unknown inter- relationships between the different unit processes. This particularly applies in underground mines, where planning restrictions and unit costs are much greater than in comparable tonnage sur face mining operations. These difficulties can often be resolved by the application of judgment based on extensive experience, but the costly trial -and-error methods required for new technology discourage innovation.Most modern medium- and large-scale mines are now extensively mechanized. Consequently, the performance of each unit operation by individual items of equipment should be predictable for a given set of conditions. An essential prerequisite is that quantitative performance data are available from field measurements. Such information can then be used to optimize the design and management of the complete mining system to achieve the minimum tot al mining cost. One of the most significant factors influencing all unit costs is the degree of rock fragmentation. The importance of this variable is indicated by the fact that opt imization of rock fragmentation implies minimization of tot al mining system costs."

Jan 1, 1980

By E. W. Williams

THE Ontario Research Foundation has developed a process for producing low-density steel shapes by direct reduction of iron oxide powders. The process is a combination of reduction, sintering (without compaction), and carburizing, and has been described by Cavanagh (1). Iron oxide powder, in the form of mill scale or highly concentrated iron ore, carefully sized, is poured into a porous mould. A reducing agent, generally coke breeze, is placed around this mould in a heat resistant sagger which is sealed off and heated to 2,000°F. for a number of hours. The coke/ ore ratio, the particle size distribution, the temperature and time of soaking, and the size and shape of the reduced product, determine the densities and carbon contents attained. The Defence Research Board sponsored a programme of research into some of the mechanical properties of the material (which was named Controlled Density Steel) and this paper is an account of various factors which govern the tensile strength of the steel. The ?practically attainable range of density is from 1.5 to 5.5 gm./ cc. but higher densities are obtained on hot working. This paper, however, is restricted to discussion of results for moulded products.

Jan 1, 1957

By V. Concha, M. Hashemzadeh

"The objective of this study was to gain a better insight into the kinetics of chalcocite leaching in an acidic ferric sulfate media. Chalcocite leaching in acidic media is known to occur in two sequential stages, with the first stage being much faster than the second. The leaching residue from the first stage is typically assumed to be a covellite type of material. This study hypothesized that the mineralogy after the first-stage leaching varies in response to different leaching conditions. We investigated the dependency of the mineralogy of the first-stage leaching residue on temperature and initial ferric concentration. The experimental results showed that chalcocite leaching behavior altered upon temperature and initial ferric concentration. A proposed combined reaction model was found to be able to describe the experimental data. The first stage was described very well by the shrinking core diffusion model while the second stage was described very well by the shrinking core chemical reaction model. This finding has important implications for mine operations to manipulate leaching conditions to create the desirable leaching kinetics.INTRODUCTION The kinetics of chalcocite leaching in sulfate media has been extensively studied (Cheng & Lawson, 1991; Fisher, 1994; Fisher, Flores, & Henderson, 1992; Niu, Ruan, Tan, Jia, & Sun, 2015). Sullivan (John D. Sullivan, 1930) proposed a two-stage process for chalcocite leaching in an acidified ferric sulphate solution. The two-stage leaching of chalcocite is presented as the following reactions:"

Jan 1, 2017

By S. Homulos

"Introductory and GeneralTHE Northwest Territories comprise all that region -of Canada lying between Yukon Territory and Hudson bay and north of the 60th parallel of latitude. For purposes of mine .administration the Territories are divided into three districts: Yellowknife, McKenzie, and Arctic and Hudson Bay. Mining recording offices for the respective districts are maintained at Yellowknife, Fort Smith, and Ottawa. The mine inspection for the entire area, and also for Yukon Territory, comes under the Federal Department of Resources and Development. Two mining inspectors are responsible for these inspections: the Chief Inspector of Mines, with headquarters in Ottawa, who makes trips into the north at least twice a year, and a Resident Inspector, stationed in Yellowknife.The Resident Inspector is constantly making inspections of active properties. This involves a considerable amount of air travel as the region is large and properties are widely scattered.Although there has been prospecting and staking of claims in each of the three districts of the Northwest Territories, actual mining has been conducted only in the Yellowknife district, and for purposes of this paper we are solely concerned with that district."

Jan 1, 1952

By P. Müller, W. J. Przybylowicz, V. M. Prozesky, D. de Bruin

"Abstract -The common style of gold mineralization in the Basal Reef and other auriferous conglomerates of the Witwatersrand Supergroup comprises clusters of gold grains occurring interstitially to quartz and pyrite pebbles as well as gold accumulations attached to the surface of and infilling hairline cracks and fractures in round, compact, detrital pyrite. The latter textural association is generally interpreted as a result of remobilization of originally detrital gold during regional metamorphism and related hydrothermal fluid circulation. There is general agreement that, although gold solubility was Iow, ore modification occurred during the metahydrothermal event, but uncertainty exists about the magnitude and scale of gold remobilization .Micro-textural and chemical investigation of compact round pyrite and associated gold accumulation has established that gold is preferentially deposited on chemically heterogeneous pyrite surfaces. Combinations of alternating high- and low-As zones in pyrite result in mixed np-type conductivity accompanied by electron exchange and the reduction-driven deposition of gold at the cathode. This mode] does not explain gold accumulations which are not immediately linked to chemical heterogeneities and it is inferred that an additional control on the deposition of gold was exerted by physical defects which lead to zones of increased charge density and/or areas of focussed conductivity. The inferred precipitation mechanisms suggest that submicrocopic physical and chemical controls are the important factors that determined the sites of gold nucleation and that precipitation mechanisms based on physicochemical changes of the hydrothermal system were not involved. The Basal Reef contains on average close to 5% of round, detrital, chemically zoned pyrite which provides a large number of electrochemically active pyrite surfaces. The extremely effective electrochemical precipitation mechanism together with the low solubility of gold in Witwatersrand fluids is the main reason for the spatially restricted remobilization of gold in the conglomerate reefs."

Jan 1, 1994