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By S Z. Petho

The South Deep surface shaft system is being sunk to a final depth of 2750 m below surface and on completion will be the deepest single drop shaft in the world. The shafts will intersect the target reef horizon at 2650 m below surface. In order to negate the requirement for a shaft pillar, which would be extremely large at this depth, the reef horizon in the vicinity of the intersection is currently being mined. A high quality crushed waste/classified tailings backfill is being placed in the longwall stoping panels around the shaft intersection area. This will limit closure and ride which following shaft reef intersection could have a detrimental effect on the long term shaft stability. This paper discusses underground instrumentation results and numerical modelling exercises carried out to confirm that the shaft system will be stable throughout the life of the mine. Instrumentation projects include closure and ride measured between backfill paddocks and haulage leveling exercises carried out to determine the far field rockmass response to mining with stiff backfill. Results from the numerical modelling exercises show good correlation with measured data. This indicates that a high degree of confidence can be placed in the model input parameters and consequently in the design of the shafts to ensure their long-term stability.

Jan 1, 1998

By Hustwick I

New Zealand Steel Mining Limited operates two independent sand mining operations on the West Coast of the North Island of New Zealand. (Fig. 1)Waikato North Head 30km south of Auckland supplies ironsand concentrate as the raw feed for New Zealand Steel's works at Glenbrook, and Taharoa 70km further south, exports ironsand concentrate to Japan. Taharoa uses two sets of six low pressure Warman centrifugal pumps in series to load bulk ore carriers 3km off shore through two underwater pipelines.Waikato North Head delivers the ironsand to Glenbrook l8kms through a 200mm ID buried pipeline using two stages of high pressure positive displacement (HPPD) pumping.A high level of operating and maintenance expertise has been developed since commissioning the two systems which are proving to be reliable, efficient and of minimal impact environmentally.

Jan 1, 1990

By Eupene GS, Cheong GE

Operations at the Mount Bonnie gold/silver project are described. The project is based on the gossan of a stratiform and stratabound polymetallic sulphide deposit. The gossan contains approx- imately 100 000 tonne of ore grading 8g/tonne Au and 230g/tonne Ag. This is mined in an open cut, and transported to a stockpile area lkm away, from which it is fed to the treat- ment plant. The ore is crushed through two stages and fed to a fine ore storage shed, from which it is reclaimed, milled and cyanide leached in draft tube agitators. The pulp is filtered using a horizontal belt filter to recover a pregnant solution. Silver sulphide is precipitated using sodium sulphide solution, and collected as a mixed sulphide/precoat concentrate on a drum filter. The solution is then passed through carbon columns where the gold is adsorbed and is subsequently recovered by methanol desorption using a process developed by Micron Research, and electrowinning. Modifications to the treatment plant circuit based on operational experience are Described.

Jan 1, 1984

By McDougall I, Claoue-Long J

A combination of high precision 40Ar/39Ar and U-Pb dating has been used to determine the age of hydrothermal minerals and host rocks in a number of Lachlan Fold Belt (LFB) gold deposits in New South Wales, Au4 ralii In particular, this investigation demonstrates that the UAr/ Ar technique of K-Ar dating can be used to determine the timing of mineralization in Palaeozoic systems.A close temporal link between mineralization and Late Ordovician to Early Silurian magmatism is indicated by the dating work. Hydrothermal sericite from the Goonumbla p8rph gy Cu deposit and Glendale Au prospect yieldsAt/ Ar step heating ages between 437.9 ¦ 1.1 and 441.2 ¦ 1.1 Ma (16), and4 minjrnum age of about 425 Ma has been obtained by Ar/ Ar dating of hydrothermal amphibole from the Browns Creek Au-Cu skarn deposit. Hydrothermal aluniI8 frog the Gidginbung epithermal Au deposit yields reset 44 Ar/ Ar ages of 401.0 ¦ 1.3 to 417.3 ¦ 1.3 Ma (16). U-Pb dating by ion microprobe on magmatic zircons from the vicinity of the Goonumbla and Gidginbung deposits gives ages of 438 ¦ 3.5 Ma (2 6), and 435 ¦ 2.5 Ma (2 (7) respectimly, W a minimum age of 435 Ma has been obtained by Ar/ Ar dating of magmatic phases from volcanic rocks adjacent to the Browns Creek skarn deposit. Magmatic episodes near the Sheahan-Grants gold skarnpost give ages of 479.2 ¦ 1.1 and 467.9 ¦ 4o1 by 'Ar/ 9Ar dating of magmatic amphibole. Most Ar/3yAr age spectra show the effects of partial Ar loss at between 360-420 Ma, probably due to heating caused by granitoid emplacement.The radiometric dating work in this paper suggests a restricted metallogenic epoch in the Late Ordovician-Early Silurian LFB, NSW, of similar duration to that found in the Andean margin and the western Pacific island arcs around the Pacific Rini.

