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By M. Epiney, A. Ghahreman, R. Kim1and

"Pre-oxidation and cyanide leaching behavior of gold in the presence of sulfide minerals were reviewed, focused on the effects of oxygen injection in the gold leaching process. Generally, pre-oxidation and gold leaching kinetics from iron sulfide refractory minerals, such as pyrite, pyrrhotite, marcasite, pentlandite and arsenopyrite, can be enhanced with higher dissolved oxygen (DO) concentration. However, most of copper sulfide minerals dissolved well both in water and cyanide solutions, and copper from the minerals consumed DO and cyanide to oxidize and leach. Only in the presence of chalcopyrite, gold leaching was effectively occurred with increasing DO. However, chalcocite and covellite severely retarded gold leaching. Stibnite, an antimony mineral, formed a passive film on the gold surface under any DO conditions, and it slowed gold leaching. This impeding effect can be alleviated by leaching at low pH or adding lead salt. Using oxygen and lead together can make synergistic effect in oxidation of sulfide minerals and can enhance gold extraction. Depending on the mineralogical characteristics of the ore, the optimum DO and lead concentrations can be optimized. However, lead can cause environmental problems, and so its dosage should be minimized or eliminated by substituting it with oxygen injection.INTRODUCTIONGold ores containing sulfide minerals are becoming more significant as high grade gold oxide deposits are continuously becoming difficult to find. In light of this situation, to produce more gold, recovery methods from refractory gold ore containing various sulfide minerals should be investigated. Generally, sulfide minerals have impeding effects on gold leaching: formation of a passive film on the gold surface, high consumption of chemicalssuch as cyanide and oxygenduring leaching, reduction of gold cyanide by sulfide ions, etc. (Senanayake, 2008). Therefore, sulfides must be properly treated for better gold recovery. Pre-oxidation of sulfide minerals by injecting pure oxygen can decrease the impeding effects in gold leaching. Prior to cyanidation, sulfide minerals can be oxidized to metal hydroxide and sulfate form, which consume negligible cyanide in the following cyanidation circuit (Bodnaras et al., 1993). Moreover, gold cyanidation can be enhanced by increasing concentration of the dissolved oxygen (DO). In general, the optimum concentration ratio of [CN-]/[O2] is calculated as 6, but it goes higher in the real system (Marsden &House, 2006), which means that the reaction is typically controlled by DO concentration."

Jan 1, 2017

By T. L. McCall

A short description of mining practice in the Sydney coal field in general is followed by a discussion of the operations in the No. 12 colliery of the Dominion Coal Company, Limited, as being typical of the trend in operating methods obtaining throughout the field. Development of longwall mining to the present system of three walls in line is outlined, together with a summary of the cycle of operations involved in systematic operation.

Jan 1, 1944

By P. Nos, L. Kolbeinsen, M. W. Kennedy, A. Filzwieser, R. T. Jones, A. MacRae

Modern furnace designs often incorporate extensive use of cooled elements to achieve long campaign lives at high operating intensities. However, contact between water and high temperature fluids can result in powerful Boiling Liquid Expanding Vapour Explosions (BLEVEs). Therefore cooling such elements with water carries inherent risks when used under slag and particularly below molten metal or matte. Alternative cooling media exist that can reduce or eliminate the risk of BLEVEs. These media are analysed and discussed in the context of deeply cooled furnace elements. Important factors in selecting alternative coolants are explored including: critical heat flux, thermal limits, toxicity, flammability, unit cost, etc. Key cooling system design criteria are reviewed in the context of both traditional and alternative coolants. Results of Computational Fluid Dynamics are presented for an example tap-block cooler design using a number of selected coolants. Research needs to advance the safe use of alternative coolants are presented.

