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By Norman G. Foster

The mass spectra of 14 previously unreported alkylthiophenes are pre-sented. Low ionization voltage data of selected compounds from these 14 and 23 previously reported alkylthiophenes are presented and discussed for their value in supporting fragmentation mechanisms analytical correlations. A comparison with and corroboration of earlier correlations is made. Additional correlations concerning detection of side chain branching and the detection of ethyl-alkyl and propyl-alkylthiophenes are made. A discussion of the possible fragmentation routes and mechanism of fragmentation is given. Speculative structures are inferred s out some of the ions and hence this work provides a basis for suggesting fation mechanisms for the alkylthiophenes according to modern theories ass spectrometry. Verification of these mechanisms must await the availability of isotopically labeled molecules which are labeled in specific lotions that permit the definition of the paths of frag-mentation. Some suggestions for further work to generalize on the correlations and studies made to this point are presented.

Jan 1, 1965

By W. H. Ode, W. A. Selvig

"INTR0DUCTIONAccording to the Standard Specifications for Classification of Coals by Rank of the American Society for Testing Materials (A.S.T.M. Designation: D388-38).1/ high-volatile bituminous coals, subbituminous coals, and lignites are classified on the basis of calorific values on the ""moist"", mineral-matter-free basis. The moist basis refers to coal containing its natural bed moisture but not including visible water on the surface of the coal. It is assumed that the natural bed moisture of coal in the ground represents the moisture-holding capacity of the coal when in equilibrium with air at approximately 100 percent relative humidity. This moisture is sometimes referred to as inherent moisture as opposed to extraneous moisture, which wets the surface of the coal.To simplify procedures for determining the moisture-holding capacity of coal it is assumed, for all practical purposes that the moisture content of coal when brought to a standard condition of moisture equilibrium in an atmosphere of 97 percent relative humidity and 300 C. represents the bed moisture of the coal. The A.3.T.M. specifications provide that this condition of moisture equilibrium shall be obtained by bringing the coal to a standard condition of moisture equilibrium at 300 C. in a vacuum desiccator containing a saturated solution of potassium sulfate (97 percent relative humidity) according to the procedure proposed by Stanfield and Gilbart. 4/ No mention is made in the specifications for bringing partly air-dried samples to their natural bed moisture condition probably because of the hysteresis effect that has been noted by various investigators. 5/ In this connection it has been found from sorption studies that the adsorption and desorption curves for lignite are not entirely reversible. The hysteresis effect has been explained by some investigators as resulting from shrinkage of the lignite during drying, which causes a collapse of some of the capillaries, so the dried lignite cannot take up as much water as it held originally."

Apr 1, 1953

By Jos. R. Guiteras

The present discussion first presents data to justify the fireproofing of mine shafts. This is followed by a brief outline of fireproofing methods with examples from practice. A summary of authoritative recommendations on fire prevention concludes the discussion. Acknowledgment is made to D. J. Parker, district engineer, Mine Safety Station, Salt Lake City, Utah, for his valuable criticism of the paper. Fireproofing a mine shaft implies lining the shaft with fireproof material or rendering fireproof the material already composing the shaft lining. A brief study of the part mine shafts and shaft stations have played in disastrous end tragic underground fires furnishes convincing evidence that every possible effort to make all mine shafts fireproof is amply justified. The fire hazard in coal minus obviously is much greater than in metal mines. In this discussion the point of views is mainly that of the metal miner; it is tine opinion of the writer that all fires in metal mines are preventable.

Jan 1, 1939

By A. B. Hooker

Since man first mined underground, there has been need for adequate illumination; this need has never been fully supplied. At first, suitable lamps were not available. Gradually they have been developed, but along with that development the need for better and better lamps has continued owing to the following conditions and factors: 1. Increasing hazards from gas and dust ignitions. 2. The speeding of operations with mechanized mining, which necessitates greater visibility. 3. A demand that cleaner coal be loaded, which requires higher levels of illumination. 4. The cost of compensation for injuries that has created a demand for better illumination and safer lamps. Use of better lamps has been retarded by: 1. Prejudice and resistance to change on the part of the workers in some districts. 2. The cost and upkeep of the lamps. 3. The present types of lamps, while a great improvement over the old lamps, do not entirely fulfill the requirements for a safe and efficient light for underground workers.

