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By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, A. M. Elmahdy, Keiko Sasaki

"Seawater has been reported to depress molybdenite in a copper-molybdenum (Cu-Mo) flotation process at high pH due to the precipitation of Mg(OH)2. Meanwhile, to improve mineral recoveries, collectors are usually added into the flotation cells, thus adding the complexity to the mechanism of bubble-particle interactions involved in Cu-Mo flotation. Therefore, understanding the interaction mechanism in seawater flotation and in the presence of collectors is important to explain the minerals depression. The present work investigated the effect of kerosene on the bubble collision and attachment to pure chalcopyrite and molybdenite surfaces in MgCl2 solution as one of the seawater major components at pH 6 and 11. Mineral surfaces were characterized using atomic force microscopy (AFM). In addition, minerals floatability in the same system were tested in a column flotation. The study of bubble-particle interactions shows that following several collisions, bubble could displace the intervening liquid layer on the mineral surfaces, forming a three-phase contact (TPC). A TPC formed more rapidly in the presence of emulsified kerosene in a 0.01 M MgCl2 solution at pH 6 for both minerals. The reason is kerosene increased the surfaces hydrophobicity and destabilized the intervening liquid layer on the surfaces. Moreover, the average time required to form a TPC was shorter on molybdenite surface. This can be attributed to the effect of adsorbed kerosene on molybdenite surface and molybdenite surface roughness.INTRODUCTIONIn froth flotation, bubbles are used to separate hydrophobic mineral particles from hydrophilic particles. In this process, bubble-particle interactions (i.e., collisions, attachment, and detachment) are crucial with regard to mineral recoveries. The effectiveness of froth flotation depends on the formation of stable aggregates between the hydrophobic particles and the bubbles, allowing the bubble to carry the particles to the froth layer. To form such aggregates, the bubbles and particles must collide, and the intervening liquid layer must be drained below the liquid layer critical thickness, forming a stable threephase contact (TPC) (Ralston & Dukhin, 1999). Particles detachment may take place if the particles still have sufficient kinetic energy and the TPC is not formed. Previous studies of bubble-particle interaction in electrolyte solutions have been conducted using atomic force microscopy (AFM) (Assemi, Nguyen, & Miller, 2008), and by approaching the bubble using mica plate (Pushkarova & Horn, 2008), however, these studies did not focus on the bubble-particle collisions. Bubble collisions and attachment to hydrophobic (Teflon) and hydrophilic (glass) surfaces in a a-terpineol solution have been investigated by Krasowka et al. (2003)."

Jan 1, 2016

By M. Epiney, A. Ghahreman, R. Kim1and

"Pre-oxidation and cyanide leaching behavior of gold in the presence of sulfide minerals were reviewed, focused on the effects of oxygen injection in the gold leaching process. Generally, pre-oxidation and gold leaching kinetics from iron sulfide refractory minerals, such as pyrite, pyrrhotite, marcasite, pentlandite and arsenopyrite, can be enhanced with higher dissolved oxygen (DO) concentration. However, most of copper sulfide minerals dissolved well both in water and cyanide solutions, and copper from the minerals consumed DO and cyanide to oxidize and leach. Only in the presence of chalcopyrite, gold leaching was effectively occurred with increasing DO. However, chalcocite and covellite severely retarded gold leaching. Stibnite, an antimony mineral, formed a passive film on the gold surface under any DO conditions, and it slowed gold leaching. This impeding effect can be alleviated by leaching at low pH or adding lead salt. Using oxygen and lead together can make synergistic effect in oxidation of sulfide minerals and can enhance gold extraction. Depending on the mineralogical characteristics of the ore, the optimum DO and lead concentrations can be optimized. However, lead can cause environmental problems, and so its dosage should be minimized or eliminated by substituting it with oxygen injection.INTRODUCTIONGold ores containing sulfide minerals are becoming more significant as high grade gold oxide deposits are continuously becoming difficult to find. In light of this situation, to produce more gold, recovery methods from refractory gold ore containing various sulfide minerals should be investigated. Generally, sulfide minerals have impeding effects on gold leaching: formation of a passive film on the gold surface, high consumption of chemicalssuch as cyanide and oxygenduring leaching, reduction of gold cyanide by sulfide ions, etc. (Senanayake, 2008). Therefore, sulfides must be properly treated for better gold recovery. Pre-oxidation of sulfide minerals by injecting pure oxygen can decrease the impeding effects in gold leaching. Prior to cyanidation, sulfide minerals can be oxidized to metal hydroxide and sulfate form, which consume negligible cyanide in the following cyanidation circuit (Bodnaras et al., 1993). Moreover, gold cyanidation can be enhanced by increasing concentration of the dissolved oxygen (DO). In general, the optimum concentration ratio of [CN-]/[O2] is calculated as 6, but it goes higher in the real system (Marsden &House, 2006), which means that the reaction is typically controlled by DO concentration."

