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The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008

The preferred alternatives in heap design and their motivation are identified as- -normal heap leaching, to be generally applied wherever possible, - flooded vat leaching, to be appliedwhere wetted ore lacks adequate cohesion or if limited space necessitates it,- thin layer leaching, to be applied where deleterious vat chemistry necessitates it.A number of the following features would probably be incorporated in the optimization of normal local heap leach operations- pre-cyanidation - pre-agglomeration - retaining walls- staged (counter-current) heap treatment- control of calcium levels- reduced pH and trickler irrigation

Jan 1, 1984

Intensive exploration for iron ore in the banded iron-formations (BIF) of the Pilbara region of Western Australia began in the early sixties and almost immediately established the Hamersley area as a major iron province. The early genetic models for the BIF-hosted ores were based mainly on macroscopic examinations of ores from the "hardcap" zone, and generally accepted a direct relationship with weathering effects on a Mesozoic to Tertiary land surface. Brandt (1964) was the first to suggest a difference in age between the high-grade hematite ores and the more common hematite-goethite types. He initially accepted a supergene origin for both, but later opted for a hydrothermal origin for the hematite ores. Apart from MacLeod (1966), the published views of the next decade reflect a largely parochial interpretation of individual ore bodies, centred mainly on supergene models but with some support for hydrothermal concepts. Except for Ayres (1971), none of the models were backed by detailed mineragraphic data. In 1976, an AMIRA-sponsored CSIRO group began a Province-wide investigation of the wide variety of ore types and BIF, with emphasis on geochemical and textural studies. The resulting conceptual model for a world-wide unified supergene and supergene-metamorphic hypothesis is generally accepted in the Hamersleys.

Jan 1, 1986

By Yoon R-H, Luttrell GH

A theoretical model has been developed to predict the probability of particle collection by air bubbles in a quiescent flotation pulp. The model considers the effects of both hydrodynamic and surface chemistry forces acting during the bubble-particle interaction. Hydrodynamic forces considered include the gravitational, buoyancy, streamline and film thinning resistance forces. The surface chemistry forces considered include the electrostatic, dispersion and hydrophobic forces. The hydrophobic force has been estimated from extended DLVO theory. The model is capable of predicting hydrodynamic and surface chemistry conditions under which bubble-particle adhesion is possible. Validity of the model has been verified experimentally.

Jan 1, 1993

By Eren H

For a hydrocyclone of fIXed geometry, DC, Di, DO and ? are constants, the variable parameters affecting the performance are Qi, Fi, Du and H. (See Appendix 2 for definition of symbols).The relationship between d50c, Qi, Fi, Du and H gives models which can effectively be used for performance predictions. Such models have already been established by Lynch et al and by Plitt.These models have been tried in a limited manner under continuous operating conditions for on-line cowol. For on-line control effective and accurate instrumentation is required for which a new set up is proposed. Using this set up, a new model was established. A feature in this model is that deviations from the norm of operational parameters affecting d50c were considered. It is shown that these deviations generated by the disturbance of one or more of variations in the parameters, can be monitored by a computer and suitable signals generated to control servo mechanisms for restoring the required d50c value.The logic followed in developing the computer software is described and the application of the model is indicated.

Jan 1, 1990

By D Gericke, R Cooke

This paper presents an assessment of the status in design and operation of deep level backfill distribution systems by referring to case studies and practical experience. The improvements in design and operation of the systems can largely be attributed to an improved understanding of slurry flow behaviour and a corresponding integrated design approach that includes slurry flow modelling, system design and application of the latest technology. The conclusions summarise the lessons learnt from such case studies and stresses the importance of design reviews and audits of existing systems as a means to ensure that the mistakes of the past are not repeated in the future.

Jan 1, 1998

By Adeloju S, McQuade CV, Riley SJ

Metal contamination of sediments can be an issue for minesites discharging water. Water sampling of receiving waters is frequently undertaken. Sampling and analysis of sediment is less common. The variability of receiving environments makes the formulation of a generic sediment sampling strategy virtually impossible. Each situation needs to be carefully assessed before sampling is undertaken. This paper outlines the approach taken for one such survey.The main factors that need to be considered in a survey of surficial sediments are sample representativeness and sample variability. A simple data set from one site within a regional survey is used to illustrate the importance of these factors. The metal content of sediment is shown to vary significantly over small spatial scales.The variability associated with the spatial distribution of samples within a site is shown to be the most significant source of variability in the study. This variability could bias the results of a study if not planned for in the sampling methodology. Taking multiple samples from within each site (sub-site samples) and combining the data gives a more representative indicator of overall conditions than a single sample. The optimum number of sub-site samples to be taken from each sampling site was found to be 15.It is shown that a composite of sub-site samples can give a good indication of the average site metal content, while considerably reducing the sample preparation and analysis effort.