Jan 1, 1938

By Frank B. Fulkerson

Barge traffic on the Nation's inland waterways over the past 15 years has been increasing at a rate much faster than intercity freight traffic by all modes, largely due to the growing consumption of mineral commodities, development of more powerful towboats and large and more specialized barges, improvements to loading and unloading facilities, and competition among bargelines for contract shipment of bulk commodities. The Bureau of Mines, in a study to determine barge traffic projections for inland waterways in the South-Central States to the year 1980, gathered data on origin-destination patterns by commodity, quantity moved, equipment used, and rates charged; the trend of each of these factors over time; and the extent of competition between water trans-port and other means of transportation. The Mississippi River and the Gulf Intracoastal Waterway, which together carryover half the Nation's barge traffic, are major carriers of coal, crude petroleum, steel, marine shells, sulfur, salt, cement, and alumina. Greater quantities of these products will be transported by barge; however, oil pipe-lines and unit trains for coal are expected to limit increased barge traffic of these two commodities. Increasing quantities of fertilizer materials will be transported upstream. Although congestion at certain locks is a current problem, the Mississippi River below St. Louis and other open-river stretches have the capacity to handle the increasing number of barges for the foreseeable future.

Jan 1, 1969

By E. E. Maust

The literature on the activation of sphalerite for flotation by short¬chain xanthates leaves unanswered the question of whether a compact surface film of activator sulfide is necessary or merely sufficient for high flotation recoveries. Studies by Guarnaschelli and Plaksin indicate that xanthate adsorption and flotation of sphalerite are increased with increasing hole/ electron ratio. These results, and the known acceptorlike behavior of many heavy-metal impurities in zinc sulfide, suggest that activation may result from a traditional semiconductor doping effect at the surface. Using the theory of chemisorption states on ionic crystals as developed by Levine and Mark, the Bureau of Mines has carried out A calculation to estimate the surface-state energies of various metals when they are substituted at zinc sites on (110) sphalerite surfaces. Based on a simple Madelung-Born treatment of ionic solids, the calculation indicates that many of the metals known to activate sphalerite for subsequent flotation have lower surface-state energies than nonactivators. The results of these calculations are discussed from the standpoint of consistency with the proposed activation mechanism and observed flotation results. The satisfactory agreement obtained is taken to be support for the proposed mechanism, and further elaboration of a surface-doping model is attempted.

Jan 1, 1976

By L. R. Burdick

Anthracite barley is considerably cheaper than rice. Its use, therefore, is attractive from a cost standpoint, - but its smaller size (through 3/16 inch over 3/32 inch round-mesh screen) makes it more difficult to use on some equipment when fairly high combustion rates are necessary to carry plant loads. Tests wore made in one plant to determine the performance of rice and various types of barley on a chain-grate stoker in a two-arch refractory furnace. In general, the efficiency and capacity increased with increased fuel size and volatile content. This performance is presented in tabular and curve form, together with a short review of the ignition and burning process on chain-grate stokers and a discussion of the operating procedures and limitations during the tests. In this particular installation, higher combustion rates and efficiencies could have been obtained with barley if the grate links had been designed for more uniform air flow through the grate surface. Careful maintenance and operation are particularly necessary for satisfactory results with barley on equipment not especially designed for its use.

Jan 1, 1950

By R. G. Sandberg

Many gold-bearing ores throughout the Western United States contain small quantities of mercury. The presence of mercury not only decreases the gold-loading capacity of the activated carbon, but complicates the fire refining of cathodes and creates a potential health hazard. The Bureau of Mines investigated methods to limit mercury extraction during gold ore leaching and to remove mercury from cyanide leach solu-tions. Mercury dissolution was reduced from 40 to 10 pct by decreasing NaCN concentration from 20 lb to 0.34 lb per ton of solution at a pH of <11. When 0.1 lb CaS per ton of ore was added to a leach slurry, mer-cury extraction was reduced from 27 to 0.4 pct. Less than 0.5 pct of the mercury was solubilized when <0.1 lb CaS per ton of are, along with lime and NaCN, was added to a simulated grinding circuit.

Jan 1, 1984

By O. C. Blade

This survey report, the first for this type of fuel, is issued to provide information on the characteristics of the burner-fuel oils now manufactured for sale. Reports of surveys of diesel fuel, conducted under a cooperative agreement between the American Petroleum Institute and the Bureau of Mines, United States Deportment of the Interior, have been published annually since 1950.2/ This survey of burner-fuel oils is similar to the diesel-fuel surveys In pattern and has been conducted under an extension of the same agreement at the request of the Oil-Heat Institute of America and the petroleum industry. It is not intended to conflict with the diesel-fuel survey but rather to supplement it. Burner-fuel oils, also specifically referred to as heating oil, range oil, furnace oil, "Bunker C," and fuel oil, are sold in increasing volumes for use in this country and for export. Sales of all grades of fuel oil in the United States have increased from 340 million barrels in 1926Y to over a billion barrels per year. 4/ Distillate fuel oil sales, in proportion to total fuel-oil volume sold, increased from 42 percent in 1950 to 50 percent in 1954. Sales of distillate and the heavier residual oils during recent years are shown: [ ] It must be realized that the data given are not accurate indications of the use of these materials as burner fuels. Some burner fuel, used as range oil, is kerosine, which is not included above. A large volume of fuel oil--approximately 30 percent of the distillate type and some residual fuel oil--is sold as diesel fuel. Smaller