Jan 1, 1990

Controlled Source Audio Magnetotelluric (CSAMT) surveys were carried out by Glass Earth (New Zealand) Limited (Glass Earth) in 2006 - 2007 to investigate epithermal gold targets in the central North Island of New Zealand. The surveys were conducted using a Zonge GDP 32 8-channels receiver and a Zonge XMT 32 transmitter powered by a 16 KW generator. The electric field dipole was maintained at 20 m length (five dipoles per 100 m spread) and the frequency ranged from 4 KHz to 4 Hz. Only scalar (TM mode) signals were recorded, using one magnetic coil per spread. The transmitter bipoles were 1 - 4 km in length and located about 5 to 10 km from each survey area.   Sixteen individual target areas were surveyed by June 2007. The CSAMT survey lines (100 - 400 m spacing) were determined mainly on results from previous ultra-detailed airborne magnetic and gravity surveys conducted by Glass Earth in 2005. The data from each CSAMT line was carefully examined to remove any spurious signals and processed using Zonge SCS2D software, which can produce smooth 2D resistivity inversions of the field data. The results were presented as resistivity sections and maps to help the identification of exploratory drilling targets, mainly from the existence of subsurface high resistivity zones (resistors) that can be interpreted as caused by silicification associated with epithermal mineralization.   An example of processing and interpretation of the CSAMT data is presented in this paper on results from Glass EarthÆs Tahunaatara target, where CSAMT surveys have identified zones of epithermal mineralization confirmed by exploratory drilling.

Jan 1, 2007

Attempt has been made to determine the nature of charge on activated carbon surface by studying the electro-kinetic properties of the carbon in the presence of cations, anions and aurocyanide solutions. The zeta-potential measurements were made in the presence of individual ions and also in combinations. The cations and anions chosen were those commonly associated with gold bearing ores in Kalgoorlie area. It was found that the iso-electric point of Norit Carbon was at pH 4.45; below this pH the charge was positive, while above, it was negative. In the absence of gold cyanide solutions and in the presence of individual cations the i.e.p. shifted to the alkaline range (pH 7.2-8.5) while in the presence of anions the i.e.p. was shifted to less than pH 3.5. In the presence of aurocyanide solutions, the iso-electric point was still in the acid region irrespective of whether anions or cations were present. The probable mechanism for such a behaviour has been attempted after measuring the specific conductivities of solutions before and after gold adsorption, by studies using the electron- probe-mirco-analyser, and S.E.M. on the carbon surface.