Jan 1, 1998

The high-shear colloidal mixer is generally recognised as the most efficient method of mixing cement based grouts. Only recently however has this technology been applied to the production of cemented rockfill (CRF) for use in underground mines in North America. Traditionally, paddle type mixers have been used to produce the cement based slurries required for the preparation of CRF. While considerable success has been achieved with these mixers, tremendous advantages are attained with the colloidal mixer. The combined effect of the highly efficient mixing action and the ability to mix low water/solids ratios, allows for reductions in the cement content for a given strength requirement. Cement can also be replaced by cheaper fillers such as flyash, resulting in further cost savings. Although large-scale dedicated CRF batching plants are typical, there is a growing need for mobile plants capable of operating anywhere underground. The compact size and rapid batching speed of high-shear colloidal mixers has allowed them to be incorporated into skid mounted systems capable of producing and discharging cement based slurries onto rockfill aggregate for the production of CRF. In many cases run-of-mine development waste can be used as CRF aggregate with these slurry plants thereby reducing the cost of waste rock removal. These relatively low cost portable plants have now allowed several mines to economically recover isolated pillars and realise positive returns on their investment.

Jan 1, 1998

By Nelson G

The construction and placement of tunnels by means of jacking is continually advancing. This paper presents an outline of the construction of a major highway tunnel placed by a combination of mining and progressive placement by hydraulic jacking of precast units. Features of the project were the relatively shallow ground cover between rail and road routes over the tunnelling and jacking operations and also the weight of tunnel sections to be moved into position.

Jan 1, 1993

This paper will examine the prospects for Queensland's non-fuel mineral industries as we approach the 21st century. The opportunity for growth is unprecedented. Exploitation of recent discoveries, proposals and developments in downstream processing are predicted to contribute to a doubling of the State's mineral exports to around $10 billion by the year 2000. In 1995 - 96 the value of Queensland's mineral production was $6 billion, comprising $1892 million metallic minerals, $127 million non-metallic minerals and $4 025 million total fuel minerals. For many years Queensland has been among the world's major producers of copper, silver, lead, zinc, bauxite and mineral sands. Recently Queensland has become an important producer of magnesia. Queensland's ability to compete results from its location close to rapidly developing Asian markets, the diversity of its major minerals and an increasing ability to add value to the resources base using competitively priced energy. Northwest Queensland is one of the richest base metal provinces on earth following the recent discovery of five world-class orebodies. Of these deposits, Osborne (copper-gold) has commenced production and Cannington (silver-lead-zinc) and Ernest Henry (copper-gold) are scheduled to be developed by 1997. Century Zinc Limited and the Queensland Government are negotiating with native title claimants on the development of Century (zinc-lead-silver). Expansion is in progress at the Mount Isa copper mine (renamed the Enterprise) and copper smelter and a high analysis fertiliser project may be developed based on Phosphate Hill. Korea Zinc Company Limited has reached agreement to construct and operate a 350 000 Mtpa zinc smelter/refinery near Townsville. There are future expansion prospects for the vertically integrated major industrial mineral operations based on Weipa bauxite and Kunwarara magnesite. Upgrading of the Boyne Island aluminium smelter will require a doubling of alumina consumption. Downstream processing options for Kunwarara magnesite are being investigated and are expected to lead to increases in production and the manufacture of a range of value-added products. At the Yabulu refinery near Townsville, nickel and cobalt production using imported ore is to be increased and a commercial cobalt plant is to be built. Additional opportunities for further processing and manufacturing are associated with proposed new mines at Ely (bauxite), Skardon River (kaolin) and Goondicum (ilmenite). Recently discovered resources of zeolite and perlite also offer exciting development possibilities. Other manufacturing opportunities such as glass and ceramics based on local and plentiful clay and silica sand could replace imports. Silica sand at Cape Flattery is currently exported and production is expected to double.

Jan 1, 1997

The occurrence of metallic minerals in Australia to the time of the proclamation of South Australia as a Colony in 1836 was unknown. It is, therefore, perhaps, surprising that British settlers arriving in the Coromandel included among their number a German scientist Johannes Menge who had been appointed by the South Australian Company to the post of Mine and Quarry Agent and Geologist on 1 July 1836. His instructions were to `explore the natural productions of the Colony above and below ground and to superintend the working of quarries of stone and slate, the boring for water, metal, lead, coal and other mines at a salary of ú150 per annum for one year and for as much longer as the Company require your services not however exceeding five years'. In the event, he was to have little influence on those matter.

Jan 1, 1993

Chlorine as a lixiviant for gold possesses a number of significant chemical and Idnetic advantages over cyanide but because of its corrosive and vaporous nature the method of implementation needs to be significantly modified. At comparable reagent concentrations the dissolution rate for gold in the C12/Cl- systems is some 10 - 100 times that achieved in the 02/CN system. The dissolution rate in the chlorine system is largely a function of the concentration of C12, Cl- and pH. Under conditions of low Cl', (less than 50 g/1), the dissolution rate begins to drop off dramatically over the pH range from 3 - 4. Increasing the level of dissolved chloride ions shifts the pH of this rate reduction to around pH 5 at 100 g/l NaCl, and to around pH 6 at 300 g/l NaCl.