Jan 1, 2015

By A. K. Snelgrove

Introduction ?Concerning the inland commodities, as wel to be drawen from this land (Newfoundland) there is nothing which our East and Northe.rly countries of Europe doe yeelde, but the like also may be made in (ît) as plentifully by time and industry : Namely, rosen, pitch . . . metalls, and many moe. All which the countries will aford, and the soyle is apt to yeelde ... For besides these alreadie recounted and infinite moe, the mountains generally make shew of minerall substance : Iron very common, lead, and somewhere copper. I will not auerre of richer metalls: albeit ... more then hope may be concieued thereof. " - Narrative of Captain Hayes, second-in-command to Sir Humphrey Gilbert's Expedition, IJ83 (From Hakluyt). The investigations set forth in the following pages were made in the field in Newfoundland during the summer of 1927, and later in the laboratories and library of McGill University, and in the library of the Canadian Geological Survey at Ottawa, with the purpose of collating and adding to our knowledge of the geology of an area roughly wedge-shaped in outline, and nearly nine thousand square miles in extent, stretching across the centre of the island of Newfoundland, from the southwest to the northeast coasts. To the description of this district, which contains most of the known mineral occurrences of Newfoundland, the term mineral belt is here introduced.

Jan 1, 1928

By Guoqiang Lan, Jun Song, Bin Ouyang

Rare-earth pyrochlores, commonly exhibiting anomalously low lattice thermal conductivities, are considered as promising topcoat materials for thermal barrier coatings. However the structural origin underlying their low thermal conductivities remain unclear. In the present study, we investigated the phonon properties of a group of RE pyrochlores, Ln2Zr2O7 (Ln = La, Nd, Sm, Gd) employing density functional theory and quasi harmonic approximation. Through the relaxation time approximation (RTA) with Debye model, the thermal conductivities of those RE pyrochlores were predicted, showing good agreement with experimental measurements. The low thermal conductivities of RE pyrochlores were shown to largely come from the interference between the low-lying optical branches and acoustic branches. The structural origin underlying the low-lying optical branches was then clarified.

Jan 1, 2015

By J K. Irwin

The authors discuss the application of drum and friction hoists under modern conditions and give four examples of friction hoists proposed for various applications. The paper concludes with a summary of the advantages and limitations of friction hoists relative to drum hoists. Introduction T H~ introduction of the multiple-rope friction hoist m the late 1940's has complicated the se-lection of the right hoist for a given job. Once such considerations as rope safety factor, drum to rope ratio, hoisting distance, tons per hour and/or service duty have been decided upon, the selection of a drum hoist is relatively simple. We now ask our-selves "which hoist -drum or friction? (See Figure 1 and Figure 2). When a friction hoist is a possibility we are immediately concerned with how many ropes to use, whether to hoist balanced or counter-balanced, whether a friction hoist will be flexible enough for the application and, of course, what the relative costs will be.

Jan 1, 1964

By I. Ruiz Bustinza, L. F. Verdeja, Daniel Sbarbaro, R. Parra, J. Mochón

The oxidation of sulfides is a complex process involving gaseous products and intermediate species given rise to emission and absorption spectra which carry out important information about the reaction process. This information could be used for on line monitoring of pyrometallurgical reactor if the appropriate sensors were available. We present in this paper an analysis of the concept that has been successfully applied in iron and steel making industry, as well on fuel combustion control, where the spectra measurement gives the possibility for online monitoring and automatic control of high temperature processes. This concept has not been widely applied in the nonferrous pyrometallurgical primary production. The design of new sensors is discussed from the analysis of spectra measurements during flash combustion of copper concentrates at laboratory scale.

Jan 1, 2015

By M. Stogran-Baker, E. Legault-Seguin

"Fluorspar mining in the St. Lawrence area of Newfoundland and Labrador began in the 1930s and ended in the mid-1980s. In 2013, Canada Fluorspar (NL) Inc (CFI) discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods and began developing this resource. This paper discusses the flowsheet development of the AGS vein deposit. Testing at SGS began in 2009 with samples from other deposits in the area. The testwork included pilot-scale dense medium separation (DMS), laboratory-scale flotation tests to develop the flowsheet and a flotation pilot plant. The more recent work that is presented here has been devoted to the AGS vein, and included a variability testing program that gave tremendous insight into the metallurgical drivers of processing the deposit. The ore was found to be fairly variable in terms of fluorite grade, but also gangue mineralogy, which had greater implications on the DMS performance. The gangue mineralogy was also found to significantly impact the grindability characteristics of the DMS product. This paper will detail the testing conducted and the mitigating steps which were identified for the operation.INTRODUCTION Fluorspar is the industrial trade name for the mineral fluorite (CaF2), which is the primary industrial source of fluoride. There are a number of categories of fluorspar, most notably acid-grade fluorspar and metallurgical fluorspar (metspar). Acid-grade fluorspar has stringent specifications and is suitable for the production of hydrofluoric acid that is used for many applications. The typical specifications of acid-grade fluorspar are >97% CaF2 and less than 1% each of SiO2 and CaCO3, with a particle size distribution in the order of 80% passing 100 µm. Metspar is typically used for metallurgical purposes, typically as a flux in smelting, and has significantly more relaxed specifications (< 15% SiO2). The principle source of fluorspar in Canada has been from the Burin Peninsula in Newfoundland and Labrador. More than 3 million tonnes of fluorspar were produced there between 1940 and 1978 and from 1987 to 1990, when production ceased (Fulton & Montgomery, 1994)."

