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By Sam S. Taylor

Disposal of brines produced with crude petroleum and natural gas is a continually increasing problem. The necessity for studying this problem has been realized more generally in recent years, and in August 1934 an agreement was made between the Kansas State Board of Health and the United States Bureau of Mines to conduct a cooperative technical study of methods of brine disposal. To date one paper in the technical press4/ and three reports5/6/ 7/ have been published in which are given results of studies carried on under this cooperative agreement. In the Mid-Continent fields, the methods used most generally for handling oil-field brines are: (1) Impounding in evaporation ponds; (2) controlled diversion into surface streams; and (3) injection into subsurface formations through wells assigned for this purpose. Various States recognize one or more of the methods as legally authorized procedure. Impounding brine in ponds and solar evaporation have proved inadequate as a general rule, owing, usually, to the porous nature of the soil, the low rate of evaporation, or both. Diversion of

Jan 1, 1937

By Victor R. Spironello

The Bureau of Mines has studied slags associated with ferrous melting, to evaluate substitutes for the auxiliary flux mineral, fluorspar. A waste material recovered from alumina reduction cells, "used potlining," was tested in an 18-in-ID basic-lined cupola and in a 1/4-ton, pilot-scale, basic oxygen furnace (BOF). One potlining fraction, No. 1 cut, is a carbonaceous (graphitic) material and represents the bulk of the entire cell lining. The other fraction, No. 2 cut, is a refractory backup. These materials contain significant quantities of fluorine and other elements fn various compounds. The potlining fractions were blended in ratios believed representative of available materials. Both lump and pelletized forms provided extremely fluid slag. No adverse effects were found on furnace performance, chemistry or strength of the metals produced, or the environment. Fluorine recovery in the slag and fluorine losses to the scrubber water and solids were about the same as when fluorspar was used. There was apparently no lining loss from the cupola, but there was lining attack in the BOF. Since the fluidizing ability of potlining is due in part to sodium and other elements such as aluminum and silicon, less fluorine is needed in the slags when potlining is used.

Jan 1, 1983

By Ed D. Thimons, Douglas E. Pollock, Andrew B. Cecala, Gregory J. Chekan, Jay F. Colinet, John A. Organiscak

Researchers at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) work to reduce respirable dust exposures in mining operations. One focus of this research is silica dust control for surface and underground operations in the metal/nonmetal mining industry. PRL researchers analyze dust sampling results from the Mine Safety and Health Administration (MSHA) to identify high-risk occupations to guide research efforts. Research is then conducted in an effort to improve existing technologies and/or develop new controls for reducing worker exposure to airborne silica dust. During the last few years, PRL researchers have conducted research related to the following goals: improving protection provided by enclosed cabs on mobile surface mining equipment, reducing dust generation from surface drills, reducing dust levels in iron ore operations, and developing a new method to clean dust from workers’ soiled clothes. A description of each of these controls and subsequent dust reductions quantified through site surveys will be provided.

By S. S. Gross

A program was conducted to determine whether sufficient quantities of the flame retardant, ammonium phosphate, could be incorporated in a water-based foam solution to prevent or delay reignition (burnback) without. significant degradation of foam properties. Up to 20% of mono and diammonium phosphate was added .to d high expansion foam solution. This mixture was applied as a high expansion foam to burning wood and coal samples. The effect of this mixture on burnback was laboratory tested by placing the wood or coal sample in front of a radiant panel. It was found that diammonium phosphate levels of 20% by weight prevented reignition without degrading foam properties. A field test was then conducted using a 20%, diammonium phosphate mixture and a control with no phosphate on a wood crib fire. The experimental foam did extinguish the crib fire faster than the control as evidenced by the smoke from the crib. However neither crib reignited.