Jan 1, 2017

By T. R. Skerry, H. P. Hudson, T. E. Warren

"ALTHOUGH coal is generally the cheapest fuel on the basis of heating value it has been at a disadvantage in competition with other fuels because means have not been available for efficient •Conversion of its thermal energy to mechanical work. Taking the •railway application •as an example, the cost of Diesel oil is about three times that of its thermal equivalent in coal, but the overall efficiency of a Diesel locomotive is about five times that of a coal-fired steam locomotive. Accordingly, the Canadian railways are replacing all coal-fired steam Locomotives, as they are retired from service, with Diesel units. This conversion in itself represents a major loss to the coal industry because the value of railway fuel is approximately 130 million dollars per year, and there are other applications in the medium power range where oil is displacing coal. There is, therefore, a strong incentive to attempt development of an efficient coal-burning engine.Coal has never been a promising fuel for reciprocating internal combustion engines because of the time required for its combustion in pulverized form . This is not less than one-tenth of a second so that the speed of such an engine would have to be very slow. There are also serious difficulties of a mechanical nature arising from the necessity for intermittent combustion and the use of close-fitting pistons."

Jan 1, 1952

By L. Fernandes

A two level factorial study was undertaken to investigate the relative impacts of factors affecting the kinetics of polytetrafluoroethylene, PTFE, assisted pressure oxidation of chalcopyrite. A copper flotation concentrate, principally composed of chalcopyrite, was leached in 850 mL of leach solution under conditions similar to those of the CESL process. The factors manipulated were: the amount of 1/8" PTFE beads added (100 g or 650 g), oxygen pressure (690 kPa or 1030 kPa), and concentrate addition (10 grams or 65 grams). Copper extraction data, which indicated complete leaching under certain conditions, were fit using a shrinking core model from which rate constants were estimated and further used to generate a statistical model containing only the factors of significance and their interactions. Results indicated a strong positive effect of PTFE addition and a strong negative effect of increasing pulp density. A weak negative interaction between increasing PTFE addition and pulp density was attributed to PTFE/concentrate agglomeration.

Jan 1, 2014

By Michael S. Moats, Prashant Bagri

"In recent years with increasing concerns about energy consumption in hydrometallurgical processing, there is an ongoing attempt to use Catalytic Titanium Anodes (CTAs) for copper electrowinning. For this work, anodes with IrO2 - Ta2O5 coatings were prepared in the laboratory with the same total coating loading but varying the number of layers by changing the speed of withdrawal in dip coating. A second set of CTAs were fabricated on niobium, Ti Grade 1, Ti Grade 7 and Ti Grade 36 metal substrates. All the anodes prepared in the laboratory were characterized using standard electrochemical techniques and subjected to accelerated life testing. It was found that the coating would not adhere to the niobium substrate, the grade of titanium had a minimal to no effect on the life of the anode, and it is observed that as the coating speed slows, there is an increase in the electrochemically active surface area of the coating which seems to directly contribute to an increase in the Tafel slope of the anodes. There was inconclusive evidence on the effect of coating speed on anode lifetime.INTRODUCTIONLarge scale hydrometallurgical extraction of copper has become widely practiced over the last 40+ years. The hydrometallurgical route entails leaching, solvent extraction and electrowinning. With the increasing desire to process refractory sulphides like enargite and chalcopyrite through the hydrometallurgical route, use of hydro-processing of copper is expected to remain high.In conventional electrowinning, copper is deposited on the cathode and an inert anode is used for oxygen evolution. Presently, the most common anode material is rolled lead-calcium-tin and the cathode is 316L stainless steel (Robinson et al., 2013). This lead alloy is fairly inexpensive and is robust, providing lifetimes typically of 4+ years. The main drawbacks of lead alloys are their relatively high oxygen evolution overpotential, the need for cobalt in the electrolyte to reduce their corrosion, the contamination of cathode product by lead, and the generation of harzardous by-products (Hiskey, 1999)."