Jan 1, 2018

By I. Tinto

"IntroductionEnvironmental pollution problems, caused by gases or effluents, by high noise levels or from air borne dust, are placing increasing demands of the operators, from statutory authorities, and from the general public, to adopt more stringent dust control measures. This requires that a successful plant dust control program be an integral part of any plant operation. While a successful environmental program is a key factor in maintaining productivity and good labour relations, anticipation of future environmental regulations during the plant design phase can avoid the high cost of plant upgrading, or dealing with pulmonary conditions in the work force in subsequent years.Particulate removal, conventionally called dust collection, involves the removal of coarse- and fine-particulates from the airstream. Although generally limited to that required for contro!Hng plant generated air emissions, particulate control equipment also has a wide application for air cleaning and filtration inside the plant, as well as for recovery of usable products.In the late 1950s and early 1960s the public became more concerned with the problems of air pollution. This increasing concern was stirred by an awareness of the extremes to which water pollution had progressed in many of the rivers and lakes, by increasing perception of air pollution as detected by visible smog and harsh chemical odors, by the alarming rate of increase of smog plagued cities and communities, and by specific incidents where ill health could be traced to specific episodes of air pollution. Particle size is perhaps the most important single factor affecting particulate control. Large particles (over 5 microns) constitute the major mass fraction of most sources of emission and economical control equipment dqes exist for their efficient control. However, while these larger particles frequently represent the source of soiling and unsightly smoke plumes, they are not a major health problem as they tend to settle relatively quickly, are more easily scrubbed from the atmosphere by rain, and are not able to penetrate the respiratory system. By far the most important form of particulate air pollution is the fine particulate, (below 3 microns) which is harmful to the pulmonary system. The adverse effects caused by this particulate matter on human health are for the most part related to injury to the surfaces of the respiratory system. Particulate material in the respiratory tract may produce injury itself, or it may act in conjunction with gases, altering their sites or their modes of action. A combination of particulates and gases may produce an effect that is greater than the sum of the effects caused by either individually (i.e. synergistic effect)."

Jan 1, 1989

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By Lawrence Devon Smith

"The concept of risk is well established in the mining industry. It is acknowledged when estimates of reserves are expressed as proven or probable, when mining and metallurgical recoveries are applied to the ore, and when contingencies are added to costs. However, it is difficult to provide a quantitative assessment of risk. The significant sources of risk in a mineral project and how these are addressed in project evaluations are discussed. The discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.IntroductionThis paper examines the components of the discounted cash flow discount rate and proposes a method of estimating project-specific discount rates. The motivation for this work comes from experience of project evaluations in which owners and purchasers had agreed on virtually every aspect of the evaluation except how much the project was worth. Agreement was reached on reserves, grad~, recovery, capital costs, operating costs, taxes, and, by combining these components, even on the fmal cash flow values. The only difference in opinion concerned the discount rate to be used in the calculation of the net present value. Depending on the life of the project, such differences of opinion can cause a variation of more than 50% in the value placed on a project! This is illustrated in Figure 1."

