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By Carol E. Jones

Outline ? Reclamation is a primary mitigation. ? Understand baseline environment and land use. ? Determine reclamation goals. ? Selecting reclamation technology. ? Determine technical risk. Reclamation ? Primary Mitigation ? Through land and water disturbance, mining can have significant local and regional environmental impacts. ? Impacts can also result from associated land use changes. ? Reclamation is a primary tool that the mining industry uses to manage its environmental impacts.

May 1, 2008

By Eugen Gluck, Gus Van Weert, Peter Kondos

"Microwaves have the capability to heat up sulphides, especially clusters of particles of approx. 1 mm. Some sulphides absorb microwaves more readily than others. Molybdenite is especially effective in this regard, possibly due to its flaky nature and/or electrical conductivity. Even where it occurs in low concentrations in a deposit, individual rocks may be ore grade due to the high monetary value of MoS2. Such rocks often result from crushing mined veinlets or stockwork, or are contained in the cutoff grade fraction of ROM. Machine segregation of rocks high in MoS2 by infrared sensors after microwaving could therefore advantageously be used to upgrade lower grade ore between Mine and Mill. This would reduce the size of the latter, and thus its CAPEX and OPEX. Such upgrading could also yield shipping ore for a distant Mill, or extend ore reserves.Barrick Gold Corp. has been supporting the development of MW/IR sulphide sorting for the past three years. The results of MW/IR sorting work on molybdenite and other (pyritic) ore samples from a variety of sources are being presented here.INTRODUCTIONThis paper looks at mechanized, i.e. machine ore sorting technologies currently available and under development, and what conditions would be needed for the potential application of such ore sorting to sulphide mining and milling. Current machine sorting involves no-contact sensing technology for rocks, and signal processing after sensing to activate airblast segregation of certain rocks, normally the smallest mass to keep compressed air costs down.The forerunner of modern sorting is probably magnetic separation, which utilizes an inherent property of certain ores to divert it into mag and non-mags fractions. Radiometric ore sorters, which have been applied successfully for decades in the pre-concentration of uranium ores (Wotruba and Riedel, 2006) initiated modern sorting. In the 90’s, sensor-based machine sorting became a viable means of increasing the overall economic recovery of a resource. This technology became driven by the availability of low cost computing equipment and the concurrent development of algorithms, and by the availability of extremely fast response sensors and air actuators, allowing the sorting equipment to run faster, dropping the cost per tonne. It has been in industrial minerals processing that rock sorting has been most widely adopted, not really surprising. Liberation occurs on a different scale than in the base metal industry. Most industrial minerals are mined from massive deposits, requiring (in the past) no upgrading. Many of these operations now run into product contamination problems, which ore sorting can solve. One illustration: in Finland, a quarry is separating limestone from dolomite at 500 tonnes / hour, with individual rocks weighing up to 15 kg. Many of these industrial minerals operations have stockpiles of earlier discarded below-quality rocks, now being reprocessed with the help of ore sorting. The economics of this are very favourable, going from zero or negative value (stockpiles can not be left when closing the mine) to full product value for at least a portion of the stockpile. This suggests that in the future the economics of overburden sorting could become attractive under the right circumstances and such treatment could well become an integral part of open pit mine development."

Jan 1, 2009

By Klaus Tietz, Hamish Adam, John Selby, Ian Glazier, Brian Sinfield

"Room-temperature tunable diode laser (TDL) analyzers are gaining in acceptance for highly critical safety monitoring applications in a variety of industries. This paper describes the testing, evaluation and deployment of a laser-based hydrogen cyanide monitoring system at the Campbell Complex of Goldcorp’s Red Lake Gold Mines in Balmertown, Ontario, Canada.A trial, single channel installation was followed by a staged multi-channel installation. Unexpected technical issues with the multi-channel installation were addressed and resolved.INTRODUCTIONLaser-based gas detection has several advantages over existing gas detection techniques (Ballangrud, 1993; Silver, 1992; Bomse, 1995; Table 1). For practical purposes, lasers generate light at a single wavelength. Room temperature tunable diode lasers (TDL) emit light in the near infrared (NIR) part of the electro-magnetic spectrum. Many gases of interest, including HCN, NH3 and others, absorb energy in the near infrared (NIR). Each gas has a unique absorption signature, or spectrum, made up of a large number of individual “absorption lines”. A TDL can be tuned to select a single absorption line of a target gas, which does not overlap with absorption lines from any other gases. Therefore, laser gas sensing is selective and does not suffer from interference from other gases. The single-wavelength nature of laser light also means that laser gas analysers have a linear response over a wide dynamic range.Tunable Diode Lasers (TDL) generate only a few mW of power. However, all this power is concentrated at one wavelength, the wavelength where gas absorption occurs, resulting in high signal-to-noise ratios and short response times, typically of about 1 or 2 seconds (Ballangrud, 1993). This also means that long path lengths can be used, enabling accurate measurements of very low concentrations, even with weakly absorbing gases. Tunable Diode Lasers provide all the advantages of other semiconductor devices: they are small, solid-state devices, operate at room temperature, and have long-term reliability (over 15 years). Currently, they can be obtained for any wavelength throughout the NIR (700nm to 2000nm). Because many gases absorb in the NIR, the technique is widely applicable."