Jan 1, 1982

By John E. Conley

The great demand for metallic aluminum for the prosecution of World War II caused the consumption of bauxite, the common ore of aluminum, to increase greatly. Prior to the war, the domestic deposits 'of bauxite, which occur chiefly in Arkansas and less extensively in Georgia, Alabama, and Mississippi, supplied only: about 30 ,percent of the ore required for aluminum-metal production and approximately 40 percent of alumina for all purposes. Enemy activities during the war seriously interfered with shipment of bauxite from the normal peacetime source in Surinam, Netherlands Guiana, South America, and focused attention on the necessity for increasing production from known domestic deposits. Even in peacetime, the production of aluminum ore in the United States could not satisfy requirements. Field drilling and exploration by Bureau of Mines engineers resulted in the discovery of important tonnages of high-grade bauxite suitable for treatment by the conventional Bayer process, Although an ore containing approximately 55 percent Al2O3 and only 2 to 4 percent SiO2 is preferable, it was necessary to use ores containing up to 8 or 10 percent SiO2. Because of the lower recoveries of aluminum with increased silica content, the Reconstruction Finance Corporation, through the Metals Reserve Company, established a base price of $4 for a 50-percent Al2O3 ore, containing 13-percent silica, with a premium or penalty of 14 cents for each percent of Al2O3 over or under 50; each percent of SiO2 under 13 was awarded a 20-cent premium, and each percent over 13 suffered a penalty of 43 cents; all prices were on the basis of 1 long ton of ore, dry basis.

Jan 1, 1949

By F. D. DeVaney

Manganese-bearing deposits f the Leadville, Colo., district are of two distinct types. Manganosiderite, a combined or intimately mixed ferrous and manganous carbonate, occurs in unaltered zones as the predominant mineral. From 50 feet below the surface to as deep as 900 feet, psilomelane and wad, both black manganese oxide minerals, are found in intimate contact with hematite and limonite. A typical analysis of the black oxide ore shows 20.08 percent Fe, 18.64 percent Mn, 15.91 percent insoluble, 14.91 percent moisture, 0.94 percent Zn, and 2.13 percent Pb. A considerable tonnage of the oxide ore has been mined for production of spiegeleisen and for other purposes.

Jan 1, 1940

By F. D. DeVaney

Manganese-bearing deposits of the Leadville, Colo. district are of two distinct types. Mangano siderite, a combined or intimately mixed ferrous and manganous carbonate, occurs in unaltered zones as the predominant mineral. From 50 feet below the surface to as deep as 800 feet, psilomelane and wad, both black manganese oxide minerals, are found in intimate contact with hematite and limonite. A typical analysis of the black oxide ore shows 20.08 percent Fe, 19.64 percent Mn, 15.91 percent insoluble, 14.91 percent moisture, 0.94 percent Zn, and 2.13 percent Pb. A considerable tonnage of the oxide ore has been mined for production of spiegeleisen and for other purposes.

Jan 1, 1940

By Lester J. Crow

This study advances the use of elemental sulfur in structural materials by demonstrating its value in bonding high-strength, well-graded basalt aggregates to form sulfur-basalt concretes. Sulfur is an excellent bonding agent, and the strength of a thermoplastic sulfur-aggregate mixture depends, to a large degree, on the strength and grain-size distribution of the aggregate used. A 3-cubic-foot, electrically powered mixer with heat applied to the barrel was used to mix the sulfur and aggregate. Sulfur content of several mixtures was varied to obtain the best workability with a minimum of sulfur in excess of that necessary to fill the voids. The average grain sizes and grain-size distributions were also varied to determine their effects on strength. Unconfined compression tests of forty-five 6-by l2-inch cylinders yielded average strendths of 3,348 psi to 10,398 psi. The highest strength single cylinder was 10,717 psi. The cylinders were tested from 24 hours to 6 days after pouring; after 24 hours the rise in strength was very slight. From the results obtained it appears that sulfur can be a useful construction material. An evaluation was made of a high-vacuum application for sulfur concrete. Sulfur has a high vapor pressure at elevated temperatures, 50° to 100° C; consequently, significant losses by sublimation can be expected. At lower temperatures the losses are not significant; however, this factor will limit its use at a higher temperature.