Jan 1, 1982

By M, C A. RosiFre, R C. Figueiredo e Silva

Jaspilites and underlying basalt contacts of the Archaean volcano- sedimentary Grpo Parß Group, Carajßs, host giant iron mineralisation in the ~100-km long, E-W trending Carajßs fold. Preliminary, unpublished geochronological data point to a Palaeoproterozoic mineralisation event. Geochemically, jaspilites are typical volcanogenic banded iron formations. Basalts exhibit evidence of spilitic seawater interaction. Iron-associated hydrothermal alteration of mafic rocks was induced by fluid infiltration in amygdales, with development of chlorite- and hematite-dominated zones. In the case of jaspilites, iron mineralisation encompasses: partial replacement of jaspilitic microcrystalline hematite by blasts of martitic magnetite; jasper recrystallisation, producing fine-grained, hematite-free granoblastic quartz; martite recrystallisation, forming lobate¦subhedral hematite; pervasive porosity development by quartz-chert leaching; incipient cavity filling by microlamellar hematite; and advanced filling by coarser, euhedral and comb-textured, tabular- shaped hematite.Peak hydrothermal ore textures indicate typical epithermal-crust conditions, supported by preliminary fluid-inclusion calculations at 160 - 200¦C. Such temperatures and extreme fluid-to-rock ratios during alteration must have exceeded the ambient metamorphic conditions, with the infiltrating fluid relatively hot and capable of leaching SiO2. Therefore, mineralisation developed over exhumed, Archaean, brittly deformed rocks, with mineral associations representative of very low- to low-grade metamorphism. Considering that chlorite (¦talc) abounds in mafic rocks; hydrothermal albite is developed; dolomite fills veins and vugs; the typical rare-earth-element (REE) pattern of jaspilites is significantly modified in higher-grade hard hematite ores (higher LREE); pyrite, copper sulfide minerals and rare gold occur in association with carbonate-quartz-rich alteration zones, it is suggested that an alkaline, H2O-Fe-CO2 mineralising fluid dominated, also containing species like S¦Cu¦Au. Peak-mineralising conditions are likely to have resulted from a single, evolving fluid, via incipient- through advanced-stage alteration phases. The porous, high-grade soft hematite-type ore (SH), rich in microlamellar and anhedral hematite, must have derived from interaction with this relatively hot SiO2-leaching fluid, whereas the high-grade massive hard hematite-type ore (MH) developed due to closer fluid-rock temperature equilibrium conditions, attained by mineral reactions, with relative increase in the Fe/Σcations ratios allowing the precipitation of subhedral-tabular hematite that partially cements the soft-hematite ore. SH and MH hematite ore types must thus reflect intermediate and high fluid:rock ratios, respectively. Since the N5 deposit is to date understood to contain the largest amount of the MH ore, its units are interpreted as the loci of the highest fluid:rock ratios in the district. Preliminary mineralogical information regarding the S11 deposit of the Serra Sul (south range) implies higher-temperature conditions. The near-equant grain size and the granoblastic intergrain relationship, coupled with the presence of riebeckite, augitic pyroxene and garnet, suggest hornfels textures. The data collected, though still relatively sparse, permit the speculation that the immense driving force for the Carajßs world-class iron deposits was a relatively shallow, igneous-related hydrothermal system. If such a model is correct, then the Carajßs Palaeoproterozoic iron deposits could represent an end-member of the iron oxide-copper-gold hydrothermal system in the province.

Jan 1, 2005

Historical exploration of the Ballarat East goldfield defined two primary quartz vein lode types. Tracking the intersection of these lodes with vertical lines of enrichment (or so-called æindicatorsÆ) was the basic practice for historical mining. This strategy proved highly successful in terms of identifying quartz veins associated with mineralisation. However, it provides little understanding of the timing or processes involved in the formation of these veins, or the associated emplacement of gold. Current underground mapping shows the Ballarat East gold deposit can be subdivided into four stages of vein formation. The earliest veins (V1 and V2) strike north-south and formed during bedding flexural slip and limb thrust fault propagation in parasitic chevron folds. V3 veins are subhorizontal and relate to further fold tightening involving a transition from east-west compression to north-south extension that initiated re-shear of bedded slip surfaces and additional strike-slip faults. Sporadic V4 veins overprint the shallow-dipping sections of V2 and V3 veins and are associated with weak north-south compression. The V4 veins mineralogy is distinguished by a high carbonate content and sphalerite-galena sulfide assemblage. Vein sampling indicates a significant increase in gold mineralisation where overprinting by the later deformation/veining has occurred. As a result of these observations, a new model is emerging that identifies the chronology, structural control and spatial distribution of respective quartz vein types. This is a major advance in terms of exploration targeting, resource modelling and mine planning.

Jan 1, 2008

The Jacobs Sliding Floor (Floor) is experiencing a surprisingly long competitive life. The first Floor was used on the Camino Tunnel in California in 1960. At that time the Robbins Company had built only seven TBMs, and the future for such machines was considered doubtful by many, as compared to drill and blast methods. This was then, and still is, commonly called the "conventional" method. Robbins' TBM No. 8 was for the Hydro Electricity Commission of Tasmania (HEC) for their Poatina Hydro Project in 1961. In this writer's view, the Poatina experience was the start of successful hard rock boring machines. But, by coincidence, the HEC is using the newest Floor for their King River Hydro project, where driving with the Floor started in July 1986 on the King Tunnel. This paper examines the history and developments in both Floor design and other "conventional" tunnelling equipment, and the site specific conditions that have allowed this old concept to still be competitive in certain select situations. Parametric costing data and some actual progress records are included.