Jan 1, 2011

By Glenn Kosick, John Starkey, Glenn Dobby

"A practical new test has been developed for SAG hardness determination. Using two kilogram samples of minus one inch diamond drill core or crushed muck samples, the Starkey SAG Test has been shown to give accurate predictive information which directly relates to on-stream SAG mill performance. Typical results and test criteria are discussed in the paperAchievements to date include:• Identification of hardness profiles and the location of hard and soft zones in a large ore body.• Accurate prediction of the hardness of a bulk sample by using an adjacent diamond drill hole.• Derivation of a plotted curve relating pilot plant power to laboratory relative hardness.• Demonstration that for every test done to date, the Starkey SAG Test produced a product size distribution identical to that produced in a pilot plant or full scale plant SAG operation.This test can now be used for blast hardness monitoring and short term control of mine production in existing plants and for identifying the proper locations for bulk samples in new projects. In addition, new SAG mill design can now be rationalized in a low cost way to eliminate unforeseen production shortfalls.IntroductionThis paper is presented to introduce the Starkey SAG Test, a practical new laboratory tool for measuring the relative hardness of small ore samples in a semi-autogenous grinding (SAG) environment. The test was first designed for use on diamond drill core samples during the prefeasibility stage of new mining projects, to provide new information about the ore body at reasonable cost. It is a new tool and does not replace existing pilot plant test requirements.The test will also be useful for throughput prediction in existing SAG plants by assisting in short and long term mine planning, where forecasting of metal grades and milled tonnage is used to control mine profitability. Because in-plant hardness testing has previously been unavailable on small samples, this test offers exciting possibilities for SAG mill operations where hardness variation is or could be a problem.The Starkey SAG Test provides the following benefits to the mining industry"

Jan 1, 1994

The Stability Graph Method is widely used in Canadian underground hard rock mines for open stope support design and is frequently used in the mine planning phase to assess the viability of stope geometries and to determine maximum permissible spans. The Method is well accepted due to its simplicity and suitability to a wide range of mining methods requiring the use of sublevels to access and extract the mining blocks. While this Method is reliable in situations where the maximum induced tangential stress creates adequate compressive stress keeping the face in a state of confinement, the Method fails to reflect the effect of low confinement caused by lower compressive stresses and instances where tensile stresses are developed. In this paper, a new Rock Stress Factor, A?, an update to the original Rock Stress Factor, A, is proposed, which will reflect the impact of low confinement or overstress regime on critical face stability. Two case studies, based on two Canadian operating gold mine shows that using the new Rock Stress Factor A? to predict the stability of stope hanging-wall and footwall gives better agreement with the CMS survey results, compared with the prediction using the original rock stress factor.

May 1, 2011

By David Humphreys

It is difficult to overstate the importance of China to the future of the world mining and metals industries. In a remarkably short time, China has risen to become the world?s largest producer and consumer of steel and its second largest consumer of non-ferrous metals such as copper and aluminium. It is currently the world?s largest buyer of copper on international markets, the second largest buyer of iron ore, and the third largest buyer of alumina. At the same time, it is the world?s largest or second largest producer and exporter of tin, lead, zinc, magnesium and a host of minor metals and industrial minerals, as well as a fast-growing exporter of coal.

May 1, 2002

By W. A. Lang

Introduction Under our present civilization, industrial developments will be greatest in those areas in which energy .can be most economically produced and efficiently used, where labour is in adequate supply, and where markets for the products of industry are available. A knowledge of fuels- the present major sources of energy- and of their utilization is therefore of vital importance. With that in mind, the aim in this paper will be to outline the known reserves of fuels in Alberta, to give their characteristics, to indicate the markets served by each, and to offer some suggestions for the future development of the coal industry. The paper should be regarded as a compilation of published data rather than as an original treatise. Alberta is richly blessed by having large reserves of mineral fuels. The estimated reserves of coal are 46,562 million tons. Alberta is the oil and gas province of Canada. The world's largest deposit of bituminous sand occurs along the Athabaska river in Alberta. In addition, there are large areas of forested land in the northern and western sections of the Province, and the rivers serve for the development of hydro-power.

