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By Frederico Muylaert Margem, Sergio Neves Monteiro, Marina Rangel Margem

Natural fibers presents interfacial characteristics with polymeric matrices that favor a high impact energy absorption by the composite structure. The objective of this work was then to assess the charpy impact resistance of polymeric composites reinforced with one or two layers of batt jute and malva fibers. The results showed a remarkable increase in the notch toughness with increasing layers of jute blankets and malva. This can be attributed to a preferential debonding of the fiber/matrix interface, which contributes to an elevated absorbed energy.

Mar 1, 2018

By Kiyoshi Shibata

A new assessment model has been proposed for metal production and its recycling system. The model consists of three processes, smelting of ore, cascading and upgrading of metal scrap. The present approach is to assess the total energy consumption of the system, by introducing two equations for describing the relationships between critical impurity content and the mass of production or scrap recycling. The total energy consumption in the system can be described as a function of recycling rate and performance of the upgrading process. The present model suggests that the impurity removal efficiency and yield in the upgrading process are essential to reduce the energy consumption in the systems. Especially, such points should be explicitly controlled in recycling of aluminum. The potential capability of this model was also discussed by obtaining several quantitative information required for the process design and the operational control of beneficial recycling of metals.

Jan 1, 1998

By O. Barbosa F.

The thermochemistry of the systems SCN-H2O, Au-SCN-H2O and Ag-SCN-H2O is discussed. Potential-pH diagrams at 25°C are drawn for each system considering several sets of concentrations of the species involved. The information provided by the potential-pH diagrams is.complemented by distribution curves for each series of gold and silver complexes with thiocyanate. The analysis includes comparisons between the thiocyanate systems and the analogous cyanide systems, pointing out analogies and differences between the leaching of gold and silver with thiocyanate and with cyanide. The possibility of using soluble oxidizing agents such as ferric ions, hydrogen peroxide and Caro's acid is evaluated. The thermodynamic data used in the calculations and the chemical reactions represented in the Pourbaix diagrams are all reported in three Appendices. The overall results indicate the thermodynamic conditions for gold and silver leaching by thiocyanate.

Jan 1, 1989

By Augusto Viana Leandro Teixeira

Rare Earth Elements (REE) are fundamental for modern life products and green technologies. Supply constraints and the price peak of 2011 boosted intensive research for alternatives for processing and separation. Complex monazite- type, rare earth ores usually contain high acid consumption impurities, such as iron and aluminum, and radioactive thorium in their composition. These impurities are not removed by conventional concentration processes due to fine, micro-level association between the REE carrying minerals and the gangue minerals. This work presents a selective process route for REE extraction from iron-rich, monazite ores. The process involves sulfation by addition of concentrated sulfuric acid and pyrohydrolysis at temperatures of approximately 700–750 °C. Experimental results show REE extraction higher than 70% and low iron (below 5%) and thorium extraction (below 10%). A method based on thermogravimetric analyses was shown to be adequate to predict the behavior of a given ore sample in the sulfationselective pyrolysis-leaching process.

By P. Tim Johnson

Relentless increases in demand for nickel and vanadium for uses such as steelmaking, catalysts and battery materials, plus the growing financial and environmental costs of their primary extraction, have led to much interest in potential secondary sources of these metals. The presence of such metals in heavy fuel oils, bitumen and related materials offers both opportunities and challenges for potential extraction methods, especially with the growing production and importance of metal-rich fossil fuels around the world. For several decades, Tetronics’ DC plasma smelting technology has been used for the recovery of metals such as nickel and chromium from stainless steel melt dusts and other wastes in compact, environmentally-friendly and efficient plants. This paper explores the suitability of DC plasma smelting as part of a wider flowsheet with feed preparation and aluminothermic reduction techniques for smaller-scale extraction operations based on this important niche secondary source of these key metals.

By R. Angulo

Carbon nanotubes (CNTs) have recently emerged as materials with outstanding properties. This has promoted their consideration as reinforcements for other material systems, such as ceramics. However, one of the fundamental problems with producing CNT-reinforced ceramics is the effective dispersion of CNTs during processing. This has been successfully carried out recently using organic solvents. This paper is a preliminery investigation into the rheological behavior of aqueous CNT-alumina slips, with the objective of moving towards a more environmentally friendly aqueous tape casting process for the production of CNT-ceramic composites.