Jan 1, 2003

By S. W. Marcuson, P. J. Mackey

The Canadian non-ferrous mining and metallurgical industry has made great strides in environmental protection during the past half century. The path taken by the copper-nickel smelting industry in reaching today’s level is traced in this paper. Following the practice at early copper smelters in Wales and in the US, Canadian smelters originally used tall stacks to disperse furnace of-gases. This was the normal mode of operation and was accepted by society and by Government. Gradually, Government regulations required fixation of sulphur dioxide emissions and Canadian companies responded with significant technical developments to achieve this result. The initial development in Canada of the first new technologies such as the Cominco Flash Suspension Roaster and the Freeman Flash Smelting Process - both representing early versions of the modern established flash smelting technologies - and then later technologies such as the Inco Flash Smelting Process and the Noranda Process, both of which continue to this day, are discussed in this paper in terms of their contributions to the development of environmentally friendly plants. The evolution of these and other technologies is also discussed. Some comments regarding how the industry will face the future are also included.

Jan 1, 2015

By N. H. Grace

"IntroductionDURING the past half century, the economy of Western Canada was largely centred on agriculture. However, the impact of World War II has led to an acceleration in the development of a variety of natural resources so that, today, Western Canada is experiencing great industrial development. Consequently, the availability •of low-cost energy assumes prime importance. In the final analysis, industrial growth and expansion are intimately linked to the energy resources.Coal ReservesHas Western Canada adequate coal reserves to meet the present accelerating demand for power in the days that lie ahead? This question must be answered before detailed consideration can be given to the probable patterns •by which various energy sources in Western Canada may be expected to meet the expanding demand. Figure 1 indicates the extent and distribution of the Canadian coal reserves, the data having been prepared by Dr. B. R. MacKay for the Royal Commission on Coal in 1946 (1). The amount of readily recoverable coal is listed as one-half the quantities shown on the chart. It is interesting-to note that upwards of 90 per cent •of the Canadian coal reserves .are located in the three most westerly Canadian provinces. It has been estimated that the coal reserves, at the present rate of mining, would be adequate for about 3,000 years. Consequently, it may be concluded that the coal •reserves in Western Canada •are indeed adequate to meet tremendous energy demands for many centuries. When the oil and natural gas have been exhausted, the great coal reserves will still be available."

Jan 1, 1953

By H. W. Wevers

Fatigue failure and accompanying brittle failure occurs frequently in heavy mining equipment. This paper discusses how fracture mechanics can be applied as a tool for crack control and crack management. Information is provided to determine if particular components are prone to brittle failure. By using existing fracture mechanics formulae, an estimation of the critical crack size can then be made. It is explained that for a successful application of fracture mechanics, both the actual engineering stress in the component and the mechanical properties of the applied material must be known. The importance of toughness at low temperatures is quantitatively illustrated by calculating critical crack sizes at room temperature and at below-zero temperatures. Understanding the possibilities of fracture mechanics will also produce a climate in which the purchaser of equipment can more precisely analyze the relative quality of components with respect to crack tolerance and failure prevention. In this manner, communication between the user and manufacturer of equipment may also become more precise and effective, leading to improved design.

Jan 1, 1977

By Robin N. Adair

Abstract -The Halfmile Lake stratiform volcanogenic massive-sulfide deposit consists of pyrrhotite­ rich breccia-matrix sulfides and pyrite-pyrrhotite-rich layered sulfides that form a laterally continuous sheet stratigraphically underlain by an extensive pyrrhotite-chalcopyrite-quartz stringer zone. Mineralization is hosted by a sequence of felsic pyroclastics and volcanic-derived, fine-grained metasediments. The proportion of volcanic to sedimentary rocks indicates increasing vent proximity from southwest to northeast across the deposit area. Fine- to medium-grained felsic pyroclastics and roughly equal amounts of fine-grained metasediments comprise the stratigraphic footwall to the mineralization. Quartz-feldspar porphyritic bodies cut this sequence and may have provided the heat source for exhalite activity. Felsic tuffs, locally crystal-rich, and lesser amounts of metasedimentary rocks make up the immediate stratigraphie hanging wall. This sequence is stratigraphically overlain and locally interfmgered with matie volcanics that contain substantial proportions of felsic fragments. Deposition of sulfides post-dated the beginning of felsic volcanism, which places the deposit in the middle of the Lower Tetagouche Group. Compositions of the volcanic rocks range from basait to rhyolite and exhibit sub-alkaline affinities. Strongly overprinted whole-rock, trace-element, and REE geochemical signatures resulting from mineralizing hydrothermal activity confirm the genetic relationship be­tween the stringer zone and the mineralized sheet. Large-scale D1 folding has overturned the entire sequence. D1 thrust faults and related sheath-like folds have profoundly affected sulfide distribution. D2 is manifested by a penetrative S2 foliation, and D3 is represented by large-scale open folds.