Jan 1, 1949

By Joseph J. Mgumbwa

Pillars are any structures left between two or more underground openings. The stability of pillars is normally considered to depend on shape (defined by width to height ratio), rock mass strength, extraction ratio, in situ stresses and the gross structural features (i.e. joints, contacts, faults etc). Recent experience has shown that pillar stability is also controlled by the relative orientation of the orebody with respect to the in situ principal stress. In inclined orebodies, pillars are loaded in compression and shear, thus creating unsymmetrical stress distribution. Failure mechanisms of these pillars are little known. This paper investigates the failure mechanisms of pillars under shear loading. Two dimensional elastic numerical modeling was used to examine the behavior of pillars in different orebody inclinations relative to the major farfield stress orientation. First, the paper reviews pillar design approaches including the empirical pillar design chart and uses numerical modeling to investigate the effect of the major farfield stress orientation on pillar stability. It is concluded that the empirical pillar design chart be used with caution, and that for orebodies under shear loading mine planning and design should take this into consideration since such geometrical orebody/stress relations put mine structures at higher risk of instability.

Oct 1, 2010

By K. Norris

"The Campbell mill has undergone numerous changes over the past 43 years. However the rate of change has increased significantly in the last 4 years. A new grinding circuit, carbon-in- pulp circuit, pressure oxidation plant, and column flotation circuit are all new additions. Other changes have occurred in the last 2 years including a large reduction in sodium cyanide consumption, and the introduction of a computer controlled grinding circuit. More improvements are planned in the next 2 years. Some of these improvements include the construction of an effluent treatment plant, and the replacement of filtering and Merrill-Crowe precipitation with carbon-in-leach and electrowinning.Recent changes and improvements to the Campbell mill are a commitment by Campbell mill personnel and Placer Dome Inc. to decrease operating costs, increase gold recovery and gold production, improve industrial hygiene and safety, and meet environmental compliance with current government legislation.INTRODUCTIONThe Campbell Mine has been and continues to be one of Canada's premier gold mines. Campbell Mine is 100% owned and operated by Placer Dome Incorporated. Milling of ore commenced in 1949 at a rate of 300 tons/day producing 58,000 ounces per year of gold. In 1992 Campbell Mine will mill 1340 tons/day of ore at a grade of 0.6 ounces/ton, producing 275,000 ounces of gold at a cash cost of $205.00 Cdn./ounce.This paper discusses some of the changes that have been made to the Campbell mill in the past 4 years. The flowsheet has undergone extensive changes and will continue to change rapidly in the next 2 to 3 years. A simplified flowsheet of the Campbell mill is shown in figure 1."

Jan 1, 1992

Background Chronology 2008 Positions May 8, 2010 Summit Going Forward Say one thing and do another ??Genuine passion to see our customers succeed?, ?A passion for exceeding our customer?s expectations? Self serving actions to gain competitive advantage at the expense of the customer No single supplier or technology can manage the overall mine and its integrated operation - April 2005: Informal meeting at Toronto CIM 2004 -Unanimous interest - July 2005: Formal Calgary Meeting, developed: - Scope and vision statement , - OEM/OTM communication plan, - industry communication plan - Aug?Nov 2005: Aligned with SMART - Nov 2005?May 2006: Direct OEM, OTM communication - May ?Sept 2006: Developed baseline standards - Sept -April 2007: Developed SMART document - Sept 2007: Document distribution and request OEM OTM response - Jan ?May 2008: Acquired OEM OTM feedback and positions May 2008: Results presented to SMART and discussions on next steps

May 1, 2010

By Catalin Florin Petre, Elahe Ghasemian Langeroudi, Abdelaaziz Azizi, Éric Proulx, Caroline Olsen, Paul Blatter, Faïçal Larachi, Claude Gagnon