Jan 1, 2008

By Yong Li, Tao Jiang, Xiangxin Xue, He Yang

"In this paper, we describe the current status and research progress on the utilization of typical industrial solid wastes in China. We propose a creative method called “eco-utilizing wastes” with an aim of both integration and increment but without second-time waste and pollution, in terms of the characteristics of typical industrial solid wastes, such as titanium-bearing blast furnace slag, high-silicon iron tailing and boron-enriched slag as well as oil shale.Situation of Typical Industrial Solid Wastes in ChinaThough mineral resources in China are abundant, most of these are low grade ores. Moreover, the distribution of mineral resources is asymmetric, which causes the increase of cost and decrease of the economic benefit. Over-exploitation of mineral resources results in a large number of solid wastes. The accumulation of solid wastes not only means the waste of valuable resources, but also causes environment deterioration. There exist some problems in the current practice of the disposal of industrial solid waste, such as only emphasizing the final results and causing new pollution and waste [1]. So the research and development of a high value-added method has a high practical relevance to our nation. Based on the present status and research progress of industrial solid wastes in China, a creative new idea and method for eco-utilization of solid wastes is proposed in this paper."

Jan 1, 2012

By Lauri Holappa

Copper converting is mostly performed in Peirce-Smith converters. The process is still very similar to the original one developed in the early 20th century. It is a batch process in a horizontal cylindrical reactor with air blowing via tuyeres along the length of the reactor side. The Peirce-Smith converter has its roots in Bessemer's inventions in the 1850's as he tested both horizontal and vertical vessels for steel converting. However, for steel making a vertical pear-shaped converter with air bottom-blowing was established. In the course of time, there was a distinct necessity for oxygen usage instead of air due to harmful effects of nitrogen to steel properties and its cooling effect. In-bath blowing of oxygen did not succeed, however, and top-blown oxygen converter with oxygen lance (LD or BOF) was first developed in he 1950's and emerged rapidly to a dominating position. Somewhat later oxygen bottom-blowing via special shrouded tuyeres was developed (OBM or Q-BOP) but has attained only fractional share. Bottom-blowing technique had, however, impact on the current combined blown converters which adopted the benefits of both top and bottom blowing. In copper converting Peirce-Smith type converters have kept their position until today although new processes have been introduced and at least few of them seem to be emerging. In one respect copper converting has a clear leading position i.e. in the progress of continuous converting processes (Mitsubishi, Ausmelt). These processes utilise top-blowing lances instead of in-bath blowing tuyeres. A different principle for continuous converting is flash converting by Kennecott Outokumpu, which makes smelting and converting independent of each others. Solid ground matte is used as a feed for flash converting in a reactor shaft similar to Outokumpu matte flash smelting. A comparable process has been presented by Inco too. The paper discusses principal physico-chemical and process technical similarities and differences in copper and steel converting. Although these processes are metallurgically quite different it seems that during the modem history of ferrous and non-ferrous metallurgy, starting from the 1850's, the exchange of knowledge between these disciplines has been quite intensive. In long-term perspective, many similarities in the development can be found but also divergences due to different ambient circumstances.

Jan 1, 2003

By S. N. Monteiro, J. Alexandre, L. G. Pedroti, D. P. Santos, B. C. Mendes, A. R. G. Azevedo, G. C. Xavier

The glass cutting industry is responsible for generating large quantities of waste, during the stages of cutting and polishing. The disposal of this material generates a cost to the company, thus looking for ways to repackage it, so there is the possibility of incorporating it into the adhesive mortar. The objective of this work is the characterization of waste and assessment of the properties of these mortars, fresh, and check the possibility of their use. As for the characterization, were carried out particle size testing, density and pozzolanic activity, for the fresh state were performed tests of air content, water retention consistency and entrained particular index. Were incorporated 0,10, 15 and 20% of the amount of sand. The results showed that the material on display ha spotential for use in adhesive mortar, with values within the limits stipulated by Brazilian standards.

Mar 1, 2017

By Ian M. Ritchie

Right across the universities of the developed world, the traditional disciplines of physics and chemistry are losing ground. Extractive metallurgy, which depends so heavily on chemistry, is also contracting despite a clear need for people with this kind of training in the mining industry. Reasons for this loss of popularity are discussed in this paper. High on the list is one of image. The extraction of metals is widely seen as a dirty, polluting, sunset industry which involves working in remote and uncomfortable corners of the earth for inadequate compensation. Ways in which the image problem can be overcome are considered. It is concluded that a concerted effort needs to be made by the universities and industry to redress this situation. The importance of extractive metallurgy, both now and in the future, when a greater emphasis will be placed on sustainability and recycling, needs to be stressed. In addition, courses need to incorporate training for a career path that leads on beyond extractive metallurgy.