Jan 1, 1987

By C Moorhead, J Jones

A common problem in the mining industry is that company geologists can operate in relative isolation to the rest of the company (Jones and Moorhead, 2011). This may result in poor knowledge transfer and often priority conflicts with geology, operations and project departments. This problem is amplified by the acquisition of mineralogy capabilities and other metallurgical (met) test work undertaken by many companies in order to solve for complex orebody problems. Met data is often not located and viewed in 3D space so that geologists and engineers can create and work with geometallurgical (geomet) models (Bye, 2006). Visualisation of data in an interactive graphical 3D model provides a bridge enabling met professionals to collaborate with engineers and geologists to provide a common understanding of the relevance of geomet data.In recognition of this problem, Newcrest has undertaken an effective collaboration strategy to improve internal and external engagement through the use of large visualisation displays (Jones, 2009). The displays are underpinned by IT systems and information management practices that recognise the needs of underlying disciplines. Today it is generally understood within Newcrest that this is required to improve decision-making, deliver faster cycle times and improve governance.Collaboration in companies has been generally associated with the introduction of new IT functions (IBM, 2008). However, the science and engineering process that are used to structure modern IT-based collaboration systems and practices are now known to be simplistic compared to the long-standing practices associated with collaboration and knowledge management in disciplines such as geology and mining.CITATION:Jones, J and Moorhead, C, 2013. Geometallurgical communication as a distributed information system, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 133-138 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By I Brandes de Roos

Water has played a key role in the Pilbara’s 60-year history of iron ore operations. In contrast to many of the current-day mining environments, iron ore mining was initially hosted by geological formations that were typically above the water table. Such mining operations required no dewatering or dewatering at rates that were less than mine and mining township requirements. The challenge for these operations was not pit dewatering but water supply for mining operations and municipal supply for nascent mining towns.The current industry sees new deposit styles being increasingly targeted, including channel iron and Marra Mamba Formation deposits. These deposits are often lower in the landscape and can require extensive dewatering. Furthermore, increased water demand for ore beneficiation has resulted in major programs of water-supply borefield development. Added to this is the emergence of magnetite projects and their significant levels of water use in ore beneficiation.The large volumes of water that are being extracted to support Pilbara iron ore mining is attracting attention. The Western Australian Department of Water has recently commissioned a study to assess the potential use of surplus mine water as a medium- to long-term supply for irrigated agriculture.This paper outlines the changing landscape of water management in Pilbara iron ore operations and explores strategies for maximising mining productivity. Water management is presented as an enabler for productivity improvements that can potentially provide long-lasting benefits post-closure.CITATION:Brandes de Roos, I, 2015. Shifting waters in the Pilbara’s iron ore industry, in Proceedings Iron Ore 2015, pp 507–510 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By D K. Miller, L W. Armstrong

In April 2006, Orica Quarry Services undertook an investigation to determine the likely vibration and frequency response of three water storage tanks to quarry blasting, immediately adjacent to the tanks. Of the three tanks that were studied, two are relatively tall with a æwineglassÆ shape; one is constructed of steel (4 ML storage capacity) while the other is constructed of concrete (2 ML storage capacity). The third is a ground-embedded concrete tank that is relatively squat and broad in shape (38 ML storage capacity). A vibration limit of 25 mm/s and an acceleration limit of 0.16 g were imposed on the tanks. However, this report shows that this acceleration limit, whilst having relevance to low frequency earthquake motions, is quite inappropriate for the high frequency blast vibrations that are typical in a quarry blasting environment. The investigation involved firing 11 single blastholes of known charge weights and distances from the tanks, and measuring the tank vibration response using blast monitors placed on and around each tank. Analysis of the data collected from the cement tanks showed resonant responses over a broad range of frequencies, with dominant and lesser responses in vertical and lateral motion recorded at 9.8 Hz, 12 Hz, 16.8 Hz, 17 Hz, 31.3 Hz and 38.1 Hz. Unfortunately, most of the data collected on the steel tank was corrupted by noise due to electrical sources and/or mechanical sources such as the water agitator inside the tank. Advanced Monte Carlo vibration models were then constructed using the single blasthole information. Knowing the resonant frequencies enabled the modelling of electronic delay sequences for the reduction of resonant vibrations. Ultimately programmable and accurate electronic delay detonators were deemed essential to allow blasting in relatively close proximity to the tanks while avoiding resonant frequencies. Three blast designs were modelled, ranging in maximum instantaneous charge (MIC) from 4 kg to 22 kg, and 60 holes to 160 holes. The modelling showed that two of the designs (using small charge weights) could be used no closer than 71 m from the storage tanks. This is based on a 90 per cent confidence level of achieving vibration levels within the 0.16 g acceleration limit, even though the velocity levels predicted to be generated at this distance were significantly less than the 25 mm/s limit. The third design incorporated larger charge weights and could be used for blasting at distances no closer than 220 m from the tanks. The present work, conducted in an operating quarry, demonstrates the usefulness of Monte Carlo waveform superposition techniques for the control and reduction of ground vibration (either velocity or acceleration) under restrictive environmental constraints. However, a discussion is also presented to demonstrate that it is somewhat restrictive to impose an acceleration limit based on the motion produced by low frequency earthquakes rather than the motion produced by high frequency blast vibrations.