"The recovery of gold from ores is often accompanied by the release of other species in the leach solution. This state of affairs leads to depleted free cyanide levels in the slurry. Therefore, separation and quantification of these cyanicides and free cyanide at different stages of the cyanidation process as well as in waste solutions is crucial to provide mitigation tools by preventing leaching of deleterious metals for environmental considerations.COREM and the research group of Prof. Larachi have been working together on the control of gold passivation and cyanicides during cyanidation for several years. Previously, a first capillary electrophoresis (CE) protocol for the speciation of sulfur and cyanicides (SCN-, Cu, Fe) during cyanidation of gold complex sulfide ores was developed and validated for assessing industrial process water.The separation of zinc cyanide complexes used to be confronted with a number of difficulties due to the weak and/or undetectable cyanocomplexes in formally available CE protocols. Moreover, according to our knowledge, no direct CE protocol exists to separate free cyanide. Therefore, a new study aimed at developing a second CE protocol for the detection and quantification of cyanide complexes of zinc and nickel as well as of free cyanide in the cyanidation process water.To achieve this goal, six common carrier electrolytes such as pyridine, trimellitic acid, 4-methylbenzylamine, sodium chromate, phthalic acid and tris base were studied, using an indirect UV detection method. The best results were obtained using sodium chromate for which all ions were successfully separated and quantified. In addition, the effect of electric field strength, injection volume, electro-osmotic flow (EOF) modifier and background electrolyte (BGE) concentration were examined, while peak height, peak area and noise were considered for optimization.As a result, the new protocol is expected to complete the initial CE protocol by detecting cyanide complexes of zinc and nickel as well as free cyanide. Moreover, analytical determination of free cyanide in the presence of weak cyanide complexes achieved by the new protocol was also compared to conventional titration using silver nitrate solution. This new CE protocol will contribute to applied research and help plants to better understand and eventually control the behaviour of cyanidation circuits."

Jan 1, 2011

By R. H. O. Wagner

"This paper describes the bench testing, pilot plant studies of alternative flowsheets, to determine the feasibility of gold recovery, by carbon in pulp extraction, in the Schumacher Mill gold flotation tailings. The economics were calculated based on pilot plant recoveries and actual industry operating costs.The economics of the carbon in pulp treatment of the gold flotation tailings were not justifiable. The economics of desliming the gold flotation tailings followed by carbon in pulp treatment were marginal, but favourable. INTRODUCTIONPamour Porcupine Mines, Limited is a gold, silver and copper producer located in Timmins, Ontario. In 1983 the head grade of Pamour's gold ores averaged nine one hundredths of a troy ounce of gold per short ton.Pamour operates two area mills to concentrate the gold ores. Free milling gold ores are processed at the Pamour One Mine mill, whereas the refractory carbonaceous gold ores, and complex gold, silver, and copper sulphide ores, are processed through the Schumacher Mine mill.The complex Schumacher mill feed ores do not all react favourably to flotation methods, consequently this study was commissioned to investigate the feasibility of the carbon in pulp cyanidation of the Schumacher mill gold flotation tailings. These tailings contain ten to fifteen percent of the gold in the mill feed. During the study period, the average grade of the Schumacher mill flotation tailings was nine one thousandths of a troy ounce of gold per ton, or one quarter of a gram of gold per metric tonne."

Jan 1, 1984

By S. H. Ash

No single factor in modern civilization has played a more important part in the lives of our people than mechanization in industry and to it civilization owes much of its progress. In no industry has mechanization met more opposition than in coal mining, where ?the introduction of mechanical equipment has been opposed on many fronts for economic and social reasons. The term 'mechanization? as used in this report refers to the application of machinery to cutting, loading, and transporting coal from the face to the mine cars. During 1933, 84.7 per cent of the underground production of the bitu-minous-coal mines of the United States (1) was cut by machines, while in Washington only 17.6 per cent was machine-cut. Information in this report has been obtained from personal observations and from operating officials in the Roslyn-Cle Elum coal fields, especially D. R. Swem, manager of coal operations, and Thomas Murphy, superintendent, of the Northwestern Improvement Company, to whom the author is indebted for assistance. INTRODUCTION Although Washington coal-mining problems relating co mining methods, ventilation, drainage, and preparation of coal have been discussed in many publications, little has been published on mechanization in this region, principally because it has not been accepted generally that mining machines, mechanical loaders, and conveyors are necessary or economically adaptable to the variable and steeply inclined coal beds of Washington. Production of coal in Washington reached its maximum in 1918, when 4,128,424 short tons were produced; from that year, the trend was downward until 1934, when production was 1,383,103 short tons, the lowest since 1898; for the past two years, production has risen steadily.