Jan 1, 2016

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016

By G. Whittle, R. Peevers, P. Moryoussef

Enterprise optimization is a relatively new optimization approach to mine planning used to jointly consider all aspects of a mining operation affecting the mine planning process and related valuation. In this paper, it is applied at SEMAFO's Mana operations in Burkina Faso, consisting of several open pits and a proposed underground mine. The surface-minable ore is relatively shallow, and the pits are long and linear. The underground operations, as currently envisioned, will consist of a stoping operation accessed by two ramps from the surface. Power is a concern at this property due to local power being produced largely by diesel generators, and it has become one of the key optimization constraints. Other important parameters are the mining and processing rates, underground configuration and cutover elevation. Enterprise optimization was found to improve net present value for the Mana Operations property by simultaneously optimizing multiple parameters and constraints to arrive at an optimal pit and mining phase design, optimal cut-off grades over time, and optimal ore feed based on ore hardness, power constraints, and head wades. Reserves were expanded several times over the course of the study to improve the valuation of the mining operation and put SEMAFO in its present enviable position of ongoing reserve increases.

Jan 1, 2011

By E. Ghali

"Corrosion of support system components (e.g., bolts, mesh, plates) is a safety and economic concern in underground mines. This paper reports the results of a five-year study wherein corrosion coupons were installed at select locations in participating mines, recovered at regular intervals, analyzed for signs of corrosion, and tested to quantify loss in capacity. Complementary tests were conducted on recovered mesh and friction bolt specimens. The data provide insights into contributing factors for support systems corrosion, which aid in the selection of appropriate support strategies and reliable assessment of the useful life and need for rehabilitation of a support system.RÉSUMÉ La corrosion des composantes des systèmes de soutien (p. ex. boulons, grillages et plaques) est une préoccupation économique et de sécurité dans les mines souterraines. Cet article présente les résultats d’une étude de cinq ans pendant laquelle des coupons de corrosion ont été installés à des endroits spécifiques dans les mines participantes; ces coupons ont été retirés à des intervalles réguliers, analysés pour des signes de corrosion et mis à l’épreuve pour quantifier la perte de capacité. Des essais complémentaires ont été effectués sur les grillages récupérés et sur les échantillons de boulons d’ancrage. Les données aident à comprendre les facteurs qui contribuent à la corrosion des systèmes de soutien, ce qui est utile dans le choix de stratégies appropriées de soutien et pour une évaluation fiable de la durée de vie utile et du besoin de remise en état d’un système de soutien."

Jan 1, 2015

By J. L. Miller, R. W. Burns

This paper sets out the various phases of bringing a merchant bar mill into operation from feasibility consideration through financing, design and scheduling to completion.

Jan 1, 1967

By T. R. Eger

Miners can be exposed to whole-body vibration (WBV), when sitting or standing to operate mobile equipment. In order to prevent vibration-induced injury it is important to understand how miners can be exposed to vibration, the health risks associated with vibration exposure, methods to evaluate vibration exposure, and strategies to reduce vibration exposure. WBV exposure typically occurs when operating mobile equipment, such as a load-haul-dump vehicle, haulage truck, or dozer. The probability of health effects such as low back pain, neck pain, headaches, and gastrointestinal track problems occurring from daily vibration exposure can be determined based on criterion values published in ISO 2631-1 and EU Directive 2002/44/EC. A special case of WBV termed foot-transmitted vibration (FTV) occurs when a miner is exposed to vibration that travels through the feet. FTV typically occurs when standing on vibrating surfaces associated with the operation of locomotives, jumbo drills, bolters, or raise platforms; however, there is no set standard to evaluate health effects associated with FTV. Recent medical evidence confirms workers exposed to FTV can develop cold induced blanching of the toes, in addition to numbness and tingling in the feet and toes. In order to reduce the risk of adverse health effects from exposure to vibration, the hierarchy of controls (elimination; substitution; engineering; administration; and personal protective equipment) should be followed. Best practices should be used to minimize vibration exposure through equipment purchases (i.e. vehicles with lower vibration emissions and seats that attenuate vibration), reduced driving speeds, and improved road maintenance for example. The elimination of other risk factors, which increase injury risk when combined with WBV exposure, such as awkward working postures, should also be eliminated. Very little is known about FTV exposure therefore further research is required in order to develop exposure standards and identify prevention strategies.