Jan 1, 1955

By John Nagy

Dust explosion data obtained in laboratory studies by the Bureau of Mines are presented for activated carbon, asphalt, charcoal, carbon black, coal, coke, gilsonite, graphite, lignite, miscellaneous carbons, pitch, tunnel dust, and mixtures of these materials with other ingredients. The explosion hazard is shown to increase as the volatile content of the dusts increases.

Jan 1, 1965

By Richard F. Link

The principal procedures for the statistical analysis of gold assay and other trace-element data depend on applying either the normal frequency distribution or the lognormal frequency distribution. The consequences of applying both methods are examined through reference to example data from United States and South African gold mines. It is concluded that for estimation of average grades, except for certain data with a very high coefficient of variation (ratio of standard deviation to mean), use of the lognormal distribution is ordinarily undesirable because bias may be introduced and little efficiency can be gained. However, if biased average grades can be tolerated, as in the examination of data from surveys in exploration geochemistry, use of the log-normal distribution may be desirable. Various statistical analyses are detailed, and the tables presented to implement the analyses are more complete than those previously published.

Jan 1, 1971

By W. P. Yant, G. W. Jones

During the testing of porcelain insulators with a " 60 - cycle flash - over apparatus " , gases are liberated having an odor greatly resembling that of ozone . Since the two main constituents of normal air are nitrogen and oxygen , and high voltages (approximately 90,000 volts ) are used during the tests , the conditions are favorable for the production of ozone or oxides of nitrogen , and perhaps both simultaneously . The presence of these gases is only noticeable during the testing period . They soon disappear after the test is over . No fatalities have ever resulted from these gases at the plant visited nor are there any records of any of the men who worked on the tests being confined to their homes from this cause . New employees sometimes complain of a depressed feeling and shortness of breath , which is most noticeable after leaving work and getting into fresh air , but they som become accustomed to it and no ill effects are noticed . In view of previous work*** which the Bureau of Mines has done on oxides of nitrogen in connection with mine gases and problems in gas analysis , tests were made at the plant of the Westinghouse High Voltage Insulator Company at Derry , Pa . to determine the kind and amount of gases liberated .

Jun 1, 1923

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Coordinating Fuel Research ( C.F.R. ) Committee of the Coordinating Research Council ( C.R.C. ) and the Bureau of lines of the United States Department of the Interior . The first of these reports presented data on motor gasolines sold during the winter of 1935-35.4/ Further reports have been issued describing motor gasolines sold during the succeeding summers and winters to and including the summer of 1941.5/ No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942 . However , starting with the winter of 1942-43 , the semi - annual reports have been resumed

Jan 1, 1945

By Frank A. Peters

With the current renewed interest in advancing the technology for producing alumina from domestic raw materials, revisions of previous cost estimates to provide planning data are urgently needed. Completely new cost estimates on a 1973 basis are included for four alumina-from-clay processes and one alumina-from-anorthosite process. These estimates are based on new or previously calculated material balances, recalculated heat requirements, and new equipment designs. The use of larger and more modern equipment has permitted a significant reduction in labor requirements as well as equipment costs. Chemical prices, labor rates, and utility rates typical of late 1973 are used in these cost estimates. In addition to the revised cost estimates, all 21 previously published alumina evaluations compiled by the Bureau of Mines were updated to show the effect of inflation using an inflation index and late 1973 chemical prices, labor rates, and utility rates.

Jan 1, 1974

By H. E. Powell

This Bureau of Mines study describes two processes for recovering zinc, copper, silver, and iron from the magnetic fraction of a waste generated by the primary smelting of zinc in horizontal retort distillation furnaces. The laboratory-scale procedures include reduction melting to produce a high-copper iron and matte smelting to produce a copper-silver-iron matte and metallic iron. Zinc is fumed in each process and recovered as the oxide. Direct reduction melting yields a metallic iron high in copper and a small rich matte from the sulfur contained in the waste. The products of the second process are a matte containing essentially all of the silver, about 80 pct of the copper and 37 pet of the iron, and an iron-copper alloy containing all of the remaining copper. Extraction with metallic lead or sodium sulfate recovers essentially all of the copper from the molten high-copper iron and yields an acceptable foundry iron.