Jan 1, 1970

By Franklin D. Cooper

This Bureau of Mines report reviews in detail the foundry coke situation in the United States in 1975. It discusses intrinsic production problems and identifies opportunities for modifying operating practices so that the quality and yield of foundry coke can be enhanced without unnecessary investment in new equipment. Major topics include operating data and attendant practices and problems, the relationship of carbonization phenomena to coke quality and yield, environ- mental impacts of foundry coke plant operations, suggested research and development opportunities, and data on components of oven charges and on foundry coke production and shipments.

Jan 1, 1977

By L. K. Weaver

The Bureau of Mines has started an engineering study of oil recovery by miscible-phase displacement. As a preliminary part of the investigation a literature and patent study was made to prevent duplication of work already done, to become acquainted with those actively engaged in research of this type, and to learn where the recovery method has been attempted. This bibliography gives results of this study. The bibliography includes 254 references to U.S. and foreign patents and published literature relating to miscible-phase displacement processes of oil recovery. It is divided into the following sections: (1) U.S. patents, (2) foreign patents, (3) literature references, (4) author index, and (5) publication and source reference. The patents and literature references are listed alphabetically by author by intervals of years. References to February 1963 are included.

Jan 1, 1963

By M. F. Bucek

This report summarizes the activities performed and the results achieved during a two-phased investigation of the technical and economic feasibility of disposing of coal mine refuse underground in active mines, Three coal regions in the United States that are most severely affected by coal refuse disposal problems are identified: southwestern Pennsylvania, southern West Virginia, southwestern West Virginia and eastern Kentucky. For each region, a conceptual mine model is presented that describes the geologic conditions, mining methods, and environmental circumstances typical of that region. The model mine that was prepared for the Kanawha Region in Southwestern West Virginia and eastern Kentucky was selected as the basis for developing alternative conceptual designs of underground disposal systems in the second phase of this investigation. Procedures used in selecting the regions and in modeling typical mines are described in Part I of the report. Part II of the report describes existing methods for stowing refuse underground, presents three alternative conceptual designs of stowing system that would be appropriate for the model mine postulated in the first phase of the study, discusses technical characteristics and environmental effects relative to the various systems, and evaluates the technical and economic feasibility of the three alternative disposal system designs. Comparisons costs among systems and with costs or surface disposal are presented.

Jan 1, 1980

By J. G. Donaldson

Optimum conditions are given for chloridizing pyrite, marcasite, chalcopyrite, arsenopyrite, stibnite, and covellite with chlorine gas. The formation of metal chlorides is affected by the time and temperature of chloridizing, and by particle size of the sample. Chloridizing data also are given for chemically precipitated antimony (III) sulfide and copper (II) sulfide.

Jan 1, 1962

By J. A. Bartol

A survey was made of accident data and operating practices related to overloading and uneven load distribution on haulage trucks in noncoal open pit mines. Safety and economic aspects were analyzed. A bibliography of the literature was prepared. Review was made of available or projected systems for weighing or load indicating that might be applied to haulage trucks. A model specification was prepared for an overload detection system. Several promising systems for overload detection were identified. One was installed and tested briefly in a 170-ton rear dump truck in a copper surface mine.

Jan 1, 1982

By J. W. Walkiewicz

The Bureau of Mines investigated alloys containing lanthanum (La), praseodymium (Pr), neodymium (Nd), cobalt (Co), copper (Cu), iron (Fe), and magnesium (4g) as possible components of a permanent magnet mate¬rial utilizing a cerium-free synthetic mischmetal (M) as a substitute for scarce samarium (Sm) metal. Magnets containing M-Co-Cu-Mg and M-Co-Cu-Fe-Mg were fabricated by powder metallurgy techniques and evaluated. A synthetic mischmetal (M20) containing 20 pct La, 60 Pr, and 20 Nd yielded the best overall magnetic properties. The M20-Co-Cu-Mg alloys had energy products as high as 13.2 MGOe, remanences as high as 7.89 kG, normal coercivities as high as 6.26 kOe, and intrinsic coercivities as high as 13.4 kOe. The best value of intrinsic coercivity, 22.9 kOe, was obtained with an M-Co-Cu-Mg magnet in which the synthetic misch¬metal contained 30 pct La, 50 Pr, and 20 Nd. These values compare favorably with those of the Sm-Co magnets fabricated and measured at the Bureau's Reno Research Center, which had energy product of 15.1 MGOe, remanence of 7.8 kG, normal coercivity of 7.5 kOe, and intrinsic coercivity of 27.4 kOe. Iron substitution for part of the cobalt resulted in a decrease of magnetic properties, although several percent iron can be added before a drastic loss of magnetic properties occurs.