Aug 1, 2013

As a bubble travels through the pulp region of a flotation cell, it will collect the most hydrophobic particles of an intermediate particle size range, this being the primary source of true flotation selectivity. Despite its role on bubble-particle attachment, however, particle hydrophobicity is still missing a mathematical definition that can be used for plant simulation. In this paper, particle hydrophobicity is defined in terms of the induction time necessary for attachment and then linked to the mass of collector adsorbed per particle. This allows particle hydrophobicity to be written as a function of density of collector adsorption as well as particle size and mineralogy. The model is calibrated from the experimental measurement of the flotation rate constant. Liberation data from an industrial flotation rougher is used for model validation. It is demonstrated that the model can describe a broad experimental dataset by means of a minimal number of parameters. Main industrial application is in simulating the effect of the chemical environment upon plant metallurgical performance.

Jan 1, 2006

By W. E. MacDonald

This paper relates the story of 100 years of mining in the Harbour Seam at the Princess Colliery, Sydney Mines, Nova Scotia. Several interesting anecdotes are included along with the discussion of the evolution of coal mining methods in the area. Finally, some of the recently introduced equipment at Princess Colliery is described, and prospects for the future of the industry are outlined.

Jan 1, 1968

By J. J. McDougall

Until quite recently, the coal in the Cape Breton field was won from comparatively thick seams with light cover, and from submarine areas, and the system of mining naturally followed was pillar-and-stall. This sytem permitted of cheap extraction, and enabled production from localities where other methods could not be employed to good advantage. Thus the pillar-and-stall system, applied to conditions as stated, justified its adoption. Our working seams today, however, are practically all under heavy cover, or are moving in that direction, and with this gradual increase in cover came the increased cost of roadway maintenance. At Princess colliery, the system of pillar-and-stall was followed until roof and bottom conditions became such that further operations were unprofitable, and the longwall method was then adopted as an economic necessity. This fact should be borne in mind when operating costs of both systems are being compared. The longwall method is not held as a cure for all difficulties of heavy cover, but through it these difficulties can be overcome with less expense than by pillar-and-stall. The longwall system of mining, strictly speaking, is one by which a seam of coal is totally extracted in one operation. There are, however, many modifications of longwall, and in some cases it is difficult to determine whether certain practices should be classed as longwall or pillar-and-stall, or a combination of both.

Jan 1, 1928

IDS: The Company IDS Ingegneria Dei Sistemi, founded in 1980, is a world leader as a high technology solution provider in selected niche defense and civil market sectors ? Private and Independent ? IDS?s Quality System is certified ISO 9001 Ed. 2000 ? IDS has the highest Military Clearance ? Continuously measure (24x7) mine wall movements with sub-millimetric accuracy at long distance (up to 4 Km) ? Provide reliable early warning for progressive slope movements potentially leading to mining wall failures ?Map the long term evolution of slow moving slopes to get a better knowledge of the rock mass strength

Aug 1, 2013

By Ltd. (CYMCO) Technology Center Yunnan Metallurgical Group Co., S. Jian, T. Song, J. D. Miller