Jan 1, 2007

The purpose of this paper is to discuss briefly the problems encountered in designing and sinking No 7 shaft, and to present the methods employed in the operation.The illustrations accompanying the paper show the details of the construction of the equipment used in completing No 7 shaft, consequently the descriptions appearing in the text are brief outlines only. Mineral leases Nos 7 and 8, held by the Broken Hill South Limited, comprise an area of 69.5 acres. The length of the holding is approximately 2500 ft.The western orebodies, which are the main producing masses, enter the property at the northern bonndary. Generally, the dip of the orebody is to the west, and the pitch to the south, but local variations occur and even a reversal of pitch has been noticed. The angle of dip is approximately 70 degrees and the angle of pitch 45 degrees.

Jan 1, 1932

In the new refinery, at the works of the Broken Hill Associated Smelters Proprietary Limited, situated at Port Pirie, South Australia, the refining routine is similar to that carried on in the old one in that bullion is progressively refined first for arsenic and antimony, then for copper and gold, then for silver, and finally for zinc. However, actual procedure differs in that each refining operation is now conducted continuously, whereas in the old refinery intermittent batch treatment was practised.The early experimental work was concerned solely with the development of the continuous desilverising process, which, in addition to continuous treatment, embraces the novel feature of conjugate solution formation with consequent production of a silver product relatively high in silver and low in lead.

Jan 1, 1932

The Kidston breccia pipe is situated approximately 280 km west northwest of Townsville, north Queensland. It is currently Australia's largest gold producer with production varying between 8,000 and 16,000 tonnes of ore per day. Current reserves are estimated at 36.2 million tonnes averaging 1.74 C/t Au and 2.21 g/t Ag. Alluvial gold in the gullies surrounding the deposit was first discovered in the 1880's and between 1907 and 1948 small scale open cut and underground mining was undertaken. Advances in extractive metallurgy and an increase in the gold price were major factors influencing the recent exploration and development of large scale mining of the deposit by Placer Pacific and Kidston Gold Mines. The breccia pipe is trapezoid in shape with surface dimensions of 1100 m by 900 m. Clasts show only limited evidence of mixing during brecciation, with the pre-breccia stratigraphy still discernible on the basis of clast types. This lack of mixing together with the intimate association with intrusive activity, suggests that the brecia formed by collapse, probably associated with the escape of a large volume of irothermal fluid from a crystallising hatholith. Mineralisation and alteration are also sratially and temporally associated with rhyolite emplacement and brecciation. Pre-breccia mineralisation consists of laminated stockwork quartz veins associated with muscovite, quartz and orthoclase-epidote alteration. Stockwork veins contain either anomalous molybdenite or gold. Uneconomic early stage post-breccia mineralisation and alteration consists of cavity infill quartz-epidote and calcite associated with potassic and propylitic alteration respectively. Economic late stage post-breccia cavity infill and sheeted veining consists of quartz-carbonate-sulphide infill associated with phyllic alteration. The grade of gold mineralisation generally decreases downwards in the system with an increase in the amount of pyrrhotite relative to pyrite. Pre-breccia stockwork quartz veins mineralisation is genetically related to the