Jan 1, 1983

By J. R. Ross

A reconnaissance for sources of scandium and a metallurgical investigation of recovery methods for byproduct scandium from uranium mill solutions were conducted by the Bureau of Mines. The work on scandium was undertaken to obtain information on domestic resources and to explore and develop recovery procedures in consonance with the Bureau's long-range program for conservation and wise utilization of mineral resources. The element scandium is widely distributed in the earth's crust in trace amounts, but it seldom occurs as an important constituent in any mineral. An exception is thortveitite, (Sc,Y)2 Si207) a rare mineral that contains various amounts of scandium and yttrium and may contain up to 42 percent scandium oxide (SC203). Knowledge of the chemistry of scandium has expanded rapidly in recent years (1, 4, 9)4 but only fragmentary information is available about the metal because it is still largely a laboratory curiosity without established uses (2, 3). A recent study shows some of the physical proper-ties of the metal are (1) density of 3.05 grams per cubic centimeter) (2) melting point of 1,540° C, (3) hexagonal close-packed structure) (4) hardness of about 50 Brinell (500-kilogram load), and (5) an alloy behavior similar to yttrium and rare-earth metals (2). The price of $2,850 a pound for scandium oxide of 99.9 percent purity and $2,700 a pound for oxide of 99 percent purity reflects the scarcity and complex chemistry of the element.

Jan 1, 1962

By Sam G. Demou

Drag bit cutting tests were conducted chiefly to determine bit forces encountered in rock types representing a range of compressive strength and hardness and thus enable the design engineer to estimate a continuous miner's performance in a range of rock types. Testing was carried out on the Bureau of Mines uniquely designed, instrumented rock cutting device (RCD). This device can make 3-ft-long cuts at various depths and speeds to approximate full-scale drag bit cutting by continuous miners. Point attack and cutter bits were tested on four rock types ranging in compressive strength from 7,200 psi (trona) to 29,600 psi (Valders white rock). Cutting tests were made at depths up to 1 in and speeds up to 70 in/sec. Data included normal and cutting forces, groove depth, groove width, and weight of rock broken. The effect of varying the cutting speed was determined, and specific energies were calculated for the various conditions. The bit wear was also observed. For the rocks tested, compressive strength and hardness are good indicators of forces, specific energy, and wear encountered. Results, especially bit wear observations, show the possibility of extending continuous miners, already being used in trona, to Indiana limestone (10,000 psi). Rapid bit deterioration precludes use in Tennessee marble (16,800 psi) and Valders white rock (29,600 psi).

Jan 1, 1983

By J. W. Adams

Two different techniques were wed to make measurements of the absolute value of electromagnetic noise in an operating hardrock mine, Grace Mine, located near Morgantown, Pennsylvania. Diesel-powered haulage equipment is used in this mine, and the electromagnetic noise environment it creates was measured to see how it differs from the environment created by electric-powered haulage equipment. One technique measures noise over the entire electromagnetic spectrum of interest for brief time periods. Data are recorded using broadband analog magnetic tape and are later transformed to give spectral plots. The other technique records noise amplitudes at several discrete frequencies for a sufficient amount of time to provide amplitude probability distributions. The specific measured results are given in a number of spectral plots and in amplitude probability distribution plots.