Jan 1, 1992

By W. A. Lang

"I.-IntroductionAn attempt bas been made in this paper to provide a basis for appraisal of the future of the coal briquetting industry in Alberta by outlining the processes used for briquetting various ranks of coal, by specifying the requirements of a briquetted fuel, by indicating .the status of the industry in the United States, by giving developments in Western Canada, by assessing costs of processing, and by discussing briquetting researches in progress. Much of .the detail bas been omitted since this might mask, rather than reveal, the more important phases of the problem. Reference will be made when possible to published articles where many of the details can be obtained.It should be stated at the outset that, in the writer’s opinion, there are three possible developments in Alberta as regards briquetting: (a) an expansion of the briquetting of the fines of • non-coking and coking coals of semi-anthracite, and of low and medium volatile bituminous rank; (b) the processing of the fines of high-volatile C bituminous coals; and (c) the upgrading of the lower rank high-moisture sub-bituminous coals. Details of the chemical and physical properties of these coals can be obtained in publications of the Research Council of Alberta (1, 2), and of the Fuel Research Station, Bureau of Mines, Ottawa (3).Semi-anthracite and low and medium volatile bituminons coals occur in the mountain areas of Alberta, where, during the upthrust of the Rocky mountains, the coal beds served as the sliding surface. This resulted in the coals being; crushed and consequently they contain a h1gh percentage of fines. In some cases they are high in mineral matter and require to be cleaned before being processed. However, the cleaning of fine coal is both difficult and costly. Both the amount of fines present in the mine-run coal and the amount of mineral matter associated with the coal have increased through the introduction of mechanized mining and through the recovery of coal by stripping operations."

Jan 1, 1950

By T. A. Utigard, S. Pedler

Ilmenite from the Everett deposit in Quebec was characterized both chemically and mineralogically. The sample investigated contained the following main components: 40% Fe2O3, 21% TiO2 and 21% SiO2. The ilmenite grains contained about 20 to 25% hematite intergrown blades, with widths ranging from 2 to 30 \u03bcm. Crushing the sample to less than 0.85 mm led to significant liberation of the ilmenite from the gangue minerals. Gravity separation followed by magnetic separation of this size fraction led to a TiO2 concentrate grading of about 30% TiO2, with a recovery of 94%.

Jan 1, 2010

A newly developed damage model was used in the study of rock fragmentation mechanisms involved in crater blasting. Simulations show that at the detonation of the explosive charge, a crushed zone around the explosive charge is formed due to compressive failure and then a strong pressure wave is sent out forming a pressurized ring that propagates at the dilatation wave velocity. As the pressurized ring leaves the crushed zone, two tensile stress components perpendicular to the radial stress are developed in response to the action of the radial pressure, causing tensile failure and forming a damage zone around the charge. The formation of this damage zone is quite independent of the depth of the explosive charge provided there is no interference by the reflection from the free face. When the pressurized ring reaches the free face, it is reflected there and causes rock failure on the ground surface that forms another damage zone. Under the simulation conditions, it is revealed that the depth of charge is a factor controlling the relationship between the two damage zones. At a depth smaller than the optimum, the two damage zones coalesce into one and there is excessive rock breakage; otherwise, the two damage zones tend to isolate from each other with the increase in the depth of charge. Calculations of fragmentation indicate that the average fragment size increases and the uniformity of fragments decreases when the depth of charge increases as observed in practical blasting.

Jan 1, 1998

By D. C. Peck, James. R. S., Chubb. P. T.

"Abstract -The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered matie intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendritic­ pegmatitic matie pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and mag­ matie breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to lOOJo within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that af­ fected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd :Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Severa! factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic inter­ action with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion .The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril&apos;sk-Talnakh region, Siberia; Duluth Com­ plex, U.S.A.) in terrns of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economie concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginal­ type POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953