Jan 1, 1973

By W. L. Crentz

Before Korea was partitioned along the 38th parallel following World War II, the coal fields of South Korea, with the possible exception of the Samchok area, were not considered important to the industrial needs or Japan or Korea. Much of the demand for electric power in South Korea was met by hydroelectric installations north of the 38th parallel. Following cessation of hostilities between Japan and the&apos; Allied nations in 1945, hydroelectric power continued to flow into South Korea from the north until 1949, when the North Koreans severed the power lines into South Korea, thereby forcing that section of the country to depend almost entirely upon coal to generate electric power.

Jan 1, 1953

By Lloyd Williams

1. The investigation shows that the bed identified as Wilder in this report is the only bed in Overton County that has produced commercial coal and is the only bed in which coal reserves were estimated for this report. Three other coal horizons were recognized but lacked enough data for reserve estimates. 2. Known measured and indicated reserves of coal, based on a minimum bed thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, are estimated to be 19 million short tons, as of January 1, 1953. Of this total, 10 million tons represents coal 28 inches and more thick. Areas of the Wilder bed were omitted from the estimate because available data relative to the bed characteristics were too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1955

By Harry R. Nicholls

Six different chemical explosives were detonated in a test series to com-pare their relative performance in granite. From 5 to 255 feet from the detonation point, strain, acceleration, and particle velocity were recorded and analyzed for amplitude and pulse shape. Strain energy was calculated from strain data, and displacement data were obtained from particle velocity data by integration. The results show that explosives which have a characteristic impedance more closely matching that of the rock generate larger peak amplitudes than explosives with a lower characteristic impedance. The results also show that as the ratio of characteristic impedance of exp1osive-to-rock approaches unity, more rock is crushed and a larger percentage of the avail-able explosive energy is transferred to the rock as seismic energy. The effect of characteristic impedance is shown to be greater than the effect predicted from acoustic theory and is believed to be indicative of shock wave effects at the explosive-rock boundary.

Jan 1, 1965

By Thomas J. Peters

The Lime Creek study area lies 100 air km east of Boise, and 70 air km northeast of Mountain Home, Idaho. The eastern boundary of the 28,000-hectare, east-west-elongate study area lies 0.2 km west of the 3,077-m-high Smoky Dome. The area is mainly underlain by Cretaceous granitoid rocks of the Idaho batholith. No mineral resources were identified, but two mines and one prospect were found in the study area. At the President and the Last Chance mines, in the southwest corner of the study area, gold mineralization occurs along steeply dipping east-northeast-trending faults and associated quartz veins, and within adjacent Cretaceous granitic rock. The mineralized material is not rich enough to mine underground, and near surface, open-pit-mineable deposit areas could not be identified. The third prospect, the Ventura, is within altered pink granite of probable Tertiary age, but metal concentrations are very low. Geothermal activity was not observed within the study area, but hot springs do occur in the Vicinity. Bedrock observed is only suitable for the most basic high bulk and low end value applications, such as crushed aggregate. Numerous sources for crushed stone occur closer to markets. Alluvial concentrate (placer) samples did not contain free gold, and no substantial alluvial bars were seen; deposits were too small to contain resources.

Jan 1, 1993

By William L. Crentz

In the past, Westmoreland County together with Fayette County produced about one-third of the bituminous coal mined in Pennsylvania. The Pittsburgh bed in Westmoreland County has furnished enormous quantities of coal to the by-product and beehive ovens, gas-manufacturing plants, and general industrial manufacturers over a wide area until about 20 years ago. Little attention was paid to the thinner beds because of the superior quality of the Pittsburgh. The approaching exhaustion of Pittsburgh coal will require accelerated-exploitation of these coals if Westmoreland County is to continue as an important source of bituminous coal, Much of the Pittsburgh coal in Westmoreland County is low-sulfur and requires no mechanical cleaning for the preparation of a metallurgical fuel. Even those areas where the sulfur percentage increased to a maximum of about 2 percent, a relatively easy washing operation usually produced a cleaned coal, which found ready acceptance by the coke industry. Davis reported the remaining recoverable reserves of the .Pittsburgh bed in Westmoreland County to be 255,439,000 tons as of January 1, 1937. Since that date, more than 100,000,000 tons of Pittsburgh coal has been extracted so that the time is not too distant when this important coal bed will be depleted. A study of the Pittsburgh bed in Westmoreland -County has not been made a part of this report as the remaining reserves of the coal can be used in coke making with a, minimum of preparation. The production from the Upper &apos;Freeport bed will increase as the supply of coal from the Pittsburgh bed diminishes, and as of the present time it supplies a substantial proportion of the county&apos;s coal output.

Jan 1, 1951