Jan 1, 1991

The Fraser Range is composed dominantly of basic pyroxene granulites derived from basalts, many of which appear to have been vesicular and*pillowed. Acidic and basic garnet-bearing granulites are important in the west, and acidic granulites and narrow anortho- site layers are dominant in some regions east of the Fraser Range. An extensive flat-lying olivine gabbro sheet cuts the granulites, and in places has been converted to spinel-bearing meta-gabbros and pyroxene granulites. The granulites of the Fraser Range (Proterozoic) are separated from the gneisses and schists of the Goldfields regions (Archaean) by the Fraser Fault, over which there is a large gravity anomaly (gradient 20 milligals per mile). Some of the problems associated with the concentration of Cu, Ni, etc. liberated from mineral lattices during metamorphism, and other principles of metal concentration in granulite terranes, are discussed. The recognition of vesicular and pillowed zones, even though highly metamorphosed, is of fundamental importance.

Jan 1, 1969

By Tozawa K, Nishimura T, Sasaki K

Liquidus surfaces in a part of the systems ZnO-PbO-Si02 and ZnO-"FeO"-SiO 2 were constructed by the quenching method. The ex- periments were carried out in air in the system ZnO-PbO-Si02. In the part investigated the primary phases were three ternary compounds (PbO.ZnOòSiO2, 2PbOòZnO.2SiO2 and barysilite), three lead silicates, Zn2SiO4 and SiO2. Iso- therms on the liquidus surface of each primary phase field were determined from 750 to 1300¦C. In the system ZnO-"FeO"-SiO 2 the experiments were carried out in an atmosphere of purified nitrogen. In the part investigated the primary phases were Fe2SiO4, Zn2SiO4 and Si02. Iso- therms on the liquidus surface of each primary phase field from 1150 to 1300¦C and the ternary eutectic (1130¦C, 15.9% ZnO, 48.2% "FeO" and 35.9% Si02) were determined.

Jan 1, 1980

The techniques originally developed to process digital images of Mars, later gained widespread acceptance when applied to Landsat data: they are now making a significant impact in fields of geology outside remote sensing. The three ingredients of success are seen to be firstly, the perceptual attributes of image displays and the use of colour; secondly, the absolute ability to register data from a variety of sources; and thirdly, the speed of specialist "interactive" digital image display systems. The future lies in further exploiting these attributes through a Geographic Information Systems (GIS) approach to data handling, integration and display.

Jan 1, 1986

By Fowler T. J

Examples are provided of discontinuity analysis at selected sites in central Victoria. Discontinuities are rock fractures of low tensile strength, including bedding, foliations and joints, which are analysed during rock excavation design, to quantitatively determine the defect orientations, spacing and lengths. Their analysis can reduce the cost of mining operation and improve safety. Extrapolation beyond the exposed face is required, although difficult without an understanding of the regional geology. For rock engineering purposes assumptions are commonly made that discontinuity characteristics are uniform throughout the rock mass, however this is often invalid, as rock masses have usually undergone large-scale deformation, exhibit anisotropy and inhomogeneity. Structural geologists are able to interpret large-scale deformation responses for the purposes of structural correlation and extrapolation. Examples of discontinuity analysis linked to regional geological assesment from sites in central Victoria, reveal that discontinuities exhibit similar characteristics in a range of rock types of different ages and composition. Spacing variations between individual sites are believed to be a result of local rock type differences.

Jan 1, 1997

In the past ten years or so there has been a renewed interest worldwide in the processing of refractory gold ores. The Archean province of Western Australia contains both numerous and major gold deposits, and has a long history in the development and practise of treating refractory ores (eg Blaskett and Woodcock, 1953). Depletion of shallow oxidised ores in recent years has re-focused attention on deeper sulphidic ores, and as a consequence has renewed interest in treatment methods for those ores which are refractory. Mineralogical factors he at the heart of reasons as to why these ores are refractory, and are the key to designing and improving treatment options in the longer term. This paper presents an overview of mineralogical factors that are relevant to the processing of refractory gold ores in the Archean of Western Australia. It is based on a number of research projects and other work on a variety of gold deposits, mainly in the Eastern Goldfields region, carried out over the past five years or so.

Jan 1, 1991

The recent installation of top gas temperature probes in blast furnaces at Australian Iron & Steel Pty. Ltd. - Port Kembla, has provided the means for studying radial gas flow distribution in blast furnace shafts. This paper describes the top gas temperature probes and outlines their development and results of initial studies aimed at obtaining a suitable relationships between temperature profiles and furnace parameters. The effects of various combinations of burden materials have been outlined by the results reported. The use of probes has also helped to clarify the effect of casting cycles on furnace operation leading to increased emphasis on the reduction of the interval between gun-up and drill-out. Areas for future studies are also broadly Outlined.

Jan 1, 1975

The Olympic Dam copper-uranium-gold-silver deposit, located approximately 520 km north-northwest of Adelaide, South Australia (Figure 1) was discovered in 1975 by Western Mining Corporation. A joint venture to facilitate development of the deposit was formed in mid-1979 between WMC (51 per cent) and the British Petroleum Group (BP, 49 per cent). Production commenced in 1988, and current annual output from the mining and treatment of 2.2 Mt of ore is approximately 65 000 t of refined copper and 1400 t of uranium oxide. Significant amounts of refined gold and silver are also produced.

Jan 1, 1993

A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990