Jan 1, 2003

By Patrick R. Atkins

Energy issues will have increasing impacts on decision making in all facets of society over the next few decades. Industrial users of energy and producers of products that affect energy use must be fully aware of the implications of their processes and products on the energy situation. This paper describes a model that has been developed for the aluminum industry that allows scenarios to be evaluated to gain improved understanding of possible implications for our businesses. A brief overview of the model is provided.

Jan 1, 2006

By Vinicius Alves Gomes, Jean Igor Margem, Thallis Cordeiro, Frederico Muylaert Margem, Roberto Faria Jr., Sergio Neves Monteiro, Marina Rangel Margem

Natural fibers are attracting the interest of engineering sectors owing to specific advantages such as lightweight and lower cost as well as for their inherent condition of being renewable, biodegradable, recyclable and neutral with respect to CO2 emission. In particular, the fiber extracted from the malva plant stem is nowadays recognized as one of the strongest lignocellulosic fibers. However, the thermal properties of the malva fibers have yet not been fully investigated. The present work had as its objective to investigate, by photoacoustic spectroscopy and photothermal techniques the thermal properties of diffusivity, specific heat capacity and conductivity of a pressed malva fibers sample. The results revealed that these fibers showed a superior thermal insulation capacity.

Jan 1, 2015

By Bora Derin

The partial pressure ratios of sulfur and oxygen for several copper flash smelting plants were derived using the Reddy-Blander (RB) model and predicted dissolved sulfur contents available in the literature. The sulfide capacities (Cs) of six different flash smelting plants (FeO-CuO0.5- CaO-MgO-FeOwAIOl.s?SiO2) slags were calculated. The log (Po2/PS2) versus matte grades of various industrial processes was determined. The PoiPS2 ratio increased with an increase of copper grade. The calculated partial pressure ratios for the copper flash smelting are in good agreement with those of the experimental data.

Jan 1, 2003

By Daniel K. Kim

The charge for the copper refinery is a mixture of anodes produced at San Manuel from BHP source concentrate and copper purchased from external sources. Control of unwanted impurities in the tankhouse - is very important and beneficial. Currently available removal/recovery technologies were reviewed for the control of bismuth and antimony levels in the electrolyte. Recent studies have focused on solvent extraction (SX) technology and generated successful results for the removal and subsequent recovery of bismuth and antimony. The SX system employs the reagent, ACORGA SBX-50, in conjunction with a patented high chloride stripping system. The latter enables recycle of the eluant, avoiding the high costs associated with conventional systems, such as regeneration of resin. Concerns over potential transfer of organics and chloride ion to the electrolyte were readily addressed, solved and demonstrated using conventional, established technology. This paper describes the benefits of electrolyte purification, the flexibility afforded by the SX system, the operational practices necessary for maintaining adequate control of bismuth and antimony impurities in the electrorefining environment and possibilities for future development /exploitation of the Zeneca SX system at the San Manuel refinery.

Jan 1, 1998

By Fathi Habashi

Nitric Acid has been used for over 50 years in the uranium industry and in phosphate fertilizer manufacture. Its application in the treatment of sulfide concentrates is relatively recent. A review of recent developments is given.

Jan 1, 1999

By Filippos Patsiogiannis

Laboratory size (5 kg) aluminum killed low carbon steel melts were desulfurized with synthetic fluxes in zirconia crucibles. The sulfur, oxygen, aluminum, silicon, and manganese contents in the melt were determined as a function of refining time and temperature. With a good argon shield and synthetic flux cover, melt reoxidation was not observed. Sulfur removal followed first order reaction kinetics. The effectiveness of calcia saturated calcium-aluminate (12CaO.7Al2O3) based fluxes in desulfurizing the steel melts was evaluated. The effects of initial sulfur level of the melt, weight of the flux (slag), and additions of tellurium, fluorspar, and barium oxide to the melt on the kinetics of desulfurization were also studied.

Jan 1, 1993

By G. E. S. Lima, I. K. R. Andrade, N. G. Viana, R. O. G. Martins, L. M. Sathler, L. G. Pedroti, C. M. M. E. Torres, W. E. H. Fernandes, C. M. Silva, M. A. Caetano

In Brazil, kraft pulp mills are rapidly expanding and industrial waste generation is increasing. Technical feasibility of using solid wastes from kraft pulp mills as raw material in other industries may be an interesting approach to manage environmental and economic aspects of the industry. This paper proposes the incorporation, in different proportions (0, 2.5, 5 and 7.5%), of alkaline solid wastes from pulp mills, namely dregs and grits, to clinker in the Portland cement industry. The research was carried out in two steps: (i) characterization of dregs, grits and clinker; (ii) laboratory testing (determination of soundness by the Le Chatelier method, determination of setting times, determination of water content of the paste with normal consistency, determination of compressive strength and static modulus of elasticity). The results showed that the addition of dregs and grits to the clinker up to 2.5% were feasible according to the Portland cement Brazilian standards.