Jan 1, 1974

By Ben Aleck

The objective of this program was to adapt Space Shuttle technology on high-performance spherical pressure vessels to cylindrical pressure vessels. Specifically, a cylindrical aluminum liner overwrapped with fiberglass filaments and prestressed by yielding the liner under a sizing pressure was to be replaced by a higher strength-to-weight ratio steel liner overwrapped with a higher strength-to-weight ratio filament. The steel was cryoworked stainless steel and the new fiber was Kevlar 49. In addition, the heavyweight ends of the aluminum liner were to be replaced by thin-walled domes which required multiple helix angle wraps for their support, in place of the single kite-string wrap from pole to pole of the aluminum overwrapped design. The use of cold swaging of tube-ends to form bosses, demonstrated on subscale development efforts, had not been achieved full-scale when the contract was initiated. Difficulties arose with the full-scale demonstration which were not solvable at the time with the designs and equipment available. hence, an unanticipated development was the finally selected method of making the 4-in.-diameter stainless steel liner with a single boss and no welds in an 0.020-in.-thick wall, from an 0.050-in.-thick, 13-in.-diameter disk. The demonstration vessel failed by leakage during the prestressing step because embedded oxides had formed flaws in the boss region. Such flaws have been avoided by proper temperature control during hot spinning. Hence, a new design was developed which weighs half as much as its recently developed predecessor. Funds ran out before adequate testable hardware was produced.

Jan 1, 1983

By Rudy J. Matetic

Over-exposure to noise remains a widespread and serious health hazard in the U.S. mining industries despite 25 years of regulation. Every day, 80% of the nation’s miners go to work in an environment where the time weighted average (TWA) noise level exceeds 85 dBA and more than 25% of the miners are exposed to a TWA noise level that exceeds 90 dBA, the permissible exposure limit (PEL). Additionally, MSHA coal noise sample data collected from 2000 to 2002 show that 65% of the equipment whose operators exceeded 100% noise dosage comprise only seven different types of machines; auger miners, bulldozers, continuous miners, front end loaders, roof bolters, shuttle cars (electric), and trucks. In addition, the MSHA data indicate that the roof bolter is third among all the equipment and second among equipment in underground coal whose operators exceed 100% dosage. A research program was implemented to: 1) determine, characterize and to measure sound power levels radiated by a roof bolting machine during differing drilling configurations (thrust, rotational speed, penetration rate, etc.) and utilizing differing types of drilling methods in high compressive strength rock media (>20,000 psi). The research approach characterized the sound power level results from laboratory testing and provided the mining industry with empirical data relative to utilizing differing noise control technologies (drilling configurations and types of drilling methods) in reducing sound power level emissions on a roof bolting machine; 2) distinguish and correlate the empirical data into one, statistically valid, equation, in which, provided the mining industry with a tool to predict overall sound power levels of a roof bolting machine given any type of drilling configuration and drilling method utilized in industry; 3) provided the mining industry with several approaches to predict or determine sound pressure levels in an underground coal mine utilizing laboratory test results from a roof bolting machine and 4) described a method for determining an operators’ noise dosage of a roof bolting machine utilizing predicted or determined sound pressure levels.

Jan 1, 2006

By Gary A. Kingston

Rolled steel, steel forgings, and steel castings in the Pacific Northwest (Washington and Oregon) are produced principally in the Seattle, Wash., and Portland, Oreg., metropolitan areas. Steel-mill products are rolled from carbon and some alloy &eels by three companies into shapes such as reinforcing bar, rods, rounds, squares, flats, and hot-rolled strips; structural shapes, - such as angles, channels, and I-beams, also are rolled. Carbon and alloy steel ingots are poured and forged at a Seattle plant into ship shafting, drive shafts, billets, slabs, bars, rings, hooks, and other items. Static, shell, investment, and centrifugal castings are produced at 19 steel foundries in a wide range of steel specifications. All Pacific Northwest steel output is based on remelting steel scrap. Local iron ore might be used in the future to supplement steel scrap as a metal source. Ore reduction would probably be achieved by methods other than the blast furnace. Current melt-shop practice and problems are basically the same in Pacific Northwest steel plants as in cold-melt shops in other parts of the country. Quality steel production is receiving more emphasis in this region with the installation of modern analytical equipment and vacuum pouring and melting facilities.

Jan 1, 1962