"As sulfide zinc ore deposits become exhausted, nonsulfide zinc ore deposits become the other resource for zinc production. However, flotation for zinc recovery from nonsulfide deposits is much more difficult than the flotation of sphalerite from sulfide deposits and may become an option for zinc production only if a suitable processing technology is developed. In this regard, research efforts are being devoted to the flotation of nonsulfide zinc oxide minerals. Some common methods which have been used for the flotation of zinc oxide minerals include sulfidization-flotation, activation, and direct flotation with anionic and cationic collectors. The traditional flotation techniques have low efficiency and difficulty in separation and recovery of the zinc minerals from gangue minerals, for example, smithsonite (ZnCO3) from other carbonate gangue minerals and hemimorphite (Zn4Si2O7 (OH)2·H2O) from silicate gangue minerals. In this study potassium lauryl phosphate was evaluated as a collector for the flotation of nonsulfide zinc minerals. Results from contact angle and microflotation experiments at pH 6–9 show that hemimorphite (Zn4Si2O7 (OH)2·H2O) can be floated from quartz and that smithsonite (ZnCO3) can be floated from calcite. However, when dodecylamine, which is a common collector reported in literature for the flotation of nonsulfide zinc minerals, was used as collector, no significant difference between nonsulfide zinc minerals and gangue minerals was observed at any pH value. Initial evaluation suggests that potassium lauryl phosphate is effective at low concentration and may be a promising collector for zinc oxide mineral flotation.INTRODUCTIONBefore the twentieth century, zinc was mainly produced from nonsulfide ores (Large, 2001; Gilg, Boni, & Cook, 2008). With the development of differential flotation processes in the late 19th century major production switched from nonsulfide zinc sources to sulfide zinc ores (Hitzman, Reynolds, Sangster, Allen, & Carman, 2003; Gilg et al., 2008). However, as it is becoming more difficult to find new sulfide ores, recovery from nonsulfide deposits is being considered. Nonsulfide flotation for zinc recovery is much more difficult than the flotation recovery of sphalerite from sulfide deposits and may become an option for zinc production if a suitable technology is developed. Zinc and lead oxide ores are difficult to beneficiate ores due to their similar floatability with gangue, high solubility in water, and the influence of slimes (Fa, Miller, Tao, & Li, 2005). In order to improve the performance of oxidized minerals, lots of effort is being devoted to this field of study (Ejtemaei & Mahdi, 2014)."

Jan 1, 2016

By Yann Sivry, S. Subramanian, Divyasree C. Prabhakaran, Jean Riotte

The potential of a bacterial strain isolated from water samples collected from a chromite mine in Odisha, India has been assessed for the bioremediation of hexavalent chromium, a toxic environmental pollutant. The isolate was identified as Sphingopyxis sp., a Gram negative bacterium, adopting molecular biological protocols and biochemical characterization techniques. Detailed investigations on the bioremoval of Cr(VI) were carried out using Sphingopyxis sp. cells and the various parameters affecting the biosorption process were evaluated. About 55 % biosorption of Cr(VI) was obtained using Sphingopyxis sp. bacterial cells and the residual chromium in solution was found to be bio-reduced to the trivalent form, namely Cr(III). Thus, complete bioremediation of Cr(VI) could be achieved using the mine isolate, with contributions from both biosorption and bioreduction mechanisms. The Cr(VI) biosorption isotherm obtained for the isolate was found to follow a typical Langmuirian behavior and the free energy value of biosorption was determined to be ~-25 kJ/mol, indicative of involvement of chemical binding forces in the bioremediation process. The chromium biosorption kinetics by the isolate followed a pseudo second order reaction. The FTIR spectral studies revealed that carboxyl, hydroxyl, amino and phosphate groups were involved in the biosorption process. X-ray photoelectron spectroscopic studies on the bacterial cells interacted with Cr(VI) confirmed the presence of both Cr(VI) and Cr(III) on the cell surface. The electrokinetic studies revealed that the surface potential of the bacterial cells were less electronegative subsequent to interaction with Cr(VI), compared to the cells alone, which further testified to the binding of positively charged Cr(III) ions, formed by bioreduction of Cr(VI), to the bacterial cell surface. A marginal shift in the iso-electric point obtained for the bacterial cells interacted with Cr(VI), corroborated the involvement of chemical binding forces in the bioremediation process.

Jan 1, 2016

By N. L. Richards

In manufacturing for the 21st century, the first company to market often leads the pack in product development and sales. In this respect, manufacturing processes play an important role in transforming “raw materials” into a product(s) for sale to a customer. Thus it can be seen that upfront modelling of a design concept, or modelling of manufacturing processes in a plant, can play an important role in effectively ensuring the overall design and manufacturing route is carried out in an expeditious manner. In the paper various scenarios are considered with respect to modelling the microstructure and/or process, in various manufacturing processes. Also considered are the effects of service condition on the manufactured product in terms of creep and fatigue.