Jan 1, 1937

By K. Wood, R. McIvor, P. Blythe, M. Lavallee

A new analytical approach for characterizing and improving the performance of ball milling is presented. Individual ball mill circuit design and operating variables can be related to overall circuit performance through two distinct parameters for classification and breakage. The ball mill circuit functional performance equation is presented.Total mill x Classification x Test specific x Grinding power draw system efficiency grinding rate rate ratio= Production rate of new product size materialExamples from industrial plants and applications in the research and development field are discussed.

Jan 1, 1990

By James A. Finch, Stéphanie Somot

"The self-heating facility developed at the Noranda Technology Centre [Rosenblum and coworkers, 2001; 1995] has now been established in the Department of Mining, Metals and Materials Engineering at McGill University. A research program into mechanisms has been initiated (with support now from four industrial partners under Camiro). The first investigation is into the role of pyrrhotite (Po), the most commonly suspected mineral to trigger self-heating. Following a standard experimental protocol, self-heating was assessed on samples of Po mixed with sand as an inert material. With increasing Po content, self heating progressively increased but, interestingly, the samples visually appeared less and less oxidized. A high Po content, it was hypothesized, may give a more reducing environment favouring formation of H2S. The presence of this gas could be significant as it has a high exothermic heat of reaction with oxygen. The system was modified to test the hypothesis by including copper pieces and copper sulphate to react with (and therefore reveal) the gas as copper sulphide. Evidence is presented in support of H2S production, which to our knowledge has not been shown before and introduces a potentially important avenue of investigation into self-heating mechanisms.INTRODUCTIONSelf-heating of sulphide minerals poses potential environmental and safety hazards in mining of ores, and storage and transport of concentrates. While some conditions are known to be critical, the reactions remain poorly understood making self-heating difficult to predict and control.A major advance in measurement was introduced by Rosenblum and co-workers [Rosenblum et al., 2001; Rosenblum and Spira 1995]. A self-heating assessment method was developed and applied to various sulphide-bearing materials The method is based upon automated calorimetric cells with data acquisition, now available to McGill researchers and which have been used for the study reported here."

Jan 1, 2006

By M. Vallée

"RÉSUMÉDurant les 10 dernières années, les améliorations dans le contrôle des limites des sautages et les arpentages après l’exploitation ont fourni des informations préalables et post facto sur les limites minières réalisées par rapport à la planification, plus particulièrement pour les grands chantiers exploités par les méthodes chambres vides et sous-niveaux. Cependant, peu de recherches ont été faites pour améliorer la délimitation du minerai, l’estimation des ressources et des réserves, les études de faisabilité et la récupération minière dans d’autres types de gisements. Il faudra d’abord expliciter les impacts des lacunes, en quantité et en qualité, de l’information géologique et de l’échantillonnage sur le rendement de l’extraction. Il faudra également remplacer la notion de « dilution générale » par celles de « dilution » et de « perte de minerai ». Les impacts des lacunes observées sur l’exploitation des gisements d’or filoniens sont démontrés par une simulation basée sur des résultats d’études antérieures à la mine Thompson d’Inco, des impacts financiers de densités d’information moindre et par des analyses des valeurs actualisées nettes (VAN) de deux cas types.Deux gisements similaires, de 3 m et 6 m de largeur et exploités par chambres vides sont étudiés, en prenant pour cas de base la délimitation sur maille de 7,5 m (25 pi.) et en étudiant les impacts des limites moins précises supportées par une maille de 15 m (50 pi.), en assumant que ces imprécisions moyennes de +/- 0,62 m se transforment soit en surestimation (dilution), soit en sous-estimation (pertes de minerai).Les impacts d’information moins précise ont été beaucoup plus forts sur le gisement plus étroit : autant la dilution que les pertes de métal ont diminué les VAN du gisement de 3 m de 39,27 % et 45,41 % respectivement, tandis que les VAN du gisement de 6 m ont été diminuées que de 12,84 % et 11,55 %.Ces impacts des valeurs actualisées nettes diminuées justifient et exigent des efforts plus systématiques pour s’assurer que les travaux de mise en valeur et les études de faisabilité soient réalisés de façon requise pour optimiser l’exploitation et offrir aux investisseurs des rendements compétitifs par rapport à ceux des autres secteurs industriels. ABSTRACTDuring the past 10 years, research work to improve the survey of stope limits after mining supplied useful information, particularly for large open and sub-level stopes, regarding waste dilution caused by differences between final production limits and planned stope limits.However, the efficiency of this information to improve the overall efficiency of the mining process is limited, given that the impacts of inaccurate ore limits leading to dilution (sensu stricto) and ore losses have not been considered adequately. Geological/sampling information should be optimized in terms of quantity and/or quality for the deposit characteristics and the constraints of the mining method used. As industry practice regarding the definition and recording of dilution is flexible and as ore losses frequently are poorly documented, the use of these terms is reviewed.Simulations were carried out on two typical narrow gold deposits, based on an earlier study at Inco’s Thompson mine regarding the impacts of wide to narrow delineation grids using recorded variations of vein geometry. Vertical to sub-vertical deposits of 3 m and 6 m widths mined by long-hole open stopes were considered. Deposits delineated by 7.5 m (25 ft) grids were taken as a base case and the impacts of less accurate limits in conjunction with long hole mining based only on a 15 m (50 ft) delineation grid. The impacts of overestimation (dilution) and underestimation (metal losses) were considered separately, using the average error of +/-0.62 m recorded in the Inco study.The impact of less accurate information was much stronger on the narrower deposit: both dilution and ore losses diminished the net present value of the 3 m wide deposit"