Mar 1, 2017

By Michael Altepeter

Big River Zinc Corporation, located in Sauget, Illinois, operates a neutral leach residue circuit. The residue produced in the circuit is sold to lead smelters for subsequent recovery of valuable metals. A research program was initiated several years ago to find a means of treating the residue at Big River Zinc to recover the valuable metals. The Ausmelt submerged lance reactor was selected as the best alternative for the first step of the process. Pilot scale tests were conducted at Ausmelt's facilities in Melbourne, Australia. Separations were excellent. 99%+ of the Zn, Pb, Cd, and Ag contained in the residue reported to the oxide fume. 99%+ of the SiO2,, Fe, Mg, and Ca in the residue reported to the slag which passed the EPA TCLP test. Subsequent leaching of the oxide fumes and purification of the leach solutions using conventional procedures produced solUtions suitable for zinc electrowinning and an upgraded lead sulfate cake for sale.

Jan 1, 1992

By E. V. Redin, B. A. Dubrovsky, E. V. Knyazev, A. I. Starikov

"Ti-V magnetite is one of the most abundant composite ore resources in the world. This ore cannot be fully processed via blast furnace technology because of high content of Ti02. According to the investigations carried out in the USA and Japan ITmk3 RHF (Rotary Hearth Furnace) technology is a breakthrough in Ironmaking. Reduction, melting and slag removal can be achieved in just 10 min. The main objective of the investigation is to establish optimum operation conditions for the production of iron nuggets from Ti-V magnetite ore via the ITmk3 by means of the lab scale testing. Samples of ore from the Maly Kuybas deposit (Southern Ural), carbon reductant and fluxes were chemically analyzed. Green pellets were processed via a lab chamber furnace to simulate RHF conditions. The nuggets and slag were chemically analyzed. This preliminary test work provides valuable information which may be used for large-scale testing in a commercially sized RHF.IntroductionThe ITmk3 process upon which this paper focuses was developed by Kobe Steel in its research facilities [l]. After pilot testing at Kobe Steel's Kakogava Works in 1999-2004 the pilot demonstration plant was built and operations were successfully carried out by Mesabi Nugget joint venture in 2002-2004. Steel Dynamics put into operation the commercial plant at the Mesabi Nugget site in Hoyt Lakes (Minnesota) in 2010. Results were consistent with nugget characteristics confirming ITmk3' s flexibility with respect to raw material inputs. At the same time, no research in the field of nugget from the Ti-V magnetite bearing ore with high content of Ti02 and Alz03 has been done. It is well known, if a lot of Ti02 and Alz03 enter the blast furnace, slag becomes viscous. The viscous slag is obstacle for stable operation of the blast furnace. Besides, high content of Alz03 raises the melting temperature of gangue minerals disturbing the coalescence of reduced iron to the nuggets."

Jan 1, 2013

By Lucio Fabio Cassiano Nascimento, Luis Henrique Leme Louro, Sérgio Neves Monteiro, Jheison Lopes dos Santos, Fernanda Santos da Luz, Fábio Oliveira Braga, Rubens Lincoln Santana Blazutti Marçal, Hugo Concolato de Oliveira Freitas, Édio Pereira Lima Júnior

Epoxy matrix composites reinforced with up to 10, 20 and 30 vol% of continuous and aligned natural mallow fibers and 30 vol% of mallow and jute hybrid fabric were for the first time ballistic tested as personal armor against class III 7.62 mm FMJ ammunition. The ballistic efficiency of these composites was assessed by measuring the dissipated energy and residual velocity after the bullet perforation. The results were compared with that in similar tests of aramid fabric (Kevlar™) commonly used in vests for personal protections. Visual inspection and scanning electron microscopy analysis of impact-fractured samples revealed failure mechanisms associated with fiber pullout, rupture and layers delamination. When compared to Kevlar™, the mallow fiber and hybrid fabric composite displayed practically the same ballistic efficiency. However, there is a reduction in both weight and cost, which makes both, mallow fiber and hybrid fabric composites, a promising material for personal ballistic protection.

Mar 1, 2018