Jan 1, 2010

By A. H. Lang

"The name Barkc:rville district is applied loosely to the gold-bearing area around the historic town of Barkerville; the first mining camp in western Canada. The region is partly in the Cariboo mining division and partly in the Quesnel mining division. It contains two producing lode gold mines; the Cariboo Gold Quartz and the Island Mountain; and numerous other deposits. The regional structural pattern is outlined in this paper; the structural details of the producing mines are described in the papers that follow.The discovery of rich placer deposits in this district in 1860 was followed by the Cariboo gold rush. Placer mining in the area flourished until 1875 and then declined as the shallow diggings were exhausted, but important operations are still active. The total placer production amounts to about $50,000,000. An extraordinary number of quartz veins outcrop in the district, but many have only a small gold content. The miners soon recognized that the placer gold must have been derived from the erosion of these veins, and some directed their attention to the possibility of quartz mining. The erection of a 4stamp mill in 1876 was the first attempt at ore reduction in British Columbia, exclusive of arrastras. Efforts to mine the Cariboo lodes on a large scale were not successful, however, until 1933, when, due to the pertinacity of F. M. Wells and to the increased price of gold, the Cariboo Gold Quartz mine commenced production, followed by the Island Mountain mine in 1934. This success led to development work at many properties in the district, but the only ones that have reached production to date are the Columbia Tungstens, where scheelite has been mined intermittently since 1937, and the Cariboo Hudson, from which gold was produced in 1938 and 1939."

Jan 1, 1954

By S. Oppenheimer, P. Au, R. M. Kearsey, J. Tsang, E. McDevitt

A new superalloy, ATI 718Plus® Alloy (718Plus), has been developed to have a 55oC higher temperature capability over the traditionally used Alloy 718, while maintaining favourable processing characteristics and intrinsic raw material costs. The fatigue and dwell-fatigue behaviour of four microstructural variations of 718Plus are evaluated and compared to Waspaloy: 1) standard heat treated condition (HT1), 2) standard heat treated condition with thermal exposure at 732ºC (1350ºF) for 1000 hours (HT2), 3) fine grain condition with a modified d phase (HT3), and 4) fine grain overaged through modified heat treatment (HT4). The results show that the steady-state fatigue crack growth rates of each microstructural variation and both alloys are identical, with all of the 718Plus variations showing a clear advantage over Waspaloy in the fatigue crack threshold regime. Dwell-fatigue results show that Waspaloy has better resistance to crack propagation under dwell conditions; however, optimization of the precipitate phase shows vast improvement in the dwell-fatigue resistance of 718Plus.

Jan 1, 2010

By J. F. Fiset, N. Bouzoubaâ, N. Reynier, C. Laviolette, Canadian Nuclear Laboratories

Canadian Nuclear Laboratories (CNL) is developing a disposal strategy for radioactive wastes, which contain significant amounts of uranium, cesium, and mercury. There are safety and economic incentives for the extraction of these elements before permanent storage in deep underground repositories. In addition, the actinide elements are also an important component in rare earth element (REE) ores and considered as impurities. Actinides separation from REE tailings is a significant concern in order to manage radioactive nuclides. Reprocessing mine wastes may present significant financial and environmental benefits. Experiments were carried out with radioactive cemented wastes (RCW) prepared at CanmetMINING. For all of the tested RCW batches, solubilisation yields are above 97% for Cs and 98% for U and Hg. Sulphuric acid leaching with potassium iodide improved the solubilisation of Hg by oxidation and formation of the tetraiodide complex (e.g. HgI4 2-, Kf = 2.1030). Cs and Hg were removed selectively by using potassium cobalt hexacyanoferrate (KCFC) and Lewatit TP214 ion-exchange resin respectively. U recovery using the chelating resin Lewatit TP260 was the most efficient. The presence of high iodine concentration improved the U uptake by the resin. The best U elution was obtained using 1 M Na2CO3, which resulted in 99% U recovery. U was then precipitated as sodium diuranate. A counter current effluent recirculation was performed successfully on RCW. The process was also applied to submerged tailings collected from two U mines and an REE ore. This paper presents an innovative process, using sulphuric acid and potassium iodide, for U, Cs, a

Jan 1, 2016