Jan 1, 2005

By R. Haecker, S. Bajic, R. Thorpe, A. Palko, M. Kalstrom

"Historically, mineral processors have used inferential data like plant instrumentation, assays, and grind sizes to monitor the performance of their plants. The ability to monitor the minerals themselves on a daily basis has eluded all but the very largest and richest of operations. The advent of a new generation of compact, robust, and user-friendly SEM-based automated mineralogy systems looks set to accomplish this, aiming to bring daily mineral monitoring of plant performance within the reach of all mills from mid-size upwards. This paper describes the use of this machine at Greens Creek Mine, a 2.5 ktpd Ag-Au-Pb-Zn operation with a complex flotation flowsheet. During the trial, the machine provided turnaround from sample collection to reporting averaging 24-36 h for key daily samples. All equipment was located within the compact mill, and proved highly reliable despite the challenging environment. Turnaround time was fast enough for metallurgists to understand, and, where possible, respond to ore and process changes while they were still happening. The plethora of data generated was filtered to a simple report whereby mill management could quickly absorb key daily mineral-based performance indicators. This paper will describe how the data was used to understand the key drivers behind metallurgical efficiency at Greens Creek, and how metallurgists began using the information to enhance daily mill performance."

Jan 1, 2014

By Zetti Gavelán

Lack of skilled workforce in mining industry during the current decade has been a serious concern for most mining organization globally. At the beginning of this decade the major envisioned difficulty was related to generational breach of mining professionals. By 2003, mining industry recover from a low metal prices cycle following by a worldwide mining investment boom in 2005 that triggers a talent war among mining companies that was not only limited to professional level but skilled operators as well. Despite world?s economy collapse in October 2008, impact on mining industry was small comparing to other industries and appears to show evidence of healing. Under this context, fundamentals that have been driven lack of skilled workforce for the mining industry in previous years still valid. Starting in 2007, Minera Argentina Gold SA - Barrick Veladero, subsidiary of Barrick Gold, initiated an innovative selection and training program for candidates without exposure to mining. Following our corporate social responsibility mandates, Barrick Veladero decided to change its hiring process entirely, concentrating on selection and training of local people with no experience rather than hire experienced mining operators. This paper shares Barrick Veladero experiences on its hiring program, challenges faced, and current results.

May 1, 2010

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By G. Barbery

"Particle composition distribution is an essential feature of materials processed by physical separation methods. The amenability to segregate a feed material in a concentrate and a tailings stream depends to a large extent on what is called usually the ""liberation"" of the various mineral phases that are present in an ore. In fact the energy consumed in crushing and grinding has the major justification of producing particles that are as close as possible to monominerallic. Monophasic particles are able to reveal physical differences in mineral properties that make their separation possible. For many years, various authors have insisted on the concept of liberation, without noting that, in practice, it can be a pure concept which does not lead to measurements or predictions. The present paper insists on the concept of particle composition distribution, in which the complete distribution is the information to be obtained, and not the ""liberation·· of various phases, just like for particle size distribution, the complete distribution is an objective commonly desired, and not one or two values representing the coarse or fine fraction.2. NOTATIONS-EQUATIONSFor the purpose of the paper, a particle will be characterized by its volume Vp, and its volumetric composition with respect to a mineral of interest, which will be given the notation ""O"". All the other minerals present will be called ""1"". This notation does not imply that the particles are biphasic, but that we are interested in the composition of particles with respect to one phase only. The volumetric composition will be given the sybol m:"

Jan 1, 1986