Jan 1, 1987

By McGaffin I, Loah J

PT Newmont Minahasa Raya (PT NMR) is an Indonesian joint venture subsidiary of the Newmont Gold Company of Denver, Colorado, USA. PT Newmont Minahasa Raya operates a 700 000 tonne per annum gold plant in the Minahasa region of North Sulawesi, Indonesia. At full capacity the plant is expected to produce an average of 150 000 to 180 000 ounces of gold per year until the year 2007 based on current existing reserves.Exploration began in 1986 and high grade mineralisation was discovered in 1988. Subsequent drilling defined a resource of approximately 2000 000' ounces. Reserves as of 1 January 1997 were 7 035 000 tonnes grading 8.46 grams per tonne, for 1 913 000 contained ounces. Metallurgical testwork commenced in 1991. Construction of the plant started in late-1994 and the first gold was poured in March 1996.

Jan 1, 1997

The Matakan Unit of New Ireland, Papua New Guinea is a highly fossiliferous lagoonal deposit containing numerous coal pods and lenses. The unit is strati graphically part of the massive reefal Lelet Limestone of Miocence age. These organic-rich sediments have a high hydrocarbon potential as evident from microscopical observations as well as Rock- Eval pyrolysis data. The coal is varied in regard to dominant macerals, vitrinite being predominant in some parts and pollen and spores present in sufficient proportions to constitute a cannel coal elsewhere. The highly fossiliferous carbo as Rock-Eval pyrolysis data. The coal is varied in regard to dominant macerals, vitrinite being predominant in some parts and pollen and spores present in sufficient proportions to constitute a cannel coal elsewhere. The highly fossiliferous carbonaceous sedimentary rocks associated with the coal are rich in pyrite expressed in the sulphur content (19.7 - 22.8%). A high primary productivity and anoxic sediment pore waters or just above sediment - water interface have given rise to sufficient organic matter accumulations to yield a potential hydrocarbon source rock. Atomic H/C ratios of the coals are between kerogen type III and type II mainly, expressing the mixed nature of the coal and that of the associated sediments is type II. Early generated hydrocarbons (exsudatinite) have formed from pollen exines filling the pollen cavities and in places filling micro- fissures in the surrounding vitrinite.

Jan 1, 1987

Exploration for uranium in Australia commenced only during the 1940s, but in this short period has been very successful as one third of the world's low cost uranium reserves have been discovered in Australia. Total uranium exploration expenditure in Australia up to the end of 1983 was $A(1983) 554 million; this discovered 20 potentially economic deposits and official reserves of 560 000 tonnes of uranium oxide at an average cost of $1 per kg of U 0 . An exponential 8 eserves indicates distribution of uranium r that there could be 54 undiscovered uranium deposits in Australia, each with reserves of 20 000 tonnes U308 or more, in addition to smaller deposits. Using a constant uranium price of $A(1983) 79 per kg, no deposit is economic at a grade below 0.12 per cent U 08 or with reserves of less than 3 000 tonnes. Selecting deposits with reserves of 5 000 tonnes U 0g or more as prime exploration targets, only 39 per cent of discoveries will yield a real internal rate of return (IRR) of 10 per cent or more. After committing a minimum exploration budget of $10 million to this search, an explorer has one chance between 7 and 12 of discovering a deposit that will repay the exploration investment.

Jan 1, 1984

The paper considers the nature of outbursts of coal and firedamp as they occur. t follows the development of methods of working used to try and induce outbursts safely under controlled conditions and details the life support systems used to provide maximum rotection to persons who may be affected by s_lontaneous outbursts. Tilt: NATURE OF OUTBURSTS IN THE UNITED KINGDOM .1y some areas in the coalfields of the ingdom are affected by outbursts of :hal and firedamp. The main area affected is he western end of the Anthracite coalfield r: West Wales. In this area 206 outbursts .eve been recorded resulting in the loss of 8 lives. Anthracite is a high rank coal produced v the geological effects of age, depth and ynamic metamorphism. Outbursts have been xperienced over a wide area of the anthracite field but have been most frequent, and most evere, in the areas where carbon content is its highest and where the coal measures cave been subjected to the highest degree of eulting and overthrusting. Most outbursts ire associated with geological abnormalities ,:id the coal ejected during outbursts is sually of a soft and powdery nature.

Jan 1, 1980

By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003